Search Results (21)

Spectroscopic techniques such as Surface-Enhanced Raman Scattering (SERS), Surface-Enhanced Infrared Absorption (SEIRA), and Surface-Enhanced Fluorescence (SEF) are essential analytical techniques used to study the composition of materials by analyzing the way materials scatter light, absorb infrared radiation or emit fluorescence signals. This provides information about their molecular structure and properties. However, traditional SERS, SEIRA, and SEF techniques can be limited in sensitivity, resolution, and reproducibility, hindering their ability to detect and analyze trace amounts of substances or complex molecular structures. Metasurfaces, a class of engineered two-dimensional metamaterials with unique optical properties, have emerged as a promising tool to overcome these limitations and enhance spectroscopic techniques. This article provides a state-of-the-art overview of metasurfaces for enhanced SERS, SEIRA and SEF, covering their theoretical background, different types, advantages, disadvantages, and potential applications. Full article

In this paper, we proposed an ultra-thin composite metasurface for broadband sound absorption, in which a compound Helmholtz structure and porous materials are coupled in a parallel-series arrangement. The Helmholtz structure comprises multiple compound cells with hybrid-damping modes, in which the over-damping and matched-damping impedance are integrated for a lower and broader absorption spectrum. By coupling the porous materials, the metasurface obtains above 85% average absorption over 750–10,000 Hz with a thickness of 31 mm, and the performance below 1600 Hz is significantly enhanced compared to the pure porous materials. This metasurface could possess broad applications in modern equipment considering its extraordinary absorption and compact structure. Full article

In this communication, the design and fabrication of optical active metamaterials were developed by the incorporation of graphene and joining it to different substrates with variable spectroscopical properties. It focuses on how graphene and its derivatives could generate varied optical setups and materials considering modified and enhanced optics within substrates and surfaces. In this manner, it is discussed how light could be tuned and modified along its path from confined nano-patterned surfaces or through a modified micro-lens. In addition to these optical properties generated from the physical interaction of light, it should be added that the non-classical light pathways and quantum phenomena could participate. In this way, graphene and related carbon-based materials with particular properties, such as highly condensed electronics, pseudo-electromagnetic properties, and quantum and luminescent properties, could be incorporated. Therefore, the modified substrates could be switched by photo-stimulation with variable responses depending on the nature of the material constitution. Therefore, the optical properties of graphene and its derivatives are discussed in these types of metasurfaces with targeted optical active properties, such as within the UV, IR, and terahertz wavelength intervals, along with their further properties and respective potential applications. Full article

Current optical tweezering techniques are actively employed in the manipulation of nanoparticles, e.g., biomedical cells. However, there is still huge room for improving the efficiency of manipulating multiple nanoparticles of the same composition but different shapes. In this study, we designed an array of high-index all-dielectric disk antennas, each with an asymmetric open slot for such applications. Compared with the plasmonic counterparts, this all-dielectric metasurface has no dissipation loss and, thus, circumvents the Joule heating problem of plasmonic antennas. Furthermore, the asymmetry-induced excitation of quasi-bound states in continuum (QBIC) mode with a low-power intensity (1 mW/µm²) incidence imposes an optical gradient force of −0.31 pN on 8 nm radius nanospheres, which is four orders of magnitude stronger than that provided by the Fano resonance in plasmonic antenna arrays, and three orders of magnitude stronger than that by the Mie resonance in the same metasurface without any slot, respectively. This asymmetry also leads to the generation of large optical moments. At the QBIC resonance wavelength, a value of 88.3 pN-nm will act on the nanorods to generate a rotational force along the direction within the disk surface but perpendicular to the slot. This will allow only nanospheres but prevent the nanorods from accurately entering into the slots, realizing effective sieving between the nanoparticles of the two shapes. Full article

An ultra-wideband electromagnetic (EM) absorber is proposed. The proposed absorber consists of two thin metasurfaces, four dielectric layers, a glass fiber reinforced polymer (GFRP), and a carbon fiber reinforced polymer (CFRP) which works as a conductive reflector. The thin metasurfaces are accomplished with 1-bit pixelated patterns and optimized by a genetic algorithm. Composite materials of GFRP and CFRP are incorporated to improve the durability of the proposed absorber. From the full-wave simulation, more than 90% absorption rate bandwidth is computed from 2.2 to 18 GHz such that the fractional bandwidth is about 156% for the incidence angles from 0° to 30°. Absorptivity is measured using the Naval Research Laboratory (NRL) arch method in an EM anechoic environment. It was shown that the measured results correlated with the simulated results. In addition, the proposed absorber underwent high temperature and humidity tests under military environment test conditions in order to investigate its durability. Full article

This study is aimed at the design, calibration, and development of a near-infrared (NIR) liquid crystal multifunctional automated optical polarimeter, which is aimed at the study and characterization of the polarimetric properties of polymer optical nanofilms. The characterization of these novel nanophotonic structures has been achieved, in terms of Mueller matrix and Stokes parameter analyses. The nanophotonic structures of this study consisted of (a) a matrix consisting of two different polymer domains, namely polybutadiene (PB) and polystyrene (PS), functionalized with gold nanoparticles; (b) cast and annealed Poly (styrene-b-methyl methacrylate) (PS-PMMA) diblock copolymers; (c) a matrix of a block copolymer (BCP) domain, PS-b-PMMA or Poly (styrene-block-methy methacrylate), functionalized with gold nanoparticles; and (d) different thicknesses of PS-b-P2VP diblock copolymer functionalized with gold nanoparticles. In all cases, backscattered infrared light was studied and related to the polarization figures-of-merit (FOM). The outcome of this study indicates that functionalized polymer nanomaterials, depending upon their structure and composition, exhibit promising optical characteristics, modulating and manipulating the polarimetric properties of light. The fabrication of technologically useful, tunable, conjugated polymer blends with an optimized refractive index, shape, size, spatial orientation, and arrangement would lead to the development of new nanoantennas and metasurfaces. Full article

Phase change metasurfaces based on VO₂, which are pre-heated with electric current and optically addressed by projected structured light hologram, are considered to become a new paradigm in programmed THz/middle IR flat optics. Macroscopic quasi-homogeneous arrays of Au nanoparticles show large near IR absorption and a significant photothermal effect capable of boosting a light-triggered switching of VO₂ and are to be carefully examined. We propose a new approach to simultaneously probe the altered temperature and electric conductivity of a hybrid Au particle-VO₂ film composite by monitoring a phase shift and attenuating a surface acoustic wave in a YX128° cut LiNbO₃ substrate. The method shows a temperature resolution of 0.1 °C comparable with the best existing techniques for studying nanoobjects and surfaces. The laser-induced photothermal effects were characterized in a macroscopic array of Au nanostars (AuNSts) with different surface coverage. In a monolayer of 10 nm Au, coupled plasmonic nanoparticles were deposited on the LiNbO₃ substrate. An optically triggered insulator-metal transition assisted by photothermal effect in AuNSts/VO₂/TiO₂/LiNbO₃ composites was studied at varied light power. We believe that the proposed SAW-based method is of significant importance for the characterization and optimization of radiation absorbing or/and electrically heated elements of metasurfaces and other devices for lab-on-chip and optical communication/processor technology. Full article

Highly sensitive detection of enhanced terahertz (THz) fingerprint absorption spectrum of trace-amount tiny molecules is essential for biosensing. THz surface plasmon resonance (SPR) sensors based on Otto prism-coupled attenuated total reflection (OPC-ATR) configuration have been recognized as a promising technology in biomedical detection applications. However, THz-SPR sensors based on the traditional OPC-ATR configuration have long been associated with low sensitivity, poor tunability, low refractive index resolution, large sample consumption, and lack of fingerprint analysis. Here, we propose an enhanced tunable high-sensitivity and trace-amount THz-SPR biosensor based on a composite periodic groove structure (CPGS). The elaborate geometric design of the spoof surface plasmon polaritons (SSPPs) metasurface increases the number of electromagnetic hot spots on the surface of the CPGS, improves the near-field enhancement effect of SSPPs, and enhances the interaction between THz wave and the sample. The results show that the sensitivity (S), figure of merit (FOM) and Q-factor (Q) can be increased to 6.55 THz/RIU, 4234.06 1/RIU and 629.28, respectively, when the refractive index range of the sample to measure is between 1 and 1.05 with the resolution $1.54\times {10}^{-5}$ RIU. Moreover, by making use of the high structural tunability of CPGS, the best sensitivity (SPR frequency shift) can be obtained when the resonant frequency of the metamaterial approaches the biological molecule oscillation. These advantages make CPGS a strong candidate for the high-sensitivity detection of trace-amount biochemical samples. Full article

All-dielectric metasurfaces are a blooming field with a wide range of new applications spanning from enhanced imaging to structural color, holography, planar sensors, and directionality scattering. These devices are nanopatterned structures of sub-wavelength dimensions whose optical behavior (absorption, reflection, and transmission) is determined by the dielectric composition, dimensions, and environment. However, the functionality of these metasurfaces is fixed at the fabrication step by the geometry and optical properties of the dielectric materials, limiting their potential as active reconfigurable devices. Herein, a reconfigurable all-dielectric metasurface based on two high refractive index (HRI) materials like silicon (Si) and the phase-change chalcogenide antimony triselenide (Sb₂Se₃) for the control of scattered light is proposed. It consists of a 2D array of Si–Sb₂Se₃–Si sandwich disks embedded in a SiO₂ matrix. The tunability of the device is provided through the amorphous-to-crystalline transition of Sb₂Se₃. We demonstrate that in the Sb₂Se₃ amorphous state, all the light can be transmitted, as it is verified using the zero-backward condition, while in the crystalline phase most of the light is reflected due to a resonance whose origin is the contribution of the electric (ED) and magnetic (MD) dipoles and the anapole (AP) of the nanodisks. By this configuration, a contrast in transmission (ΔT) of 0.81 at a wavelength of 980 nm by governing the phase of Sb₂Se₃ can be achieved. Full article

Metalenses can greatly reduce the complexity of imaging systems due to their small size and light weight and also provide a platform for the realization of multifunctional imaging devices. Achieving dynamic focus length tunability is highly important for metalens research. In this paper, based on single-crystal Ge and a new low-loss phase change material Ge₂Sb₂Se₅ (GSSe), a tunable metalens formed by a double-layer metasurface composite was realized in the mid-infrared band. The first-layer metasurface formed by Ge nanopillars combines propagation and the geometric phase (equivalent to a half-wave plate function) to produce single- or multiple-polarization-dependent foci. The second-layer metasurface formed by GSSe nanopillars provides a tunable propagation phase, and the double-layer metalens can achieve the tunability of the focus length depending on the different crystalline fractions of GSSe. The focal length varies from 62.91 to 67.13 μm under right circularly polarized light incidence and from 33.84 to 36.66 μm under left circularly polarized light incidence. Despite the difference in the crystallographic fraction, the metalens’s focusing efficiency is maintained basically around 59% and 48% when zooming under RCP and LCP wave excitation. Meanwhile, the incident wave’s ellipticity can be changed to alter the relative intensity ratios of the bifocals from 0.03 to 4.26. This continuous varifocal metalens with adjustable intensity may have potential in practical applications such as optical tomography, multiple imaging, and systems of optical communication. Full article

Owing to the outstanding physical properties of graphene, its biosensing applications implemented by the terahertz metasurface are widely concerned and studied. Here, we present a novel design of the graphene metasurface, which consists of an individual graphene ring and an H-shaped graphene structure. The graphene metasurface exhibits a dual-resonance response, whose resonance frequency strongly varies with the geometrical parameters of the proposed metasurface, the carrier density of graphene, and the analyte composition. The transparency window, including width and position, can be artificially controlled by adjusting the geometrical parameters or the Fermi energy. Furthermore, the sensing parameters of the graphene metasurface for cancerous and normal cells are investigated, focusing on two factors, namely cell quantity and position on the metasurface. The simulated results clearly show that the theoretical sensitivity, figure of merit, and quantity of the graphene metasurface for breast cells reach 1.21 THz/RIU, 2.75 RIU${}^{-1}$, and 2.43, respectively. Our findings may open up new avenues for promising applications in the diagnosis of cancers. Full article

Both MXene and black phosphorus (BP), which actg as hot two-dimensional (2D) materials, have unique optical properties and important applications for nano-micro optical devices. Here, a composite MXene/BP-based metasurface, consisting of Ti₃C₂T_x and BP layers, is proposed for investigating the optical responses and electric field by using the finite-difference time-domain numerical simulation method in the microwave band. The research results show that the Fano resonance-like spectra can be observed when the coupling of surface plasmons (SPs) on the BP and MXene layers appears. Furthermore, the field enhancement, based on the Fano resonance-like optical responses, can be improved by an order of magnitude through adjusting the structural parameters and the polarization direction of incident light for the proposed metasurface. The findings may provide important theoretical insights into the design and realization of high-performance plasmonic devices. Full article

A bandpass filter integrated metalens based on electromagnetically induced transparency (EIT) for long-wavelength infrared (LWIR) imaging is designed in this paper. The bandwidth of the metalens, which is a diffractive optical element, decreases significantly with the increase of the aperture size to a fixed f-number, which leads to the decline of imaging performance. The same material composition and preparation process of the metalens and the EIT metasurface in the long-wavelength infrared make it feasible that the abilities of focusing imaging and filtering are integrated into a metasurface device. With the purpose of validating the feasibility of this design method, we have designed a 300-μm-diameter integrated metalens whose f-number is 0.8 and the simulation was carried out. The introduction of EIT metasurface does not affect the focusing near the diffraction limit at the target wavelength, and greatly reduces the influence of stray light caused by non-target wavelength incident light. This bandpass filter integrated metalens design method may have a great potential in the field of LWIR compact optical systems. Full article

In this paper, we present an ultrawideband reflective metasurface with the properties of an LTC-PC, which is an orthotropic composition with two mutually orthogonal symmetric axes, v and u, and 45° rotation about the vertical y-axis. Based on the metasurface unit cell, it seems like a circular pie embedded with a rectangular patch. The converter can convert LP electromagnetic (EM) waves to CP waves over the bands from 20.18 GHz to 33.93 GHz, with a 3-dB AR bandwidth of up to 50.8% and a circular polarization wave that is RHCP (right hand CP). Moreover, the linear-to-circular PCR exceeds 98% in the frequency bands of 20–34 GHz. A comprehensive theoretical investigation was conducted to determine the fundamental cause of the LTC polarization conversion. The $∆{\phi }_{uv}$ between two reflection coefficients at v- and u-polarized incidences is ±90°, which fully anticipates the axial ratio of the reflected wave. Any reflective metasurface can be used as an efficient LTC-PC if the $∆{\phi }_{uv}$ is close to ±90°. Full article

The broadband perfect absorption of visible light is of great significance for solar cells and photodetectors. The realization of a two-dimensional broadband perfect absorber in the visible range poses a formidable challenge with regard to improving the integration of optical systems. In this paper, we numerically demonstrate a broadband perfect absorber in the visible range from 400 nm to 700 nm based on metasurface composite structures. Simulation results show that the average absorptance is ~95.7% due to the combination of the intrinsic absorption of the lossy metallic material (Au) and the coupling resonances of the multi-sized resonators. The proposed perfect absorber may find potential applications in photovoltaics and photodetection. Full article