Search Results (13,109)

The two-spotted spider mite, Tetranychus urticae Koch, is a major agricultural pest whose control is increasingly constrained by resistance to synthetic acaricides. This study evaluated the long-term field efficacy of three commercial entomopathogenic fungal (EPF) biopesticides—Velifer^® (Beauveria bassiana), Metab^® (B. bassiana + Metarhizium anisopliae), and Botanigard^® (B. bassiana)—against larval and protonymph stages of T. urticae on two host plants, Italian cypress (Cupressus sempervirens) and sweet orange (Citrus sinensis). Two foliar applications were conducted during the 2023 growing season (25 May and 25 July), and mite populations were monitored for 140 days after the final application. A randomized complete block design was used, and efficacy was calculated using the Henderson–Tilton formula. All EPF treatments significantly reduced mite populations compared with the untreated control throughout the monitoring period. Velifer consistently achieved the highest suppression of larval populations, particularly on C. sinensis, with efficacy comparable to the chemical standard. Botanigard showed more gradual but sustained population reduction over time, whereas Metab exhibited lower but stable efficacy in all cases. Treatment performance was strongly influenced by host plant species and mite developmental stage, with larvae consistently more susceptible than protonymphs. On C. sinensis, Velifer achieved the highest larval suppression (84.6%), comparable to the chemical standard abamectin, while Botanigard and Velifer were most effective on C. sempervirens. Survival analysis confirmed isolate- and host-dependent differences in hazard effects over time. These results demonstrate that EPF-based products can provide sustained, long-term suppression of T. urticae under field conditions, supporting their integration into integrated pest management programs. Full article

Lignin, the most abundant renewable source of aromatic compounds, plays a pivotal role in advancing sustainable biorefineries and reducing dependence on fossil resources. Recent progress in integrated lignin valorization pathways has unlocked opportunities to convert this complex biopolymer into high-value chemicals, materials, and energy carriers, despite its structural heterogeneity and recalcitrance posing major challenges. This review highlights the significant advancements in depolymerization strategies, including catalytic, oxidative, and biological approaches, which are reinforced by innovations in catalyst design and reaction engineering that enhance selectivity and efficiency. It also discusses emerging technologies, such as hybrid chemo-enzymatic systems, solvent fractionation, and continuous-flow reactors, for their potential to improve scalability and sustainability. Furthermore, this review examines the integration of lignin valorization with upstream pretreatment and downstream recovery, emphasizing process intensification, co-product synergy, and techno-economic optimization to achieve commercial viability. Despite these developments, critical gaps remain in understanding the molecular complexity of lignin, developing universally applicable catalytic systems, and optimizing economic and environmental performance. To guide future research, it poses two key questions: how to design catalysts for selective depolymerization across diverse lignin sources, and how to configure biorefineries for maximum lignin utilization while ensuring sustainability? Addressing these challenges will be essential for lignin’s role in next-generation biorefineries and a circular bioeconomy. Full article

This study presents various microwave reactor designs specifically engineered for continuous microwave CO₂ desorption, marking a significant advancement in microwave-heating systems. This study explored both horizontal and vertical continuous microwave reactor configurations. The horizontal design incorporates a modified conveyor belt system with cleated belts and Teflon sidewalls, rendering it particularly suitable for the regeneration of gas. Conversely, the vertical design utilizes a cascade gate opening mechanism, facilitating precise control over the microwave intensity and exposure duration. The efficiency of microwave power utilization was enhanced through the numerical modeling and optimization of the reactor dimensions. This study assessed the impact of waveguide placement, cavity size, and sorbent material thickness on power absorption and heating. The findings indicate that strategic waveguide positioning and optimal cavity dimensions significantly influence the microwave energy distribution and absorption, leading to reduced hotspots and more uniform heating. This study offers valuable insights into the design and optimization of microwave reactors for CO₂ desorption, contributing to more efficient and effective commercial applications of this technology. These results underscore the potential of microwave technology to revolutionize desorption processes and pave the way for further advancements in this domain. Design 2 exhibited more uniform heating owing to its slower and controlled temperature increase, making it more suitable for applications requiring consistent thermal performance over extended periods. Full article

High-speed data acquisition systems based on field-programmable gate arrays (FPGAs) often face synchronization challenges when interfacing with commercial analog-to-digital converters (ADCs), particularly under constrained hardware routing conditions and vendor-specific clocking assumptions. This work presents a vendor-independent FPGA–ADC synchronization architecture that enables reliable and repeatable high-speed data acquisition without relying on clock-capable input resources. Clock and frame signals are internally reconstructed and phase-aligned within the FPGA using mixed-mode clock management (MMCM) and input serializer/deserializer (ISERDES) resources, enabling time-sequential phase observation without the need for parallel snapshot or delay-line structures. Rather than targeting absolute metrological limits, the proposed approach emphasizes a reproducible and transparent data acquisition methodology applicable across heterogeneous FPGA–ADC platforms, in which clock synchronization is treated as a system-level design parameter affecting digital interface timing integrity and data reproducibility. Experimental validation using a custom Kintex-7 (XC7K325T) FPGA and an AFE7225 ADC demonstrates stable synchronization at sampling rates of up to 125 MS/s, with frequency-offset tolerance determined by the phase-tracking capability of the internal MMCM-based alignment loop. Consistent signal acquisition is achieved over the 100 kHz–20 MHz frequency range. The measured interface level timing uncertainty remains below 10 ps RMS, confirming robust clock and frame alignment. Meanwhile, the observed signal-to-noise ratio (SNR) performance, exceeding 80 dB, reflects the phase–noise-limited measurement quality of the system. The proposed architecture provides a cost-effective, scalable, and reproducible solution for experimental and research-oriented FPGA-based data acquisition systems operating under practical hardware constraints. Full article

Astaxanthin, derived from Haematococcus pluvialis, is a potent antioxidant with significant therapeutic potential. However, its large-scale commercialization is hindered by the “thick-wall challenge”, a phenomenon where the stress conditions required for astaxanthin accumulation also trigger the formation of resistant secondary cell walls. This challenge complicates extraction and reduces bioaccessibility, thereby increasing production costs. Recent advancements have focused on uncoupling astaxanthin biosynthesis from cell wall reinforcement, utilizing metabolic engineering and strain selection to reduce wall formation while maintaining high yields. Furthermore, green extraction techniques, such as electrotechnologies and ionic liquids, are being explored to improve efficiency and environmental sustainability. This review synthesizes these innovations, including biorefinery systems that maximize biomass valorization, and discusses emerging clinical applications. We highlight the challenges in bridging the gap between laboratory successes and clinical translation, and suggest future directions for resolving the thick-wall challenge, advancing astaxanthin production, and expanding its therapeutic uses in nutraceuticals and pharmaceuticals. Full article

Roses held profound cultural and economic significance in ancient Greece and Rome, yet comprehensive documentation of their species diversity, cultivation practices, and horticultural innovations remains fragmented across archaeological, iconographic, and textual sources. This multidisciplinary study synthesizes evidence from classical texts, archaeological remains including recently identified rose stem fragments from Oplontis, and iconographic materials—including frescoes, coins, and mosaics—to reconstruct the horticultural systems and cultural landscape of roses in classical antiquity. Analysis of literary sources, particularly Theophrastus’s fourth-century BCE taxonomic descriptions, reveals systematic cultivation of diverse rose varieties with flowers ranging from white to deep crimson, including yellow variants, characterized by morphologies from simple to double forms and valued for fragrance intensity and re-blooming capacity. Archaeological evidence from sites such as Paestum, Pompeii, and Oplontis, including pollen samples, preserved wood fragments with diagnostic prickle patterns, and fresco representations, documents commercial rose production and specialized cultivation techniques that demonstrate significantly greater morphological diversity than textual sources alone indicate. Field research and collection documentation establish the origins of Mediterranean rose cultivation, while iconographic analysis identifies roses in religious ceremonies, festivals, and daily life contexts. Textual sources provide detailed propagation methods, seasonal management practices, and evidence of Mediterranean hybridization events, alongside extensive documentation of medicinal and cosmetic applications. Economic analysis reveals specialized trade networks, commercial production centers, and diverse applications in perfumery, garland making, and pharmaceutical industries. This research establishes that Greek and Roman civilizations developed sophisticated rose cultivation systems integrating botanical selection, horticultural innovation, and cultural symbolism that directly influenced medieval and Renaissance practices and informed modern trait categorization systems. These findings demonstrate the foundational role of classical antiquity in European rose heritage, revealing how ancient horticultural knowledge, species diversification through hybridization, and cultivation techniques created an unbroken transmission that shaped contemporary rose industries and established conservation priorities for this horticultural heritage. Full article

Despite increasing interest in probiotics as antibiotic alternatives in swine production, few studies have directly compared the functional efficacy of different commercial probiotic formulations under controlled conditions. We conducted an in vitro study using porcine intestinal epithelial (IPEC-J2) and macrophage-like (3D4/21) cell models to compare the efficacy of three commercial probiotic consortia (C1: three strains of Bacillus velezensis; C2: B. licheniformis + B. subtilis; C3: Clostridium butyricum). Treatments were evaluated for their ability to inhibit pathogenic Escherichia coli, Clostridium perfringens, and Salmonella spp., enhance epithelial barrier integrity, and modulate immune responses. Experimental endpoints included pathogen inhibition assays, adhesion to IPEC-J2 cells, transepithelial electrical resistance (TEER), tight junction protein expression, and cytokine profiling via RT-qPCR and proteomics. Data were analyzed using the Kruskal–Wallis test with false discovery rate (FDR) control at 5%. C1 cell-free supernatant (CFS) strongly inhibited pathogen growth (84.8 ± 5.3% inhibition of ETEC F4⁺F18⁻ vs. medium control; p < 0.05), whereas C2 had no effect, and C3 inhibited only one isolate. The coculture of IPEC-J2 cells with C1 CFS increased the expression of TJ proteins ZO-1, MUC13, and MUC20 (+12.9–46.6% vs. control; p < 0.001) and anti-inflammatory TGF-β; reduced pro-inflammatory IL-6 in LPS-stimulated 3D4/21 cells. In comparison, C2 and C3 showed minimal impact on epithelial barrier integrity and immune modulation, as indicated by negligible changes in TEER values, tight junction protein expression (ZO-1, MUC13, MUC20), and cytokine profiles relative to the control. In conclusion, C1 demonstrated greater in vitro efficacy than C2 (B. licheniformis + B. subtilis) and C3 (Clostridium butyricum), including pathogen inhibition assays, epithelial adhesion, TEER measurements, and cytokine modulation, suggesting its potential as a leading candidate for functional probiotic applications. Full article

This study evaluates the effects of hydrothermal and oleothermal treatments on the physical, colorimetric, and mechanical properties of Dabema wood. Samples were heated at 100, 160, and 220 °C for 2, 3.5, and 5 h. Equilibrium moisture content decreased from 13.16% in untreated wood to approximately 43% lower after hydrothermal treatment at 160 °C for 5 h and to 64% lower after oleothermal treatment at 220 °C for 5 h. Water absorption decreased from 78% in untreated samples to 25%–64% following hydrothermal treatment and to 17%–44% after oleothermal treatment. Hydrothermal treatment caused significant darkening, whereas oleothermal treatment maintained a lighter, more stable color. Mechanical properties improved substantially: in compression, MOE increased by 113% after oleothermal treatment at 220 °C for 5 h. In bending, MOR and MOE rose by 25%–35% under optimal oil-heat conditions. In tensile, MOE increased by 30%, and maximum tensile stress improved by up to 130%. Oleothermal treatments yielded the most stable enhancements, whereas severe hydrothermal treatments sometimes reduced mechanical performance despite improving moisture resistance. Multivariate analysis (PCA) and response surface methodology (RSM) indicate that oleothermal treatment at 160 °C for 3.5–5 h provides the best compromise between stiffness and color stability. Thermogravimetric analyses (TG/DTG) show hydrothermal treatment promotes hemicelluloses degradation, whereas oleothermal treatment stabilizes the cellulose–lignin network. Overall, hydrothermal treatment enhances dimensional stability, while oleothermal treatment achieves an optimal balance of stiffness, mechanical performance, and color retention. Deep color changes from furanic resin formation under hydrothermal conditions are strongly suppressed by oil during oleothermal processing, yielding lighter and more durable wood. For commercial applications such as furniture and structural components, oleothermal treatment is recommended, whereas hydrothermal treatment is more suitable when dimensional stability is prioritized over mechanical performance. Full article

Conventional anticorrosive coatings suffer from limitations of low solid content and rigorous surface pretreatment, posing environmental and cost challenges in field applications. In this study, a novel high-solid-content (>95%) epoxy-polysiloxane (Ep-PSA) ceramic metal coating was prepared that enables low-surface-treatment application. The originality lies in the synergistic combination of nano-sized ceramic powders, high-strength metallic powders, polysiloxane resin (PSA), and solvent-free epoxy resin (Ep), which polymerize through an organic–inorganic interpenetrating network to form a dense shielding layer. The as-prepared Ep-PSA coating system chemically bonds with indigenous metal substrate via Zn₃(PO₄)₂ and resin functionalities during curing, forming a conversion layer that reduces surface preparation requirements. Differentiating from existing high-solid coatings, this approach achieves superior long-term barrier properties, evidenced by |Z|_0.01Hz value of 9.64 × 10⁸ Ω·cm², after 6000 h salt spray exposure—four orders of magnitude higher than commercial 60% epoxy zinc-rich coatings (2.26 × 10⁴ Ω·cm², 3000 h salt spray exposure). The coating exhibits excellent adhesion (14.28 MPa) to standard sandblasted steel plates. This environmentally friendly, durable, and easily applicable composite coating demonstrates significant field application value for large-scale energy infrastructure. Full article

The Barcelona Basic Model (BBM) is a well-established constitutive framework for describing the mechanical behaviour of unsaturated collapsible soils within the context of critical state soil mechanics. Despite its robustness, its application in engineering practice remains limited due to the complexity of its formulation and challenges associated with reliable parameter determination. This study presents a practical framework for the selection and calibration of BBM parameters for Jossigny silt, using laboratory test data reported in the literature, employing a sequential approach supported by engineering judgement and a clear understanding of the original model formulation. The calibrated parameters are implemented in PLAXIS to simulate laboratory tests with different stress paths, allowing for the evaluation of the model’s ability to reproduce observed soil behaviour compared with those reported in the literature through a benchmark exercise conducted using the same reference tests. The calibrated parameter set successfully reproduces soil response under different stress paths, capturing the mechanical behaviour by achieving average values of R² = 0.98, MAE = 0.01, and RMSE = 0.013. The proposed framework is intended to bridge the gap between advanced constitutive modelling and routine engineering analysis by providing a transparent, step-by-step calibration procedure readily implementable in commercial finite element software. Full article

Radiative cooling (RC) offers a passive pathway to reduce surface and system temperatures by emitting thermal radiation through the atmospheric window, yet its daytime effectiveness is often constrained by geometry, angular solar exposure, and practical integration limits. This work experimentally investigates the use of passive non-imaging optics, specifically compound parabolic concentrators (CPCs), as enhancers of RC performance under realistic conditions. A three-tier experimental methodology is followed. First, controlled indoor screening using an infrared lamp quantifies the intrinsic heat gain suppression of a commercial RC film, showing a temperature reduction of nearly 88 °C relative to a black-painted reference. Second, outdoor rooftop experiments on aluminum plates assess partial RC coverage, with and without CPCs, under varying orientations and tilt angles, revealing peak daytime temperature reductions close to 8 °C when CPCs are integrated. Third, system-level validation is conducted using a modified GUNT ET-202 solar thermal unit to evaluate the transfer of RC effects to a water circuit absorber. While RC strips alone produce modest reductions in water temperature, the addition of CPC optics amplifies the effect by factors of approximately three for ambient water and nine for water at 70 °C. Across all configurations, statistical analysis confirms stable, repeatable measurements. These results demonstrate that coupling commercially available RC materials with non-imaging optics provides consistent and measurable performance gains, supporting CPC-assisted RC as a scalable and retrofit-friendly strategy for urban and building energy applications while calling for longer-term experiments, durability assessments, and techno-economic analysis before deriving definitive deployment guidelines. Full article

The economic and legal framework is transforming with the change in the globalization paradigm, accompanied by structural and quantitative changes in intellectual property assessment. This study aims to justify commercialization and analyze the innovation management of intellectual property as a fundamental socio-economic institution and improve theoretical perspectives on its current development processes. This study surveyed 100 companies to identify the factors determining intellectual property use and its commercialization. The analysis of the structure of intellectual property revealed a 14% decrease in trademark applications and a 2% increase in patent applications. This research highlights the specifics of intellectual property generation through machine learning: mass creation of new objects, reduction in innovation product development cycles, increased accuracy of market demand forecasting, and adaptive problem solving. An analysis of budget expenditures on intellectual property in the EU based on the specific value of patent activity identified five classification groups (ranging from 0.17 to 0.23% to 1.23–2.26% of GDP), each exhibiting different economic activities and innovation intensity. Full article

The tomato leafminer, Tuta absoluta (Meyrick) (Lepidoptera: Gelechiidae), is one of the most destructive pests of tomato crops worldwide. Its high reproductive potential and increasing resistance to conventional insecticides have made the development of sustainable management strategies essential. Biological control using entomopathogenic fungi (EPF), particularly when established as endophytes, has emerged as a promising approach. This study investigated the endophytic colonization capacity and greenhouse performance of three commercially available EPF formulations: Beauveria bassiana (Velifer^®), Lecanicillium lecanii (Lecan^®), and a Beauveria bassiana–Metarhizium anisopliae mixture (Metab^®), for the suppression of T. absoluta in tomato. Our experiment was conducted under commercial greenhouse conditions using soil drench applications at manufacturer-recommended doses. Endophytic colonization was assessed through surface-sterilized leaf assays, while pest suppression was evaluated via weekly measurements of larval mine length, infestation incidence, and survival dynamics. B. bassiana (Velifer^®) exhibited the highest endophytic colonization frequency and consistently reduced mine length and infestation levels compared with untreated plants. Survival analysis using Cox proportional hazards revealed significant reductions in infestation risk for Velifer^® (hazard ratio, HR = 0.420), Metab^® (HR = 0.480), and Lecan^® (HR = 0.599), relative to the negative control, whereas the chemical positive control provided the strongest overall suppression (HR = 0.287). Our findings demonstrate that commercial EPF formulations can significantly reduce T. absoluta infestation under greenhouse conditions and represent a valuable component of integrated pest management programs. Full article

The current landscape of Environmental, Social, and Governance (ESG) ratings is fragmented by methodological inconsistencies, lack of standardization, and substantial divergences among rating providers. These discrepancies hinder comparability, reduce transparency, and undermine the reliability of ESG assessments, limiting their effectiveness for both investors and corporate decision-makers. To address these issues, this study introduces a standardized approach to ESG rating construction, aimed at enhancing the objectivity and interpretability of corporate sustainability evaluations. The methodology integrates the Global Reporting Initiative standards with the United Nations Sustainable Development Goals, thereby identifying a coherent set of key performance indicators across the ESG pillars. By relying solely on publicly available data and incorporating mechanisms for managing missing information, the model provides a transparent and reproducible framework for sustainability assessment. Its validity is demonstrated through an empirical application to firms in the financial and manufacturing sectors across Europe and the United States, with benchmarking against established ratings from providers. Rather than replicating existing ESG scores, the model offers a transparent and reproducible alternative built on disclosed performance data, without relying on forward-looking statements, corporate promises, or commercial data providers. By penalizing non-disclosure and enabling sector-specific sensitivity analysis, the framework supports more accountable and customizable sustainability assessments, helping align ESG evaluations with strategic and regulatory priorities. Full article

This paper describes recent engineering designs that allow full-duplex SerDes connectivity between a number of cascaded Xilinx radio frequency system-on-chip (RF-SoC) and VCU FPGA systems. The design allows for unlimited scalability with all-to-all connectivity across FPGA systems and RF-SoCs that allow for bidirectional data transport in streaming mode at a capacity of 50 Gbps per ADC-DAC channel. A custom massively parallel systolic-array architecture supporting 8 parallel data streams from time-interleaved ADC/DACs allow real-time matrix–vector-multiplication (MVM). The MVM can be 8 × 8, 8 × 16, …, 8 × 1024 in supported matrix size, and is demonstrated in real time sustained throughput of 1 TeraMAC/second, for matrix size 8 × 512. The MVM is the building block supporting machine learning and filtering, with the computational graph split across FPGA systems using the SerDes connections. The RF data processed by the FPGA chain can be further utilized for higher-level AI workloads on an NVIDIA DGX Spark platform connected to the system. We demonstrate two platforms in which ZCU111 and ZCU1285 RF-SoC boards perform direct-RF data acquisition, while compute engines operating in real time on VCU128 and VCU129 FPGA boards showcase both digital beamforming and polyphase FIR filterbanking in a real-time bandwidth of 1.0 GHz. Full article