Search Results (55)

Self-fluxing Ni-based coatings (NiCrFeBSiC) were deposited through gas-flame spraying and evaluated in three conditions: as-sprayed, flame-remelted, and furnace-heat-treated (1025 °C/5 min). Phase analysis (XRD) revealed FeNi₃ together with strengthening carbides/borides (e.g., Cr₇C₃, Fe₂₃(C,B)₆); post-treatments increased lattice order. Cross-sectional image analysis showed progressive densification (thickness ~805 → 625 → 597 µm) and a drop in porosity from 7.866% to 3.024% to 1.767%. Surface roughness decreased from Ra = 31.860 to 14.915 to 13.388 µm. Near-surface microhardness rose from 528.7 ± 2.3 to 771.6 ± 4.6 to 922.4 ± 5.7 HV, while adhesion strength (ASTM C633) improved from 18 to 27 to 34 MPa. Wettability followed the densification trend, with the contact angle increasing from 53.152° to 79.875° to 89.603°. Under dry ball-on-disk sliding against 100Cr6, the friction coefficient decreased and stabilized (0.648 ± 0.070 → 0.173 ± 0.050 → 0.138 ± 0.003), and the counterbody wear-scar area shrank by ~95.6% (0.889 → 0.479 → 0.0395 mm²). Wear-track morphology evolved from abrasive micro-cutting (as-sprayed) to reduced ploughing (flame-remelted) and a polishing-like regime with a thin tribo-film (furnace). Potentiodynamic tests indicated the lowest corrosion rate after furnace treatment (CR ≈ 0.005678 mm·year⁻¹). Overall, furnace heat treatment provided the best structure–property balance (lowest porosity and Ra, highest HV and adhesion, lowest and most stable μ, and superior corrosion resistance) and is recommended to extend the service life of NiCrFeBSiC coatings under dry sliding. Full article

Carbon fibre reinforced polymer (CFRP) is a composite material known for its light weight and exceptional durability, composed of carbon fibres within a polymer matrix. Despite its high cost, CFRP is favoured for its outstanding strength-to-weight ratio and rigidity. It is widely used in the aerospace industry and ship superstructures, among others. These components often rub against different materials in various structural and mechanical assemblies. These interactions typically occur where metallic fasteners, bearings, hinges, and sliding components interface with CFRP parts causing, for example, fretting wear. The main novelty of the present study consists of a systematic comparison of titanium (Ti6Al4V) and aluminium (AA2024-T6) alloy spheres under identical test conditions, evaluating how each material interacts with different CFRP configurations. CFRP was tested against titanium and aluminium alloy spheres as counterbodies under reciprocating sliding conditions. Different contact conditions (applied loads) were used for tribotests. The wear volume and coefficient of friction were determined, as well as the wear mechanisms. Different analytical techniques were employed, such as profilometry, optical microscopy (OM), and scanning electron microscopy (SEM/EDS), to characterise the wear tracks. It was possible to determine the coefficient of friction as well as the wear rate on both CFRP specimens and their respective counterbodies. It was found that the coefficient of friction (CoF) depends on load, fibre orientation, and counterbody material, ranging from 0.14 to 0.29. The lowest wear rate coefficient was observed for CFRP sliding against titanium alloy in the layer configuration, at 1.48 × 10⁻¹³ mm³/N·m. In contrast, aluminium alloy counterbodies experienced significantly higher wear, with a maximum wear rate of 6.88 × 10⁻⁵ mm³/N·m. Wear volume increased with load across all conditions and was highest for the CFRP cross-section against aluminium alloy. Full article

Marking techniques are employed to guarantee the identification and traceability of biomedical materials. This study investigated the impact of laser and mechanical marking processes on the tribological performance of ISO 5832-1 austenitic stainless steel (SS), specifically examining corrosion resistance, the coefficient of friction, and wear volume in ball-cratering wear tests. The laser marking was performed using a nanosecond Q-switched Nd:YAG laser. Cytotoxicity tests assessed the biocompatibility of the biomaterial. Non-marked surfaces were also evaluated for comparison. A phosphate-buffered saline solution (PBS) served as both the lubricant and corrosion medium. The surface finishing was analyzed using optical microscopy and scanning electron microscopy coupled with a field-emission gun (SEM-FEG), combined with an energy-dispersive X-ray spectrometer. The oxide film was examined through X-ray photoelectron spectroscopy (XPS). Wear tests lasted 10 min, with PBS drops applied every 10 s at 75 rpm; solid balls of AISI 316L stainless steel (SS) and polypropylene (PP), each 1 inch in diameter, were used as counter-bodies. Corrosion resistance was assessed using electrochemical methods. Results showed variations in roughness and microstructure due to laser marking. The tribological behaviour was influenced by the type of marking process, and the wear amount depended on the normal force and ball nature. None of the samples was considered cytotoxic, although laser-marked surfaces exhibited the lowest cellular viability among the tested surfaces and the lowest corrosion resistance. Full article

A friction composite material which contains cellulose fiber, carbon fiber, wollastonite, graphite, and resin for use in oil-cooled friction units, hydromechanical boxes, and couplings was developed. The fabrication technique includes the formation of a paper layer based on the mixture of stated fibers via a wet-laid process, impregnation of the layer with phenolic resin, and hot pressing onto a steel carrier. The infrared spectra of the polymeric base (phenolic resin) were studied by solvent extraction. The structural-phase analysis of the obtained material was carried out by the SEM method, and the particle size distribution parameters of the composite components were estimated based on the images of the sample surface. The surface roughness parameters of the samples are as follows: Ra = 5.7 μm Rz = 31.4 μm. The tribotechnical characteristics of the material were tested in an oil medium at a load of 5.0 MPa and a rotation mode of 2000 rpm for 180 min in a pair with a steel 45 counterbody. The coefficient of friction of the developed material was 0.11–0.12; the degree of wear was 6.17 × 10⁻⁶ μm/mm. The degree of compression deformation of the composite is 0.36%, and the compressive strength is 7.8 MPa. The calculated kinetic energy absorbed and power level are 205 J/cm² and 110 W/cm², respectively. The main tribotechnical characteristics of the developed friction material correspond to industrial analogues. Full article

Titanium alloys are widely used in medicine due to their unique properties, including inertness with respect to living tissues, light weight, high strength, and impact toughness. For successful implementation, titanium alloy implants should possess high wear resistance and hydrophilicity. This article investigates the surface modification process of VT-1 and VT-6 titanium alloys by electron-beam processing (EBP). The EBP effect on the modified surface′s wear resistance, roughness, and hydrophilicity was analyzed. The specimens were made by machining them at a CNC turning center. The specimen surfaces were modified at the SOLO facility by a submillisecond modulated electron beam with a controlled power density of thermal impact, allowing it to reach and stabilize 1400 °C in 400 µs and then maintain it on the surface for 600 µs. A friction machine with a counterbody was used to study the wear resistance of the specimen surface. The study revealed that EBP reduces the roughness parameters of the surface. EBP also decreases the contact angle of wetting, indicating an increase in hydrophilicity compared to the original surface. Experimentally, it was shown that the formation of a nanostructure consisting of needle-like α-strips induced by EBP improves the wear resistance of the surface layer. Full article

The article presents the results of a comparison of the wear resistance of coatings with a two-layer architecture (adhesion layer–wear-resistant layer) of Zr-ZrN, Zr-(Zr,Ti)N, Zr,Hf-(Zr,Hf)N, Zr,Nb-(Zr,Nb)N, Zr,Hf-(Ti,Zr,Hf)N, and Zr,Nb-(Ti,Zr,Nb)N coatings, deposited on a titanium alloy substrate. The wear resistance was studied using two different counterbodies: Al₂O₃ and steel. When in contact with the Al₂O₃ counterbodies, the best wear resistance was demonstrated by samples with Zr,Hf-(Zr,Hf)N and Zr,Nb-(Zr,Nb,Ti)N coatings. In tests conducted in contact with the steel counterbody, the best resistance was demonstrated by samples with Zr-ZrN and Zr,Hf-(Ti,Zr,Hf)N coatings. The wear resistance of samples with (Zr,Hf)N and (Zr,Nb,Ti)N coatings was 2.5–3.3 times higher than that of the uncoated sample. The Zr,Nb adhesion layer ensures better adhesion of the coating to the substrate. It was found that not only the adhesion strength of the adhesion layer to the substrate and coating is of significant importance but also the strength of the adhesion layer itself. The surface film of titanium oxide must be completely etched off to ensure maximum strength of the adhesive bond between the coating and the substrate. It has been established that the adhesion of the coating and the titanium substrate is also affected by the characteristics of the outer (wear-resistant) coating layer, which is the composition and structure of the wear-resistant coating layer. Delamination can occur both at the boundary of the adhesive layer with the substrate and at the boundary of the wear-resistant and adhesive layers of the coating depending on the strength of the adhesive bonds in the corresponding pair. It is necessary to ensure a good combination of properties both in the substrate–adhesion layer system and in the adhesion layer–wear-resistant layer system. Full article

This study involved the investigation of the mechanical and tribological behaviors of DIN 1.2344 and WP7V tool steels, quenched in a salt bath after austenitization at 1050 °C, followed by triple tempering for 2 h. The selection of tempering temperatures produced two hardness levels under four metallurgical conditions, with the hardest level found only for WP7V steel (54 and 57 HRC). The mechanical properties were evaluated using Rockwell C, Vickers, and nanoindentation methods, along with unnotched impact tests, according to the SEP 1314 guidelines. Wear tests were conducted in a tribometer configured for a reciprocating setup, with a frequency of 5 Hz, a load of 25 N, and a time of 60 min, at room temperature and at 200 °C. As counterbodies, alumina balls of 5 mm in diameter were used. Wear tracks were evaluated through scanning electron microscopy, EDS, interferometry, and Raman spectroscopy. Friction and wear behaviors were affected by the variation in temperature for softer steels (DIN 1.2344 and WP7V of 48.5 HRC): the higher the temperature, the better the tribological performance. The harder steels were not sensitive to temperature testing. These effects depend on maintaining iron oxide (hematite) at the point of contact. The wear rates determined for the hardest material (57 HRC), considering its impact resistance, make it unsuitable for severe conditions such as hot stamping. Full article

Titanium possesses many useful properties and is a technologically important material in engineering. However, lubrication of titanium has long been a problem that has prevented titanium from being more widely used. This is due to its poor tribological properties, deriving from its high tendency towards adhesive wear, material transfer, and abrasive wear. Lubrication is a system engineering which involves material combinations, material surfaces, lubricants, and operating conditions as a system. In this work, the boundary lubrication behavior of commercially pure titanium (CP-Ti) sliding against various counterbody materials in a motor oil (0W-30) was investigated under ball-on-plate reciprocating sliding conditions. The counterbody materials (balls) include CP-Ti, ceramic (Al₂O₃), steel (AISI 52100), and polymer (nylon). The results show that depending on material combination, the lubricating behavior can be divided into three categories, i.e., (1) lubrication failure (Ti-Ti), (2) improved lubrication but with friction instability (Ti-Al₂O₃), and (3) effective lubrication (Ti–steel and Ti–nylon). Lubrication failure of the Ti-Ti pair leads to high and unstable friction and severe wear from both the plate and ball, while friction instability of the Ti-Al₂O₃ pair leads to friction spikes and high wear rates. Effective lubrication of the Ti–steel pair results in low and smooth friction and much-reduced wear rates of the Ti plate by nearly 10,000 times. However, there is a load-dependence of the lubrication effectiveness of the Ti–steel pair. Although the Ti–nylon pair is effectively lubricated in terms of much-reduced friction, the nylon ball suffers from severe wear. The friction and wear mechanisms of the various sliding pairs are discussed in this paper. Full article

This paper presents research on the effects of the addition of various contents of graphene oxide and sintering temperature on the mechanical, tribological, and electrical characteristics of WC-ZrO₂ composites. Wet processing and spark plasma sintering provided dense samples with simultaneous reduction of graphene oxide (rGO) during sintering. The obtained results showed that the best mechanical properties were observed at a sintering temperature of 1700 °C in samples with 0.5 vol.% rGO content; namely, indentation fracture toughness (5.8 ± 0.4 MPa·m^1/2) and flexural strength (872 ± 43 MPa) increased by 9% and 24.3% compared with the sample without rGO. In addition to improved mechanical performance, rGO-reinforced composites exhibited lower wear rates and friction coefficients than non-rGO composites, due to the formation of a graphitic lubricating tribolayer on worn surfaces and counterbodies in a friction pair, which provided sufficient lubrication to reduce the coefficient of friction and wear rate. The resulting composites also showed low electrical resistivity, suggesting the possibility of using electrical discharge machining to manufacture ceramic products of complex shapes from them. Full article

In recent years, Golden Hard Anodizing (G.H.A.^®) has been developed as a variant of the traditional hard anodizing process with the addition of Ag⁺ ions in the nanoporous structure. The tribological properties of this innovative surface treatment are still not well understood. In this study, ball-on-disk tests were conducted in dry sliding conditions using 100Cr6 (AISI 52100) bearing steel balls as a counterbody and GHA^®-anodized EN AW-6082 aluminum alloy disks. The novelty of this work lies in the mapping of the wear properties of the tribocouple under different test conditions for a better comparison of the results. Three different normal loads (equal to 5, 10, and 15 N) and three different reciprocating frequencies (equal to 2, 3, and 4 Hz) were selected to investigate a spectrum of operating conditions for polished and unpolished G.H.A.^®-anodized EN AW-6082 aluminum alloy. Quantitative wear maps were built based on the resulting wear rate values to define the critical operating limits of the considered tribocouple. The results suggest that the coefficient of friction (COF) was independent of test conditions, while different wear maps were found for polished and non-polished surfaces. Polishing before anodizing permitted the acquisition of lower wear for the anodized disks and the steel balls. Full article

The coatings of ZrN, (Zr,Ti)N, (Ti,Zr,Hf)N and (Ti,Zr,Nb)N deposited on the titanium alloy substrate were compared. The wear resistance in the pin-on-disk test together with the Al₂O₃ indenter and the corrosion resistance in 3.5% NaCl solution were studied. It was found that the (Zr,Nb,Ti)N coating has the best resistance to wear, but has low corrosion resistance. The (Ti,Zr,Hf)N coating, on the contrary, has the best corrosion resistance, but low resistance to wear. The ZrN coating has good corrosion resistance combined with good resistance to wear. This coating is best suited for use in friction conditions with a ceramic counterbody under the influence of seawater. An important resource for increasing the properties of coatings is increasing their adhesion to the substrate, which can be achieved in two combined ways: (1) complete removal of the original oxide layer from the surface of the substrate and (2) the use of optimal compositions of the adhesive sublayer, which have not only high adhesive properties in relation to both the substrate and the coating, but also high strength. While the introduction of Nb into the ZrN coating composition increases wear resistance and the introduction of Hf increases corrosion resistance, the ZrN coating without additives best resists wear and corrosion simultaneously. Full article

In the existing literature, there are few studies on the effect of deposition bias on the tribological properties of carbon-doped high-entropy alloy coatings. In order to further study the effect of the deposition bias on the properties of coatings, (AlTiVCrNb)C_xN_y coatings were deposited via unbalanced RF magnetron sputtering. The microstructure and tribological properties of carbon-doped high-entropy alloy ceramic coatings under different deposition biases were studied. The composition, morphology, crystal structure, and chemical morphology of each element of the coating were analyzed using scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The hardness, elastic modulus, friction, and wear properties of the coating were further characterized using a nanoindentation instrument, reciprocating sliding friction, a wear tester, and a white light interferometer. The coating density reached the optimal level when the deposition bias value was 90 V. The hardness and elastic modulus of the (AlTiVCrNb)C_xN_y coating increased first and then decreased with an increase in deposition bias, and the maximum hardness was 23.98 GPa. When the deposition bias was 90 V, the coating formed a good-quality carbon transfer film on the surface of the counterbody due to sp2 clusters during the friction and wear process. The average friction coefficient and wear rate of the (AlTiVCrNb)C_xN_y coating were the lowest, 0.185 and 1.6 × 10⁻⁷ mm³/N·m, respectively. The microstructure, mechanical properties, and tribological performance of the (AlTiVCrNb)C_xN_y coating were greatly affected by the change in deposition bias, and an (AlTiVCrNb)C_xN_y coating with excellent structure and friction properties could be prepared using graphite co-sputtering. Full article

Tailor-made materials used for advanced applications are nowadays of great research interest in various industrial and technological fields, ranging from aerospace and automotive applications to consumer goods and biomedical components. In the present research, Inconel 718 superalloy specimens were fabricated by the selective laser melting (SLM) technique. Structural characterization of the 3D-printed samples showed that they consisted of γ solid solution along with spherical carbide particles. To explore the applicability of these materials in abrasive tribological applications, reciprocating sliding tests were performed under dry conditions versus an Al₂O₃ counter-body. A 3D representation (triboscopy) of the tangential force during each sliding cycle was carried out in order to obtain better insight on the evolution of friction and to visualize localized tribological phenomena. Quantification of wear was performed with confocal microscopy and the wear mechanisms were analyzed with SEM and EDS techniques. Furthermore, the effect of surface finishing (as-printed and polished) on friction and wear were also investigated, and a comparison with other industrial materials is also included to evaluate the applicability of these alloys. The results indicated that surface finishing had an effect on friction during the run-in stage, whereas in steady-state conditions, no significant differences were observed between the as-printed and polished specimens. In all cases, the main wear mechanisms observed were a mixture of two-body and three-body abrasion, along with oxidative wear (indicated by the formation of an oxide-based tribo-layer). Full article

The mechanical characteristics and sliding friction behaviors of AA7075 samples were studied in regard to structural states formed in them by ECAP and depending on the ECAP pass number. In addition, the effect of a counterbody’s material on the tribological characteristics of the samples was investigated by the examples of AISI 52100 steel, alumina Al₂O₃ and silicon nitride Si₃N₄. Vibration acceleration and acoustic emission signals with parameters such as acoustic emission energy and median frequency were used for characterizing the sliding regimes. The structural state and mechanical properties of the ECAPed AA7075 samples significantly affected their wear behaviors in dry sliding. The counterbody material had a significant influence on the formation of a transfer layer and the subsurface deformation of samples. The dynamic behavior of the tribosystem was studied and the relationship between the sliding parameters, vibrometry and acoustic emission signals was established. Full article

The performance and durability of high-pressure fuel systems in combustion engines are critical for consistent operation under extreme conditions. High-pressure fuel systems are traditionally lubricated with fuel that is compressed and delivered to the combustion chamber. However, lubrication with fuel presents significant challenges in these systems when used with low-viscosity fuels, leading to increased wear rates, especially in reciprocating contacts. This study delved into the tribological performance of steels of varying alloy content (annealed and hardened variants of AISI-52100, CF2, and D2) against alumina and hard 52100 counterbody materials in ethanol and decane environments. Friction and wear behaviors were evaluated, highlighting the influence of material interactions and environmental factors. Elastohydrodynamic lubrication analysis of the tested systems indicated that ethanol and decane form lubricating films of nanometer-scale thickness, confirming the boundary lubrication regimes of the performed tests. In summary, the tribological behavior trends were similar for alumina and 52100 counterbodies. Even though soft 52100 steel demonstrated low friction, its wear was the largest for both tested environments and counterface materials. Among all the tested materials, hard D2 experienced the lowest wear. 52100 and D2 steels showed opposite friction change behavior when comparing hard and soft samples, with lower friction observed for softer 52100 steel and harder D2 steel. Meanwhile, the wear was lower for harder candidates than for softer ones independent of the environment and counterbody material. Raman spectroscopy analysis of the formed wear tracks indicated the formation of carbon films with larger intensities of characteristic carbon peaks observed for more wear-resistant materials. These results suggest the synergistic effect of hardness and tribochemical activity in reducing the wear of materials. Full article