Search Results (277)

As a typical porous medium, unsaturated loess demonstrates critical hydro-mechanical coupling properties that fundamentally influence geohazard mitigation, groundwater resource evaluation, and foundation stability in geotechnical engineering. This investigation develops a novel theoretical framework to overcome the limitations of existing models in converting electrical resistivity tomography (ERT) profiles into water content distributions for unsaturated loess through quantitative inversion modeling. Systematic laboratory investigations on remolded loess specimens with controlled density and water content conditions revealed distinct resistivity–water interaction mechanisms. A characteristic two-stage decay pattern was identified: resistivity exhibited an exponential decrease from 420 Ω·m (water saturation (S_w = 10%)) to 90 Ω·m (S_w = 40%), followed by asymptotic stabilization at S_w ≥ 40%. The derived quantitative correlation provides a robust mathematical basis for water content profile inversion. Field validation through integrated ERT and borehole data demonstrated exceptional predictive accuracy in shallow strata (<20 m depth), achieving mean absolute errors of <5%. However, inversion reliability decreased with depth (>20 m), primarily attributed to density-dependent charge transport mechanisms. This underscores the necessity of incorporating coupled thermo-hydro-mechanical processes for deep-layer characterization. This study provides a robust framework for engineering applications of ERT in loess terrains, offering significant advancements in geotechnical monitoring and geohazard prevention. Full article

Upon reaching stabilized production in waterflooded reservoirs, waterflood performance curves are conventionally used to predict technically recoverable reserves (TRRs). However, as reservoirs enter high water-cut stages, the relationship between the relative permeability ratio and saturation becomes nonlinear, causing deflection in waterflood performance curves. This leads to systematic overestimation of both predicted TRR and ultimate recovery factors. To overcome these limitations in conventional TRR prediction methods, this study establishes a novel relative permeability ratio-saturation relationship based on characteristic relative permeability curve behaviors. The proposed model is validated for three distinct fluid-rock interaction types. We further develop a permeability-driven forecasting model for oil production rates and water cuts. Comparative analyses with a conventional waterflood curve methodology demonstrate significant accuracy improvements. The results show that while traditional methods predict TRR ranging from 78.40 to 92.29 million tons, our model yields 70.73 million tons—effectively resolving overestimation issues caused by curve deflection during high water-cut phases. This approach establishes a robust framework for determining critical development parameters, including economic field lifespan, strategy adjustments, and ultimate recovery factor. Full article

This study aims to investigate the processes associated with mass movements and their relationship with the behavior of the Amazon River delta-estuary (ADE) wetlands. The methodological approach involves using water spectral indices and ground-penetrating radar (GPR) to diagnose areas of soil water saturation and characterize regions affected by mass movements in Amazonian cities. It also involves identifying areas of critical saturation content and consequent mass movements. Analysis of risk and land use data revealed that the affected areas coincide with zones of high susceptibility to mass movements induced by water. The results showed the following: the accumulated annual precipitation ranged from 70.07 ± 55.35 mm·month⁻¹ to 413.34 ± 127.51 mm·month⁻¹; the response similarity across different sensors obtained an accuracy greater than 90% for NDWI, MNDWI, and AWEI for the same targets; and a landfill layer with a thickness variation between 1 and 2 m defined the mass movement concentration in Abaetetuba city. The interaction between infiltration, water saturation, and human-induced land alteration suggests that these areas act as wetlands with unstable dynamics. The analysis methodology developed for this study aimed to address this scenario by systematically mapping areas with mass movement potential and high-water saturation. Due to the absence of geological and geotechnical data, remote sensing was employed as an alternative, and in situ ground-penetrating radar (GPR) evaluation was suggested as a means of investigating the causes of a previously observed movement. Full article

Corrosion-related failures have emerged as a critical driver of premature support bolt failures in underground mines, emphasizing the urgency of understanding the phenomenon with respect to enhancing safety in underground environments. This study investigated key factors influencing bolt degradation through extensive experimental evaluation of cable bolts in simulated underground bolt environments. Multi-stranded cable specimens were exposed to saturated clay, coal, mine water, and grout/cement environments. Water samples were collected weekly from critical packing sections and analyzed for pH, electrical conductivity, and dissolved oxygen. The mineralogy and atmospheric conditions were identified as principal corrosion factors, and clay-rich and coal matrices accelerated corrosion, linked to high ion mobility and oxygen diffusion. Secondary factors correlated context-dependently: pH was negatively associated with corrosion in mineral-packed environments, while conductivity was correlated with non-mineral matrices. Notably, multi-stranded cables exhibited higher localized galvanic corrosion in inter-strand zones, highlighting design vulnerabilities. This work provides pioneering evidence that geological conditions are primary drivers for corrosion-related failures, offering actionable guidance for corrosion mitigation strategies in mining infrastructure. Full article

In order to accurately analyze the liquefaction and the reinforcement effect of saturated silty and sandy soils treated by dynamic compaction, a hydro-mechanically coupled explicit analysis method was proposed. The method, in combination with the cap model, was carried out using the Abaqus finite element software. Then, parametric analysis was carried out by means of the development and dissipation of excess pore water pressure, effective soil stress and the relative reinforcement degree. And the effects of the drop energy, tamper radius and soil permeability on the liquefaction zone and soil improvement of saturated soil were examined. The results demonstrated that the liquefaction zone and the effective reinforcement were determined by the drop energy rather than the permeability or tamper radius. A 2.5-times increase in drop energy can increase the maximum liquefaction depth by 1.1 m (4.6 m to 5.7 m) and the effective reinforcement depth (I_r ≥ 0.08) by 0.6 m (1.2 m to 1.8 m). It is recommended that the reinforcement effect should be improved by a lower drop energy with a low drop height and a heavy tamper in actual projects. It should also be noted that a smaller tamper radius was conducive to local soil improvement but also generated higher localized excess pore water pressures. Soil permeability critically controls liquefaction potential and excess pore water pressure dissipation. Low permeability soils experienced significant liquefaction depths and slower consolidation, whereas high permeability gravels (k = 10⁻² m/s) showed minimal liquefaction and great improvements in depth. To diminish the effect of the underground water, the gravel cushions should be used to drain pore water out before dynamic compaction. Full article

The dynamic non-equilibrium effect (DNE) describes the non-unique character of saturation–capillary pressure relationships observed under static, steady-state, or monotonic hydrodynamic conditions. Macroscopically, the DNE manifests as variations in soil hydraulic characteristic curves arising from varying hydrodynamic testing conditions and is fundamentally governed by soil matrix particle size distribution. Changes in the DNE across porous media with discrete particle size fractions are investigated via stepwise drying experiments. Through quantification of saturation–capillary pressure hysteresis and DNE metrics, three critical signatures are identified: (1) the temporal lag between peak capillary pressure and minimum water saturation; (2) the pressure gap between transient and equilibrium states; and (3) residual water saturation. In the four experimental sets, with the finest material (Test 1), the peak capillary pressure consistently precedes the minimum water saturation by up to 60 s. Conversely, with the coarsest material (Test 4), peak capillary pressure does not consistently precede minimum saturation, with a maximum lag of only 30 s. The pressure gap between transient and equilibrium states reached 14.04 cm H₂O in the finest sand, compared to only 2.65 cm H₂O in the coarsest sand. Simultaneously, residual water saturation was significantly higher in the finest sand (0.364) than in the coarsest sand (0.086). The results further reveal that the intensity of the DNE scales inversely with particle size and linearly with wetting phase saturation (Sw), exhibiting systematic decay as Sw decreases. Coarse media exhibit negligible hysteresis due to suppressed capillary retention; this is in stark contrast with fine sands, in which the DNE is observed to persist in advanced drying stages. These results establish pore geometry and capillary dominance as fundamental factors controlling non-equilibrium fluid dynamics, providing a mechanistic framework for the refinement of multi-phase flow models in heterogeneous porous systems. Full article

Concrete resistivity is a critical parameter for assessing durability and monitoring the structural health of reinforced concrete. This study systematically evaluates the effects of the water-to-cement (w/c) ratio, saturation ratio (SR), and temperature on concrete resistivity using three different predictive models: linear regression, cubic Support Vector Machine (SVM), and Gaussian Process Regression (GPR). Each model was independently trained and tested to assess its ability to capture the nonlinear relationships between these key parameters. Experimental results show that resistivity decreases significantly under increasing load due to geometrical effects. For a w/c ratio of 0.4, resistivity decreases by −12.48% at 100% SR and by −6.68% at 60% SR under 20% loading. Higher w/c ratios (0.5 and 0.6) exhibit more pronounced resistivity reductions due to increased porosity and ion mobility, with a maximum decrease of −13.68% for w/c = 0.6. Among the developed predictive models, the Matern 5/2 Gaussian process regression (GPR) model demonstrated the highest accuracy, achieving an RMSE of 5.21, R² of 0.99, MSE of 27.19, and MAE of 3.40, significantly outperforming the other approaches. Additionally, a permutation importance analysis revealed that the saturation ratio (SR) is the most critical variable influencing resistivity, followed by the water–cement ratio, while temperature has the least impact. These findings provide valuable insights into the durability assessment and corrosion prevention of reinforced concrete, offering practical implications for the optimization of material design and structural health monitoring in civil engineering. Full article

This study presents the first quantitative comparison of catastrophic phase inversion behavior of water-in-oil emulsions stabilized by nanocrystalline cellulose (NCC) and molecular surfactants with different headgroup charge types: anionic (sodium dodecyl sulfate referred to as SDS), cationic (octadecyltrimethylammonium chloride referred to as OTAC), nonionic (C12–14 alcohol ethoxylate referred to as Alfonic), and zwitterionic (cetyl betaine referred to as Amphosol). By using conductivity measurements under controlled mixing and pendant drop tensiometry, this study shows that NCC markedly delays catastrophic phase inversion through interfacial jamming, whereas surfactant-stabilized systems exhibit concentration-dependent inversion driven by interfacial saturation. Specifically, NCC-stabilized emulsions exhibited a nonlinear increase in the critical aqueous phase volume fraction required for inversion, ranging from 0.253 (0 wt% NCC) to 0.545 (1.5 wt% NCC), consistent with enhanced resistance to inversion typically associated with the formation of rigid interfacial layers in Pickering emulsions. In contrast, surfactant-stabilized systems exhibited a concentration-dependent inversion trend with opposing effects. At low concentrations, limited interfacial coverage delayed inversion, while at higher concentrations, increased surfactant availability and interfacial saturation promoted earlier inversion and favored the formation of oil-in-water structures. Pendant drop tensiometry confirmed negligible surface activity for NCC, while all surfactants significantly lowered interfacial tension. Despite its weak surface activity, NCC imparted strong coalescence resistance above 0.2 wt%, attributed to steric stabilization. These findings establish distinct mechanisms for governing phase inversion in particle- versus surfactant-stabilized systems. To our knowledge, this is the first study to quantitively characterize the catastrophic phase inversion behavior of water-in-oil emulsions using NCC. This work supports the use of NCC as an effective stabilizer for emulsions with high internal phase volume. Full article

The safe disposal of high-level radioactive waste (HLW) is imperative for sustaining China’s rapidly expanding nuclear power sector, with deep geological repositories requiring rigorous site evaluation via underground research laboratories (URLs). This study presents a controlled-source audio-frequency magnetotellurics (CSAMT) survey at the Xinchang site in China’s Beishan area, a region dominated by high-resistivity metamorphic rocks. To overcome electrical data acquisition challenges in such resistive terrains, salt-saturated water was applied to transmitting and receiving electrodes to enhance grounding efficiency. Using excitation frequencies of 9600 Hz to 1 Hz, the survey achieved a 1000 m investigation depth. Data processing incorporated static effect removal via low-pass filtering and smoothness-constrained 2D inversion. The results showed strong consistency between observed and modeled data, validating inversion reliability. Borehole correlations identified a 600-m-thick intact rock mass, confirming favorable geological conditions for URL construction. The study demonstrates CSAMT’s efficacy in characterizing HLW repository sites in high-resistivity environments, providing critical geophysical insights for China’s HLW disposal program. These findings advance site evaluation methodologies for deep geological repositories, though integrated multidisciplinary assessments remain essential for comprehensive site validation. This work underscores the feasibility of the Xinchang site while establishing a technical framework that is applicable to analogous challenging terrains globally. Full article

Light non-aqueous phase liquids (LNAPLs) are significant groundwater contaminants whose migration in aquifers is governed by dynamic groundwater level fluctuations. This study establishes a multiphase flow coupling model integrating hydraulic, gaseous, LNAPL, and chemical fields, utilizing continuous multi-point water level data to quantify water table orientation variations. Key findings demonstrate that (1) LNAPL migration exhibits directional dependence on water table orientation: flatter gradients reduce migration rates, while steeper gradients accelerate movement. (2) Saturation dynamics correlate with gradient steepness, showing minimal variation under flattened gradients but significant fluctuations under steeper conditions. (3) Water table reorientation induces vertical mixing, homogenizing temperature distributions near the interface. (4) Dissolution and volatilization rates of LNAPLs decrease progressively with water table fluctuations. These results elucidate the critical role of hydraulic gradient dynamics in controlling multiphase transport mechanisms at LNAPL-contaminated sites, providing insights for predictive modeling and remediation strategies. Full article

The cryopreservation of limited sperm samples, especially those retrieved from patients, poses significant challenges due to the small number of viable cells available for freezing. Traditional microliter cryopreservation methods are fraught with difficulties, as thawed sperm cells become nearly impossible to locate under a microscope due to their mobility and the multiple focal planes presented by larger drops. This search time is critical, as sperm cells enter a state of decline post thaw. Conversely, when sperm cells are cryopreserved in nanoliter volumes, they can be easily discovered but do not survive the freezing and thawing processes entirely. This phenomenon is attributed to the diffusion of water molecules from the droplet into the surrounding oil, which, while designed to limit evaporation, inadvertently increases solute concentrations in the aqueous environment, leading to cellular desiccation. This article elucidates the mechanisms underlying this lethal diffusion effect and presents a novel approach for freezing in nanoliter volumes, which has demonstrated significantly improved survival rates through carefully optimized procedures in clinical trials. Our findings highlight the importance of adapting cryopreservation techniques to enhance the viability of individual sperm cells, ultimately facilitating better outcomes in assisted reproductive technologies. This study provides the first quantification of nanoscale water diffusion dynamics during cryopreservation, establishing a predictive model that explains the catastrophic loss of sperm viability and identifying the critical role of water diffusion as a major impediment for limited samples. The novelty of our results lies in both elucidating this specific mechanism of cell death and introducing a novel approach: utilizing water-saturated oil as a protective layer. This method effectively mitigates the osmotic stress caused by water loss, demonstrating remarkably improved cell survival. This work not only advances the scientific understanding of cryopreservation at the nanoscale but also offers a practical, impactful solution poised to revolutionize fertility treatments for patients with low sperm counts and holds promise for broader applications in biological cryopreservation. Full article

The massive heavy oil reserves in the Athabasca region of northern Alberta depend on steam-assisted gravity drainage (SAGD) for their economic exploitation. Even though SAGD has been successful in highly viscous oil recovery, it is still a costly technology because of the large energy input requirement. Large water and natural gas quantities needed for steam generation imply sizable greenhouse gas (GHG) emissions and extensive post-production water treatment. Several methods to make SAGD more energy-efficient and environmentally sustainable have been attempted. Their main goal is to reduce steam consumption whilst maintaining favourable oil production rates and ultimate oil recovery. Oil saturation within the steam chamber plays a critical role in determining both the economic viability and resource efficiency of SAGD operations. However, accurately quantifying the residual oil saturation left behind by SAGD remains a challenge. In this experimental research, sand pack Expanding Solvent SAGD (ES-SAGD) coinjection experiments are reported in which Pentane -C₅H₁₂, and Hexane -C₆H₁₄ were utilised as an additive to steam to produce Long Lake bitumen. Each solvent is assessed at three different constant concentrations through time using experiments simulating SAGD to quantify their impact. The benefits of single-component solvent coinjection gradually diminish as the SAGD process approaches its later stages. ES-SAGD pentane coinjection offers a smaller improvement in recovery factor (RF) (4% approx.) compared to hexane (8% approx.). Between these two single-component solvents, 15 vol% hexane offered the fastest recovery. The obtained data in this research provided compelling evidence that the coinjection of solvent under carefully controlled operating conditions, reduced overall steam requirement, energy consumption, and residual oil saturation allowing proper adjustment of oil and water relative permeability curve endpoints for field pilot reservoir simulations. Full article

Oat bran offers notable health benefits, but excessive incorporation into bread often compromises quality and consumer acceptance due to its competition for water, particularly with gluten, impairing dough structure. The pre-hydration of fibrous ingredients could alleviate their negative impact on bread quality. This study aimed to determine the optimal pre-hydration level of oat bran to achieve maximal quality in bread enriched with pre-hydrated oat bran that replaced 20% white flour in a white bread formula. Oat bran was pre-hydrated to six water activity (a_w) levels, ranging from 0.9951 to 0.9989. The results revealed that oat bran hydrated near its saturation point (a_w = 0.9979) yielded the composite bread with the most desirable structural and textural properties, including the highest specific loaf volume, minimal crumb hardness, and superior springiness and cohesiveness—attributes comparable to those of the control white bread. Conversely, hydration levels either below or above this saturation threshold led to a decline in bread quality. Optimally saturated oat bran exhibited significantly reduced water absorbency, ensuring sufficient water availability for gluten network development. The findings underscore the critical role of precise hydration in optimizing the functional properties of oat bran for bread-making applications. Full article

Residual oil saturation in reservoirs is primarily influenced by viscous and capillary forces, with interfacial tension (IFT) being a critical factor in fluid distribution due to capillary pressure. Adjusting IFT is essential for enhancing oil recovery, particularly in waterflooding, which is the most common secondary recovery technique after primary production. The salinity of injected water directly affects the IFT between crude oil and brine, making it a crucial factor in optimizing recovery. However, limited studies have examined IFT using live oil samples under actual reservoir conditions. In this study, a high-pressure, high-temperature (HPHT) drop shape analyzer was used to measure the IFT between live oil and brine under reservoir conditions. Five live oil samples and two sodium chloride (NaCl) brine concentrations (30,000 and 100,000 ppm) were tested at a reservoir temperature of 180 °F. Measurements were conducted above the bubble points of the oils, replicating undersaturated reservoir conditions. The results revealed that the impact of pressure on IFT was more complex than that of salinity. IFT generally decreased with increasing pressure but showed mixed behavior across different samples. Conversely, IFT consistently increased with higher salinity. These findings enhance the understanding of IFT behavior under reservoir conditions, supporting improved reservoir simulations and oil recovery strategies. Full article

The instability of mine roadways is significantly influenced by the coupled effects of groundwater seepage and non-uniform loading. These interactions often induce localized plastic deformation and progressive failure, particularly in the roof and sidewall regions. Seepage elevates pore water pressure and deteriorates the mechanical properties of the rock mass, while non-uniform loading leads to stress concentration. The combined effect facilitates the propagation of microcracks and the formation of shear zones, ultimately resulting in localized instability. This initial damage disrupts the mechanical equilibrium and can evolve into severe geohazards, including roof collapse, water inrush, and rockburst. Therefore, understanding the damage and failure mechanisms of mine roadways at the mesoscale, under the combined influence of stress heterogeneity and hydraulic weakening, is of critical importance based on laboratory experiments and numerical simulations. However, the large scale of in situ roadway structures imposes significant constraints on full-scale physical modeling due to limitations in laboratory space and loading capacity. To address these challenges, a straight-wall circular arch roadway was adopted as the geometric prototype, with a total height of 4 m (2 m for the straight wall and 2 m for the arch), a base width of 4 m, and an arch radius of 2 m. Scaled physical models were fabricated based on geometric similarity principles, using defect-bearing sandstone specimens with dimensions of 100 mm × 30 mm × 100 mm (length × width × height) and pore-type defects measuring 40 mm × 20 mm × 20 mm (base × wall height × arch radius), to replicate the stress distribution and deformation behavior of the prototype. Uniaxial compression tests on water-saturated sandstone specimens were performed using a TAW-2000 electro-hydraulic servo testing system. The failure process was continuously monitored through acoustic emission (AE) techniques and static strain acquisition systems. Concurrently, FLAC^3D 6.0 numerical simulations were employed to analyze the evolution of internal stress fields and the spatial distribution of plastic zones in saturated sandstone containing pore defects. Experimental results indicate that under non-uniform loading, the stress–strain curves of saturated sandstone with pore-type defects typically exhibit four distinct deformation stages. The extent of crack initiation, propagation, and coalescence is strongly correlated with the magnitude and heterogeneity of localized stress concentrations. AE parameters, including ringing counts and peak frequencies, reveal pronounced spatial partitioning. The internal stress field exhibits an overall banded pattern, with localized variations induced by stress anisotropy. Numerical simulation results further show that shear failure zones tend to cluster regionally, while tensile failure zones are more evenly distributed. Additionally, the stress field configuration at the specimen crown significantly influences the dispersion characteristics of the stress–strain response. These findings offer valuable theoretical insights and practical guidance for surrounding rock control, early warning systems, and reinforcement strategies in water-infiltrated mine roadways subjected to non-uniform loading conditions. Full article