Search Results (161)

The burgeoning crisis of plastic waste accumulation necessitates innovative approaches towards sustainable packaging solutions. Polylactic acid (PLA), a leading biopolymer, emerges as a promising candidate in this realm, especially for environmentally friendly packaging. PLA is renowned for its compostable properties, offering a strategic avenue to mitigate plastic waste. However, its dependency on specific industrial composting conditions, characterized by elevated temperatures, humidity, and thermophilic microbes, limits its utility for household composting. This study aims to bridge the research gap in PLA’s recyclability and explore its feasibility in mechanical recycling processes. The research focuses on assessing the mechanical characteristics of PLA and PLA-based composites post-recycling. Specifically, we examined the effects of two extrusion methods—conical and parallel—on PLA and its composites containing 20 wt.% basalt fibers (BF). The recycling process encompassed repeated cycles of hot melt extrusion (HME), followed by mechanical grinding to produce granules. These granules were then subjected to injection moulding (IM) after 1, 3 and 5 recycling cycles. The tensile properties of the resulting IM-produced bars provided insights into the material’s durability and stability. The findings reveal that both PLA and PLA/BF composites retain their mechanical integrity through up to 5 cycles of mechanical recycling. This resilience underscores PLA’s potential for integration into existing recycling streams, addressing the dual challenges of environmental sustainability and waste management. The study contributes to the broader understanding of PLA’s lifecycle and opens new possibilities for its application in eco-friendly packaging, beyond the limits of composting. The implications of these findings extend towards enhancing the circularity of biopolymers and reducing the environmental footprint of plastic packaging. Full article

The growing concern for environmental sustainability has led to an increased interest in biodegradable materials derived from renewable resources. This study explores the innovative use of residual biomass from the green photosynthetic microalga Chlamydomonas reinhardtii, left over after polysaccharide extraction, as a natural filler in the development of the compostable protein-based material SP-Milk^®. The microalgal biomass was characterized using Fourier transform infrared spectroscopy (FTIR) and UV-Visible Spectroscopy to assess its chemical and structural composition. Subsequently, it was incorporated into a biodegradable protein matrix, and the resulting biocomposites were evaluated for mechanical and thermal properties. The results demonstrate that the incorporation of algal filler improves the mechanical strength and elasticity of the material while reducing its glass transition temperature, highlighting its potential for use in sustainable applications as a possible substitute for conventional plastics. The biocomposite materials developed, based on the protein-based material SP-Milk^® and residual microalgal biomass, are environmentally friendly, contributing to the reduction in pollution and the risks associated with plastic accumulation. Thus, this study offers a simple, effective, and sustainable strategy for the valorization of microalgal biomass, enabling the production of biodegradable materials with enhanced mechanical performance, suitable for applications such as sustainable packaging within a circular economy framework. Full article

Pisco is an emblematic spirit in Peru and Chile, made from fermented grapes, gaining growing scientific interest over the last two decades. This study aimed to map 20 years of research on Pisco through a systematic bibliometric review. A search was conducted in the Scopus database covering the period from 2004 to 2024, applying the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) methodology for the transparent selection of scientific articles. The search strategy considered titles, abstracts, and keywords, using the terms “Pisco” and “schnapps”, excluding unrelated fields such as geology (basin, seismic, fossil). The initial search yielded 360 records. After removing non-original articles (books, book chapters, conference papers, and reviews), 101 articles remained. A further screening excluded irrelevant studies (e.g., those referring to the city of Pisco rather than the beverage), resulting in 78 articles included for final analysis. It was observed that 19% of the studies focus on the history, culture, and appellation of origin; 14% on environmental sustainability; 10% on innovation and quality; and 9% on the bioactive properties of by-products. Other areas include extraction technologies (9%), distillation process modeling (8%), and marketing and economics (8%), among others. Recent trends are related to clean production practices. Thus, Pisco by-products and their components can be exploited by applying technologies such as supercritical fluids, drying, and biofilms, while, for waste management, the processes of composting, solar photo-Fenton, and ozonation can be applied. Moreover, it is important to highlight that the valorization of Pisco by-products opens opportunities for translation into the market, particularly in developing cosmetics, nutritional supplements, and bio-packaging materials, contributing to sustainability and innovation in new industries. However, a more holistic view is still needed in Pisco research. These findings suggest that future research should prioritize the integration of consumer-based sensory evaluations and sustainable production innovations to optimize Pisco’s quality, enhance market acceptance, and promote environmentally responsible industry practices. Full article

This study develops highly flexible, biodegradable polymer blends using bio-based polyhydroxyalkanoate (PHA) polymers for Fused Deposition Modeling (FDM) 3D printing. A Design of Experiment (DoE) approach optimized blend compositions by varying crystallinity levels of three PHAs, processed via twin-screw extrusion. Rheological analysis revealed that PHA blends exhibited 30–50% lower viscosity than PLA at low shear rates, ensuring improved processability. Tensile testing confirmed favorable mechanical properties, with elongation at break exceeding 2000%, significantly surpassing PLA (29%). Differential scanning calorimetry (DSC) indicated partial miscibility and crystallinity reductions of up to 50%, influencing printability. Optimized 3D printing parameters demonstrated minimal warping for blends with crystallinity below 18%, ensuring high-dimensional stability. During home composting tests, PHA blends showed significant degradation within two months, whereas PLA remained intact. Scanning electron microscopy (SEM) confirmed microbial degradation. Cytotoxicity tests demonstrated that the blends were non-toxic, supporting applications in tissue engineering. These findings highlight the potential of PHA-based blends as sustainable, high-performance materials for biomedical, packaging, and environmental applications. Full article

Instant coffee powder is highly sensitive to environmental humidity, which can significantly affect its quality during storage. The objective of this study was to evaluate the storage stability of instant coffee by assessing the moisture uptake and monitoring the evolution of key quality indicators under different environmental relative humidity (ERH) conditions. To this purpose, instant coffee was removed from its original packaging and stored at 11, 32, and 65% relative humidity (ERH) at 20 °C. Quality parameters related to both the powder (visual appearance and solubilization time) and the resulting brew (pH) were monitored over time. The coffee stored at 11% ERH demonstrated stability throughout the observation period. Storage at 32% ERH resulted in short-term powder stability, but a notable pH decline after six months. At 65% ERH, critical moisture levels were exceeded within one week, resulting in rapid visual degradation, impaired solubilization, and reduced brew quality within three months. The acquired findings on the behavior of a dry food powder under various storage conditions are particularly relevant in the context of the increasing application of compostable packaging with low moisture barriers, in conjunction with the need to manage the secondary shelf life of dry food powders whose use is often parceled. Full article

The inherent brittleness of bio-based poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) significantly restricts its industrial applications despite its industrial compostability. Blending with elastomeric polymers addresses mechanical limitations; however, interfacial incompatibility compromises miscibility as our previous work established. Herein, we investigate coffee oil epoxide (COE) as a bio-based plasticizer for PHBV/natural rubber (NR) blends in sustainable packaging applications. COE, derived from spent coffee grounds, was incorporated into PHBV/NR/peroxide/coagent composites via twin-screw extrusion. FTIR spectroscopy with chemometric analysis confirmed successful COE incorporation (intensified CH₂ stretching: 2847, 2920 cm⁻¹; reduced crystallinity), with PCA and PLS-DA accounting for 67.9% and 54.4% of spectral variance. COE incorporation improved optical properties (7.73% increased lightness; 21.9% reduced yellowness). Rheological characterization through Cole–Cole and Han plots demonstrated enhanced phase compatibility in the PHBV/NR/COE blends. Mechanical testing showed characteristic reductions in flexural properties: strength decreased by 16.5% and modulus by 36.8%. Dynamic mechanical analysis revealed PHBV/NR/COE blends exhibited a single relaxation transition at 32 °C versus distinct glass transition temperatures in PHBV/NR blends. Tan δ deconvolution confirmed the transformation from bimodal distribution to a single broadened peak, indicating enhanced interfacial interactions and improved miscibility. These findings demonstrated COE’s potential as a sustainable additive for biodegradable PHBV-based packaging while valorizing food waste. Full article

Poly(lactic acid) (PLA) is one of the most important bio-based and industrial compostable materials in food packaging. Its barrier properties towards oxygen and moisture are well documented. However, data on barrier properties of PLA towards organic molecules are scarce in the literature. This study investigated the diffusion of various organic molecules, including n-alkanes, 1-alcohols, 2-ketones, ethers, esters, amines, and aromatics, in two commercial PLA films with thicknesses of 20 µm and 30 µm. The diffusion coefficient (D_P) values were determined from lag time in permeation tests conducted at temperatures ranging from 20 °C to 90 °C. The films were also characterized in terms of crystallinity, rigid and mobile amorphous fractions, and molecular weight. Activation energies (E_A) were calculated based on the temperature dependence of the D_P using the Arrhenius approach. In total, 290 D_P values for 55 individual substances were determined, and 38 E_A values were derived from these data. The E_A correlated well with the molecular volume of the investigated substances. Moreover, the pre-exponential factor D₀ showed a correlation with E_A. These correlations enabled the establishment of diffusion modeling parameters for PLA, allowing the prediction of D_P for untested substances. The diffusion behavior of PLA was further compared with the literature data for polyethylene terephthalate and polyethylene naphthalate, providing insights into the relative performance of these materials. Full article

Organic fertilizers are a revolutionary concept in coconut farming as they provide a package for sustainable coconut production. This review examines the multiple advantages of organic fertilization methods and types of organic fertilizers, which include compost, vermicompost, livestock manure, green manure, crop residues, and biofertilizers. The review focuses on the best practices, application methods, time of application, frequency and rate of application of nutrients for coconut palm at various developmental stages. The study provides a detailed and systematic review of the environmental, economic and social impacts of organic fertilization. Benefits include enhanced soil health, biodiversity promotion, carbon sequestration, cost effectiveness, quality improvement of the yield, food security and possibilities of creating rural income. Issues including resource accessibility difficulties, nutrient deficiencies, and intensive labor requirements are explored in detail, as well as future trends that focus on advanced technologies, new research areas, and policy approaches. Thus, the study reviews organic fertilization as a coherent concept that can be applied to coconut production and other goals of environmental protection, food security, and sustainable development of agriculture. Full article

In the food packaging industry, significant efforts have been dedicated to addressing the pressing market demand for environmentally friendly and sustainable products. Biocomposite films based on compostable and biobased polymers represent a sustainable alternative to conventional packaging materials, offering biodegradability and enhanced functional properties. Additionally, there is growing interest in utilizing waste materials from agriculture and the food industry. This study focuses on the development of multifunctional eco-sustainable biocomposite films by combining poly(lactic acid) (PLA) as a biopolymeric matrix and extracts derived from coffee silverskin (CS), a significant agro-industrial waste byproduct of the coffee roasting process. Extracts of coffee silverskin were obtained via extraction with several solvents. Several properties of the prepared biocomposites were measured using techniques such as scanning electron microscopy (SEM), infrared spectroscopy (FTIR, ATR), differential scanning calorimetry (DSC), and oxygen and water vapor permeability, together with mechanical and physico-chemical characterization and measurements of water content, film solubility, and degree of swelling. The results demonstrate that optimized formulations of PLA/CS biocomposite films exhibit enhanced oxygen barrier properties, reduced permeability, and significant antioxidant activity. These findings underscore the potential for agro-waste valorization in creating eco-friendly food packaging solutions. Full article

As awareness of environmental issues deepens and the demand for sustainability grows among societies, businesses, and consumers, minimizing the environmental impact of food packaging has become increasingly important. Bioplastics offer a promising solution due to their use of renewable resources (such as plants), their biodegradability, and their ability to retain the protective properties of traditional plastics. This review discusses recent advancements and trends in sustainable food packaging, emphasizing the role of bioplastics. Several typical types of bioplastics are introduced, along with an analysis of their advantages and limitations. Furthermore, this study investigates consumers’ attitudes toward bioplastic food packaging, emphasizing their perceptions of its sustainability and practical use. The findings reveal that consumers generally hold a positive attitude toward bioplastics, particularly appreciating their biodegradable and compostable properties. However, their expectations are often overly high, as they believe bioplastics must meet two key criteria: being made from renewable raw materials and being fully biodegradable or compostable. Additionally, most consumers lack the knowledge or ability to dispose of bioplastic waste properly. This issue highlights two critical areas for policymakers: aligning consumer expectations with realistic sustainability goals and educating the public on correct waste sorting and disposal practices. Full article

This Special Issue on integrated waste management explores innovative approaches and multifaceted strategies aimed at addressing the critical challenges facing modern waste management systems. The featured eight original research articles cover diverse topics, including sewage sludge valorization, municipal waste biodrying, recyclables collection optimization, biomass-to-energy policies, and the management of compostable packaging waste. Technological advancements, such as AI-driven waste sorting and route optimization algorithms, are highlighted alongside policy frameworks supporting circular economy principles. The studies also address barriers to implementation, including public awareness gaps, technological disparities, and financial constraints, while emphasizing the importance of stakeholder collaboration across governments, industries, and communities. Additionally, environmental risks associated with waste management practices, such as nanoparticle contamination and leachate emissions from ashes, are critically analyzed. This Special Issue provides a holistic perspective on waste management, combining technical innovations, environmental stewardship, and policy integration. The insights of the works published in this Special Issue aim to guide researchers, policy-makers, and practitioners toward building resilient, sustainable, and resource-efficient waste management systems in alignment with global sustainability goals. Full article

Non-degradable plastic bags are a major contributor to marine and soil pollution. They represent a significant percentage of the generated solid waste and can last for hundreds of years in the environment. The aim of the present study was to find alternatives to conventional non-degradable plastic bags by obtaining biodegradable and compostable bags starting from simple materials like starch, poly(lactic acid) (PLA), and glycerol. Increasing the strength and hardness of the polymer was achieved by adding a mineral (talcum). The preliminary studies indicated that two compositions are suitable for advanced testing to produce the initial granular material. These materials were tested for the determination of melt flow index (MFI), Fourier Transform Infrared Spectroscopy (FTIR), and the polymers response to heating (thermogravimetric analysis, TGA and differential scanning calorimetry, DSC). The polymer biodegradability was evaluated by burial in two types of soil. The obtained results were compared with the same set of experiments performed on conventional polyethylene bags. After three months in the soil, only the materials synthesized in this study show signs of accentuated degradation while polyethylene bags are still intact. The surface morphology was explored by scanning electron microscopy (SEM). The results indicated that the biodegradable thermoplastic material meets the requirements of the European standard EN13432/2002 regarding compostable and biodegradable packaging. Full article

Methane (CH₄) emissions from the waste industry in the U.S.A. and the European Union (EU) have decreased by over 38% from 1990 to 2021. The success in CH₄ emission reduction in the U.S.A. is attributable to two main reasons. Firstly, the increase in the recycling and composting share to 32% of managed waste, thus removing decomposable material from landfills, and secondly, the implementation of methane capture and utilization programs, which have reduced the CH₄ released into the atmosphere from 1990 to 2022 by over 60%. By 2022, the EU had reduced landfilling to 23% of the total waste, with waste-to-energy and composting more than double that of their U.S. counterparts, and recycling alone attaining a share of 30%. The EU’s success has been the result of aggressive European legislation requiring biodegradable MSW going to landfills to be reduced by 2035 to 10% of that in 1995, and 65% of packaging waste to be retrieved and recycled by 2025. In terms of N₂O emissions, in the EU there was a decrease from wastewater processes from 1990 to 2021, but an overall increase due to waste-to-energy operations, whereas in the U.S.A., both wastewater treatment and solid waste incineration appear to contribute to N₂O emissions. Full article

In this study, a pilot-scale in-vessel composter was used to treat a mixture of industrial biowaste, with soybean curd residue and saw dust as the major substrates. The composter is capable of treating up to 350 tons/month of waste, producing up to 150 tons/month of high-quality compost within a retention time of 7–10 days. The final compost has an average nitrogen–phosphorus–potassium content of 6%, moisture content of 28%, pH of 6.1, organic matter of 68%, and carbon–nitrogen ratio of 19:1. It also has a good amount of humic acid and macronutrients. Composts from all stages of the composting process—pre-mix, directly after discharge, after one-month of curing, and right before packaging—were evaluated with metagenomic analysis to identify the microbes that may add value to the compost. Full article

Food contact materials release bioactive molecules that are potentially detrimental to health. Despite the relevance of this daily and repeated exposure, little attention is paid to single-use materials in contact with food. In Cameroon, despite the local tradition of using biodegradable and compostable leafy plants and the government’s decision to ban the use and marketing of plastics, they are still massively used in contact with food. The aim of this study was to explore the dynamics of the ongoing trend in the use of plastics for food handling. A cross-sectional study was conducted in March 2023 to investigate consumers’ perceptions of the benefits and drawbacks of plastics and traditional leaves as food contact materials. Two hundred consumers were interviewed at eight restaurants in Kumba municipalities through a structured questionnaire. The result of this study revealed that consumers considered that plant-based materials do not affect human health; they know that leaves, compared to plastics, are easier to dispose of and that plastic is an environmental hazard. Age and education turned out to significantly affect all the answers, while income did not. The current study highlights the need to provide clear and updated information on the long-term danger posed to health and the environment by plastics used to cook, store, protect, and transport food. Despite the numerous advantages and benefits of traditional leaves as food contact material, their traditional use by the population has been lost. Consumers in Cameroon are at a critical juncture in choosing biodegradable and compostable food contact materials. This transition can be accelerated if governments invest in actions and measures to curb and potentially reverse the widespread adoption of plastics as a symbol of modernity. Scientific and technological research should engage in the innovation of traditional plant-based materials. This local example is also intended to provide impetus for more global investment in traditional plant-based materials for food packaging to support sustainability and the planetary health agenda. Full article