Search Results (81)

The global emphasis on clean energy has increased interest in producing hydrogen from petroleum reservoirs through in situ combustion-based processes. While field practices have demonstrated the feasibility of co-producing hydrogen and oil, the question of which offers greater economic potential, oil, or hydrogen, remains central to ongoing discussions, especially as researchers explore ways to produce hydrogen exclusively from petroleum reservoirs. This study presents the first integrated techno-economic model comparing oil and hydrogen production under varying injection strategies, using CMG STARS for reservoir simulations and GoldSim for economic modeling. Key technical factors, including injection compositions, well configurations, reservoir heterogeneity, and formation damage (issues not addressed in previous studies), were analyzed for their impact on hydrogen yield and profitability. The results indicate that CO₂-enriched injection strategies enhance hydrogen production but are economically constrained by the high costs of CO₂ procurement and recycling. In contrast, air injection, although less efficient in hydrogen yield, provides a more cost-effective alternative. Despite the technological promise of hydrogen, oil revenue remains the dominant economic driver, with hydrogen co-production facing significant economic challenges unless supported by policy incentives or advancements in gas lifting, separation, and storage technologies. This study highlights the economic trade-offs and strategic considerations crucial for integrating hydrogen production into conventional petroleum extraction, offering valuable insights for optimizing hydrogen co-production in the context of a sustainable energy transition. Additionally, while the present work focuses on oil reservoirs, future research should extend the approach to natural gas and gas condensate reservoirs, which may offer more favorable conditions for hydrogen generation. Full article

As a natural fiber, cashmere is favored for its softness, finesse, and warmth. However, its poor flame-retardant properties seriously affect the safety of cashmere. Current flame-retardant treatments for cashmere tend to lead to heavy metal pollution and significantly reduce wearer comfort. In this work, natural and environmentally friendly calcium alginate fibers were blended with cashmere to obtain blended fibers. The blended fibers exhibited good hygroscopicity and softness. The incorporation of calcium alginate fibers enhanced the flame retardancy of the blends, and the LOI of the blended fibers reached 40.2 without smoldering. It was due to a stable CaO protective layer formed by Ca²⁺ during combustion and the dense carbon layer with the decomposition intermediates of cashmere, which exerted a flame-retardant effect in the condensed phase. This study provided an eco-friendly approach to producing high-quality flame-retardant cashmere products. Full article

Biofuels, such as ethanol (CH₃CH₂OH), remain significantly underutilized globally despite their potential to mitigate environmental effects associated with fossil fuel combustion. Ethanol (ETH) can seamlessly blend with petroleum-derived gasoline, boosting its octane rating as a virtuous side effect. However, in several countries, octane number (ON) boosters such as methyl-tert-butyl-ether (MTBE) are still blended into the gasoline (also known as gas or petrol) sold in fuel stations, despite this being restricted or banned due to deleterious effects on the environment and health. Additionally, in nations overproducing naphtha from refining petroleum condensates, such as in the Middle East, investments in extra carbon chain rearrangement units can be an outlet to enhance gasoline production, since they produce high-ON streams; however, aromatic concentration becomes a limiting constraint. A discrete-event simulation algorithm combines sixteen main (primary) manufacturing variations into two secondary manufacturing and three supply chain variations, building gasoline yield and property plots over 512 gasoline production scenarios. Full article

The critical consequence of climate change resulting from global warming is the increase in temperature. In combined cycle power plants (CCPPs), the Electric Power Output (PE) is affected by changes in both Ambient Temperature (AT) and Sea Surface Temperature (SST), particularly in plants utilizing seawater cooling systems. As AT increases, air density decreases, leading to a reduction in the mass of air absorbed by the gas turbine. This change alters the fuel–air mixture in the combustion chamber, resulting in decreased turbine power. Similarly, as SST increases, cooling efficiency declines, causing a loss of vacuum in the condenser. A lower vacuum reduces the steam expansion ratio, thereby decreasing the Steam Turbine Power Output. In this study, the effects of increases in these two parameters (AT and SST) due to global warming on the PE of CCPPs are investigated using various regression analysis techniques, Artificial Neural Networks (ANNs) and a hybrid model. The target variables are condenser vacuum (V), Steam Turbine Power Output (ST Power Output), and PE. The relationship of V with three input variables—SST, AT, and ST Power Output—was examined. ST Power Output was analyzed with four input variables: V, SST, AT, and relative humidity (RH). PE was analyzed with five input variables: V, SST, AT, RH, and atmospheric pressure (AP) using regression methods on an hourly basis. These models were compared based on the Coefficient of Determination (R²), Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), Mean Square Error (MSE), and Root Mean Square Error (RMSE). The best results for V, ST Power Output, and PE were obtained using the hybrid (LightGBM + DNN) model, with MAE values of 0.00051, 1.0490, and 2.1942, respectively. As a result, a 1 °C increase in AT leads to a decrease of 4.04681 MWh in the total electricity production of the plant. Furthermore, it was determined that a 1 °C increase in SST leads to a vacuum loss of up to 0.001836 bar_a. Due to this vacuum loss, the steam turbine experiences a power loss of 0.6426 MWh. Considering other associated losses (such as generator efficiency loss due to cooling), the decreases in ST Power Output and PE are calculated as 0.7269 MWh and 0.7642 MWh, respectively. Consequently, the combined effect of a 1 °C increase in both AT and SST results in a 4.8110 MWh production loss in the CCPP. As a result of a 1 °C increase in both AT and SST due to global warming, if the lost energy is to be compensated by an average-efficiency natural gas power plant, an imported coal power plant, or a lignite power plant, then an additional 610 tCO₂e, 11,184 tCO₂e, and 19,913 tCO₂e of greenhouse gases, respectively, would be released into the atmosphere. Full article

Condensate oil, due to its inherent physical and chemical properties, can accelerate the spontaneous combustion of corrosion products in storage tanks during transportation or storage, posing significant risks to the safety and sustainability of energy infrastructure. While prior research has primarily examined crude oil or reactive sulfur effects on tank corrosion, the mechanistic role of condensate oil in promoting corrosion product ignition remains unclear. To address this knowledge gap, this study investigates the impact of condensate oil on simulated tank corrosion product compounds (STCPCs) through a combination of microstructural analysis (XRD and SEM) and thermal behavior characterization (TG-DSC). The results reveal that condensate oil treatment markedly increases STCPC surface roughness, inducing crack formation and pore proliferation. These structural changes may enhance the adsorption of O₂ and condensate oil, thereby amplifying STCPC reactivity. Notably, condensate oil reduces the thermal stability of STCPC, increasing its spontaneous combustion propensity. DSC analysis further demonstrates that condensate oil introduces additional exothermic peaks during oxidative heating, releasing heat that accelerates STCPC ignition. Moreover, condensate oil lowers the apparent activation energy of STCPC by 1.44 kJ/mol and alters the dominant reaction mechanism. These insights advance the understanding of corrosion-induced spontaneous combustion and highlight critical sustainability challenges in petrochemical storage and transportation. By elucidating the hazards associated with condensate oil, this study provides actionable theoretical guidance for improving the safety and environmental sustainability of energy logistics. Future work should explore mitigation strategies, such as corrosion-resistant materials or optimized storage conditions, to align industrial practices with sustainable development goals. Full article

The peak load boiler (PLB) is a heat production facility that uses SA178 Gr. A and SA516 Gr. 70 low-carbon steels as tube and plate materials, respectively. Recently, failures were frequently observed near plugged tubes due to water leakage, raising concerns about corrosion mechanisms and their impact on tube durability. This work investigates the corrosion failure mechanisms using a combination of endoscopy, ultrasound inspection, oxide scale analysis (X-ray diffraction), chemical analysis (ion chromatography and inductively coupled plasma mass spectrometry), and computational fluid dynamics simulations. The undamaged tube near the leaked tube exhibited oxide scale levels comparable to those directly affected. Surface examinations revealed gas-side pits indicative of localized corrosion, while oxide scales were predominantly composed of iron oxides formed under humid conditions and sodium compounds derived from boiler water. Analysis of the leaked water revealed its mixture with combustion gases, forming an acidic, chloride-rich environment that significantly accelerates corrosion. Computational fluid dynamics simulations demonstrated that leaked water vapor facilitated the condensation of acidic ions near affected tubes, promoting dew point corrosion. These phenomena, driven by localized condensation and chemical concentration at the dew point temperature, exacerbate material degradation, emphasizing the importance of targeted prevention strategies. Full article

Energetic co-particles have been proven effective in balancing high-energy and safety performance, which might be used as insensitive oxidizers in solid propellants. In this work, the high temperature interactions between several co-particles and aluminum (Al) powders in the presence of ammonium perchlorate (AP) have been studied. The co-particles are based on octogen (HMX) and hexanitrohexaazaisowurtzitane (CL-20), with balanced energy content and safety performance. They are used to combine with Al and AP to form either binary or ternary systems. Their energy release rate during decomposition and combustion have been fully evaluated. Due to the intimate contact between components in co-particles, the binary/ternary systems exhibit superior reaction efficiency compared to relevant mechanical mixtures with the same formulations. These novel energetic systems have maximum two times higher pressurization rate, 10% higher heat of explosion, 53.8% higher flame propagation rate, and much shorter ignition delay than the corresponding normal mixtures. For both HMX- and CL-20-based co-particle systems, the median size of condensed combustion products (CCPs) is smaller than those of the mechanical mixtures, with higher content of Al₂O₃. This indicates that co-particles have advantages in improving combustion efficiency of Al particles by eliminating their agglomeration. Full article

To expand the utilization of bio-based materials as flame retardants in epoxy resin (EP), a green Schiff base structural material (CSV) was synthesized via a one-pot approach employing chitosan and vanillin as the raw materials. Then, the CSV combined with 9,10-dihydro-9-oxa-10-phospha-phenanthrene-10-oxide (DOPO) (the mass ratio between CSV and DOPO was 1:2, written as CSV-DOPO) improved the flame retardancy of the EP. When the amount of CSV−DOPO in the EP was only 3 wt%, the thermogravimetric analysis (TGA) results indicated that the residue of the EP composites was 50.6% higher than that of the EP. The combustion class of the EP/3 wt% CSV−DOPO composites achieved a UL-94 V0 rating and the limit oxygen index (LOI) reached 34.0%. The cone calorimeter test (CCT) showed that the peak heat release rate (PHHR), total heat release (THR), total smoke release (TSP), and peak carbon dioxide production (PCO₂P) of the EP/3 wt% CSV−DOPO composites decreased by 32.3%, 22.0%, 4.6%, and 51.0%, respectively, compared to the EP. The flame-retardancy mechanism was studied by scanning electron microscopy (SEM) and Raman spectra. The quenching effect of phosphorus-containing radicals, the dilution effect of noncombustible gases, and the impeding effect of the carbon layer in the condensed phase contributed collectively to the excellent flame retardancy of the EP/CSV−DOPO composites. Considering the facile preparation method and small addition amount of the flame retardant, the present work provides a convenient solution for the preparation of modified EP with good flame retardancy and heat stability, which is expected to be widely used in industries. Full article

The oxidation of filter cake particles (FCPs) is beneficial for preventing filter media blockage during the hot filtration of raw biomass gasification gas. The influence of particle characteristics on hot oxidative filtration was investigated through characterization, kinetic study, and lab-scale experiments. The characterization results indicated that FCPs are particles with C content of more than 60%, containing –CH_n and C=O functional groups. After pyrolysis treatment, these functional groups gradually diminished, while the degree of atomic nucleus condensation increased. The oxidation kinetic calculation indicated that the oxidation activation energy of particles ranged from 55.24 to 117.84 kJ/mol, and higher treatment temperatures could reduce the particle reactivity. The hot oxidative filtration at 400 °C revealed that the primary reaction was C + O₂ = CO₂ rather than combustion or oxidation of combustive gas components. Furthermore, it was observed that the active minerals on the surface of carbon particles would promote the catalytic oxidation of CO. Experimental findings confirmed that the untreated FCPs containing abundant –CH_n functional groups could effectively react with low-concentration O₂. However, the presence of active minerals on the particle surface likely promoted CO oxidation within the FCP layer, thereby reducing the calorific value of the product gas. Full article

In the European Union, Regulation (EU) No 305/2011, in force since 2017 as CPR, requires the classification of cables permanently installed in buildings for reaction to fire, smoke, flaming droplets, and acidity. The latter is an additional classification evaluated through EN 60754-2, involving pH and conductivity measurements. Acidity is the weak point of a PVC cable due to the release of HCl during the combustion. Low-smoke acidity compounds, containing potent acid scavengers at high temperatures, are developed to reduce the acidity of the smoke. In order to design proper HCl scavengers to be used in PVC low-smoke acidity compounds, it becomes essential to evaluate the main actors affecting acidity and conductivity. In this paper, different cable PVC compounds were tested carrying out EN 60754-2 at different temperatures and temperature regimes: measurements of pH and conductivity were compared with ions’ concentration determined by ion chromatography, according to ISO 10304-1 and ISO 14911 for anions and cations, and inductively coupled plasma–optical emission spectrometry, according to ISO 11885. The conclusive results emphasize that HCl from PVC compounds’ thermal decomposition is the primary driver of pH and conductivity, and the contribution from the evaporation and or decomposition of additives and by-products from combustion is found to be negligible in most of the tested PVC compounds for cables. The findings highlight the effectiveness of ion chromatography and inductively coupled plasma–optical emission spectrometry as powerful analytical tools for developing efficient acid scavengers capable of maintaining performance at elevated temperatures. A further outcome regards the experimental demonstration of the limits and incongruencies of EN 60754-2 as an instrument for assessing the additional classification for acidity for cables. Finally, a statistical method to understand through pH and conductivity measurements if the scavenging mechanism acts in the condensed phase is presented. Full article

Combustion is the most advanced and proven method on the market for using agricultural by-product residues and waste from the agri-food industry. Currently, a wide range of combustion technologies is used to produce heat and electricity in low-power heating devices (>50 kW) using various types of biofuels from biomass (woody biomass, herbaceous biomass, waste and residues from the agri-food industry). Combustion of biomass fuels, especially those of wood origin, causes lower carbon dioxide (CO₂) and sulfur oxides (SO_x) emissions into the atmosphere compared to coal combustion. The growing interest in solid biofuels has contributed to intensive activities on improving the combustion process and energy devices enabling effective and economic conversion of chemical energy contained in biomass into other usable forms such as heat, electricity. Having good quality fuel, it is necessary to ensure an appropriate, clean combustion technique, which allows to achieve the highest thermal efficiency of the heating device and at the same time the lowest emission of pollutants. The article presents issues related to the theory, characteristics of the combustion process and problems related to the formation of harmful chemical compounds nitrogen oxides (NO_x), SO_x, carbon monoxide (CO), particulate matter (PM) emitted to the atmosphere during the combustion process in low-power heating devices. The analysis indicates the possibility of minimizing undesirable phenomena during the combustion of these biofuels related to ash sintering, the formation of deposits, corrosion and improving the amount of condensable solid particles formed and therefore reducing the emission of gaseous products to the environment. Full article

This work presents a comprehensive model for lignocellulosic biomass pyrolysis, addressing kinetics, energy balances, and gas product composition with the aim of its application in wood combustion. The model consists of a two-stage global mechanism in which biomass initially reacts into tar, char, and light gases (non-condensable gases), which is followed by tar reacting into light gases and char. Experimental data from the literature are employed for determining Arrhenius kinetic parameters and key energy parameters, like tar and char heating values and the specific enthalpy of primary and secondary reactions. A methodology is introduced to derive correlations, allowing the model’s application to diverse biomass types. This work introduces several novel approaches. Firstly, a pyrolysis model that determines the composition of light gases by solving mass, species, and energy balances is developed, limiting the use of correlations from the literature only for tar and char elemental composition. The mass rate of light gases, tar, and char being produced is also determined. Secondly, kinetic parameters for primary and secondary reactions are determined following a Shafizadeh and Chin scheme but with a modified Arrhenius form dependent on $T^n$, significantly enhancing the accuracy of product composition prediction. Additionally, correlations for the enthalpies of reactions, both primary and secondary, are determined as a function of pyrolysis temperature. Primary reactions exhibit an overall endothermic behavior, while secondary reactions exhibit an overall exothermic behavior. Finally, the model is validated using cases reported in the literature, and results for light gases composition are presented. Full article

The control of powder aging during Selective Laser Sintering (SLS) processing is one of the challenges to be overcome for the implementation of this technique in serial production. Aging phenomena, because of the elevated temperatures and long processing times, need to be considered when a fraction of the polymer powders present in the build chamber and not used to manufacture the parts are reused at various times. The aim of this study was to investigate the influence of successive reuse of blends of pure Polyamide 12 and its blends with two types of flame retardants (FR): ammonium polyphosphate (APP) and zinc borate (ZB). The composition of the blends was 70/30 (wt/wt) PA 12/FR. Four successive processing stages have been carried out by collecting the remaining powder blend each time. The powders were re-used using the same processing parameters after sieving. DSC measurements showed that the incorporation of FRs entailed a reduction in the processing window up to 4 °C; nevertheless, no further reduction was noted after aging. The TGA curves of aged blends of powders were also similar for pure PA 12 and PA 12 with FR. In addition, initial and reused powders presented a higher degree of crystallinity than the specimens processed from the powders. The heterogeneous character of the PA 12 after LS processing or reprocessing was shown through Pyrolysis Combustion Flow Calorimetry (PCFC) and cone calorimeter (CC) tests. FTIR analysis also showed that post-condensation reactions have occurred. The mode of action of the flame retardants was clearly seen on HRR curves at both tests. The first reuses of PA 12 powders entailed a significant reduction in time to ignition at the cone calorimeter (150 for the initial material to around 90 s for the reused material), indicating the formation of short polymer chains. Only in the case of zinc borate was it noticed that re-used powder was detrimental to the fire performance because of a strong increase in the value of pHRR (between 163 and 220 kW/m² for reused material instead of 125 kW/m² for the initial one). Full article

In order to study the effect of pressure on the ignition and combustion process of CL-20/NEPE solid propellant, the ignition delay, burning rate, and maximum combustion temperature of different solid propellant formulations with an ambient pressure of 0.1~8.0 MPa were measured experimentally by a solid propellant laser ignition experiment system, and the agglomeration process and the characteristics of condensed phase combustion products were analyzed. The experimental results show that, with the increase of pressure, the ignition-delay time decreases, and the burning rate and the maximum combustion temperature increase. With the increase of pressure, the influence on propellant ignition and combustion characteristics becomes smaller. In the experiment, the dynamic agglomeration phenomenon of aluminum particles in the propellant was recorded by a high-speed camera combined with a microscopic camera lens, and the dynamic agglomeration phenomenon of the combustion surface of the propellant and the dynamic agglomeration phenomenon, after the initial agglomeration was separated from the surface, were analyzed and expounded. Based on the experiment and combined with the agglomeration phenomenon, a mathematical model capable of predicting the particle size of aluminum aggregates was proposed. Full article

Incorporating silver wires into propellant has emerged as a highly effective strategy for enhancing propellant burning rates, a technique extensively deployed in the construction of numerous fielded sounding rockets and tactical missiles. Our research, employing a multi-faceted approach encompassing thermogravimetric-differential scanning calorimetry measurements (TG-DSC), combustion diagnoses, burning rate tests, and meticulous collection of condensed combustion products, sought to elucidate how variations in silver wire quantity and winding configuration impact the combustion properties of propellants. Our findings underscore the remarkable efficacy of double tightly twisted silver wire in significantly boosting propellant burning rates under ambient conditions. Moreover, at lower temperatures, the reduced gap between the propellant and silver wire further magnifies the influence of silver wire on burning rates. However, it is noteworthy that the relationship between burning speed and combustion efficiency is not deterministic. While a smaller cone angle of the burning surface contributes to heightened burning rates, it concurrently exacerbates the polymerization effect of vapor phase aluminum particles, consequently diminishing propellant combustion efficiency. Conversely, propellants configured with sparsely twinned silver wires exhibit notable enhancements in combustion efficiency, despite a less pronounced impact on the burning rate attributed to the larger cone angle of the burning surface. Remarkably, these trends persist at lower temperatures. Based on the principle of heat transfer balance, a theoretical model for the combustion of propellants with wire inserts is developed. The reliability of this theoretical model is validated through a comparison of calculated values with experimental data. Our research outcomes carry significant implications for guiding the application and advancement of the silver wire method in solid propellants for solid rocket motors, offering valuable insights to inform future research and development endeavors in this domain. Full article