Search Results (9)

This article provides a comprehensive overview of recent studies concerning laser heat treatment (LHT) of structural and tool steels, with particular attention to the 21NiCrMo2 steel used for carburized gear wheels. Analysis includes the influence of critical laser processing conditions—including power output, motion speed, spot size, and focusing distance—on surface microhardness, hardening depth, and microstructure development. The findings indicate that the energy density is the dominant factor that affects the outcomes of LHT. Optimal results, in the form of a high surface microhardness and a sufficient depth of hardening, were achieved within the energy density range of 80–130 J/mm², allowing for martensitic transformation while avoiding defects such as melting or cracking. At densities below 50 J/mm², incomplete hardening occurred with minimal microhardness improvement. On the contrary, densities exceeding 150–180 J/mm² caused surface overheating and degradation. For carburized 21NiCrMo2 steel, the most effective parameters included 450–1050 W laser power, 1.7–2.5 mm/s scanning speed, and 2.0–2.3 mm beam diameter. The review confirms that process control through energy-based parameters allows for reliable prediction and optimization of LHT for industrial applications, particularly in components exposed to cyclic loads. Full article

The Inconel 718 alloy is a nickel-based superalloy that can be strengthened through precipitation hardening. Due to its exceptional mechanical properties, high corrosion resistance, and good workability, it is particularly suitable for applications where components operate in corrosive environments at temperatures up to 600 °C. Under these conditions, overheating frequently occurs, leading to structural transformations and changes in mechanical properties. This experimental study examined the effect of repeated overheating on the alloy’s structure, the formation of oxide layers, and hardness. The cyclic overheating process was simulated using thermal shocks induced by solar energy, with temperatures exceeding the recommended range, between 700 and 1000 °C. Morphological characterization, elemental chemical analysis, qualitative phase analysis, and microhardness measurements highlighted the transformations induced by cyclic thermal stress at high temperatures. Full article

The structural and electro-thermophysical characteristics of organosilicon elastomers modified with multilayer carbon nanotubes (MWCNTs) synthesized on Co-Mo/Al₂O₃-MgO and metallic (Cu or Ni) microparticles have been studied. The structures were analyzed with scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, and energy-dispersive X-ray spectroscopy (EDX). The main focus of this study was the influence of metallic dispersed fillers on the resistance of a modified elastomer with Cu and Ni to the degradation of electrophysical parameters under the action of applied electrical voltage. The distribution of the temperature field on the surface of a modified polymer composite with metallic micro-dimensional structures has been recorded. The collected data demonstrate the possibility of controlling the degradation caused by electrical voltage. It has been found that repeated on/off turns of the elastomer with an MWCNTs on 50 and 100 cycles leads to a deterioration in the properties of the conductive elastomer from the available power of 1.1 kW/m² (−40 °C) and, as a consequence, a decrease in the power to 0.3 kW/m² (−40 °C) after 100 on/off cycles. At the same time, the Ni additive allows increasing the power by 1.4 kW/m² (−40 °C) and reducing the intensity of the degradation of the conductive structures (after 100 on/off cycles up to 1.2 kW/m² (−40 °C). When Ni is replaced by Cu, the power of the modified composite in the heating mode increases to 1.6 kW/m² (−40 °C) and, at the same time, the degradation of the conductive structures in the composite decreases in the mode of cyclic offensives (50 and 100 cycles) (1.5 kW/m² (−40 °C)). It was found that the best result in terms of heat removal is typical for an elastomer sample with an MWCNTs and Cu (temperature reaches 93.9 °C), which indicates an intensification of the heat removal from the most overheated places of the composite structure. At the same time, the maximum temperature for the Ni additives reaches 86.7 °C. A sample without the addition of a micro-sized metal is characterized by the local unevenness of the temperature field distribution, which causes undesirable internal overheating and destruction of the current-conducting structures based on the MWCNTs. The maximum temperature at the same time reaches a value of 49.8 °C. The conducted studies of the distribution of the micro-sizes of Ni and Cu show that Cu, due to its larger particles, improves internal heat exchange and intensifies heat release to the surface of the heater sample, which improves the temperature regime of the MWCNTs and, accordingly, increases resistance to electrophysical degradation. Full article

The results of a high-cycle fatigue testing of our samples were obtained, and a comparative assessment of the properties of the base metal and weld metal of 09G2S-type steel (13Mn6 according to the DIN17145-80 standard) before and after overheating (1200 °C, 3.7 h) was performed. The welded joints between the sheets of 09G2S steel were obtained through automatic argon arc welding. The fatigue tests were carried out under repeated tensile loading. The “maximum cycle stress—number of cycles to failure” fatigue curves of the samples were plotted. The fracture surfaces of the samples were studied, and the fatigue failure mechanisms were analyzed. It was shown that, during testing, all samples demonstrated cyclic hardening behavior. The samples of the base metal as delivered had the highest endurance limit, and the smallest endurance limit was found in the samples of the base metal and weld metal after overheating, the endurance limits of which were similar. The fracture mechanism of all samples was quasi-brittle with the presence of very thin fatigue micro-grooves. The final rupture of all samples had a ductile dimple type. Full article

Rubber composites are extensively used in industrial applications for their exceptional elasticity. The fatigue temperature rise occurs during operation, resulting in a serious decline in performance. Reducing heat generation of the composites during cyclic loading will help to avoid substantial overheating that most likely results in the degradation of materials. Herein, we discuss the two main reasons for heat generation, including viscoelasticity and friction. Influencing factors of heat generation are highlighted, including the Payne effect, Mullins effect, interface interaction, crosslink density, bond rubber content, and fillers. Besides, theoretical models to predict the temperature rise are also analyzed. This work provides a promising way to achieve advanced rubber composites with high performance in the future. Full article

The crystal structure was determined for the first time for 4-[(di-p-tolyl-amino)benzylidene]-(5-pyridin-4-yl-[1,3,4]thiadiazol-2-yl)-imine (trans-PPL9) by X-ray diffraction. The imine crystallized in the monoclinic P2₁/n space group with a = 18.9567(7) Å, b = 6.18597(17) Å, c = 22.5897(7) Å, and β = 114.009(4)°. Intermolecular interactions in the PPL9 crystal were only weak C−H⋯N hydrogen bonds investigated using the Hirshfeld surface. The electronic and geometric structure of the imine were investigated by the density functional theory and the time-dependent density-functional theory. The properties of the imine in neutral and protonated form with camforosulphonic acid (CSA) were investigated using cyclic voltammetry, UV–vis and ¹H NMR spectroscopy. Theoretical and experimental studies showed that for the 1:1 molar ratio the protonation occured on nitrogen in pyridine in the PPL9 structure, as an effect of Brönsted acid–base interactions. Thermographic camera was used to defined defects in constructed simple devices with ITO/PPL9 (or PPL9:CSA)/Ag/ITO architecture. In conclusion, a thermally stable imine was synthesized in crystalline form and by CSA doping, a modification of absorption spectra together with reduction of overheating process was observed, suggesting its potential application in optoelectronics. Full article

The actuation of silicone/ethanol soft composite material-actuators is based on the phase change of ethanol upon heating, followed by the expansion of the whole composite, exhibiting high actuation stress and strain. However, the low thermal conductivity of silicone rubber hinders uniform heating throughout the material, creating overheated damaged areas in the silicone matrix and accelerating ethanol evaporation. This limits the actuation speed and the total number of operation cycles of these thermally-driven soft actuators. In this paper, we showed that adding 8 wt.% of diamond nanoparticle-based thermally conductive filler increases the thermal conductivity (from 0.190 W/mK to 0.212 W/mK), actuation speed and amount of operation cycles of silicone/ethanol actuators, while not affecting the mechanical properties. We performed multi-cyclic actuation tests and showed that the faster and longer operation of 8 wt.% filler material-actuators allows collecting enough reliable data for computational methods to model further actuation behavior. We successfully implemented a long short-term memory (LSTM) neural network model to predict the actuation force exerted in a uniform multi-cyclic actuation experiment. This work paves the way for a broader implementation of soft thermally-driven actuators in various robotic applications. Full article

In the present work, TiC/TiB₂/Al composite coatings were synthesized onto a precipitation hardened AlSi1MgMn alloy by laser surface alloying (LSA), using 13.3 J/mm² and 20 J/mm² laser energy densities. Microstructure evaluation, microhardness, wear and corrosion performance were investigated and compared with the untreated/substrate Al alloy sample. The results confirmed sound, compact, crackles composite coating of low porosity, with a proper surface/substrate interface. Microstructural analyses revealed the formation of extremely fine nano-precipitates, ranging from of 50–250 nm in the laser melted (LMZ) and large precipitates, accompanied with grain coarsening in the heat-affected zone (HAZ), due to the substrate overheating during the LSA process. Nonetheless, both coatings achieved higher microhardness, with almost 7-times higher wear resistance than the untreated sample as a consequence of high fraction volume of hard, wear resistant TiB₂ and TiC phases inside the composite coatings. Further, cyclic polarization results in 0.5 M NaCl aqueous solution confirmed general improvement of corrosion resistance after LSA processed samples, with reduced corrosion current by more than a factor of 9, enhanced passivation/repassivation ability and complete prohibition of crystallographic pitting, which was detected with the untreated Al alloy. Full article

Free cooling strategies are gaining importance in design practice due to the increased risk of overheating in well-insulated buildings with high internal loads such as offices. The state of the art highlights that the most efficient passive solution for indoor temperature stabilization and control is the integration of thermal mass with an optimized ventilative cooling profile to enhance the thermal cycle of heat storage. Due to its cyclical behavior, thermal mass effects are difficult to predict and quantify with the traditional steady-state approach to building thermal performance. Dynamic thermal simulations help to assess a building’s behavior under transient situations, including the thermal mass influence. However, building codes usually include thermal simulations based on standard assumptions: typical meteorological year (TMY), standard occupancy, standard daily-based lighting and appliances profiles, and standard weekly-based occupancy. Thus, when assumptions change, the actual behavior of the building may vary consistently from the predicted conditions. In this paper, we focused on the ability of thermal mass to contrast the influence of variations from the standard assumptions, especially in relation to climate and ventilation profiles. The results show the necessity of encompassing different risk scenarios when evaluating a free cooling solution performance. Among the different scenarios simulated, natural ventilation misuse shows greater influence on the thermal indoor environment, especially if coupled with low thermal mass. Full article