Search Results (846)

(1) Background: Electroplating sludge (ES) and water-washed municipal solid waste incineration fly ash (WFA) are classified as hazardous solid wastes, and their conventional disposal approaches trigger severe heavy metal pollution. Conventional colored ceramic glazes heavily depend on virgin mineral ores and synthetic colorants; therefore, sustainable alternative feedstocks are urgently required. (2) Methods: WFA and ES were compounded with red clay and shale to fabricate low-environmental-risk black glazes. Material microstructures and phase compositions were characterized via X-ray diffraction (XRD) and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). Single-factor experiments were conducted to optimize the raw material ratios and sintering schedules, while heavy metal leaching toxicity was evaluated following national standard HJ/T 300-2007. (3) Results: The optimal composite formulation consists of 26.1 wt% WFA, 30.4 wt% ES, 26.1 wt% red clay and 17.4 wt% shale. Smooth, defect-free pure black glaze specimens were fabricated after sintering at 1280 °C for 90 min under a weak reducing atmosphere. Heavy metal ions were stably immobilized within the silicate crystalline and amorphous glass phases, with all leaching concentrations well below the national standard thresholds. (4) Conclusions: The proposed technology achieves the high-value co-valorization of two hazardous solid wastes while producing low-environmental-risk colored ceramic glazes, providing a feasible strategy for solid waste recycling and the low-carbon development of the ceramic manufacturing industry. Full article

The valorization of agricultural residues and post-consumer plastics is critical for achieving a circular economy. This study presents a sustainable pathway to fabricate eco-friendly acoustic panels by melt-blending recycled high-density polyethylene (rHDPE) with 10–50 wt% rice straw waste-derived nanofillers. Multi-stage chemical refinement (10% NaOH mercerization and H₂O₂ bleaching) before ball milling isolated nanofibrils under 50 nm. XRD analysis showed a crystallinity index increase from 37.0% (untreated) to 67.2% (bleached), confirming amorphous phase removal. FTIR and SEM verified successful delignification and excellent interfacial wetting. Consequently, the 50 wt% bleached cellulose composite exhibited the highest reinforcement, increasing flexural strength by 126% and flexural modulus by 132.6% over neat rHDPE. The hydrophilic framework enhanced environmental biodegradability, yielding a 15.18% maximum weight loss after a 90-day soil burial test, providing a viable end-of-life alternative to persistent synthetics. To optimize acoustic utility, a 1.76% geometric micro-perforation ratio was engineered into the panels. Backed by a 6 cm air cavity, the 50 wt% untreated composite achieved an outstanding peak sound absorption coefficient of 0.98 at a low frequency of 400 Hz. These findings establish these high-filler bio-nanocomposites as high-performance, low-carbon alternatives for noise control in construction and automotive infrastructure. Full article

This study investigates the nanomechanical response of aluminum substrates coated with crystalline or amorphous equiatomic FeNiCrCo compositionally complex alloy (CCA) layers using molecular dynamics nanoindentation. We evaluated the influence of coating microstructure and pre-relaxation via Monte Carlo/molecular dynamics (MC/MD) on deformation behavior at shallow (35 Å) and deep (65 Å) indentation depths. The relaxation process is critical for equilibrating internal stresses and homogenizing the initial stress field in amorphous phases, while preventing chaotic defect multiplication in crystalline lattices, yet it simultaneously promotes Fe and Cr surface segregation consistent with the equilibrium chemical short-range ordering of the alloy. The results reveal distinct deformation mechanisms: crystalline coatings exhibit higher peak indentation forces of about 300 ± 16 eV/Å characterized by discrete force fluctuations indicative of localized plastic events, while amorphous coatings show lower peak loads (~170–220 ± 12 eV/Å), corresponding to a reduction in load-bearing capacity of roughly 25%–40%, and smooth, continuous deformation governed by shear transformation zones. Notably, in amorphous systems, pressure-induced local crystallization occurs under load, with ordered FCC/HCP regions persisting after unloading, indicating partial irreversibility of the phase transition. Upon deep indentation into the substrate, the amorphous system exhibits a sharp increase in stiffness due to substrate compaction, whereas the crystalline system maintains high load-bearing capacity with reduced defect density in the relaxed state compared to the non-relaxed counterpart. Relaxation significantly reduces force-curve fluctuations in both systems, enhancing the stability of the mechanical response. Compared with uncoated aluminum, which exhibits extensive twin propagation and deep defect penetration, the FeNiCrCo-coated systems approximately halve the defect penetration depth and reduce the defective-atom volume fraction in the substrate by about a factor of two, thereby more effectively confining plastic deformation and preserving substrate integrity under the simulated conditions. These findings demonstrate that the synergy between coating crystallinity and rigorous relaxation protocols governs stress distribution patterns—localized hotspots in amorphous phases versus extended networks in crystalline ones—providing key insights for designing advanced protective coating–substrate systems with optimized mechanical performance. Full article

ZERODUR glass-ceramic is widely used in ultra-precision optical components because of its extremely low thermal expansion and excellent dimensional stability. However, its two-phase microstructure, composed of crystalline and amorphous phases with different mechanical properties, may cause non-uniform material removal during magnetorheological polishing, thereby limiting further improvement of nanoscale surface quality. To address this issue, this study investigates the effect of oxide abrasives on the surface homogenization of ZERODUR. A single-particle abrasive–workpiece contact model based on modified Hertz contact theory and elastoplastic contact analysis was established to compare the indentation responses of CeO₂, SiO₂, and ZrO₂ abrasives in the two constituent phases. Magnetorheological polishing experiments were conducted under identical process parameters, and the polished surfaces were characterized by AFM over scan areas of 2 μm × 2 μm, 5 μm × 5 μm, and 10 μm × 10 μm. The results show that all three abrasives improved the surface quality of the ring-polished substrate, with ZrO₂ achieving the best surface homogenization performance. The lowest roughness, Ra = 0.104 nm, was obtained at a 2 μm field of view, and the ZrO₂-polished surface showed more stable roughness evolution across different scan sizes than the CeO₂- and SiO₂-polished surfaces. These results indicate that the elastic modulus, hardness, and mechanical compatibility of abrasives with ZERODUR play key roles in governing contact stress, indentation behavior, and final surface quality. This work addresses the lack of mechanistic understanding of abrasive-dependent surface homogenization in the magnetorheological polishing of two-phase ZERODUR glass-ceramic. The main innovation is the integration of contact-mechanics-based abrasive–workpiece modeling with multi-scale AFM characterization to clarify how abrasive mechanical compatibility affects nanoscale surface uniformity and to guide abrasive selection for ultra-smooth optical manufacturing. Full article

CoCrNiTiAl_x high-entropy alloy films with varied Al contents were fabricated on 42CrMo steel substrates via magnetron sputtering. By adjusting the sputtering power of the Al target, an investigation was systematically carried out to explore the effect of different Al contents on the microstructural evolution, mechanical properties, and corrosion resistance of the film, with the underlying synergistic mechanism governing these properties being elucidated. With increasing Al content, the film microstructure gradually transforms from an amorphous phase at low Al contents to a nanocrystalline–amorphous composite structure, until it is converted into the BCC phase, and the film’s crystallinity exhibits a trend of first increasing and then decreasing. In terms of mechanical properties, the film hardness is significantly enhanced from 7.6 ± 1.3 GPa to 18.9 ± 1.1 GPa with increasing Al content, while the toughness gradually declines. Wear tests show that the film wear rate first decreases and then increases with rising Al content, reaching a minimum of 2.06 × 10⁻⁵ mm³/N·m. The superior protective state, characterized by a corrosion potential reaching −361.2 mV and corrosion current density dropping to 1.12 μA/cm², arises from the generation of an integrated, consistently structured composite passivation barrier in 3.5 wt.% solution. This study confirms that appropriate Al doping can synergistically optimize the microstructure, mechanical properties, and corrosion resistance of CoCrNiTiAl_x films, providing experimental and theoretical support for the compositional design and engineering applications of high-performance high-entropy alloy protective films. Full article

This study provides a comprehensive characterization of carbon dust adhesion on the anode surface induced by the anode effect (AE) in the Hall–Héroult process. The primary objective was to verify the hypothesis of electrophoretic carbon particle transport and its subsequent stabilization on the electrode substrate. Unlike previous studies conducted in horizontal configurations where gravitational sedimentation could interfere with observations, this research employs a unique vertical electrode setup to provide direct physical evidence of purely electrophoretic transport. Authentic industrial carbon dust was used as a tracer material, its presence on the high-purity graphite surface being definitively confirmed through the detection of trace markers (Mg, Ca) via SEM-EDS. The multiscale structural analysis revealed that spike initiation occurs through a dynamic arc-induced nucleation mechanism. Morphological observations suggest that micro-arc discharges during the AE provide the extreme localized energy for direct carbon-to-carbon “welding,” creating a conductive, porous scaffold on the vertical anode wall. XRD analysis identified crystalline cryolite (Na₃AlF₆) and chiolite (Na₅Al₃F₁₄) within this structure. It was demonstrated that these fluoride phases represent the solidified product of molten, acidic electrolyte infiltration into the carbonaceous matrix via capillary action, rather than acting as binders that crystallize during the process. Raman spectroscopy confirmed the disordered, amorphous nature of the captured dust (high D-band intensity), distinguishing it from the highly ordered graphite substrate. Confocal microscopy visualized the topographical evolution from isolated clusters to interconnected three-dimensional “islands” as a function of AE duration. The results demonstrate that the anode effect serves as a critical flashpoint where synergistic electrophoretic forces and localized thermal anomalies initiate the growth of stable, conductive carbon–matrix composite spikes, providing new insights for mitigating current efficiency losses in industrial smelters. Full article

Traditional tunable Bragg waveguide grating filters, which rely on thermo-optic or carrier effects, often face limitations such as high energy consumption, low tuning efficiency, and difficulty in achieving independent multi-parameter control. To overcome these bottlenecks, this work proposes a novel optical waveguide filter based on the heterogeneous integration of silicon nitride and the phase-change material Sb₂Se₃. The device leverages the substantial refractive index contrast between crystalline and amorphous states of Sb₂Se₃ to construct a programmable Bragg grating within the thin film layer. This is realized through laser-induced phase transition method, enabling nonvolatile manipulation of the light field. Simulation results indicate that the independent tuning of central wavelength over 19.2 nm range was achieved by adjusting the grating width and ripple width simultaneously. Likewise, the extinction ratio could be independently controlled over 22.3 dB through coordinated adjustments of the grating length and position shift. Beyond its tuning capabilities, the proposed device theoretically exhibits exceptional performance characteristics, including an ultra-low insertion loss of 0.1 dB and strong side lobe suppression. These advantages highlight the potential of this approach to provide a low energy consumption, multifunctional solution for integrated photonic devices, offering a promising pathway for the next generation of programmable photonic integrated circuits. Full article

This study presents an archaeometric characterization of fifteen blue-and-white Chinese porcelain sherds (17^th–19^th centuries) from the Jingdezhen, Anxi, and Dehua kiln systems, compared with fragments recovered from the Santana Convent (Lisbon), particularly eighteenth-century materials. A combination of non-invasive, minimally invasive and micro-destructive techniques, including Ground-State Diffuse Reflectance Spectroscopy (GSDR), X-ray Photoelectron Spectroscopy (XPS), micro-Raman spectroscopy, X-ray Fluorescence (XRF), X-ray diffraction (XRD), and stereomicroscopy, was employed to investigate cobalt pigments, glaze composition, firing conditions, and provenance indicators. The results reveal systematic differences between dark- and light-blue glazes, reflecting distinct pigment-processing technologies or simple concentration effects inducing different cobalt coordination environments and/or oxidation states. Raman spectroscopy confirms that cobalt occurs mainly as Co²⁺ ions dissolved in the amorphous silicate glaze matrix. No Raman-detectable crystalline cobalt silicate or cobalt aluminate phases were identified. XRF and XPS analyses show elevated Mn/Co and Fe/Co ratios combined with extremely low arsenic contents, suggesting the predominant use of domestic Chinese cobalt sources. XRD analyses identified quartz, mullite, and minor anorthite, consistent with traditional high-fired hard-paste porcelain technology. Dark-blue radiating star-shaped colored radiating features, particularlyfrequent in Dehua porcelains, were also identified in selected Santana Convent samples, suggesting their attribution to Dehua kiln production and demonstrating the value of glaze defects as complementary provenance markers. Full article

Background: Compomer materials combine the advantages of composite resins and glass ionomer cements, including fluoride release, durability, and aesthetics. This study evaluated the effects of silver nanoparticles (nAg⁰) and copper oxide (CuO) particles on fluoride ions release and the structural properties of a commercially available compomer. Methods: Compomer discs modified with 0.125 wt.%, 0.25 wt.%, and 0.5 wt.% nAg⁰ or CuO were prepared and analyzed in demineralized water and artificial saliva at various pH levels for 168 h. Fluoride release was measured using a fluoride-selective electrode, while structural and morphological properties were examined using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Results: Under most of the tested conditions, the modified materials exhibited higher fluoride release than the unmodified compomer, with the greatest increase typically observed at higher additive concentrations. XRD analysis confirmed the presence of crystalline phases of Ag⁰ and CuO while maintaining the amorphous nature of the compomer matrix. SEM observations revealed better particle dispersion at lower additive concentrations and increased agglomeration at a 0.5% content. Conclusions: These results indicate that the incorporation of nAg⁰ and CuO particles may enhance the fluoride-releasing potential of compomer materials; however, further studies are necessary to evaluate their mechanical, antibacterial, cytotoxic, and aesthetic properties prior to clinical application. Full article

We report a low-temperature plasma–liquid synthesis of crystalline β-Ga₂O₃ nanoparticles directly from aqueous solution. Pulsed discharge plasma bubbles generate reactive species that drive in situ dehydration and crystallization, bypassing the high-temperature calcination required by conventional methods. By varying the carrier gas, we tune morphology from uniform nanorice structures (He, Ar, and N₂) to amorphous microspheres (O₂ and air), revealing how plasma composition governs interfacial hydroxyl radical chemistry and growth kinetics. This approach demonstrates that localized plasma heating and reactive-species flux can achieve phase-selective oxide crystallization under ambient conditions, establishing plasma bubble reactors as a broadly applicable, low-temperature route for direct aqueous synthesis of crystalline wide-bandgap oxides that bridge solution chemistry and plasma nanomaterials design. Full article

Adsorption is a promising technology for phosphate removal to alleviate eutrophication. In this study, thermally modified calcium aluminate decahydrate (TCAH) was prepared via low-temperature thermal treatment of calcium aluminate decahydrate (CAH₁₀) to develop a cost-effective and high-performance phosphate adsorbent. The optimal modification temperature was determined to be 120 °C, which reduced the crystallinity of CAH₁₀, enhanced its porosity, and induced the formation of amorphous calcium aluminate phases. Batch adsorption experiments showed that TCAH exhibited a maximum adsorption capacity of 199.80 mg P/g at 25 °C. The adsorption kinetics followed the pseudo-second-order model, while the adsorption isotherms were well fitted by the Redlich–Peterson model. TCAH maintained high removal efficiency over a wide pH range of 3.0–11.0 and showed high selectivity against common coexisting anions. Characterizations using SEM-EDS, XRD, FTIR and XPS suggested that phosphate removal by TCAH was dominated by synergistic amorphous precipitation and inner-sphere complexation. In tests with real phosphorus-releasing liquor derived from excess sludge, TCAH achieved nearly complete phosphate removal at a dosage of 5 g/L within 6 h. Owing to its readily available raw materials, low preparation temperature, and outstanding phosphate capture performance, TCAH is a promising candidate for efficient phosphate capture and recovery from wastewater. Full article

We present a family of compact, programmable wavelength demultiplexers enabled by an etchless silicon nitride platform integrated with the low-loss phase-change material Sb₂Se₃. Using topology optimization (LumOpt) with a p-norm (p = 2) figure-of-merit defined over a 10 nm bandwidth, we design several devices within a common 24 × 24 μm² design region: single-wavelength routers (1530, 1550, 1570, 1590 nm), two-channel (1550/1570 nm), three-channel (1530/1550/1570 nm), and four-channel (1530–1590 nm) coarse wavelength-division demultiplexers, all sharing the same input/output waveguide configuration. Simulation results show that all devices achieve low insertion loss at target wavelengths (peak transmission better than −1.21 dB across all channels), high average transmission over the respective 10 nm bands (typically within 0.1 dB of the peak), and suppressed crosstalk (worst case below −11.52 dB). Leveraging the reversible amorphous-to-crystalline phase transition of Sb₂Se₃ via laser pulses, all devices support post-fabrication reconfiguration, overcoming the static functionality of conventional etched photonic circuits. This work establishes a scalable, software-defined platform that combines inverse design and phase-change materials for high-density, reconfigurable wavelength-routing photonic integrated circuits. Full article

The application of silk sericin as a polymeric biomaterial has recently gained interest, although its film was found to be fragile, exhibiting brittleness when subjected to relatively slight stress, and it also displayed higher water solubility. This study focused on the enhanced physico-mechanical properties of the three films obtained by the crosslinking of sericin protein from three silkworm cocoons with poly (vinyl alcohol) (PVA) to reduce phase separation and solubilization of the films by promoting miscibility between sericin and PVA. The findings demonstrated how crosslinking with glutaraldehyde enhanced thermal stability and tensile strength and controlled the solubility of the three sericin–PVA films. The sericin from G. postica, G. rufobrunnea, and Argema mimosae is composed of serine, aspartic acid, and glutamic acid, which make up 80% of the total polar amino acids. X-ray diffraction (XRD) patterns showed that sericin–PVA films have semicrystalline features, representing amorphous and crystalline regions. The XRD results also indicated that the Saturniidae sericin–PVA film (Sat-SPF), Gonometa postica sericin–PVA film (GP-SPF), and Gonometa rufobrunnea sericin–PVA film (GR-SPF) have crystallinity percentages of 66.4%, 55.9%, and 17.7%, respectively. The moisture vapor transmission rate (MVTR) values observed in this study ranged from 991.2 to 5160 g/m²/24 h, indicating that these films can effectively regulate moisture levels in wounds. The swelling capacity of the three sericin–PVA composite films depends on the crosslinking density of their structures and was also found to be sensitive to the pH of the aqueous media, demonstrating their hydrophilic nature and potential use in drug delivery systems. The water vapor permeability of sericin–PVA films increased with higher environmental relative humidity (RH) and moisture content within the films. The elongation at break for GP-SPF (107.2% ± 3.1) and Sat-SPF (73.0% ± 4.1) was significantly higher than in GR-SPF (29.3% ± 2.3). However, their tensile strength and elastic modulus were lower than those of GR-SPF. These results show that the number of polar groups (amino and hydroxyl groups) from both sericin and PVA influences all the properties of the sericin–PVA composite films. The three sericin–PVA solutions were found to have antibacterial efficacy against three Gram-positive and one Gram-negative bacteria over 24 h. Scanning electron microscopy (SEM) images revealed a rough surface with a granular network pattern, which supports the potential use of sericin–PVA films for cell adhesion and proliferation, which are essential for biomedical wound dressing applications. Full article

Metasurfaces have emerged as a powerful platform for subwavelength light manipulation, attracting widespread interest for their potential to replace bulky optical components. However, most metasurfaces are statically designed with fixed functionalities. Here, we demonstrate a high-efficiency tunable meta-waveplate by heterogeneously integrating a phase-change Sb₂Se₃ layer with a piezoelectric MEMS mirror. Leveraging the reversible amorphous–crystalline transition of Sb₂Se₃, combined with MEMS-enabled nanoscale air gap tuning, the metasurface achieves dynamic switching among zero-, half-, and quarter-waveplate functionalities at the communication wavelength of 1550 nm. The device exhibits stable polarization conversion performance under various rotation angles. Furthermore, we developed a nano-quarter-waveplate library on this platform, which provides extensive phase control over the reflected field and enables programmable beam deflection. This tunable architecture opens new avenues for adaptive photonics with dynamically switchable functionalities. Full article

Mineral exploration in the Iberian Pyrite Belt follows increasingly deeper targets. The present study introduces an innovative methodology for the detection and identification of blind metallic mineral deposits, in particular volcanogenic massive sulfides based on surface rock coatings. This approach follows the identification pathways of upward metal escape routes and metal distribution in rock fractures located in different anisotropic or isotropic planes above the Neves-Corvo VMS deposit ore lenses, using VP-SEM-EDS and XRD. Coatings are dominated by poorly crystalline to amorphous phases, with goethite and birnessite as the main Fe- and Mn-bearing minerals. Copper, zinc and lead are systematically enriched in coatings developed above or near the ore bodies, reflecting chalcopyrite, sphalerite and galena acidic leaching. Tin shows a restricted and heterogeneous distribution, while Ni and Co display no systematic relationship with the ore bodies. Barium and late Ba–Pb–(Zn) mineralization along fault zones record VMS mineralization. Lead isotopic coating signatures overlap those of IPB massive sulfide deposits, confirming a dominant VMS-derived contribution. Fe–Mn coatings were formed by precipitation from ascending meteoric fluids that leached metals from massive sulfides, their alteration halos, and surrounding lithologies, preserving the geochemical footprint of buried mineralization. This approach constitutes a new patented exploration tool. Full article