Search Results (113)

This study looks at the effect of surface conditioners hydrofluoric acid (HFA), Ytterbium fibre laser (YFL), and Hydroxyapatite nanoparticles (HANPs) on the surface roughness (Ra) and shear bond strength (SBS) of different viscosity resin cements to lithium disilicate glass ceramic (LDC). A total of 78 IPS Emax discs were prepared and categorized into groups based on conditioning methods. Group 1 HFA–Silane (S), Group 2: YFL-S, and Group 3: HANPs-S. A scanning electron microscope (n = 1) and profilometer (n = 5) were used on each conditioned group for the assessment of surface topography and Ra. A total of 20 LDC discs for each conditioned group were subsequently categorized into two subgroups based on the application of high- and low-viscosity dual-cured resin cement. SBS and failure mode were assessed. ANOVA and post hoc Tukey tests were employed to identify significant differences in Ra and SBS among different groups. LDC conditioned with HFA-S, HANPs-S, and YFL-S demonstrated comparable Ra scores (p > 0.05). Also, irrespective of the type of conditioning regime, the use of low-viscosity cement improves bond values when bonded to the LDC. LDC treated with YFL-S and HANPs-S can serve as an effective substitute for HFA-S in enhancing the Ra and surface characteristics of LDC. The low-viscosity resin cement demonstrated superior performance by achieving greater bond strength. Full article

Stray-current and soft-water leaching can induce severe corrosion in reinforced concrete structures and buried metal pipelines within subway environments. The effects of water-to-binder ratio (W/C), modulus of sodium silicate (Ms), and alkali content (AC) on the mechanical properties of fly-ash-based geopolymer (FAG) at various curing ages were investigated. The influence of curing temperature and high-temperature curing duration on the development of mechanical performance were examined, and the optimal curing regime was determined. Furthermore, based on the mix design of FAG resistant to coupled erosion from stray-current and soft-water, the effects of stray-current intensity and erosion duration on the coupled erosion behavior were analyzed. The results indicated that FAG exhibited slow strength development under ambient conditions. However, thermal curing at 80 °C for 24 h markedly improved early-age strength. The compressive strength of FAG exhibited an increase followed by a decrease with increasing W/B, Ms, and AC, with optimal ranges identified as 0.28–0.34, 1.0–1.6, and 4–7%, respectively. Soft-water alone caused limited leaching, while the presence of stray-current significantly accelerated degradation, with corrosion rates increasing by 4.1 and 7.2 times under 20 V and 40 V, respectively. The coupled corrosion effect was found to weaken over time and with increasing current intensity. Under coupled leaching conditions, compressive strength loss of FAG was primarily influenced by AC, with lesser contributions from W/B and Ms. The optimal mix proportion for corrosion resistance was determined to be W/B of 0.30, Ms of 1.2, and AC of 6%, under which the compressive strength after corrosion achieved the highest value, thereby significantly improving the durability of FAG in harsh environments such as stray-current zones in subways. Full article

The curing process of a concrete sample has a significant influence on hydration and its strength. This means that inadequate curing conditions lead to a loss of concrete quality and negative consequences in structural engineering. In addition, different state-of-the-art (SOTA) curing surface treatments and hydration periods have a significant effect on durability. This paper introduces an innovative non-destructive method to detect the development of the hydration process under different treatment conditions. Hyperspectral imaging is a non-contact measurement technique that provides detailed information on hydration characteristics within an electromagnetic wavelength range. A comparative laboratory measurement was conducted on twelve concrete samples, subjected to three curing treatments and four curing surface treatments, over a hydration period from the 1st to the 56th day. Additionally, artificial neural networks and convolutional neural networks have achieved classification accuracies of 67.8% (hydration time), 83.3% (curing regime), and 87.6% (surface type), demonstrating the feasibility of using neural networks for hydration monitoring. In this study, the results revealed differences in near-infrared spectral signatures, representing the type of curing treatment, curing surface, and hydration time of the concrete. The dataset was classified and analyzed using neural networks. For each hydration treatment, three different models were developed to achieve better prediction performance for hyperspectral imaging analysis. This method demonstrated a high level of reliability in investigating curing surface treatments, curing treatments, and hydration time. A recommended method for using hyperspectral imaging to evaluate the cured quality of concrete will be developed in future research. Full article

Coal gangue (CG), a major solid waste generated during coal development, presents critical environmental challenges due to its large-scale accumulation and associated ecological impacts, thereby necessitating the development of efficient utilization strategies. This investigation developed a composite geopolymer system through the alkali-activated co-utilization of uncalcined CG and blast furnace slag (BFS), demonstrating an environmentally sustainable approach for industrial byproduct value addition. The effects of key parameters, including BFS content, liquid-to-solid ratio, alkali activator dosage, waterglass modulus, and curing regime, on the strength development were first investigated through single-factor experiments. Based on these results, response surface methodology was applied to optimize the preparation parameters and develop a quadratic regression model describing the relationship between compressive strength and the influencing factors. The optimal conditions (a waterglass modulus of 1.06, an alkali activator dosage of 13.81%, and an initial 24 h curing temperature of 30 °C) were determined to maximize compressive strength. The reaction mechanisms were further explored using XRD and SEM-EDS, which confirmed the existence of calcium silicate hydrate, calcium aluminum silicate hydrate, and geopolymer gel in the composite geopolymer matrix. Full article

The utilization of aeolian sand (AS) as a substitute for river sand (RS) in ultra-high-performance concrete (UHPC) offers a sustainable solution to address natural sand resource shortages while enhancing AS utilization. This study systematically evaluates the influence of AS content (0–100% RS replacement by mass) on the workability, mechanical properties, and microstructure of UHPC under different curing regimes. All mixtures incorporate 0.65% by volume of straight steel fibers to ensure adequate fiber reinforcement. The results reveal that the spherical morphology, smooth surface nature, and fine particle size of AS enhance the matrix fluidity and reduce the early autogenous shrinkage of UHPC. By employing steam curing at 90 °C for 2 d followed by standard curing for 7 d (M3), UHPC samples with a 60% and 80% AS substitution achieve a compressive strength of 132.4 MPa and 130.8 MPa, respectively; a flexural strength exceeding 18 MPa; a porosity below 10%; and a gel pore content exceeding 60%. The steel fiber reinforcement contributes significantly to the flexural performance, with the fiber–matrix interface quality maintained even at high AS replacement levels. These findings highlight the feasibility of AS as an alternative fine aggregate in UHPC. Full article

Volcanic ash (VA) is an abundant resource in many world regions that can be used as a supplementary cementitious material (SCM). However, its low reactivity limits its applications as a replacement for Portland cement. In this study, the improvement of its reactivity was evaluated through the calcination of VA (CVA) at 700 °C, alkali activation with Na₂SiO₃, CaCl₂, and Na₂CO₃, as well as its combination with other SCMs (lime, fly ash, and blast-furnace slags). Additionally, the effect of curing was analysed under different regimes: standard moist curing and heat curing. The use of alkaline activators, especially 2% Na₂SiO₃ and 1% CaCl₂, along with thermal curing (70 °C for 3 days) in mortars containing 50% VA, resulted in compressive strengths at 28 days, significantly higher than those obtained for mortars with non-activated VA or those cured under moist conditions. Furthermore, the addition of 10% fly ash (FA) and 5% slag (EC) to the mortars also led to the largest improvements in compressive strength. In addition, mortars cured at 70 °C exhibited lower shrinkage and improved resistance to acid attacks, particularly in those manufactured with CVA and 1% CaCl₂. This study concludes that it is possible to optimise the design of mortars with 50% VA in replacement of ordinary cement based on activation and curing methods. These methods improve early-age strength, reduce shrinkage and water absorption, and enhance acid resistance. Full article

Steam curing is a widely used method in the production of industrial precast concrete but it often leads to thermal damage that negatively impacts the material’s long-term durability and mechanical strength. The use of supplementary cementitious materials (SCMs) has shown considerable promise in improving pore structure and alleviating these adverse effects. This study employs high-resolution X-ray computed tomography (X-CT) to thoroughly assess how steam curing temperatures and various subsequent curing regimes influence the pore characteristics of mortars containing high volumes of mineral admixtures. The results shows that steam-cured specimens under water curing (ST8012-WA) achieved a compressive strength of 51.72 MPa and flexural strength of 5.85 MPa, representing improvements of 9% and 19.8%, respectively, compared to natural curing (ST8012-NA: 47.32 MPa and 4.88 MPa). The standard-cured specimen (SD) exhibited the highest compressive strength of 54.18 MPa, highlighting the detrimental effects of elevated steam curing temperatures. The findings reveal that higher steam curing temperatures result in increased porosity and decreased mechanical strength, challenges that can be effectively mitigated through appropriate postcuring techniques. Notably, water curing following steam curing proves especially effective in reducing pore size variability and improving the material’s durability. This research offers new insights into the intricate relationships among curing temperature, pore morphology, and mechanical performance, providing practical recommendations to optimize the quality and longevity of steam-cured precast concrete components. Full article

Hepatitis C virus (HCV) is a global public health problem, but advancements in HCV treatment have improved the cure rate. This study evaluated the effectiveness of direct-acting antivirals (DAAs) in HCV-infected patients from May 2021 to April 2023 in collaboration with tertiary care hospitals in West Bengal. The HCV viral load was monitored via qRT-PCR. Sanger sequencing was performed to determine the HCV genotypes. The clinicians prescribed the patient treatment regime. The maximum number of patients in the study population (N = 398) were compensated cirrhosis patients (46.28%). The overall SVR rate of the study population was 94.47%. The decompensated cirrhosis patients experienced the lowest SVR rate (88.89%). The maximum number of patients were prescribed sofosbuvir/daclatasvir (63.77%), and the lowest SVR rate (93.23%) was observed with this treatment regime. In the study population, GT-3 was the predominant (67.43%) circulating genotype, followed by GT-1 and -4. Among 398 patients, 22 (5.53%) were non-responsive to DAA treatment. Out of these 22 non-responder patients, 77.27% (n = 17) were GT-3-infected (3a:10; 3b:07), followed by GT-1 (1c: 04; 1b: 01). Thus, increasing numbers of DAA non-responsive cases among HCV GT-3-infected and decompensated cirrhosis patients may pose serious threats in the future. Full article

Geopolymer concrete (GPC) can be produced by the chemical activation of industrial by-products and processed natural minerals that contain aluminosilicates with the presence of an alkaline activator. Raw components are one of the critical parameters affecting geopolymer performance. On the other hand, the mixing procedure of geopolymer concrete is not any less important. Few demonstrative constructions have been built using GPC as a greener alternative to Portland cement concrete. Numerous variables affect GPC manufacture, such as raw material specification, activator type and dosage, and curing regimes. Despite the conventions of the building industry, the lack of proper mix design methods limits the wide acceptance of GPC in the industry. This report conducted experimental trials on GGBS-based GPC to optimize a mixing design procedure to achieve best mechanical strength and structural integrity. Geopolymer concrete properties were evaluated through slump and unconfined compressive strength tests. The laboratory trials in this report revealed that all geopolymer mixes, except SD0HV and 1W-SG, exhibited high workability values. Also, the presence of an alkaline activator was vital to attain satisfactory compressive strength values. The alkaline activator could be used when cooled and reached room temperature after two hours of preparation and was not necessary after 24 h. Mix G-(0.5W-S) with a 0.5A.A. (alkaline activator)/precursor (GGBS) ratio, SSA (sodium silicate alternative)/SH (sodium hydroxide with 10 M molarity) ratio of 1:1, and 0.55 W/B (water to binder) ratio is recommended to achieve best mechanical performance and structural integrity. Full article

Fine gold tailings particles generated from gold mining and refining have the potential to replace high-cost quartz sand in the preparation of economical ultra-high-performance concrete (ECO-UHPC) due to their large stockpiles, low cost, and elimination of grinding. In this study, ECO-UHPC was prepared by substituting quartz sand with gold tailing sand (GTS) at substitution rates of 0%, 25%, 50%, 75%, and 100%. The mechanical properties of ECO-UHPC, including its cubic compressive strength, elastic modulus, and prismatic compressive strength, as well as its leaching toxicity, were experimentally analyzed under various early curing experiences such as ambient-water curing (WC), hot-water curing (HWC), hot-air curing (HAC), and combined curing (CC). Additionally, scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) were employed to interpret the macroscopic behavior of ECO-UHPC. The results indicate that the incorporation of waste GTS slightly reduces the fluidity of fresh ECO-UHPC, decreasing it by approximately 6.1% at a full 100% replacement. As a result of waste GTS substitution, the cubic strength of ECO-UHPC experiencing the WC environment during early curing is reduced by 0.7–12.2%. However, the strength of thermally cured ECO-UHPC is comparable to or even higher than that of pure quartz-based G0, with the maximum value occurring in G-50. Specifically, the strength of G-50 cured with HWC, HAC, and CC varies by +20.0%, +40.2%, and +57.7%, respectively, as compared to that of G-50 cured with WC. The evolution of the elastic modulus and the prismatic strength of ECO-UHPC under different early curing conditions and GTS replacement rates aligns closely with that of its cubic strength. In addition, the implementation of thermal curing conditions also limits the leaching of heavy metals from ECO-UHPC, with the best effect observed under CC. This is because appropriate thermal curing promotes the densification of a cementitious substance and the bonding of GTS-cementitious material. Overall, this study demonstrates the feasibility of utilizing waste GTS as a partial or full replacement for quartz sand in ECO-UHPC while maintaining desirable mechanical performance and environmental safety. The findings provide valuable insights into the influence of GTS substitution and early curing regimes on ECO-UHPC properties, highlighting the potential of thermal curing to enhance strength and mitigate leaching risks. Future research should further explore the long-term durability of GTS-based ECO-UHPC and its broader applicability in sustainable construction practices. Full article

Cleavable bio-based epoxy resin systems are emerging, eco-friendly, and promising alternatives to the common thermoset ones, providing quite comparable thermo-mechanical properties while enabling a circular and green end-of-life scenario of the composite materials. In addition to being designed to incorporate a bio-based resin greener than the conventional fully fossil-based epoxies, these formulations involve cleaving hardeners that enable, under mild thermo-chemical conditions, the total recycling of the composite material through the recovery of the fiber and matrix as a thermoplastic. This research addressed the characterization, processability, and recyclability of a new commercial cleavable bio-resin formulation (designed by the R-Concept company) that can be used in the fabrication of fully recyclable polymer composites. The resin was first studied to investigate the influence of the different post-curing regimes (room temperature, 100 °C, and 140 °C) on its thermal stability and glass transition temperature. According to the results obtained, the non-post-cured resin displayed the highest T_g (i.e., 76.6 °C). The same post-curing treatments were also probed on the composite laminates (glass and carbon) produced via a lab-scale vacuum-assisted resin transfer molding system, evaluating flexural behavior, microstructure, and dynamic-mechanical characteristics. The post-curing at 100 °C would enhance the crosslinking of polymer chains, improving the mechanical strength of composites. With respect to the non-post-cured laminates, the flexural strength improved by 3% and 12% in carbon and glass-based composites, respectively. The post-curing at 140 °C was instead detrimental to the mechanical performance. Finally, on the laminates produced, a chemical recycling procedure was implemented, demonstrating the feasibility of recovering both thermoplastic-based resin and fibers. Full article

Current space exploration focuses on returning to the Moon to expand space exploration capacity by improving technology. The long-term presence of humans and robots on the Moon requires the development of durable habitats for space missions. In recent decades, in situ resource utilization (ISRU) for construction materials has been recognized as a viable option. However, the addition of nanomaterials, which exhibit a high strength-to-weight ratio, has not been incorporated with the ISRU framework in space missions. This paper investigates the impact of carbon nanotubes (CNTs) on lunar simulant-based geopolymers’ compressive strength and water retention. The evaluation of water retention indicates another potential in water recapturing capability. In this study, CNTs can enhance the mechanical properties of lunar simulant-based geopolymer. Two lunar simulants were used, representing the Highland and Mare regions of the Moon. Experimental variables included CNT concentration, four curing regimes (ambient curing, two oven-curing methods, and microwave radiation), and dispersion time in aqueous solutions. Results showed that CNTs can positively influence both strength gain and water retention during curing regimes, but the extent of influence appears to be dependent on simulant type and curing regime. The Highland simulant consistently outperformed the Mare simulant in oven-curing regimes from a strength perspective, regardless of CNT presence. The strength benefits of CNTs were more pronounced at ambient curing temperatures. Even under poor curing conditions—where water availability may be limited at temperatures of 80 °C—CNTs aid in retaining water within the geopolymer matrix, leading to improved strength compared to counterparts. Under the same conditions, a higher concentration of CNTs further confirmed their role in water retention during geopolymerization, with consistently greater water retention observed in samples containing CNTs. Additionally, microwave radiation was explored as an alternative to conventional oven drying, showing potential for reducing curing duration. Finally, the findings suggest that combining CNTs and microwave radiation could enhance water recovery and reuse, contributing to the development of high-strength infrastructure materials on the Moon with reduced energy and cost requirements. Full article

The establishment of the patterns of formation and structure of mesh polymers, as well as the methods of their controlled synthesis, makes it possible to rationally manage the technological processes of obtaining and processing materials based on them. This paper determines the possibility of directional variation in the parameters of the molecular grid of epoxy and polyester resin copolymers using a polyamide hardener. For this purpose, the influence of temperature regimes on the curing mixing technology of the original components was studied. The values of the Huggins constants were initially calculated. For this purpose, the swelling of copolymers in chloroform, xylene, dimethylformamide and acetone was studied. Taking into account the thermodynamic criteria, based on the results obtained, a solvent was selected that provides optimal swelling conditions for the synthesized copolymer. Experimental data describing the process of collecting copolymer samples were obtained. Using the Florey equation, the parameters of the structural grids of the developed polymer compositions were calculated. Full article

This study delves into the effects of carbonation curing and autoclave–carbonation curing on the properties of calcium oxide–belite–calcium sulfoaluminate (CBSAC) cementitious material aerated concrete. The objective is to produce aerated concrete that adheres to the strength index in the Chinese standard GB/T 11968 while simultaneously mitigating CO₂ emissions from cement factories. Results show that the compressive strength of CBSAC aerated concrete with different curing regimes (autoclave curing, carbonation curing, and autoclave–carbonation curing) can reach 4.3, 0.8, and 4.1 MPa, respectively. In autoclave–carbonation curing, delaying CO₂ injection allows for better CO₂ diffusion and reaction within the pores, increases the carbonation degree from 19.1% to 55.1%, and the bulk density from 603.7 kg/m³ to 640.2 kg/m³. Additionally, microstructural analysis reveals that delaying the injection of CO₂ minimally disrupts internal hydrothermal synthesis, along with the formation of calcium carbonate clusters and needle-like silica gels, leading to a higher pore wall density. The industrial implementation of autoclavecarbonation curing results in CBSAC aerated concrete with a CO₂ sequestration capacity ranging from 40 to 60 kg/m³ and a compressive strength spanning from 3.6 to 4.2 MPa. This innovative approach effectively mitigates the carbon emission pressures faced by CBSAC manufacturers. Full article

Qualitative and quantitative aspects of the formation of various types of phase structures, sizes and compositions were considered. For the studied polycaprolactone–epoxy resin/4,4′-diaminediphenylsulfone system, a phase diagram characterized by amorphous separation with a lower critical solution temperature was constructed and its evolution was traced with increasing conversion degree of epoxy groups. A method is proposed for determining the temperature–concentration parameters that determine the type of phase structure of composite materials, based on the optical interferometry method. All types of phase structures and features of structure formation in the phase reversal region and at its boundaries have been studied using optical and scanning electron microscopy methods. The dimensions of the structural elements were determined and their correlation with the temperature and concentration regimes of the system’s curing was established. The composition of phases in cured compositions was studied using FTIR spectroscopy, DSC and scanning electron microscopy. It is shown that by varying the temperature–concentration parameters of curing reactive thermoplastic systems, it is possible to specifically regulate the type of phase structure, phase sizes and their composition, which determine the operational properties of the material. Full article