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Search Results (4,247)

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16 pages, 1028 KB  
Article
Research on Distributed Temperature and Bending Sensing Measurement Based on DPP-BOTDA
by Zijuan Liu, Yongqian Li and Lixin Zhang
Photonics 2025, 12(11), 1056; https://doi.org/10.3390/photonics12111056 (registering DOI) - 24 Oct 2025
Abstract
Traditional single-mode Brillouin optical time-domain analysis systems are inherently limited in terms of sensing capacity, susceptibility to bending loss, and spatial resolution. Multi-core fibers present a promising approach to overcoming these limitations. In this study, a seven-core fiber was utilized, with the central [...] Read more.
Traditional single-mode Brillouin optical time-domain analysis systems are inherently limited in terms of sensing capacity, susceptibility to bending loss, and spatial resolution. Multi-core fibers present a promising approach to overcoming these limitations. In this study, a seven-core fiber was utilized, with the central core and three asymmetrically positioned off-axis cores selected for sensing. The temperature coefficients of the four selected cores were experimentally calibrated as 1.103, 0.962, 1.277, and 0.937 MHz/°C, respectively. By employing differential pulse techniques within the Brillouin distributed sensing system, temperature-compensated bending measurements were achieved with a spatial resolution of 20 cm. The fiber was wound around cylindrical mandrels with diameters of 7 cm, 10 cm, and 15 cm. Experimental results demonstrate effective decoupling of temperature and bending strain, enabling accurate curvature reconstruction. Error analysis reveals a minimum deviation of 0.04% for smaller diameters and 0.68% for larger diameters. Cross-comparison of measurements conducted at varying temperatures confirms the robustness and effectiveness of the proposed temperature compensation method. Full article
22 pages, 61965 KB  
Article
The Cercal Sensilla of the Praying Mantis Hierodula patellifera and Statilia maculata: A New Partition Based on the Cerci Ultrastructure
by Yang Wang, Xiaoqun Ding, Huan Li and Yang Liu
Insects 2025, 16(11), 1093; https://doi.org/10.3390/insects16111093 (registering DOI) - 24 Oct 2025
Abstract
Cerci function as crucial sensory organs in insects, featuring a diverse array of sensilla on their surface, analogous to those found on antennae. Using scanning electron microscopy (SEM), we characterized the ultrastructure and distribution of cercal sensilla in Hierodula patellifera (H. patellifera [...] Read more.
Cerci function as crucial sensory organs in insects, featuring a diverse array of sensilla on their surface, analogous to those found on antennae. Using scanning electron microscopy (SEM), we characterized the ultrastructure and distribution of cercal sensilla in Hierodula patellifera (H. patellifera) and Statilia maculata (S. maculata). Results show that the cerci of H. patellifera and S. maculata are highly similar, with main differences observed in the number of cercal articles and the length of cerci. The cerci of both species and sexes are composed of multiple cylindrical articles, and there is variation in the number of types of sensilla on their surface articles within sex and individuals. Females possess more cercal articles than males, and their cerci are generally longer than those of males. In both sexes of these praying mantises, four types of cercal sensilla were identified: sensilla filiformia (Sf), sensilla chaetica (Sc), sensilla campaniformia (Sca) and cuticular pore (CP), with sensilla chaetica further classified into two subtypes (ScI, ScII). Sc are widely distributed over the entire cerci, while Sf are distributed in a circular pattern on the cercal articles. While the overall distribution patterns of cercal sensilla were conserved between the sexes, significant sexual dimorphism was observed in the morphological parameters of the sensory hairs, including their quantity, length, and basal diameter. Based on distinct sensilla arrangements on the cerci, we propose a novel zoning of the cerci into four parts (I–IV), which reflects a functional gradient specialized for reproductive roles: the proximal region is enriched with robust mechanoreceptors likely involved in mating and oviposition, the central region serves as a multimodal hub for integrating courtship and mating cues, and the distal region is simplified for close-range substrate assessment. These findings highlight the adaptive evolution of cercal sensilla in relation to reproductive behaviors and provide a morphological basis for future studies on mantis phylogeny and sensory ecology. Full article
(This article belongs to the Section Insect Physiology, Reproduction and Development)
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16 pages, 1825 KB  
Article
On the Possibility of Analyzing Dynamic Light Scattering Time Series Using the Co-Occurrence Matrix and Artificial Neural Networks
by Dan Chicea
Photonics 2025, 12(11), 1050; https://doi.org/10.3390/photonics12111050 (registering DOI) - 24 Oct 2025
Abstract
A Dynamic Light Scattering time series can be analyzed using several well-established procedures. An alternative is to compute a co-occurrence matrix of the time series and to establish a correlation between the moments of the intensity level distribution and the physical properties of [...] Read more.
A Dynamic Light Scattering time series can be analyzed using several well-established procedures. An alternative is to compute a co-occurrence matrix of the time series and to establish a correlation between the moments of the intensity level distribution and the physical properties of the particles in suspension using an Artificial Neural Network. We performed a comprehensive error analysis of the proposed method for estimating particle diameter from the simulated Dynamic Light Scattering (DLS) time series, both on simulated and on experimental data. The results demonstrate the potential of utilizing moments of the co-occurrence matrix as an alternative approach for processing DLS time series data to assess the size of suspended particles. Full article
(This article belongs to the Special Issue Design and Construction of Optical Systems)
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29 pages, 1060 KB  
Review
Do Environmental Education Programs Reduce Pollution and Improve Air Quality? Impacts on Knowledge and Behavior Based on Evidence from a Mapping Review
by Rubia Truppel, Anderson D’Oliveira, Laura Canale, Luca Stabile, Giorgio Buonanno and Alexandro Andrade
Atmosphere 2025, 16(11), 1229; https://doi.org/10.3390/atmos16111229 - 23 Oct 2025
Abstract
This review investigates and analyzes the state of the art on scientific evidence related to educational interventions to improve air quality indoors and outdoors through a mapping review. The review followed proposed guidelines for mapping reviews in environmental sciences and the steps described [...] Read more.
This review investigates and analyzes the state of the art on scientific evidence related to educational interventions to improve air quality indoors and outdoors through a mapping review. The review followed proposed guidelines for mapping reviews in environmental sciences and the steps described in the Template for a Mapping Study Protocol. The search was conducted in PubMed, Web of Science, Embase, Cinahl, and Google Scholar with no language restrictions, and was completed in January 2025. Three filters were applied: search, selection with inclusion and exclusion criteria (PECOS strategy), and data extraction. Two independent reviewers assessed article eligibility, and disagreements were resolved by a third researcher. Twenty-four studies that met the eligibility criteria were included. Five research questions were answered. Studies published between 1977 and 2024 were included, totaling 7289 participants aged 12 to 85. The geographic distribution was concentrated in China (five studies) and the United States (four studies), followed by South Korea, India, Australia, and other countries, with fewer publications. The methodological predominance was experimental studies; observational studies were also analyzed, although less frequently. The period with the greatest increase in the number of publications was between 2020 and 2024. The educational methods most commonly used in the studies were lectures and the delivery of information leaflets. Particulate matter with diameters of 2.5 μm and 10 μm (PM2.5 and PM10) were the most widely investigated pollutants in the studies. From our analyses, it was observed that the educational interventions to improve air quality, adopted in the selected studies, resulted in the acquisition of knowledge about the environmental effects and the importance of individual actions. The changes in behavior included the adoption of more sustainable practices and an improvement in air quality in the environment, with a significant reduction in pollutant emissions. We conclude that interventions through environmental education demonstrate great potential to improve air quality. Based on the mapped evidence, governments and global policymakers can use this information to develop new strategies or improve existing ones to reduce air pollution in affected environments and regions. Full article
(This article belongs to the Section Air Quality)
22 pages, 7154 KB  
Article
Effects of Particle Segregation and Grain Pressure on Ventilation Airflow and Temperature–Humidity Distribution in Maize Pilot Silo
by Chaosai Liu, Boyi Zhao, Hao Zhang, Tong Shen and Jun Wang
Agriculture 2025, 15(21), 2205; https://doi.org/10.3390/agriculture15212205 - 23 Oct 2025
Abstract
The distribution of grain particles within a silo influences heat and moisture transfer during stored grain ventilation, leading to grain quality losses. A study on porosity distribution analysis and ventilation tests was conducted in a pilot silo with a height of 3 m, [...] Read more.
The distribution of grain particles within a silo influences heat and moisture transfer during stored grain ventilation, leading to grain quality losses. A study on porosity distribution analysis and ventilation tests was conducted in a pilot silo with a height of 3 m, a diameter of 1.5 m, and a conical dome height of 0.85 m. The E-B constitutive model was incorporated into the secondary development of FLAC3D 5.0 to analyze the vertical pressure distribution in the grain bulk. An anisotropic porosity distribution model for the maize bulk was developed, accounting for both vertical pressure and segregation mechanisms. The differences in airflow and heat transfer during ventilation between isotropic and anisotropic porosity distributions were quantified. A nonlinear model was innovatively proposed to predict the temperature front curve (TFC) during ventilation as affected by porosity variation. The results indicate that friction between the maize kernel and the silo wall led to vertical pressure at the center of the bottom that was 10.7% higher than that near the wall. The average surface porosity of the maize bulk was 2.8% higher than at the bottom. This led to a minimum porosity of 0.409 at the center of the silo bottom, due to the combined effect of impact during the loading process and vertical pressure. The numerical simulation demonstrated excellent consistency with the experimental data. At a supply vent air velocity of 0.126 m/s, an increase in the maize bulk height from 0.725 m to 2.9 m resulted in reductions in airflow rate and average relative humidity of 20.3% and 9.67%. The airflow velocity near the wall was 13.4% higher than that in the center, leading to a faster cooling rate in the peripheral region compared to the center of the maize bulk. The airflow velocity based on the isotropic porosity model was higher at the center than that predicted by the anisotropic model, whereas the opposite trend was observed near the wall. The temperature front during ventilation based on the anisotropic porosity model exhibited a concave curve. A nonlinear model was developed to predict this temperature front, showing strong agreement with computational data. Full article
(This article belongs to the Section Agricultural Product Quality and Safety)
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18 pages, 6253 KB  
Article
Long-Term Stability of Nanobubbles Generated via Pressure Oscillation-Hydrodynamic Cavitation: A Rapid Assessment by UV–Vis Spectrophotometry
by Lei Huang, Jiaqi Dong, Ming Chen, Lei Li and Ruichao Zhang
Nanomaterials 2025, 15(21), 1613; https://doi.org/10.3390/nano15211613 - 23 Oct 2025
Abstract
The long-term stability of bulk nanobubbles is crucial for their functional applications; however, understanding the evolution of their size distribution remains a significant challenge. While conventional characterization methods, such as Dynamic Light Scattering and Nanoparticle Tracking Analysis, provide size information, they are often [...] Read more.
The long-term stability of bulk nanobubbles is crucial for their functional applications; however, understanding the evolution of their size distribution remains a significant challenge. While conventional characterization methods, such as Dynamic Light Scattering and Nanoparticle Tracking Analysis, provide size information, they are often sample-intensive and expensive, making them ill-suited for high-throughput or long-term dynamic monitoring of size distribution polydispersity. This research validated UV–Vis spectrophotometry as a simple, powerful tool for tracking these dynamic changes. Air nanobubbles generated via pressure oscillation-hydraulic cavitation were systematically monitored over 30 days using correlative DLS, NTA, and UV–Vis spectroscopy. A distinct two-stage evolution was identified: an initial “purification” phase marked by the dissolution of unstable bubbles, followed by a long-term “maturation” phase governed by Ostwald ripening. The Ångström exponent (n), derived from the full extinction spectrum, is a highly sensitive descriptor of this process. The evolution of n traced a unique V-shaped trajectory, which resulted in a pronounced hysteresis loop when plotted against the mean diameter from DLS. This hysteresis reveals that systems with identical mean diameters can possess vastly different distribution morphologies, which are inaccessible through traditional sizing methods alone. This research establishes full-spectrum UV–Vis analysis as a robust methodology, enabling rapid and efficient assessment of nanobubble stability and providing a deeper mechanistic understanding of their complex evolution. Full article
(This article belongs to the Section Physical Chemistry at Nanoscale)
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14 pages, 3357 KB  
Article
Self-Supervised Hierarchical Dilated Transformer Network for Hyperspectral Soil Microplastic Identification and Detection
by Peiran Wang, Xiaobin Li, Ruizhe Zhang, Qiongchan Gu, Lianchi Zhang and Jiangtao Lv
Sensors 2025, 25(21), 6517; https://doi.org/10.3390/s25216517 - 22 Oct 2025
Abstract
Microplastics are plastic particles less than five millimeters in diameter that have led to serious environmental problems, and detecting these tiny particles is crucial to understanding their distribution and impact on the soil environment. In this paper, we propose the Self-Supervised Hierarchical Dilated [...] Read more.
Microplastics are plastic particles less than five millimeters in diameter that have led to serious environmental problems, and detecting these tiny particles is crucial to understanding their distribution and impact on the soil environment. In this paper, we propose the Self-Supervised Hierarchical Dilated Transformer Network (SHDTNet), an improved hyperspectral image classification model based on self-supervised contrastive learning, for identifying and detecting microplastics in soil. Currently, most hyperspectral image classifications rely on supervised methods, which perform well with rich training samples. However, pixel labeling in soil microplastic detection scenarios is a difficult and costly task. By employing the self-supervised contrastive learning technique, SHDTNet addresses the problem of insufficient training samples for hyperspectral images of soil microplastics and also enhances the feature extraction module in contrastive learning to improve the network model’s feature extraction capability. Experiments on self-constructed hyperspectral soil microplastic image datasets demonstrate that the proposed method accurately recognizes unique microplastics in the soil environment without errors or missed detections, outperforming several currently available soil microplastic detection methods. Full article
(This article belongs to the Section Sensing and Imaging)
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25 pages, 7777 KB  
Article
Influence of S and Mn Initial Concentrations on the Graphite Branching in Gray Cast Iron as Quantified by 2D Image Analysis
by Luis Filiberto De Santiago-Méndez, Manuel de Jesús Castro-Román, Martín Herrera-Trejo, Hector Mancha-Molinar and Beñat Bravo
Materials 2025, 18(21), 4837; https://doi.org/10.3390/ma18214837 - 22 Oct 2025
Abstract
The morphology changes in graphite flakes due to the difference in S and Mn contents were analyzed in gray iron samples with a Carbon Equivalent (CE) of 4.0. Although these Mn and S contents are within the range of industrial usage, the morphological [...] Read more.
The morphology changes in graphite flakes due to the difference in S and Mn contents were analyzed in gray iron samples with a Carbon Equivalent (CE) of 4.0. Although these Mn and S contents are within the range of industrial usage, the morphological characteristics of graphite flakes among the different samples show significant changes in their size and distribution. Graphite flake size was estimated using the Feret diameter, and the flake’s distribution was visually characterized following established standards. As it was observed that graphite flakes also differ in branching, a new procedure was developed to quantify such branching. Based on a skeletonization technique, this new procedure provides data to obtain additional microstructural parameters of the graphite flakes, such as the percentage of branched flakes and the longest shortest path (LSP) of each graphite flake. Microstructural characterization included measuring the eutectic cell count. The results indicate that Feret values and LSP show only weak correlations with concentration estimates from initial S and Mn. The most notable relationships are between sulfur content and Feret or LSP values. In contrast, the branching percentage correlates well with free sulfur at 1150 °C and eutectic cell count and is also linked to graphite distribution types (A or B). Notably, branching percentage offers a straightforward morphological parameter that enhances graphite flake characterization. Full article
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15 pages, 3114 KB  
Article
Impact of Extrinsic Defects in Wavelength Separation Coatings on the Process of Laser-Induced Damage
by Shichen Shen, Xinda Zhou, Yinbo Zheng, Jie Li, Tianhao Zhang, Linjie Zhao, Liqun Chai and Mingjun Chen
Micromachines 2025, 16(11), 1191; https://doi.org/10.3390/mi16111191 - 22 Oct 2025
Viewed by 60
Abstract
Wavelength separation coatings can effectively separate the fundamental frequency (1ω) and third harmonic (3ω) laser beams. However, the laser-induced damage threshold (LIDT) of the surface defect-free WS coatings for the 3ω laser is 1.68 J/cm2 (obtained in the preliminary experiment), significantly lower [...] Read more.
Wavelength separation coatings can effectively separate the fundamental frequency (1ω) and third harmonic (3ω) laser beams. However, the laser-induced damage threshold (LIDT) of the surface defect-free WS coatings for the 3ω laser is 1.68 J/cm2 (obtained in the preliminary experiment), significantly lower than the ideal LIDT of the fused silica substrate (80 J/cm2). This is directly correlated with extrinsic defects such as nanoscale defects and nodular defects introduced during the coating manufacturing process. Moreover, the damage in WS coatings caused by extrinsic defects is a complex physical process involving multiple physical phenomena such as material melting, vaporization, and ejection. The mechanism by which extrinsic defects interact with lasers to form damage is not yet fully elucidated. To address this, a multi-physics coupling model considering photoelectric, thermal and stress was established to simulate the incident laser propagation within coatings, the temperature distribution and thermal stress distribution of the coating material. This model systematically investigates the influence of defect location, type, and size on the laser-induced damage process. It is found that when a 10 nm-diameter defect is located at the 32nd layer of the coatings, the light intensity enhancement factor (LIEF) for 3ω laser can reach up to 5 times that for the 1ω laser. The variation in thermal stress induced by changes in defect size is jointly determined by the defect-induced modulation effect and the interference effect realized by the coating. This work theoretically reveals the mechanism of extrinsic defects in the laser damage. It provides effective guidance for establishing control standards for extrinsic defects during the optical coating process. Full article
(This article belongs to the Special Issue Advances in Digital Manufacturing and Nano Fabrication)
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17 pages, 3323 KB  
Article
Enhancing Torque Output for a Magnetic Actuation System for Robotic Spinal Distraction
by Yumei Li, Zikang Li, Ding Lu, Tairan Peng, Yunzhi Chen, Gang Fu, Zhenguo Nie and Fangyuan Wei
Sensors 2025, 25(20), 6497; https://doi.org/10.3390/s25206497 - 21 Oct 2025
Viewed by 252
Abstract
Magnetically controlled spinal growing rods, used for treating early-onset scoliosis (EOS), face a critical clinical limitation: insufficient distraction force. Compounding this issue is the inherent inability to directly monitor the mechanical output of such implants in vivo, which challenges their safety and efficacy. [...] Read more.
Magnetically controlled spinal growing rods, used for treating early-onset scoliosis (EOS), face a critical clinical limitation: insufficient distraction force. Compounding this issue is the inherent inability to directly monitor the mechanical output of such implants in vivo, which challenges their safety and efficacy. To overcome these limitations, optimizing the rotor’s maximum torque is essential. Furthermore, defining the “continuous rotation domain” establishes a vital safety boundary for stable operation, preventing loss of synchronization and loss of control, thus safeguarding the efficacy of future clinical control strategies. In this study, a transient finite element magnetic field simulation model of a circumferentially distributed permanent magnet–rotor system was established using ANSYS Maxwell (2024). The effects of the clamp angle between the driving magnets and the rotor, the number of pole pairs, the rotor’s outer diameter, and the rotational speed of the driving magnets on the rotor’s maximum torque were systematically analyzed, and the optimized continuous rotation domain of the rotor was determined. The results indicated that when the clamp angle was set at 120°, the number of pole pairs was one, the rotor outer diameter was 8 mm, the rotor achieved its maximum torque and exhibited the largest continuous rotation domain, while the rotational speed of the driving magnets had no effect on maximum torque. Following optimization, the maximum torque of the simulation increased by 201% compared with the pre-optimization condition, and the continuous rotation domain was significantly enlarged. To validate the simulation, a rotor torque measurement setup incorporating a torque sensor was constructed. Experimental results showed that the maximum torque improved from 30 N·mm before optimization to 90 N·mm after optimization, while the driving magnets maintained stable rotation throughout the process. Furthermore, a spinal growing rod test platform equipped with a pressure sensor was developed to evaluate actuator performance and measure the maximum distraction force. The optimized growing rod achieved a peak distraction force of 413 N, nearly double that of the commercial MAGEC system, which reached only 208 N. The simulation and experimental methodologies established in this study not only optimizes the device’s performance but also provides a viable pathway for in vivo performance prediction and monitoring, addressing a critical need in smart implantable technology. Full article
(This article belongs to the Special Issue Recent Advances in Medical Robots: Design and Applications)
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24 pages, 5998 KB  
Article
Simulation of Reinforced Concrete Beam–Column Joint Pouring Process Based on Three-Dimensional Particle Flow Method
by Xiao Zhang, Muxuan Tao, Ran Ding, Jiansheng Fan, Xinhao Zhang, Mengjia Zhou and Qiang Zhang
Buildings 2025, 15(20), 3795; https://doi.org/10.3390/buildings15203795 - 21 Oct 2025
Viewed by 166
Abstract
The concrete pouring process is difficult to observe inside formwork. With increasingly complex formwork systems and denser reinforcement layouts, honeycomb defects and surface pores are prone to form at beam–column joint core locations. The modeling of pouring processes that were performed earlier is [...] Read more.
The concrete pouring process is difficult to observe inside formwork. With increasingly complex formwork systems and denser reinforcement layouts, honeycomb defects and surface pores are prone to form at beam–column joint core locations. The modeling of pouring processes that were performed earlier is insufficient and there is relatively little research on simulating concrete void defects at typical joints. Therefore, a refined numerical model based on the three-dimensional particle flow method was established to simulate the flow of fresh concrete within formwork and predict concrete voids after pouring. The feasibility of the particle flow method was verified through numerical simulations of slump flow and J-ring tests. Several groups of joint models were set up based on different influencing factors, and the developed particle flow model was used for pouring simulations to investigate the influence of various factors on concrete void formation. The results show that the void volume and distribution patterns obtained from experiments and simulations are basically consistent. The numerical model can accurately simulate the working performance of self-compacting concrete and predict the size and location distribution of pouring defects. Based on both experimental and numerical studies, the following suggestions are proposed to avoid potential void defects in practical concrete pouring projects: reasonably select the number and diameter of joint longitudinal bars; appropriately increase the spacing of column stirrups; appropriately reduce the maximum coarse aggregate particle size; and choose concrete with better fluidity and filling ability. Full article
(This article belongs to the Special Issue Application of Experiment and Simulation Techniques in Engineering)
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15 pages, 7062 KB  
Article
Analysis of the Causes of Damage to the Steel Drive Shaft Used in a Paint Mixer
by Wojciech Skotnicki and Dariusz Jędrzejczyk
Materials 2025, 18(20), 4798; https://doi.org/10.3390/ma18204798 - 21 Oct 2025
Viewed by 152
Abstract
This article presents an analysis of the causes of damage to the shaft used in a paint mixer (made of 1.0501 steel, with diameter ø = 90 mm and length l = 3451 mm). The observed damage occurred in both the shaft before [...] Read more.
This article presents an analysis of the causes of damage to the shaft used in a paint mixer (made of 1.0501 steel, with diameter ø = 90 mm and length l = 3451 mm). The observed damage occurred in both the shaft before regeneration and the part regenerated by surfacing. The initial analysis consisted of both macroscopic and microscopic observations of the shaft cross sections. Additionally, hardness measurements were made using the Vickers method (HV0.1). The results of microstructure observations were used as the basis for further finite element analysis (FEA). The FEA simulations made it possible to identify the places most susceptible to damage and assess the stress distribution during the shaft’s application. Based the FEA results, in order to improve the durability of the analyzed structural element, changes in the shaft geometry and the use of different chemical steel compositions are proposed. Full article
(This article belongs to the Section Metals and Alloys)
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16 pages, 7276 KB  
Article
Influence of Hydrogen-Based Direct Reduction Shaft Furnace Interior Structure on Shaft Furnace Performance
by Qingbin Xue, Haotian Liao, Jianliang Zhang and Kejiang Li
Materials 2025, 18(20), 4794; https://doi.org/10.3390/ma18204794 - 20 Oct 2025
Viewed by 285
Abstract
Hydrogen-based direct reduction of iron ore is a promising route to reduce CO2 emissions in steelmaking, where uniform particle flow inside shaft furnaces is essential for efficient operation. In this study, a full-scale three-dimensional Discrete Element Method (DEM) model of a shaft [...] Read more.
Hydrogen-based direct reduction of iron ore is a promising route to reduce CO2 emissions in steelmaking, where uniform particle flow inside shaft furnaces is essential for efficient operation. In this study, a full-scale three-dimensional Discrete Element Method (DEM) model of a shaft furnace was developed to investigate the effects of a diverter device on granular flow. By systematically varying the radial width and top/bottom diameters of the diverter, particle descent velocity, residence time, compressive force distribution, and collision energy dissipation were analyzed. The results demonstrate that introducing a diverter effectively suppresses funnel flow, prolongs residence time, and improves radial flow uniformity. Among the tested configurations, the smaller central diameter diverter showed the most favorable performance, achieving a faster and more uniform descent, reduced compressive force concentration, and lower collision energy dissipation. These findings highlight the critical role of diverter design in regulating particle dynamics and provide theoretical guidance for optimizing shaft furnace structures to enhance the efficiency of hydrogen-based direct reduction processes. Full article
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22 pages, 3909 KB  
Article
Tuning of Photocatalytic and Piezophotocatalytic Activity of Bi3TiNbO9 via Synthesis-Controlled Surface Defect Engineering
by Farid F. Orudzhev, Asiyat G. Magomedova, Sergei A. Kurnosenko, Vladislav E. Beklemyshev, Wei Li, Chuanyi Wang and Irina A. Zvereva
Molecules 2025, 30(20), 4136; https://doi.org/10.3390/molecules30204136 - 20 Oct 2025
Viewed by 198
Abstract
In this work, we investigate advanced photocatalyst Bi3TiNbO9 as promising piezophotocatalyst in terms of the effect of synthesis methods on the surface chemistry, structure, and catalytic performance in process of contaminant removal. Samples were prepared via solid-state reaction (BTNO-900) and [...] Read more.
In this work, we investigate advanced photocatalyst Bi3TiNbO9 as promising piezophotocatalyst in terms of the effect of synthesis methods on the surface chemistry, structure, and catalytic performance in process of contaminant removal. Samples were prepared via solid-state reaction (BTNO-900) and molten salt synthesis (BTNO-800), leading to distinct morphologies and defect distributions. SEM imaging revealed that BTNO-900 consists of agglomerated, irregular particles, while BTNO-800 exhibits well-faceted, plate-like grains. Nitrogen adsorption analysis showed that the molten-synthesized sample possesses a significantly higher specific surface area (5.9 m2/g vs. 1.4 m2/g) and slightly larger average pore diameter (2.8 nm vs. 2.6 nm). High-resolution XPS revealed systematic shifts in binding energies for Bi 4f, Ti 2p, Nb 3d, and O 1s peaks in BTNO-900, accompanied by a higher content of adsorbed oxygen species (57% vs. 7.2%), indicating an increased concentration of oxygen vacancies and surface hydroxylation due to the solid-state synthesis route. Catalytic testing demonstrated that BTNO exhibits enhanced piezocatalytic efficiency of Methylene Blue degradation (~78% for both samples), whereas BTNO-800 shows significantly reduced photocatalytic activity (45.6%) compared to BTNO-900 (84.1%), suggesting recombination effects dominate in the more defective material. Synergism of light and mechanical stress results in piezophotocatalytic degradation for both samples (92.4% and 93.4%, relatively). These findings confirm that synthesis-controlled defect engineering is a key parameter for optimizing the photocatalytic behavior of Bi3TiNbO9-based layered oxides and crucial role of its piezocatalytic activity. Full article
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29 pages, 3223 KB  
Article
Injectable In Situ Thermoreversible Gel Depot System of Lidocaine Nanoemulsion for Prolonged Anesthetic Activity in Dental and Operative Procedures
by Shery Jacob, Fathima Sheik Kather, Shakta Mani Satyam, Sai H. S. Boddu, Firas Assaf, Tasnem H. Abdelfattah Allam and Anroop B. Nair
Pharmaceutics 2025, 17(10), 1355; https://doi.org/10.3390/pharmaceutics17101355 - 20 Oct 2025
Viewed by 333
Abstract
Background/Objectives: Lidocaine hydrochloride (LD-HCl) is the most commonly used local anesthetic in dentistry, often administered with epinephrine to extend its duration and reduce systemic absorption. However, its relatively short duration of action, the need for repeated injections, and the unpleasant taste may limit [...] Read more.
Background/Objectives: Lidocaine hydrochloride (LD-HCl) is the most commonly used local anesthetic in dentistry, often administered with epinephrine to extend its duration and reduce systemic absorption. However, its relatively short duration of action, the need for repeated injections, and the unpleasant taste may limit patient compliance and procedural efficiency. This study aimed to develop and evaluate a novel injectable nanoemulsion-based in situ gel depot system of LD to provide prolonged anesthetic activity. Methods: LD-loaded nanoemulsions were formulated by high-shear homogenization followed by probe sonication, employing Miglyol 812 N (oil phase), a combination of Tween 80 and soy lecithin (surfactant–co-surfactant), glycerin, and deionized water (aqueous phase). The selected nanoemulsion (S1) was dispersed in a thermoreversible poloxamer solution to form a nanoemulgel. The preparation was evaluated for globule diameter and uniformity, zeta potential, surface morphology, pH, drug content, stability, rheological behavior, injectability, and in vitro drug release. Analgesic efficacy was assessed via tail-flick and thermal paw withdrawal latency tests in Wistar rats. Cardiovascular safety was monitored using non-invasive electrocardiography and blood pressure measurements. Results: The developed nanoemulsions demonstrated a spherical shape, nanometer size (206 nm), high zeta-potential (−66.67 mV) and uniform size distribution, with a polydispersity index of approximately 0.40, while the nanoemulgel demonstrated appropriate thixotropic properties for parenteral administration. In vitro release profiles showed steady LD release (5 h), following the Higuchi model. In vivo studies showed significantly prolonged analgesic effects lasting up to 150 min (2.5 h) compared to standard LD-HCl injection (p < 0.001), with no adverse cardiovascular effects observed. Conclusions: The developed injectable LD in situ nanoemulgel offers a promising, patient-friendly alternative for prolonged anesthetic delivery in dental and operative procedures, potentially reducing the need for repeated injections and enhancing procedural comfort. Full article
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