Search Results (122)

Preserving historical porous materials requires careful monitoring of surface humidity to mitigate deterioration processes like salt crystallization, mold growth, and material decay. While microclimate monitoring is a recognized preventive conservation tool, its role in detecting surface-specific moisture risks remains underexplored. This study evaluates the relationship between indoor microclimate fluctuations and surface moisture dynamics across 13 historical sites in Northern Italy (Lake Como, Valtellina, Valposchiavo), encompassing diverse masonry typologies and environmental conditions. High-resolution sensors recorded temperature and relative humidity for a minimum of 13 months, and eight indicators—including dew point depression, critical temperature–humidity zones, and damp effect indices—were analyzed to assess the moisture risks. The results demonstrate that multivariate microclimate data could effectively predict humidity accumulation. The key findings reveal the impact of seasonal ventilation, thermal inertia, and localized air stagnation on moisture distribution, with unheated alpine sites showing the highest condensation risk. The study highlights the need for integrated monitoring approaches, combining dew point analysis, mixing ratio stability, and buffering performance, to enable early risk detection and targeted conservation strategies. These insights bridge the gap between environmental monitoring and surface moisture diagnostics in porous heritage materials. Full article

Transpiration cooling that utilizes the phase change of a liquid coolant is recognized as an effective thermal protection technique for extreme environments. However, the introduction of phase change within the porous structure brings about challenges, such as vapor blockage, pressure fluctuations, and temperature inversion, which critically influence system reliability. This study conducts numerical analyses of coupled processes of heat transfer, flow, and phase change in transpiration cooling using a Two-Phase Mixture Model. The simulation incorporates a Local Thermal Non-Equilibrium approach to capture the distinct temperature fields of the solid and fluid phases, enabling accurate prediction of the thermal response within two-phase and single-phase regions. The results reveal that under low heat flux, dominant capillary action suppresses dry-out and expands the two-phase region. Conversely, high heat flux causes vaporization to overwhelm the capillary supply, forming a superheated vapor layer and constricting the two-phase zone. The analysis also explains a paradoxical pressure drop, where an initial increase in flow rate reduces pressure loss by suppressing the high-viscosity vapor phase. Furthermore, a local temperature inversion, where the fluid becomes hotter than the solid matrix, is identified and attributed to vapor counterflow and its subsequent condensation. Full article

Background: Often, neoadjuvant therapy, which relies on the induction of double-strand breaks (DSBs), is used prior to surgery to shrink tumors by inducing cancer cell apoptosis. However, recent studies have suggested that this treatment may also induce a fluctuating state between senescence and stemness in PA-1 embryonal carcinoma cells, potentially affecting therapeutic outcomes. Thus, the respective epigenetic pathways are up or downregulated over a time period of days. These fluctuations go hand in hand with changes in spatial DNA organization. Methods: By means of Single-Molecule Localization Microscopy in combination with mathematical evaluation tools for pointillist data sets, we investigated the organization of euchromatin and heterochromatin at the nanoscale on the third and fifth day after etoposide treatment. Results: Using fluorescently labeled antibodies against H3K9me3 (heterochromatin tri-methylation sites) and H3K4me3 (euchromatin tri-methylation sites), we found that the induction of DSBs led to the de-condensation of heterochromatin and compaction of euchromatin, with a peak effect on day 3 after the treatment. On day 3, we also observed the co-localization of euchromatin and heterochromatin, which have marks that usually occur in exclusive low-overlapping network-like compartments. The evaluation of the SMLM data using topological tools (persistent homology and persistent imaging) and principal component analysis, as well as the confocal microscopy analysis of H3K9me3- and H3K4me3-stained PA-1 cells, supported the findings that distinct shifts in euchromatin and heterochromatin organization took place in a subpopulation of these cells during the days after the treatment. Furthermore, by means of flow cytometry, it was shown that the rearrangements in chromatin organization coincided with the simultaneous upregulation of the stemness promotors OCT4A and SOX2 and senescence promotors p21Cip1 and p27. Conclusions: Our findings suggest potential applications to improve cancer therapy by inhibiting chromatin remodeling and preventing therapy-induced senescence. Full article

As the integration of renewable energy sources continues to increase, thermal power units are increasingly required to enhance their operational flexibility to accommodate grid fluctuations. However, frequent load variations in conventional thermal power plants result in decreased efficiency, accelerated equipment wear, and high operational costs. In this context, molten-salt thermal energy storage (TES) has emerged as a promising solution due to its high specific heat capacity and thermal stability. By enabling the storage of surplus energy and its regulated release during peak demand periods, molten salt TES contributes to improved grid stability, reduced start-up frequency, and minimized operational disturbances. This study employs comprehensive thermodynamic simulations to investigate three representative schemes for heat storage and release. The results indicate that the dual steam extraction configuration (Scheme 3) offers the highest thermal storage capacity and peak-load regulation potential, albeit at the cost of increased heat consumption. Conversely, the single steam extraction configurations (Scheme 1 and 2) demonstrate improved thermal efficiency and reduced system complexity. Furthermore, Scheme 3, which involves extracting feedwater from the condenser outlet, provides enhanced operational flexibility but necessitates a higher initial investment. These findings offer critical insights into the optimal integration of molten-salt thermal-storage systems with conventional thermal power units. The outcomes not only highlight the trade-offs among different design strategies but also support the broader objective of enhancing the efficiency and adaptability of thermal power generation in a renewable-dominated energy landscape. Full article

This paper presents a study on the ring formation phenomenon in lime kilns using simulation. The research focuses on the chemical recovery cycle integrated into the pulp production process at a pulp mill, with particular emphasis on the calcium cycle within the lime kilns. Lime kilns are critical components, as their unavailability can significantly impact the overall cost-effectiveness of the facility. The calcination of lime sludge occurs in a rotary kiln, where calcium carbonate in the lime sludge is converted into calcium oxide (lime). Under certain conditions, material can progressively accumulate, leading to ring formation and eventual kiln clogging, resulting in operational downtime. To investigate this issue, the authors developed a physics-based model using a finite-dimensional, one-dimensional approach that considers only longitudinal variation. Several approximations were made to maintain a reasonable simulation time without compromising accuracy. Simulations based on real operational data identified fluctuations in fuel flow rate and sulfur content from non-condensable gases as key contributors to ring formation. The results showed that these fluctuations caused instability in the temperature profiles of the solids and gas beds, leading to periods of cooling before the lime sludge reaches the outlet to the coolers. This cooling promotes the recarbonation of lime and, consequently, the formation of rings. The findings highlight that stabilizing fuel flow and managing sulfur content could mitigate ring formation and improve kiln efficiency. The developed model provides a valuable tool for predictive analysis and process optimization, potentially supporting the development of a digital twin to enhance real-time monitoring and operational control. Full article

We discuss applications of the Dirichlet $\eta \left(s\right)$ function in physics. To this end, we provide an introductory description of one-dimensional (1D) ionic crystals, which are well-known in the condensed matter physics literature, to illustrate the central issue of the paper: A generalization of the Coulomb interaction between alternating charges in such crystalline structures. The physical meaning of the proposed form, characterized by complex (in the mathematical sense) ion–ion interactions, is argued to have emerged in many-body systems, which may include effects from vacuum energy fluctuations. We first consider modifications to the bare Coulomb interaction by adding an imaginary component to the exponent of the Coulomb law of the form $s=1+ib$, where b is a real number. We then extend the results to slower-decaying interactions, where the exponent becomes $s=a+ib$, presenting numerical results for values $1/2\le a\le 2$, which include the critical strip relevant to the Riemann hypothesis scenario. Full article

Oxalic acid is the most abundant low-molecular-weight dicarboxylic acid in the atmosphere, and it plays a crucial role in the formation of new particles and cloud condensation nuclei. However, most observational studies have focused on particulate oxalate, leaving a significant knowledge gap on oxalic acid vapor. This study investigated the concentrations and formation of oxalic acid vapor and oxalate in PM_2.5 at a rural tropical coastal island site in south China across different seasons, based on semi-continuous measurements using an Ambient Ion Monitor-Ion Chromatograph (AIM-IC) system. We replaced the default 25 μL sampling loop on the AIM-IC with a 250 μL loop, improving the ability to distinguish the signal of oxalic acid vapor from noise. The data revealed clear seasonal patterns in the dependent daytime and nighttime formation of oxalic acid vapor, benefiting from high signal-to-noise ratios. Specifically, concentrations were 0.059 ± 0.15 μg m⁻³ in February and April 2023, exhibiting consistent diurnal variations similar to those of O₃, likely driven by photochemical reactions. These values decreased to 0.021 ± 0.07 μg m⁻³ in November and December 2023, with higher nighttime concentrations likely related to dark chemistry processes, amplified by accumulation due to low mixing layer height. The concentrations of oxalate in PM_2.5 were comparable to those of oxalic acid vapor, but exhibited (3–7)-day variations, superimposed on diurnal fluctuations to varying degrees. Additionally, thermodynamic equilibrium calculations were performed on the coastal data, and independent size distributions of particulate oxalate in the upwind marine atmosphere were analyzed to support the findings. Full article

In this study, we utilize information theory tools to investigate notable features of the quantum degree of mixedness ($C_f$) in a finite model of N interacting fermions. This model serves as a simplified proxy for an atomic nucleus, capturing its essential features in a more manageable form compared to a realistic nuclear model, which would require the diagonalization of matrices with millions of elements, making the extraction of qualitative features a significant challenge. Specifically, we aim to correlate $C_f$ with particle number fluctuations and temperature, using the paradigmatic Lipkin model. Our analysis reveals intriguing dependencies of $C_f$ on the total fermion number, showcasing distinct behaviors at different temperatures. Notably, we find that the degree of quantum mixedness exhibits a strong dependence on the total fermion number, with varying trends across different temperature regimes. Remarkably, this dependence remains unaffected by the strength of the fermion–fermion interaction (as long as it is non-zero), underscoring the robustness of the observed phenomena. Through comprehensive numerical simulations, we provide illustrative graphs depicting these dependencies, offering valuable insights into the fundamental characteristics of quantum many-body fermion systems. Our findings illuminate the intricate dynamics of the degree of mixedness, a crucial quantum property, with potential implications for diverse fields ranging from condensed matter physics to quantum information science. Full article

The impact of dynamic processes on equilibrium properties is a fundamental issue in condensed matter physics. This study investigates the intrinsic ferromagnetism generated by memory effects in the low-dimensional continuous symmetry Landau–Ginzburg model, demonstrating how memory effects can suppress fluctuations and stabilize long-range magnetic order. Our results provide compelling evidence that tuning dynamical processes can significantly alter the behavior of systems in equilibrium. We quantitatively evaluate how the emergence of the ferromagnetic phase depends on memory effects and confirm the presence of ferromagnetism through simulations of hysteresis loops, spontaneous magnetization, and magnetic domain structures in the 1D continuous symmetry Landau–Ginzburg model. This research offers both theoretical and numerical insights for identifying new phases of matter by dynamically modifying equilibrium properties. Full article

The Coqueiros Formation, a strategic stratigraphic unit within the Lagoa Feia Group (LFG) in the Campos Basin offshore Brazil, is known for its lacustrine carbonate deposits, which include both organic-rich shales and economically important “coquina” reservoirs. While coquina facies are widely recognized as reservoirs, the source-rock potential of the intercalated shales remains relatively underexplored. This study aims to characterize the mineralogy and thermal maturity of the Coqueiros Formation to assess its potential as a source rock, using a multi-technique approach integrating X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Raman spectroscopy analyses of shale samples from two wells: 3-BP-11-RJS and 6-DEV-18P-RJS. XRD analyses revealed a heterogeneous mineralogy dominated by carbonates (calcite and dolomite) and quartz, with significant contributions from clay minerals and trace minerals such as pyrite and barite. SEM imaging revealed a heterogeneous fabric with grain size, morphology, and porosity variations, reflecting a dynamic lacustrine depositional setting influenced by storm events and fluctuations in terrigenous input. The presence of authigenic minerals, as reported in other studies, such as saddle dolomite, mega-quartz, and various sulfides, provides evidence for hydrothermal alteration, likely related to Late Cretaceous magmatic activity in the Campos Basin. Raman spectroscopy yielded equivalent vitrinite reflectance (Ro%) values consistently exceeding 1.00, ranging from 1.03 to 1.40, indicating that the organic matter in the Coqueiros Formation shales has attained a high thermal maturity level, surpassing the oil window and reaching the condensate wet gas zone. The mineralogical and equivalent maturation data presented herein provide a valuable foundation for future studies, highlighting the complexity and heterogeneity of the Coqueiros Formation and its potential significance as a source rock within the Campos Basin petroleum system. Full article

Enhancing the energy efficiency and climate resilience of existing buildings is crucial amid growing environmental challenges. While extensive research has focused on non-residential buildings, studies on thermo-hygrometric conditions in warehouse-type buildings, particularly in subtropical climates, remain limited. This study investigated the impact of building envelope deficiencies on indoor thermal and moisture regulation at the Nori Distribution Center. Using infrared thermal imaging and long-term environmental monitoring, significant thermo-hygrometric fluctuations were identified, primarily due to design and construction deficiencies. Poor insulation, inadequate sealing, and the lack of moisture barriers contributed to unstable indoor temperature and humidity. Seasonal analysis showed that during summer, the median second-floor air temperature reached 28.8 °C, peaking at 39.2 °C, with relative humidity exceeding 70% for 45% of the time. First-floor relative humidity surpassed 70% for 72% of the time. While condensation risk remains low year-round, it increases significantly with air infiltration through gaps in the building envelope. This study recommends enhancing the sealing of the building envelope, upgrading insulation materials and moisture barriers, particularly in the roof, and optimizing the HVAC system to improve energy efficiency and storage conditions. These findings offer valuable recommendations for retrofitting warehouse-type buildings in subtropical climates to improve energy efficiency and climate resilience. Full article

Because of its low concentration and low energy in an organic Rankine cycle (ORC) system, more than 50% of low-grade thermal energy with a temperature below 300 °C is not taken seriously. The relationship between changeable working condition parameters and operating parameters is typically not taken into account in a model while studying ORC systems. It is insufficient to analyze the system performance changes solely on changes in the performance parameters of the heat exchangers. Furthermore, a model perspective of the system control solution is absent from the steady-state control of the system when the heat source varies. In this paper, we created a system model for the application scenario of a 100–200 kW ORC system with brazed plate heat exchangers in order to address the aforementioned issues using MATLAB R2016b. Additionally, a sensitivity analysis of the system was conducted based on heat exchangers of performance variations. In addition, a modeling computation and adjustment scheme were put forth to guarantee that the system could continue to produce steady power production even when the temperature of the heat source fluctuated. Preliminary results showed that the system’s internal parameters included its evaporation pressure and condensation temperature. An increase in evaporation pressure will reduce the mass flow rate and heat flux of an evaporator, thus reducing the heat transfer coefficient. The two-phase region of the evaporator accounted for the highest proportion, of 70.22%, and continued to increase to 75.83%, followed by the supercooling region, and gradually decreasing. The utilization rate of the evaporator decreased from 74.85% to 38.32%. The system output power increased first and then decreased, with a maximum value of 153.11 kW. The system efficiency increased from 5.74% to 11.04%. The increase in condensation temperature increased the proportion of the two-phase region and the superheating region, and the mass flow rate did not change much. The increase in heat flux increased the heat transfer coefficient from 1721.31 W/(m²·K) to 2374.77 W/(m²·K), and the utilization rate of the evaporator decreased from 70.56% to 51.91%. The aforementioned change rules were used in the building of the steady-state regulation model to balance out the changes in the generating power as the heat source temperature increased. The model output was cross-checked and validated against pertinent experimental test literature data. The results of this research can serve as a valid and useful guide for ORC system design and practical applications. Full article

Gravity-assisted separation heat pipes (GSHPs) are extensively utilized in telecommunications base stations and data centers. To ensure year-round cooling, integrating GSHPs directly with a vapor compression refrigeration system is a viable solution. It is unavoidable that the refrigeration system’s lubricant will infiltrate the heat pipe loop, thereby affecting its thermal performance. This paper examines the performance of a GSHP, which features a water-cooled plate heat exchanger as the condenser and a finned-tube heat exchanger as the evaporator, when the working fluid (R134a) is contaminated with a lubricant (POE, Emkarate RL-46H). The findings are compared with those from a system free of lubricant. The experimental outcomes indicate that the presence of lubricant degrades the heat transfer efficiency, particularly when the filling ratio is adequate and no significant superheat is observed at the evaporator’s outlet. This results in a 3.86% increase in heat transfer resistance. When the charge of the working fluid is suboptimal, the average heat transfer resistance remains relatively constant at a 3% lubricant concentration yet increases to approximately 5.27% at a 4–6% lubricant concentration, and further to 12.32% at a 9% lubricant concentration. Concurrently, as the lubricant concentration fluctuates between 3% and 9%, the oil circulation ratio (OCR) varies from 0.02% to 0.11%. Full article

On 31 July 2021, Ningbo, an eastern coast city in China, experienced a severe convective rainstorm, characterized by intense short-duration precipitation extremes with a maximum rainfall rate of 130 mm h⁻¹. In this research, we first analyzed this rainstorm using Doppler radar and precipitation observation and then conducted high-resolution simulation for it. A three-dimensional precipitation diagnostic equation is introduced to quantitatively analyze the microphysical processes during the rainstorm. It is shown that this rainstorm was triggered and developed locally in central Ningbo under favorable large-scale quasi-geostrophic conditions and local conditions. In the early stage, the precipitation increase is mainly driven by the strong convergence of water vapor, and a noticeable increase in both the intensity and spatial extent of uplift promotes the upward transportation of water vapor. As the water vapor flux and associated convergence weaken in the later stage, the precipitation reduces accordingly. Cloud microphysical processes are also important in the entire precipitation process. The early stage updraft supports the escalations in raindrops, with the notable fluctuations in raindrop concentrations directly linked to variations in ground precipitation intensity. The behavior of graupel particles is intricately connected to their melting as they fall below the zero-degree layer. Although cloud water and snow exhibit changes during this period, the magnitudes of these adjustments are considerably less pronounced than those in raindrops and graupels, highlighting the differentiated response of various condensates to the convective dynamics. These results can help deepen the understanding of local severe rainstorms and provide valuable scientific references for practical forecasting. Full article

This study aims to provide condensation heat transfer coefficients of R600a (isobutane) refrigerant under mass fluxes between 50 and 98 kg/m²·s at saturation temperatures of 35 °C, 40 °C and 45 °C. Additionally, experiments are conducted with varying inlet vapour quality to understand its effect on the condensation heat transfer measurement. An aluminium multiport microchannel with a hydraulic diameter ($D_h$) of 0.399 mm is used, where a plexiglass cover is mounted on the top of the microchannels to observe the flow conditions. A 1D heat transfer through the aluminium block is assumed, and heat flux through the refrigerant to the coolant is measured to obtain condensation heat transfer coefficients of R600a. The results showed that decreasing saturation temperature and increasing vapour quality increase the condensation heat transfer coefficient. Increasing refrigerant mass flux increases the heat transfer coefficient up to a specific mass flux. It is observed that the effect of inlet vapour quality becomes significant as introduced quality decreases due to increasing fluctuation. Full article