Search Results (2,126)

Carbon nanotube (CNT)-reinforced composites are promising advanced materials due to their exceptional mechanical properties. This paper presents a comprehensive investigation of the mechanical behavior of CNT/epoxy composites through theoretical modeling and experimental validation. An equivalent cylindrical fiber model was developed to transform CNTs into effective reinforcement phases, enabling the application of classical composite mechanics. Three reinforcement configurations were analyzed: two unidirectional short fiber models (aligned and staggered) and a three-dimensional four-directional braided long-fiber model. The effects of geometric parameters, including the diameter-to-thickness ratio (D/t) and fiber aspect ratio, on the effective elastic moduli were systematically evaluated. Static and dynamic compression experiments were conducted using an MTS 810 testing system and a Split Hopkinson Pressure Bar (SHPB) to examine the influence of loading rate, vacuum treatment, and reinforcement type (CNT, SiC, and hybrid SiC/CNT) on composite strength. The results indicated that 3 wt% CNT reinforcement increases the Young’s modulus by 30% under static loading and enhanced the dynamic compressive strength under impact loading. The vacuum degassing process significantly affected composite quality, with insufficient vacuum leading to strength degradation due to void formation. Theoretical predictions using Mori–Tanaka and dilute methods showed good agreement with experimental results at low reinforcement volume fractions. Scanning electron microscopy revealed uniform CNT dispersion and provided insights into failure mechanisms, including CNT pull-out and breakage. This work contributes to the understanding of structure–property relationships in CNT-reinforced polymer composites and provides guidelines for achieving their optimal design. Full article

Sustainable lightweight materials based on renewable resources have attracted increasing attention as alternatives to synthetic materials. However, developing nanocellulose cryogels with adequate structural integrity and efficient retention of phenolic compounds remains challenging, often requiring furanic and dialdehyde-based additives associated with environmental and health concerns. In this context, tannin-containing nanocellulose cryogels were produced using vanillin and hydrogen peroxide as sustainable modification agents. The effects of the additives on the structural, morphological, colorimetric, mechanical, thermal, and leaching properties of the cryogels were investigated. FTIR and colorimetric analyses revealed the presence of phenolics and the effect of hydrogen peroxide. SEM analysis showed that tannin promoted structural densification, whereas peroxide induced fragmentation of the cryogel network and pore reorganization. These changes influenced density and mechanical performance, with nanocellulose-tannin exhibiting the highest compressive strength and elastic modulus. Thermal conductivity values remained within the range reported for highly porous lignocellulosic materials (38.93–43.79 (mW/m·K)). Tannin leaching demonstrated that peroxide significantly improved tannin retention, especially in the system including vanillin which exhibited only 13,61% tannin release. Overall, vanillin and hydrogen peroxide modified the supramolecular organization and functional properties of the cryogels, highlighting their potential as additives in porous materials for thermal insulation and adsorption applications. Full article

The present work reports on the microstructural and micro-mechanical characterization of Ti-Nb-HA-based composites. The composites were prepared via a spark plasma sintering (SPS) consolidation process. The effect of two distinct levels of hydroxyapatite (HA) content (e.g., 10 and 20 wt.%) on the microstructural and micro-mechanical properties were investigated via in situ micro-pillar compression, and the results were compared against a sole Ti-Nb composite. The microstructure of the composites was composed of parent Ti and Nb grains, together with the reaction products; due to the decomposition of HA, there was a rise in different biocompatible phases. The Vickers hardness of the composite was sensitive to applied loads due to the presence of pores and voids, which was foreseen to be beneficial when the composite was used as an implant, according to the literature. The addition of 20 wt.% HA causes a decrease in hardness to 990 HV, compared to 1109 HV for 10 wt.% HA and 1275 HV for sole Ti-Nb. The addition of HA into Ti-Nb also lowers the compressive strength from 553 MPa for Ti-Nb to 189 MPa for Ti-30Nb-20HA. This was accompanied by a reduction in the elastic modulus, from 130 GPa for Ti-Nb to 29 GPa for Ti-30Nb-20HA. The deformation mechanism was ductile-dominated in all cases, with the presence of a quasi-brittle nature for HA-containing composites. Full article

Ultra-high-performance concrete (UHPC) is known for its exceptional compressive strength and durability; however, its brittle nature requires fiber reinforcement to improve toughness and tensile performance. This study investigates the synergistic effects of triple fiber reinforcement, including desized and sized carbon fibers (0.2–1.0 vol%), steel fibers (1.0 vol%), and polypropylene fibers (0.2 vol%) on the fresh, mechanical, durability, microstructure, and fire resistance properties of UHPC. The experimental program included workability, compressive and flexural strength, load-deflection behavior, electrical resistivity, dynamic modulus of elasticity, SEM analysis, and fire resistance at elevated temperatures (425 and 900 °C). The results showed that desized carbon fibers performed better than sized fibers by improving workability, fiber dispersion, flexural behavior, and fiber–matrix bonding. The optimal triple-fiber composition, DC1.0P0.2S1.0, achieved the highest flexural strength of 24 MPa while maintaining compressive strength above 141 MPa. The triple-fiber system provided effective multi-scale crack control, where PP fibers prevented explosive spalling, carbon fibers bridged meso-crack control, and steel fibers enhanced macro-crack load transfer and ductility. SEM analysis further confirmed better dispersion and stronger interfacial bonding of desized carbon fibers. Overall, the optimized triple-fiber system significantly improved flexural performance, toughness, workability, and fire resistance without notably reducing compressive strength, demonstrating strong potential for advanced structural applications. Full article

Durability tests were performed on concrete representative of nuclear power plant structures exposed to boric acid leakage. Boric acid is widely used in pressurized water reactor systems for neutron absorption and chemical control; therefore, accidental leakage or evaporation-induced concentration of borated water can create an important durability concern for adjacent concrete structures. Three boric acid concentrations (0, 2500 and 18,000 ppm) and two temperature levels (20 and 60 °C) were considered. The evolution of cube compressive strength and elastic modulus with exposure age was examined over 180 days. The results show a slight increase in concrete strength and stiffness during the early stage of exposure, followed by a continuous increase in the loss ratios of cube compressive strength and elastic modulus at later ages. The maximum measured strength–loss ratio was 4.684%, and the maximum measured elastic modulus–loss ratio was 1.755%. A service life prediction model based on loss ratio parameters was then developed from the test results. The fitted examples gave high coefficients of determination (R² = 0.9960 for cube compressive strength and R² = 0.9947 for elastic modulus), indicating that the proposed model can support durability assessment and aging management of boric-acid-corroded concrete structures in nuclear power plants. Full article

To establish a quantitative mapping relationship between macro- and micro-parameters in the PFC^2D parallel bonding model, and in view of the inherent complexity of the mutual validation process between laboratory experiments and parameter calibration, this paper takes uniaxial compression tests as the mechanical reference. By combining orthogonal experimental design, Pearson correlation analysis and multivariate analysis of variance, this study systematically investigates the effects of 10 micro-parameters on 6 macro-mechanical indicators (modulus of elasticity E, Poisson’s ratio ν, uniaxial compressive strength ${\sigma }_c$, friction-to-cohesion ratio FCR, crack initiation strength ${\sigma }_{ci}$ and crack damage stress ${\sigma }_{cd}$). To reduce the coupling dimension between cohesion and internal friction angle in the calibration of PFC macro–micro parameters, this paper defines the Friction-to-Cohesion Ratio (FCR) as the ratio of the equivalent macroscopic angle of internal friction to the equivalent macroscopic cohesion, and systematically conducts sensitivity analyses of uniaxial compression simulations. The results indicate that the elastic modulus E is primarily governed by $E^{\ast }$, ${\overline{E}}^{\ast }$, ${\overline{k}}^{\ast }$ and $R_f$; the Poisson’s ratio ν is mainly influenced by $E^{\ast }$, $k^{\ast }$, ${\overline{E}}^{\ast }$, ${\overline{k}}^{\ast }$ and $R_f$; the uniaxial compressive strength ${\sigma }_c$, the crack initiation strength ${\sigma }_{ci}$ and the crack damage stress ${\sigma }_{cd}$ are primarily regulated by ${\overline{\sigma }}_c$ and $R_f$; whilst the Friction-to-Cohesion Ratio (FCR) is mainly affected by ${\overline{\sigma }}_c$, $\overline{\phi }$, $R_f$, $\overline{c}$ and $\beta$; Elasticity parameters and strength parameters are governed by different micro-mechanisms, reflecting the fundamental decoupling of stiffness and strength in the PFC model. This study established a progressive ‘screening–validation–quantification’ sensitivity analysis framework, revealing the directional regulation patterns of various micro-parameters on macroscopic responses, thereby providing a theoretical basis for the targeted optimisation and efficient calibration of micro-parameters in PFC discrete element simulations. Full article

Freeze–thaw cycles cause mechanical deterioration and instability of slope rock masses in open-pit coal mines located in the cold regions of Northwest China. In this study, the research object is fine-grained sandstone from the Yan’an Formation in the Tarangole mining area of the Ordos Basin. Here, indoor freeze–thaw cycling, uniaxial compression, and triaxial compression tests were conducted to systematically analyze the deformation behavior, strength evolution, and failure modes of the sandstone under varying numbers of freeze–thaw cycles, freezing temperatures, and confining pressures, thereby revealing its freeze–thaw damage mechanism. The results show that the number of freeze–thaw cycles is the dominant factor affecting the elastic modulus. Freezing temperatures (especially between −5 °C and −15 °C) and the number of freeze–thaw cycles (particularly the first 10 cycles) significantly reduce peak strength. In addition, confining pressure can significantly enhance the resistance to deformation (under 15 freeze–thaw cycles, the elastic modulus increases by 181.8% as confining pressure rises from 0 to 2 MPa). Within the low confining pressure range (0–1.5 MPa), peak strain decreases monotonically with increasing confining pressure and is independent of the number of freeze–thaw cycles. Finally, the increase in the number of freeze–thaw cycles and the decrease in temperature jointly promote crack development, and the failure mode shifts from pure shear to a shear-tension composite mode. The underlying cause lies in the evolution of interparticle cementation within the soil skeleton and in the associated pore–crack structure. In addition, based on fracture damage mechanics and the modified Weibull distribution, a damage evolution equation and a constitutive model for sandstone considering freeze–thaw cycles and temperature effects were established and validated. Therefore, the research findings can provide a theoretical basis for slope support, freeze–thaw disaster prevention and mitigation, and stability assessment in the Tarangole mining area and other cold regions. Full article

Geopolymer concrete contains inorganic aluminosilicate polymer gels formed through the activation of industrial solid wastes. This study investigated the effects of fly ash (FA) and silica fume (SF) on the durability and microstructure of geopolymer concrete exposed to freeze–thaw cycles and single-side salt erosion. Five mixtures were prepared using Baioheng geopolymer cement, with FA replacement levels of 15% and 25% and SF replacement levels of 3% and 5%. Mechanical tests, freeze–thaw tests, single-side salt-freezing tests, SEM-EDS, XRD, and CT analysis were conducted to evaluate the relationship between macroscopic performance and inorganic polymer gel structure. The results showed that 25% FA reduced compressive strength and freeze–thaw resistance, mainly due to insufficient reaction products and increased defect connectivity. In contrast, 3% SF improved the 56 d compressive strength by 13.24%, maintained the relative dynamic elastic modulus at 86.64% after 100 freeze–thaw cycles, and limited the mass loss to 0.72%. SEM-EDS and XRD results indicated that appropriate SF addition increased the Si/Al ratio and promoted the formation of C-(A)-S-H/N-A-S-H-related gel products, leading to a denser inorganic polymer matrix. However, excessive SF weakened the improvement effect, possibly due to local heterogeneity and dispersion difficulty. These results indicate that controlling the composition and spatial distribution of inorganic aluminosilicate polymer gels is essential for improving the salt-frost durability of geopolymer concrete. Full article

Alkali-activated materials (AAMs) based on industrial by-products, such as ground granulated blast furnace slag (GGBFS), are increasingly considered sustainable alternatives to Ordinary Portland Cement (OPC) due to their lower environmental impact and favorable mechanical performance. Among the key parameters controlling the behavior of alkali-activated systems, the chemical composition and modulus of the alkaline activator play critical roles in determining the reaction kinetics and material properties. This study investigates the influence of potassium silicate modulus (Ms), defined as the molar ratio of silica to alkali oxide (SiO₂/K₂O), on the reactivity, setting time, flowability, and mechanical properties of alkali-activated slag pastes. Potassium silicate solutions with moduli ranging from 1.0 to 2.5 were used as activators for GGBFS. Paste specimens with different activator moduli were prepared and cured at 20 °C and 75% relative humidity for mechanical testing. The results show that the activator modulus significantly affects the fresh properties, particularly at higher modulus values. Increasing the modulus delays reactivity and prolongs the setting time, whereas the flowability of the fresh paste decreases. Nevertheless, the flowability of the mixtures remained sufficient to allow proper penetration between open textile meshes, which is essential for textile-reinforced cement/concrete (TRC) applications. No clear systematic trends were observed in the mechanical properties, including the elastic modulus, flexural strength, and compressive strength. Full article

Carbon-fiber reinforced polymer (CFRP) tendons have attracted increasing attention as corrosion-resistant prestressing elements for prestressed concrete and cable-supported structures; however, their practical implementation requires reliable verification of long-term mechanical performance and anchorage reliability. In this study, a 9.5 mm pultruded CFRP tendon and compression-type anchorage system were developed and experimentally evaluated through relaxation, creep rupture, and fatigue tests. The tendon exhibited a tensile strength of 2501 MPa and an elastic modulus of 132.5 GPa. Relaxation tests were conducted at an initial load corresponding to 70% of the ultimate tensile capacity, and the measured relaxation loss after 1000 h was 1.02%. Based on logarithmic regression of the measured data, the relaxation loss at 1,000,000 h was estimated to be 2.11%; however, this value should be interpreted as an extrapolated long-term estimate rather than a directly verified result. Creep rupture tests performed at load ratios of 82.4–100.0% yielded an estimated 1,000,000 h creep rupture load ratio of approximately 80%, although the prediction is subject to uncertainty because of the limited number of specimens and scatter in rupture times. Fatigue tests indicated that the CFRP tendon–anchorage assembly maintained stable performance up to 2,000,000 cycles without measurable degradation in elastic stiffness under the adopted loading conditions. These results suggest that the developed CFRP tendon–anchorage system has promising potential for prestressing applications, while further long-term tests with a larger number of specimens are required to improve the statistical reliability of the extrapolated relaxation and creep rupture predictions. Full article

Modulating the physical crosslink architecture of gelatin methacryloyl (GelMA) hydrogels without altering total polymer concentration or introducing exogenous components remains a central challenge in biomaterial design. Here, we present a source blending strategy in which porcine skin gelatin (PG) and salmon skin gelatin (SG), two gelatins with markedly different proline and hydroxyproline contents, are combined at seven compositional ratios (PG weight fractions 0–1.0) and subsequently functionalized to GelMA under standardized conditions (8% v/v methacrylic anhydride, 60 °C, 3 h). Near-complete degrees of substitution (95–98%) were achieved across all formulations, as confirmed by both TNBS and ¹H-NMR analyses. In the parent gelatin mixtures, increasing PG fraction progressively increased viscosity, elastic modulus (G′), gelation temperature (Tgel), and compression modulus at 4 °C, with DSC revealing independent SG (0–15 °C) and PG (20–40 °C) endothermic transitions that suggest partial hindrance of PG triple-helix formation by high SG fractions. These composition-dependent trends were preserved after functionalization to GelMA, albeit with attenuated physical crosslinking due to steric impairment by the methacrylate groups. Photocrosslinked GelMA hydrogels fabricated after pre-incubation at 4 °C exhibited systematically higher compression moduli and lower swelling degrees with increasing PG content, demonstrating that the PG/SG ratio provides an effective means for independently tuning hydrogel mechanics and mesh architecture. In vitro release assays using Rhodamine 6G further demonstrated that pre-incubation at 4 °C prior to photocrosslinking effectively modulates transport kinetics in SG-PG GelMA hydrogels. This strategy delayed characteristic release times and constrained Weibull shape parameters to the anomalous-transport regime (0.75 < β < 1), where diffusion is governed by network chain relaxation. This effect was most pronounced in the 0.4SG:0.6PG formulation, where lower SG content permitted unhindered triple-helix formation, as corroborated by DSC and compression studies. Ultimately, adjusting the pre-incubation temperature and gelatin source combination provides a straightforward, processing-additive-free strategy to achieve programmable release profiles via controlled matrix tortuosity. Full article

High-temperature temporary sealing operations require liquid plug materials that can be placed as low-viscosity precursors, converted into mechanically stable networks under reservoir temperature, and subsequently removed after service. Existing epoxy-based sealing systems generally provide high post-curing strength, but the coordination among pumpability, thermally triggered curing, and post-service degradability remains insufficiently addressed. In this work, an epoxidized soybean oil (ESO)-modified epoxy–anhydride liquid plug was designed to regulate these sequential stages within a single material system. The precursor formulation, rheological transition, curing kinetics, mechanical response, network structure, and degradation behavior were evaluated using viscosity monitoring, curing-time tests, DSC, compression testing, DMA, gel fraction and swelling measurements, FTIR, and high-temperature degradation experiments. The optimized precursor exhibited an initial viscosity of 65.4 ± 2.1 mPa·s, remaining below the pumpability threshold of 100 mPa·s before curing. Its curing time was adjustable within 1–10 h at 120–140 °C through temperature and initiator regulation. ESO incorporation produced a non-monotonic mechanical response, with the optimized network reaching a compressive strength of 112.5 ± 3.5 MPa and an elastic modulus of 142.50 ± 5.26 MPa. FTIR and thermal–mechanical analyses supported the formation of an ester-rich epoxy–anhydride network containing both rigid epoxy-derived segments and ESO-derived flexible chains. In the post-service stage, degradation was strongly temperature dependent, with the characteristic unsealing time decreasing from 84 h at 120 °C to 24 h at 130 °C and 18 h at 140 °C. The combined results define a coupled curing–degradation window in which pumpable placement, thermal network formation, load-bearing sealing, and controlled unsealing are temporally separated but structurally connected. Full article

Scaffolds designed for mechanically demanding soft tissue engineering applications should integrate mechanical support, efficient mass transfer, and good cellular compatibility. This work presents a one-pot method based on “radical-free click chemistry + carbodiimide coupling” to produce a double-network (DN) PEG–alginate cryogel. The PEG network is formed by a Michael addition reaction between thiol-based crosslinker and 8-arm PEG-acrylate. The second network is covalently crosslinked through EDC/NHS-mediated coupling of carboxyl groups in alginate and adipic acid dihydrazide (AAD). The subsequent freezing and gelation of the gel precursor at sub-zero temperatures results in an ice templated cryogel with an interconnected macroporous network. These cryogels demonstrate high elasticity, compressive modulus and rapid swelling equilibrium in aqueous environments, as well as controlled degradation under physiological conditions. Compared to the classical Ca²⁺ ion crosslinking systems, the covalent linking of the alginate in the double-network cryogel shows advantages in mechanical and structural stability. In addition, it is cell-compatible and allows culture of mesenchymal stem cells (MSCs) with homogeneous infiltration. Furthermore, the double-network cryogels supports chondrogenic differentiation of MSCs upon treatment with chondrogenic media or macrophage-conditioned media for a short period of time. These results indicate that crosslinking chemistry and polymer composition can be used to modulate the balance between mechanical performance and degradation behavior, while maintaining cytocompatibility and an interconnected macroporous network, thereby providing a scaffold design strategy for applications that require coordinated mechanical support and mass transfer, such as cartilage-related tissue engineering. Full article

Freeze–thaw durability of 3D-printed engineered cementitious composites (3DP-ECC) is strongly affected by print-induced interlayer defects and anisotropy, particularly in cold regions. This study investigated Cast-ECC and Z-direction 3DP-ECC incorporating Yellow River sediment (YRS) as an equal-mass replacement for quartz sand at 0–100%. Compressive, three-point bending, and four-point bending tests, relative dynamic elastic modulus (RDME), XCT, MIP, SEM–EDS, and Weibull damage modeling were used to evaluate degradation up to 150 freshwater freeze–thaw cycles. Moderate YRS replacement (25–50%) improved particle packing, reduced visible defects, and refined the pore structure, thereby enhancing frost resistance. The R50 mixture showed the best residual performance: after 150 cycles, compressive strength decreased from 55 to 46 MPa in Cast-ECC and from 54 to 44 MPa in 3DP-ECC, corresponding to retention rates of 83.6% and 81.5%, respectively. The residual peak load in four-point bending of 3DP-ECC-R50 was 15.4% lower than that of Cast-ECC-R50, confirming the detrimental role of interlayer defects under loading perpendicular to the layers. RDME-based Weibull fitting described the overall damage evolution (R² = 0.876–0.994), while XCT, MIP, and SEM–EDS indicated that interlayer discontinuities, pore-structure evolution, and local microstructural degradation governed anisotropic deterioration. The results support durability-oriented design of YRS-based 3DP-ECC in cold regions. Full article

To clarify the influence of α (rock–coal height ratio) and λ (rock–coal strength ratio) on the mechanical properties and failure characteristics of coal–rock composite specimens, where the weaker component varies with rock properties, four sets of coal–rock composite specimens with λ values of 0.26, 0.35, 0.59, and 3.81 were subjected to uniaxial compression tests under conditions of α = 1:3, 1:1, and 3:1. The results show that: There are significant differences in the mechanical properties of coal–rock composite specimens compared to individual coal and rock specimens. Both α and λ have significant effects on the mechanical properties and failure modes of coal–rock composite specimens. The variation in uniaxial compressive strength, elastic modulus, and peak strain in coal–rock composite specimens with respect to α is significantly influenced by rock properties. These variation patterns are not entirely identical for different rock properties. For coal–rock composite specimens at different α values, the trends in uniaxial compressive strength, elastic modulus, and peak strain as a function of λ are identical. Both uniaxial compressive strength and elastic modulus exhibit a pattern of increasing rapidly at first and then more slowly with increasing λ, and both can be quantitatively described by exponential functions. Peak strain follows a pattern of rapid decrease, rapid increase, and gradual increase with increasing λ. However, for any given change in λ, the magnitude of the changes in uniaxial compressive strength, elastic modulus, and peak strain is significantly influenced by α. When λ is small or large, the weaker component in the coal–rock composite specimen is the primary source of failure. When λ falls within a certain range, both the strong and weak components undergo relatively complete failure. When λ increases beyond a critical value, only the weaker component fails, while the stronger component remains intact and does not fail. As α increases, the degree of failure in the coal–rock composite specimen gradually decreases. Full article