Search Results (36)

The occurrence of gypsum in clastic rocks of continental saline lake basins reflects complex depositional and diagenetic processes. However, its genesis remains relatively understudied. Based on core descriptions and thin-section analyses, this study investigates the occurrence types and genetic mechanisms of gypsum in the Bottom Sandstone Member of the northern Tabei Uplift. Five types of gypsum occurrences are identified: layered gypsum, gypsum clasts, spotted gypsum, gypsum nodules, and a mixed deposition of clastic rocks and gypsum. The mixed deposition of clastic rocks and gypsum includes gypsiferous mudstone, muddy gypsum, gypsiferous mudstone containing muddy clasts, and sandy gypsum. Layered gypsum, spotted gypsum, gypsiferous mudstone, and muddy gypsum mainly result from in situ chemical precipitation during periods of high evaporation and reduced runoff. In contrast, gypsum clasts, gypsiferous mudstone containing muddy clasts, and sandy gypsum reflect processes of transportation and reworking induced by flood events. Seasonal variations in hydrodynamic conditions play a critical role in the formation and distribution of gypsum. During dry periods, surface runoff weakens or ceases, and the salinity of lake water or pore water in clastic deposits increases due to intense evaporation, promoting gypsum precipitation. During flood periods, increased runoff can erode previously formed gypsum, which is subsequently transported and deposited as gypsum clasts. The morphology of gypsum varies with its transport distance. These findings enhance our understanding of clastic–evaporite mixed systems in arid continental lacustrine settings and provide insights into sedimentary processes influenced by seasonal climatic fluctuations. Full article

The aim of this study was to examine variations in the hydrological regime of the Krapina River from 1964 to 2023. The river basin spans 1263 km² and is characterized by a temperate, humid continental climate with warm summers. Hydrological data from the Kupljenovo gauging station, which monitors 91.1% of the basin (1150 km²), indicate an average annual discharge of 11.2 m³/s, ranging from 3.25 m³/s to 18.3 m³/s. Over the 60-year study period, the minimum mean daily discharges show a statistically insignificant increasing trend, while the mean annual and maximum annual mean daily discharges exhibit statistically insignificant declines. Annual precipitation averages 1037 mm, varying between 606 mm and 1459 mm, with a non-significant decreasing trend. In contrast, the mean annual air temperatures demonstrate a statistically significant increasing trend, with a pronounced intensification beginning in 1986. The annual runoff coefficients series exhibits a statistically insignificant downward trend, with an average value of 0.293 (range: 0.145–0.399). Application of the New Drought Index (NDI) revealed a marked increase in the frequency of strong and extreme droughts since 2000. Full article

Emerging evidence indicates that large-scale forest restoration exhibits dual hydrological effects: direct reduction of local water availability through elevated evapotranspiration (ET) and indirect augmentation of water resources via enhanced atmospheric moisture recycling. However, the quantitative assessment of these counteracting effects remains challenging due to the limited observational constraints on moisture transport. Here, we integrate the Budyko model with the Lagrangian-based UTrack moisture-tracking dataset to disentangle the direct (via ET) and indirect (via precipitation) large-scale hydrological impacts of China’s four-decade forest restoration campaign across eight major river basins. Multisource validation datasets, including gauged runoff records, hydrological reanalysis products, and satellite-derived forest cover maps, were systematically incorporated to verify the Budyko model at the nested spatial scales. Our scenario analyses reveal that during 1980–2015, extensive afforestation individually reduced China’s terrestrial water yield by −28 ± 25 mm yr⁻¹ through dominant ET increases. Crucially, atmospheric moisture recycling mechanisms attenuated this water loss by 12 ± 5 mm yr⁻¹ nationally, with marked spatial heterogeneity across the basins. In some moisture-limited watersheds in the Yellow River Basin, the negative ET effect was compensated for to a certain extent by precipitation recycling, demonstrating net positive hydrological outcomes. We conclude that China’s forest expansion imposes local water stress (direct effect) by elevating ET, while the concomitant strengthening of continental-scale moisture recycling generates compensatory water gains (indirect effect). These findings advance the mechanistic understanding of the vegetation-climate-water nexus, providing quantitative references for optimizing forestation strategies under atmospheric water connectivity constraints. Full article

The Arabian Gulf, a semi-enclosed basin in the Middle East, connects to the Indian Ocean through the Strait of Hormuz and is surrounded by seven arid countries. This study examines the water cycle of the Gulf and its surrounding areas using data from the GRACE and GRACE Follow-On missions, along with ERA5 atmospheric reanalysis data, from 05/2002 to 05/2017 and from 07/2018 to 12/2023. Our findings reveal a persistent water deficit due to high evaporation rates, averaging 370 ± 3 km³/year, greatly surpassing precipitation, which accounts for only 15% of the evaporative loss. Continental runoff provides one-fifth of the needed water, while the remaining deficit, approximately 274 ± 10 km³/year, is balanced by net inflow of saltwater from the Indian Ocean. Seasonal variations show the lowest net inflow of 26 ± 49 km³/year in March and the highest of 586 ± 53 km³/year in November, driven by net evaporation, continental input, and changes in the Gulf’s water budget. This study highlights the complex hydrological dynamics influenced by climate patterns and provides a baseline for future research in the region, which will be needed to quantify the expected changes in the hydrological cycle due to climate change. Full article

Sediment transport to the sea by rivers is crucial for the stability of estuaries and coasts. The Yangtze River, the largest river in China, like many large rivers worldwide, is experiencing a decrease in sediment load reaching the coast. However, the tidal flat around Qidong Cape, located at the entrance of the North Branch of the Yangtze Estuary, is undergoing extensive siltation. The source of this sediment is unclear. In this study, a sediment core was collected and the geochemical characteristics of rare earth elements (REE) were analyzed using inductively coupled plasma mass spectrometry (ICP-MS). The results indicate the following: (1) The average content of REE is 178.57 μg/g, and the average ratio between LREE and HREE is 8.66, which is comparable to sediments from the South Yellow Sea. The chondrite-normalized and UCC-normalized patterns resemble those of the Yangtze River and the South Yellow Sea, indicating a negative gradient, a weak Ce-negative anomaly, and a distinct Eu-negative anomaly. (2) The continental shelf deposits in eastern China are primarily derived from sediment flux delivered by rivers. The sediments in the South Yellow Sea mainly originate from the Yangtze River and the Yellow River, exhibiting characteristics of a mixed source due to long-term geological processes, namely geochemical processes. The REEs in the tidal flat around Qidong Cape inherit the source area’s characteristics and originate from the weathering of upper continental rock in mainland China. Moreover, the tidal flat around Qidong Cape is influenced by both runoff and tidal actions, leading to strong land–sea interactions and reducing the environment, explaining the Eu-negative anomaly. (3) Hydrodynamic forces in the North Branch of the Yangtze River have shifted from runoff to tidal dominance since the 1930s. However, marine hydrodynamics outside the estuary have remained unchanged. Consequently, the Subei coastal current plays a key role in sediment transport and diffusion. Sediments from the south wing of the Radiative Sand Ridge in the South Yellow Sea are transported southward by the Subei coastal current, and under tidal influence, suspended sediment is deposited in the tidal flat around Qidong Cape. Therefore, the sediment source has gradually shifted from the Yangtze River to the South Yellow Sea. Full article

Understanding the factors that control carbonate systems is an important goal due to the complex interactions between the hydrophysical and chemical–biological conditions in coastal basins. The results of this paper present the state of the carbonate system in Penzhina Bay and its adjacent waters—the Shelikhov Gulf—in July 2023, during spring tides with 13 m height. The area we studied included the length of the largest river in the region, the Penzhina River, from the peak of its summer flood to its boundary with the Shelikhov Gulf (the Sea of Okhotsk). This unique dynamic basin, with a length of about 800 km, was studied over 17 days. During this period, the entire water column of Penzhina Bay, down to a depth of about 60 m, and the surface water layer of the Shelikhov Gulf were undersaturated in terms of CO₂, with low levels relative to those of the atmosphere. To explain this observation, the dissolved oxygen, nutrients in mineral and organic forms, humic substances, chlorophyll a, and photic zone thickness are presented for the entire basin under study, together with its hydrological data. The results of daily observations of the carbonate system at fixed anchorage stations characterize two contrasting regions of Penzhina Bay: one that was more exposed to continental runoff, which had salinity levels in the range of 8.0–21.3 psu during one tidal cycle; the second had smaller variations in salinity in the range of 31.6–32.9 psu during one tidal cycle. This study emphasizes the importance of biological processes and continental runoff on the variability of the carbonate system parameters and CO₂ fluxes at a water/atmosphere boundary with extreme tidal conditions in this ecosystem that is barely affected by human activities. Full article

The geographical location of Kazakhstan, situated in the central part of the Eurasian continent, has played a crucial role in shaping a distinctly continental climate. This positioning has led to Kazakhstan facing a significant challenge in terms of water resource availability. The country’s water resources are highly vulnerable to the dual pressures of climate change and human activities. It is noteworthy that the Yesil River basin is the sole region within Kazakhstan’s borders where water resources are predominantly generated, while all other river basins experience substantial outflows beyond the nation’s boundaries. This research undertaking involves a comprehensive analysis of long-term climatic data collected from meteorological stations located within the confines of the Yesil basin in Northern Kazakhstan. Additionally, the study encompasses the computation of water consumption and annual runoff within this region. Historical meteorological observations spanning from 1961 to 2020 reveal notable trends. Most significantly, a 1.2 °C increase in temperature is observed during the spring season. Winters have also become relatively milder and warmer, particularly towards the end of February, where temperatures have shifted from −16.2 °C in the first 30-year period to −14.6 °C in the second period. These findings underscore the ongoing climatic changes within the region, with significant implications for the management and sustainability of water resources in Kazakhstan. Full article

Simulating river discharge is a complex convolution depending on precipitation, runoff generation and transformation, and network attenuation. Terrestrial water storage anomalies (TWSA) from NASA’s Gravity Recovery and Climate Experiment (GRACE) and its follow-on mission can be used to estimate monthly river discharge (Q). Monthly discharges for the period April 2002–January 2022 are estimated at 2870 U.S. Geological Survey gauge locations (draining 1K to 3M km²) throughout the continental U.S. (CONUS) using two-parameter exponential relationships between TWSA and Q. Roughly 70% of the study sites have a model performance exceeding the expected performance of other satellite-derived discharge products. The results show how the two model parameters vary based on hydrologic characteristics (annual precipitation and range in TWSA) and that model performance can be affected by snow accumulation/melt, water regulation (dams/reservoirs) or GRACE signal leakage. The generally favorable model performance and our understanding of variability in model applicability and associated parameters suggest that this concept can be expanded to other regions and ungauged locations. Full article

The introduction of pollutants, such as thiacloprid and benzo[a]pyrene (B[a]P), into the waters of urbanized coastal and estuarine areas through fossil fuel spills, domestic and industrial waste discharges, atmospheric inputs, and continental runoff poses a major threat to the fauna and flora of the aquatic environment and can have a significant impact on the internal defense system of invertebrates such as mussels. Using monoclonal and polyclonal anti-Toll-like receptor 2 (TLR2) and anti-inducible nitric oxide synthetase (iNOS) antibodies for the first time, this work aims to examine hemocytes in the mantle and gills of M. galloprovincialis as biomarkers of thiacloprid and B[a]P pollution and analyze their potential synergistic effect. To pursue this objective, samples were exposed to the pollutants, both individually and simultaneously. Subsequently, oxidative stress biomarkers were evaluated by enzymatic analysis, while tissue changes and the number of hemocytes in the different contaminated groups were assessed via histomorphological and immunohistochemical analyses. Our findings revealed that in comparison to a single exposure, the two pollutants together significantly elevated oxidative stress. Moreover, our data may potentially enhance knowledge on how TLR2 and iNOS work as part of the internal defense system of bivalves. This would help in creating new technologies and strategies, such as biosensors, that are more suitable for managing water pollution, and garnering new details on the condition of the marine ecosystem. Full article

Environmental contaminants with chemical origins, such as organochlorine pesticides (OCPs) have major impacts on the health of marine animals, including sea turtles, due to the bioaccumulation of those substances by transference throughout the food chain. The effects of environmental pollution on the health of marine turtles are very important for management strategies and conservation. During recent decades, the south Gulf of Mexico and the Yucatan Peninsula have suffered from increasingly frequent disturbances from continental landmasses, river systems, urban wastewater runoff, port areas, tourism, industrial activities, pesticides from agricultural use, and other pollutants, such as metals, persistent organic pollutants (POPs) and hydrocarbons (from the oil industry activities), which contaminate water and sediments and worsen the environmental quality of the marine ecosystem in this region. In this study, we assessed the concentrations of OCPs in the blood and eggs of 60 hawksbill turtles (Eretmochelys imbricata) nesting at the Punta Xen turtle camp, and their effects on the nesting population’s reproductive performance: specifically, maternal transfer and embryonic development were analyzed. Hematologic characteristics, including packed cell volume, white blood cell count, red blood cell count, and haemoglobin levels, and plasma chemistry values, including creatinine, blood urea nitrogen, uric acid, triglyceride, total cholesterol and glucose, were also measured. The general health of the turtles in this study, as well as their levels of urea, serum creatinine, glucose, uric, acid, cholesterol, and triglyceride, fell within normal ranges and was similar to other normal values, which could indicate the turtles’ good energy levels and body conditions for nest-building activity, with all of the turtles able to successfully come ashore to nest. All the same, the obtained results also indicate that OCPs affect the nesting and reproductive performance of the hawksbill turtles, as well as their fertility and the development of the population of eggs and reproductive performance, specifically in terms of maternal transference and embryonic development. There were significant differences in the concentrations of OCPs (ΣHCHs and ΣDienes) between maternal blood and eggs, indicating that these chemicals are transferred from nesting females to eggs and, ultimately, to hatchlings. OCPs may, therefore, have an effect on the health and reproductive performance of hawksbill turtles, both in terms of their fertility and egg development. Conservation strategies need to be species-specific, due to differences in feeding, and address the reasons for any decline, focusing on regional assessments. Thus, accurate and comparable monitoring data are necessary, which requires the standardization of monitoring protocols. Full article

Drought is a multifaceted natural disaster that can impact the ecological environment, crop yield, and social economy through the hydrological cycle process. Meteorological drought occurs first, which then propagates to other forms. This study presents the propagation characteristics of meteorological to hydrological drought in different river basins of China. The main drivers of drought propagation are also quantitatively analyzed in this study. The standardized precipitation index (SPI) and standardized runoff index (SRI) were used to describe meteorological and hydrological drought, respectively. The Songhua and Liaohe River Basin (SLRB), Haihe River Basin (HARB), Huaihe River Basin (HURB), Yellow River Basin (YRB), Yangtze River Basin (YARB), Pearl River Basin (PRB), Southeast Basin (SEB), Southwest Basin (SWB), and Continental Basin (CB) were analyzed in this study. The precipitation and runoff datasets were used to compute the SPI and SRI, respectively. The results showed that the drought propagation time was mainly 1–3 months in China. In general, drought propagation had a stronger relationship in the central and eastern river basins of China than in the western river basins (SWB and CB). Spring and winter had a weaker drought propagation relationship than autumn and winter. Drought propagation was driven by precipitation in the HURB, YARB, SEB, and PRB; soil moisture and precipitation were drivers in the HARB and YRB; moreover, soil moisture and potential evapotranspiration were drivers in the SLRB and CB. This study improves the understanding of the characteristics and drivers of drought propagation in droughts in river basins. Therefore, this study might provide a reference to reveal the mechanism of drought. Full article

The sediments distributed in the marginal seas of the continental shelf are important burial materials for global organic carbon (OC). There have been many estimates of the global continental shelf OC reserves, but due to the limited acquisition of measured data, the estimated results have great uncertainty. The vast continental shelf in the northern part of the South China Sea (SCS) provides a good place for the storage of OC. Based on a large amount of sediment OC data obtained from the northern coast of the SCS, the OC storage in the surface sediment (0~10 cm) in the study area (approximately 8.63 × 10⁴ km²) was accurately calculated as 51 Tg. The study area covers different regions, such as estuaries, open seas, strait areas and upwelling development areas, and the OC content of each area is quite different. According to provenance analysis, the source of OC in sediments is mainly from the input of Pearl River runoff. The OC content is significantly higher and less affected by sediment particle size in the Pearl River Estuary and the surrounding areas; meanwhile, the OC content gradually decreases with the distance from the Pearl River Estuary. Far from the western Pearl River Estuary, the sediment OC content is mainly controlled by the particle size of the sediments and is significantly correlated with silt and clay content. The deposition rate is also an important factor affecting the burial of OC, for the high deposition rates correspond to the high levels of OC in the nearshore estuarine areas, as well as the low deposition rate region having low OC content in the sediments even though it has a high productivity of OC, such in as the upwelling sea area on the eastern side of Hainan. Full article

Freshwater streams on oceanic islands serve critical ecological and economic functions. However, these are underrepresented in assessments of pollution from contaminants of emerging concern (CEC). Furthermore, freshwater streams and their endemic fauna often have characteristics that are distinct from those of continental streams and model species, calling extrapolations from studies of such systems into question for island streams. In the current study, we assessed the presence of CEC across three sampling events and five freshwater streams on the Island of Hawai’i. We also exposed juveniles of the native fish species Sicyopterus stimpsoni to a mixture of commonly co-occurring CEC for 96 h in static renewal experiments, testing for impacts of CEC in two ecologically relevant assays of functional performance. CEC from multiple sources were ubiquitous in Hawaiian streams, including human-use pharmaceuticals, agricultural herbicides, and industrial runoff. Concentrations of CEC were comparable to published studies from continental streams, exceeding total concentrations of 1000 ng/L for the eight quantified CEC in four samples, and approaching 2500 ng/L in one sample. Effects on exposed fish were subtle and limited to treatments with higher CEC concentrations but indicated potential impacts of CEC on locomotor performance. These results indicate that Hawaiian streams follow a global trend of widespread freshwater pollution by CEC that are accompanied by subtle effects on native fish species and highlight the need for the inclusion of endemic species and ecologically relevant assays when assessing the effects of contaminants in island habitats. Full article

Data on the geochemistry of phosphorus in the continental runoff of dissolved and solid substances were systematized and generalized, with a separate consideration of the processes of runoff transformation in river mouth areas. It has been established that atmospheric deposition, which many authors consider to be an important source of phosphorus in river runoff and not associated with mobilization processes in catchments, actually contains phosphorus from soil-plant recycling. This is confirmed by the fact that the input of phosphorus from the atmosphere into catchments exceeds its removal via water runoff. An analysis of the mass ratio of phosphorus in the adsorbed form and in the form of its own minerals was carried out. It was shown that the maximum mass of adsorbed phosphorus is limited by the solubility of its most stable minerals. The minimum concentrations of dissolved mineral and total phosphorus were observed in the rivers of the Arctic and subarctic belts; the maximum concentrations were confined to the most densely populated temperate zone and the zone of dry tropics and subtropics. In the waters of the primary hydrographic network, the phosphorus concentration exhibited direct relationships with the population density in the catchments and the mineralization of the river water and was closely correlated with the nitrogen content. This strongly suggests that economic activity is one of the main factors in the formation of river phosphorus runoff. The generalization of the authors’ and the literature’s data on the behavior of phosphorus at the river–sea mixing zone made it possible to draw a conclusion about the nonconservative distribution of phosphorus, in most cases associated with biological production and destruction processes. The conservative behavior of phosphorus was observed only in heavily polluted river mouths with abnormally high concentrations of this element. Full article

In natural water, as a rule, there is a violation of radioactive equilibrium in the chain ²³⁸U … → ²³⁴U → ²³⁰Th →. Groundwater usually has a ²³⁴U/²³⁸U ratio in the range of 0.8–3.0 (by activity). However, in some regions, the ²³⁴U/²³⁸U ratio reaches >10 and up to 50. Ultrahigh excesses of ²³⁴U can be explained by climatic variations. During a cold period, minerals accumulate ²³⁴U as a normal component of the radioactive chain, and after the melting of permafrost, it is lost from the mineral lattice faster than ²³⁸U due to its higher geochemical mobility. This hypothesis was tested using data on the isotopic composition of uranium in the chemo- and bio-genic formations of the World Ocean and large lakes, which are reservoirs that accumulate continental runoff. The World Ocean has the most significant ²³⁴U enrichments in the polar and inland seas during periods of climatic warming in the Late Pleistocene and Holocene. In the bottom sediments of Lake Baikal, the ²³⁴U/²³⁸U ratio also increases during warm periods and significantly exceeds the ²³⁴U excess of the World Ocean. Furthermore, the ²³⁴U/²³⁸U ratio in the water of Lake Baikal and its tributaries increases from north to south following a decrease in the area of the continuous permafrost and has a seasonal variation with a maximum ²³⁴U/²³⁸U ratio in summer. The behavior of ²³⁴U in large water reservoirs is consistent with the hypothesis about the decisive influence of permafrost degradation on the anomalies in ²³⁴U/²³⁸U ratios in groundwater. Full article