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21 pages, 7360 KB  
Article
Solvothermal Synthesis and Carbon Capture Performance of Terephthalate-Linked Zn0.75Mg0.25 MOF-74: Effects of Synthesis Conditions on Structure and CO2 Adsorption
by Siyabonga Brighton Ndebele, Glory Makuwa, Djemima Bulanga, Thembelihle Masombuka and Major Mabuza
Clean Technol. 2026, 8(5), 152; https://doi.org/10.3390/cleantechnol8050152 - 11 Sep 2026
Abstract
Coal-fired power generation remains a major source of carbon dioxide (CO2) emissions, and metal–organic framework-74 (MOF-74) materials offer high adsorption capacity but rely on costly 2,5-dihydroxyterephthalic acid linkers that limit scalability. This study synthesized bimetallic Zn0.75Mg0.25-MOF-74 using [...] Read more.
Coal-fired power generation remains a major source of carbon dioxide (CO2) emissions, and metal–organic framework-74 (MOF-74) materials offer high adsorption capacity but rely on costly 2,5-dihydroxyterephthalic acid linkers that limit scalability. This study synthesized bimetallic Zn0.75Mg0.25-MOF-74 using terephthalic acid (TPA) as a cheaper alternative linker and evaluated the effect of synthesis reaction temperature (89–160 °C) and time (5–55.5 h) on its physicochemical properties for carbon capture. Samples were prepared solvothermally and characterized by FTIR, XRD, SEM-EDS, and N2 (77 K) and CO2 (293 K) adsorption analysis. FTIR confirmed metal–ligand coordination; XRD verified crystalline MOF-74 formation, and SEM showed well-defined rod-like morphology at 100 °C, 12 h and 125 °C, 30 h. Direct CO2 adsorption on the 125 °C, 30 h sample yielded a Type I isotherm characteristic of micropore filling, with an uptake of 0.31 mmol/g at ~1 bar and 0.072 mmol/g at flue-gas-relevant conditions (~0.135 bar). Its CO2-derived BET surface area (60.10 m2/g) and Dubinin–Astakhov micropore area (131.69 m2/g) far exceeded N2-derived values, confirming ultra-micropores accessible to CO2 but not to N2 at 77 K. TPA therefore yields a stable, microporous CO2-adsorbing framework, trading some capacity for lower cost and scalability. Future investigations should systematically evaluate long-term cycling stability and adsorption performance under mixed-gas operating conditions. Full article
(This article belongs to the Special Issue Green Solvents and Materials for CO2 Capture, 2nd Edition)
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27 pages, 1730 KB  
Article
Sustainable Transition Pathways of Green Methanol Production in China: Provincial Cost Evolution Under Carbon Neutrality Goals
by Shiwei Zhao, Wenhui Chen, Yong Jiang, Xinwei Wang and Yalin Lei
Sustainability 2026, 18(18), 9276; https://doi.org/10.3390/su18189276 - 9 Sep 2026
Viewed by 220
Abstract
Achieving sustainable industrial transformation under carbon neutrality constraints requires breaking the high-carbon lock-in of the chemical sector through renewable-based production pathways. Green methanol, produced via CO2 hydrogenation using green hydrogen and captured industrial CO2, represents a critical technological option for [...] Read more.
Achieving sustainable industrial transformation under carbon neutrality constraints requires breaking the high-carbon lock-in of the chemical sector through renewable-based production pathways. Green methanol, produced via CO2 hydrogenation using green hydrogen and captured industrial CO2, represents a critical technological option for decarbonizing methanol production while enabling circular utilization of industrial carbon emissions. Existing research on green methanol cost generally treats the CO2 feedstock cost as a uniform national constant, thereby obscuring the economic heterogeneity of different industrial CO2 sources and their spatial coupling with provincial renewable resource endowments, which limits the granularity of decision support for regionally differentiated green methanol deployment. This study constructs an integrated sustainability assessment framework for green methanol in China, systematically differentiating four typical post-combustion industrial CO2 source scenarios—steel, cement, coal-fired power and coal–chemical industries. By integrating the levelized cost of electricity (LCOE) model, green hydrogen production cost accounting, and provincial-level CO2 capture cost trajectories, the framework forecasts the provincial green methanol production cost across 29 Chinese provinces from 2030 to 2060. The results show that (1) under the four industrial CO2 source scenarios, China’s provincial green methanol cost declines persistently between 2030 and 2060, with the coal–chemical source achieving the lowest cost (2032–3434 CNY/t) and the coal-fired power source the highest (2168–3565 CNY/t) in 2060. (2) The spatial pattern shows a stable “low costs in the Three-North region and high costs in southeastern and central China” differentiation, with Qinghai, Gansu, Inner Mongolia and Xinjiang positioned below 2500 CNY/t in 2060, reflecting the resource–environment coupling mechanism governing sustainable deployment of renewable-based chemical production. (3) Green hydrogen accounts for 76.4–80.9% of total cost while CO2 capture accounts for 4.1–10.1%, so that inter-provincial cost spread within any scenario is governed almost entirely by green hydrogen cost, whereas the choice of industrial CO2 source shifts the cost level of a given province. (4) Traditional industrial provinces such as Hebei and Jilin attain near-term cost competitiveness comparable to northwestern resource-rich provinces by combining locally available low-cost CO2 sources with a favorable renewable generation mix, though this advantage narrows towards 2060. These findings provide scientifically grounded pathways for China’s sustainable chemical industry transition, supporting the coordinated achievement of industrial decarbonization (SDG 9), climate action (SDG 13), and responsible consumption and production (SDG 12), while offering actionable guidance for spatially differentiated sustainable development policies that maximize economic and environmental co-benefits. Full article
(This article belongs to the Section Energy Sustainability)
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27 pages, 5123 KB  
Article
Response Surface Optimization and Microstructural Characterization of OPC–Fly Ash–GGBS Stabilized Pond Ash for Sustainable Geotechnical Applications
by S. Jyothirmayee, Chappidi Hanumantha Rao, Musa Adamu, Amarendra Kumar Sandra and Yasser E. Ibrahim
Constr. Mater. 2026, 6(5), 59; https://doi.org/10.3390/constrmater6050059 - 3 Sep 2026
Viewed by 136
Abstract
The environmental and land management issues associated with disposal of large quantity of pond ash (PA) from coal-fired thermal power plants are substantial, necessitating sustainable reuse strategies. The aim of this study is to investigate the performance of a ternary binder system of [...] Read more.
The environmental and land management issues associated with disposal of large quantity of pond ash (PA) from coal-fired thermal power plants are substantial, necessitating sustainable reuse strategies. The aim of this study is to investigate the performance of a ternary binder system of ordinary Portland cement (OPC), fly ash (FA) and ground granulated blast furnace slag (GGBS) for the engineering properties of PA for geotechnical applications. The Box–Behnken Design (BBD) approach in Response Surface Methodology (RSM) was used for the evaluation of the effect of binder composition on the unconfined compressive strength (UCS), California Bearing Ratio (CBR), and maximum dry density (MDD). The proportions of OPC, FA and GGBS were varied within predetermined limits, and 15 experimental mixtures were prepared. The experimental results indicated that the UCS was between 760 to 1260 kPa, soaked CBR was between 5.92% to 12.36%, and MDD ranged from 14.32 to 15.88 kN/m3. The developed quadratic models showed high statistical adequacy, with p-values below 0.0001 and coefficients of determination (R2) greater than 0.99 for all responses. The optimum combination of binders was obtained using multi-response optimization which yielded 2.45% OPC, 10.84% FA and 19.58% GGBS with a desirability index of 1.0, with a predicted UCS of 1272.81 kPa, soaked CBR of 12.63%, and MDD of 15.90 kN/m3. The validation experiments showed excellent agreement with the predicted results, with small deviations (less than 1%). SEM and EDS observations revealed a denser matrix with Ca–Si–Al-rich cementitious products. These features may indicate the development of C–S–H- and C–A–S–H-type phases, along with fewer visible voids and stronger bonding between the particles. The results demonstrate that the addition of OPC, FA, and GGBS is an effective and environmentally beneficial approach for improving the mechanical and compaction characteristics of PA, supporting its potential use in pavement foundations and other geotechnical engineering applications. Full article
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26 pages, 5017 KB  
Article
Fault Diagnosis of Coal-Fired Power Plants Based on Multi-Scale Spatiotemporal Features and TabPFN
by Xilong Ye, Chenglong Miao, Weiwei Jia, Xinyi Huang, Maofa Wang and Jun Tan
Mathematics 2026, 14(17), 3166; https://doi.org/10.3390/math14173166 - 2 Sep 2026
Viewed by 196
Abstract
The safe and stable operation of coal-fired generating units is of critical strategic importance for ensuring the reliable supply of power systems. However, the fault evolution of industrial thermal systems exhibits the characteristics of strong nonlinearity and a long incubation period, coupled with [...] Read more.
The safe and stable operation of coal-fired generating units is of critical strategic importance for ensuring the reliable supply of power systems. However, the fault evolution of industrial thermal systems exhibits the characteristics of strong nonlinearity and a long incubation period, coupled with the extreme scarcity of key fault samples (Few-shot) in actual production, which severely limits the engineering application of traditional data-driven diagnostic methods. Existing deep learning models, which are highly dependent on massive and balanced labeled data, not only struggle to overcome the overfitting bottleneck in scenarios with scarce fault samples, but also frequently introduce severe label noise (Label Noise) by ignoring the physical incubation period of faults, resulting in the degradation of the model’s decision boundary. To address the above challenges, this paper proposes a novel fault diagnosis framework integrating multi-scale spatiotemporal feature engineering and the Tabular Prior-Data Fitted Network (TabPFN). Starting from the physical mechanism of the system, this paper develops a dynamic label cleaning strategy based on multivariate statistical deviation, which accurately defines the fault divergence point to eliminate the noise in the incubation period. The constructed multi-scale spatiotemporal feature engineering integrating first-order difference and sliding window statistics can effectively map the transient mutation and steady-state evolution trend of the system. The introduced pre-trained TabPFN model based on the Transformer architecture, relying on its Bayesian inference capability and in-context learning (In-Context Learning) mechanism, can realize parameter-tuning-free and efficient classification for scarce samples. Experiments based on high-fidelity dynamic simulation data from GE Steam Power show that under the strict setting of limiting the training set to only 2000 samples, the proposed method achieves a comprehensive diagnostic accuracy of up to 99.29% and an F1-score of 0.9929 for seven typical operating conditions. Multi-dimensional comparative experiments and ablation studies confirm that the proposed framework comprehensively outperforms six mainstream baseline models, including XGBoost and SVM, in terms of precision, recall, and anti-interference robustness, and also delivers outstanding performance when benchmarked against deep learning models. This provides a brand-new theoretical perspective and technical paradigm for equipment health management in the context of industrial big data. Full article
(This article belongs to the Section E1: Mathematics and Computer Science)
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31 pages, 11534 KB  
Article
Dynamic Failure Risk Assessment of CFB Boiler Heating Surfaces Based on an Integrated STGCN–DBN Framework
by Kai Zhang, Zhenyu Zhang, Xu Yang and Guangkui Liu
Modelling 2026, 7(5), 181; https://doi.org/10.3390/modelling7050181 - 1 Sep 2026
Viewed by 126
Abstract
The large-scale integration of renewable energy has compelled coal-fired power plants to operate under deep peak-shaving conditions, significantly increasing the failure risk of Circulating Fluidized Bed (CFB) boiler heating surfaces due to severe thermal and pressure fluctuations. To address the limitations of traditional [...] Read more.
The large-scale integration of renewable energy has compelled coal-fired power plants to operate under deep peak-shaving conditions, significantly increasing the failure risk of Circulating Fluidized Bed (CFB) boiler heating surfaces due to severe thermal and pressure fluctuations. To address the limitations of traditional static risk evaluations, this study proposes a novel dynamic risk assessment framework integrating a Spatial–Temporal Graph Convolutional Network (STGCN) and a Dynamic Bayesian Network (DBN). The STGCN, enhanced with an operation-adaptive dynamic cross-attention delay module, predicts spatiotemporal temperature and pressure variations across the high-temperature heating surfaces. The predicted variables are incorporated into the DBN as dynamic evidence, which utilizes Noisy-OR logic and an embedded Weibull physical degradation model to continuously quantify cumulative failure probabilities. Case study results demonstrate that the STGCN outperforms traditional LSTM and RNN baselines in prediction accuracy. Furthermore, the DBN effectively maps the distinct degradation characteristics of individual boiler components, accurately identifying the water wall and superheater as having the highest failure risks and the largest fluctuations in marginal failure probability during rapid load cycling. This integrated data-driven approach provides highly accurate, real-time risk predictions, offering essential decision-making support for the predictive maintenance and safe flexible operation of CFB boilers. Full article
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19 pages, 2913 KB  
Article
Enhancing Elemental Mercury Removal in Coal Combustion Flue-Gas over V2O5/TiO2-Based Catalysts via Coupled Oxidation and Sulfur-Assisted Fixation
by Jiulong Zhang, Jiao Liu, Xinjian Han, Weichao Xu, Jiaxin Wang, Zhiyuan Cheng, Renhua Huang, Qiangqiang Ren and Wenrui Li
Fuels 2026, 7(3), 59; https://doi.org/10.3390/fuels7030059 - 31 Aug 2026
Viewed by 164
Abstract
Elemental mercury (Hg0) removal in coal combustion flue-gas over commercial V-based SCR catalysts is still limited by insufficient low-temperature activity and the complex interference of gas components. In this work, V2O5/TiO2, V2O5 [...] Read more.
Elemental mercury (Hg0) removal in coal combustion flue-gas over commercial V-based SCR catalysts is still limited by insufficient low-temperature activity and the complex interference of gas components. In this work, V2O5/TiO2, V2O5MoO3/TiO2, and V2O5MoS2/TiO2 catalysts were comparatively investigated for Hg0 removal under simulated coal combustion flue-gas conditions. Among them, V2O5MoS2/TiO2 exhibited the best performance over the whole temperature window of 200–400 °C, reaching a Hg0 removal efficiency of 73.3% at 200 °C, which was markedly higher than those of V2O5/TiO2 and V2O5MoO3/TiO2. Under multicomponent SCR atmospheres in coal-fired plants, the catalyst also showed the highest Hg0 oxidation efficiency of 72.9%, indicating that MoS2 modification was more effective than oxide promotion in enhancing low-temperature mercury removal. XRD and FT-IR results showed that MoS2 and vanadia were successfully incorporated onto TiO2 as dispersed surface phases, while the MoS2-modified catalyst exhibited a distinct and persistent terminal V=O feature, implying the formation of a coupled Mo-S-V interfacial environment. H2-TPR and NH3-TPD demonstrated that MoS2 modification simultaneously stabilized the redox structure and moderated the surface acidity, suppressing excessively strong NH3 retention while maintaining a tunable oxidation-active surface. XPS analysis further revealed atmosphere-dependent redistribution of Oα/Oβ species, sulfur oxidation to SO32−/SO42− species, and dynamic V5+/V4+ interconversion, confirming that MoS2 acted not only as a sulfur-containing component but also as an interfacial electronic regulator. Post-reaction Hg 4f XPS showed that retained mercury mainly existed as Hg2+ species, while Hg-TPD indicated that MoS2 modification provided a more diverse and thermally stable mercury-binding environment. These results demonstrate that Hg0 removal over V2O5MoS2/TiO2 proceeds through oxidation-retention coupling rather than simple oxidation alone. The enhanced performance originates from the synergistic effects of active oxygen migration, vanadium redox cycling, sulfur-assisted stabilization, and interfacial Mo-S-V electronic coupling. This work provides a promising strategy for designing multifunctional SCR catalysts in coal-fired plants for efficient Hg0 control under practical coal combustion flue-gas conditions. Full article
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32 pages, 7450 KB  
Article
Pit Limit Optimization for Open-Pit Coal Mines in Fire-Affected Zones: A Case Study of the First Mining Area in Dananhu No. 2 Coal Mine, Xinjiang
by Yifang Long, Ziling Song, Yu Wen and Kun Zhang
Appl. Sci. 2026, 16(17), 8448; https://doi.org/10.3390/app16178448 - 25 Aug 2026
Viewed by 307
Abstract
Spontaneous combustion in fire-affected coal seams can degrade coal quality, alter rock mechanical parameters and reduce mining profitability. Traditional pit limit optimization methods ignore coal fire-induced quality degradation, ignore the coupling effect of economic fluctuation and slope stability, and lack quantitative optimization for [...] Read more.
Spontaneous combustion in fire-affected coal seams can degrade coal quality, alter rock mechanical parameters and reduce mining profitability. Traditional pit limit optimization methods ignore coal fire-induced quality degradation, ignore the coupling effect of economic fluctuation and slope stability, and lack quantitative optimization for fire-affected open-pit mines. Here, we optimize loss-reducing mining boundaries for the southern fire-affected highwall in the first mining district of the Dananhu No. 2 Mine, Hami, Xinjiang. The aim is to move beyond binary decisions that either sterilize or fully extract fire-affected reserves. We instead integrate economic return, slope stability and coal-price uncertainty into a single boundary-optimization framework. First, we established a three-dimensional Cartesian coordinate system for the study area. We then modeled and fitted the coal-seam roof and floor using MATLAB-based multiple integration, reducing edge errors in solid surfaces. Laboratory analyses of borehole coal samples defined how calorific value varied with advance distance. These data were used to derive the coal-quality curve. Net mining profit was then formulated as the objective function, replacing the conventional stripping-ratio criterion. Profit was calculated across advance distances to identify the economically optimal boundary. Mechanical parameters of thermally altered rocks were obtained from laboratory deformation tests. Rhino and FLAC3D 6.0 were then used to evaluate three-dimensional slope stability at critical locations. Coal-price perturbation scenarios were finally introduced to test the sensitivity of net profit and optimal advance distance. Under the baseline coal price, the slope remained stable at an advance distance of 193 m. At this boundary, net profit reached a maximum of RMB 676.608 million. The southern surface boundary contracted by 47 m relative to the initial boundary, reducing unnecessary land disturbance. Sensitivity analysis showed that lower coal prices sharply reduced both the optimal advance distance and maximum net profit. When coal price decreased by 30%, the optimal advance distance contracted to approximately 116.9 m. Maximum net profit fell to approximately RMB 248.239 million. Higher coal prices expanded the optimal boundary outward. Once coal price reached approximately 128.7 yuan/t, or 18.5% above baseline, the optimum reached the upper constraint of 240 m. Net profit then increased substantially with further price growth. These results provide a quantitative basis for dynamic boundary optimization and disturbance-reducing extraction in fire-affected open-pit coal mines. Full article
(This article belongs to the Topic Advances in Mining and Geotechnical Engineering)
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16 pages, 2225 KB  
Article
Characteristics of Flue Gas Dechlorination by Ethanol-Digested Calcium Oxide and Its Effect on Mercury Speciation and Concentration
by Shuzhou Wei, Yongzheng Gu, Jianshan Li, Chengzhe Shen, Xintong Wen, Hailong Liu, Tao Yang, Yunxia Shao and Xiaoshuo Liu
Materials 2026, 19(17), 3588; https://doi.org/10.3390/ma19173588 - 24 Aug 2026
Viewed by 247
Abstract
This study aims to investigate the feasibility of ethanol-digested calcium oxide (CaO-E) as a novel dechlorination sorbent for the efficient removal of hydrogen chloride (HCl) from coal-fired flue gas and further evaluate its influence on mercury speciation and transformation in flue gas, thereby [...] Read more.
This study aims to investigate the feasibility of ethanol-digested calcium oxide (CaO-E) as a novel dechlorination sorbent for the efficient removal of hydrogen chloride (HCl) from coal-fired flue gas and further evaluate its influence on mercury speciation and transformation in flue gas, thereby addressing the low efficiency and limited multi-pollutant control capability of conventional dry dechlorination technologies. Based on a laboratory-scale injection reaction system, ethanol-digested calcium-based sorbents were injected into simulated coal-fired flue gas to systematically examine the effects of key factors, including Ca/Cl molar ratio, SO2, and fly ash, on dechlorination efficiency. Density functional theory (DFT) calculations were further employed to elucidate the reaction mechanisms. Meanwhile, mercury-laden flue gas was introduced to investigate the removal characteristics of elemental mercury (Hg0) and oxidized mercury (Hg2+) by CaO-E. The experimental results demonstrated that ethanol-digested CaO exhibited significantly superior performance compared with untreated samples, and the formation of a porous calcium hydroxide structure was identified as the key factor responsible for its high dechlorination efficiency. When the Ca/Cl molar ratio reached 4.0, the dechlorination efficiency could be stably maintained above 80%. SO2 showed a pronounced inhibitory effect on the dechlorination process, whereas fly ash exhibited a slight promoting effect. Mercury removal experiments revealed that CaO-E had limited removal capability toward Hg0 but effectively reduced the concentration of Hg2+. Specifically, when the Ca/Cl molar ratios were 3 and 5, the Hg2+ concentrations decreased to 1.4 and 0.6 μg/m3, respectively. This behavior can be attributed to the fact that Hg2+ mainly exists in chlorinated forms such as HgCl2, which possess strong polarity and can be readily adsorbed by the alkaline active sites on the CaO-E surface. In addition, as the dechlorination process proceeded, chlorine-containing species in the flue gas were gradually consumed, suppressing the oxidation conversion of Hg0 to Hg2+ and thereby further reducing the Hg2+ concentration. Theoretical calculations indicated that both HCl and SO2 could undergo chemisorption on calcium active sites, while HCl possessed a lower reaction energy barrier and therefore dominated the competitive adsorption process, exhibiting preferential reactivity. Overall, ethanol-digested calcium oxide not only demonstrates excellent HCl removal performance, but also shows the capability to regulate mercury speciation in flue gas to a certain extent, providing both theoretical insights and technical support for the synergistic control of multiple pollutants in coal-fired flue gas. Full article
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18 pages, 8767 KB  
Article
Preparation and Properties of CMC-Based Composite Gel as a Flame-Retardant Dust Suppressant
by Jianguo Wang, Zhenzhen Zhang, Xinni He and Binyuan Gao
Gels 2026, 12(9), 755; https://doi.org/10.3390/gels12090755 - 24 Aug 2026
Viewed by 212
Abstract
To address the challenge of balancing flame retardancy and dust suppression in conventional coal mine treatment materials, a multi-component synergistic flame-retardant dust-suppressant gel was fabricated using carboxymethyl cellulose (CMC) as the matrix, compounded with ammonium polyphosphate (APP), zinc borate (ZB), and polycarbodiimide (PCDI) [...] Read more.
To address the challenge of balancing flame retardancy and dust suppression in conventional coal mine treatment materials, a multi-component synergistic flame-retardant dust-suppressant gel was fabricated using carboxymethyl cellulose (CMC) as the matrix, compounded with ammonium polyphosphate (APP), zinc borate (ZB), and polycarbodiimide (PCDI) as a cross-linking agent. The optimal formulation was determined via orthogonal experimental design combined with performance characterization, yielding a composition of 1 wt% CMC, 8 wt% APP, 2 wt% ZB, and 0.5 wt% PCDI. Systematic evaluations—including wettability tests, thermogravimetric analysis, and fire-extinguishing trials—demonstrated that the resultant CMC-based composite gel exhibits excellent structural stability and environmental tolerance. Specifically, the contact angle on the coal surface decreased sharply from 72.8° to 17.2°, and the mass loss rate after 30 min of wind erosion was merely 4.16%. Treatment with the gel elevated the critical temperature of the coal–oxygen reaction from 70 °C to 80 °C and reduced CO emissions by 40% at 170 °C. Furthermore, the temperatures corresponding to the maximum weight loss rate, ignition, and burnout increased by 12.9 °C, 16.8 °C, and 28.9 °C, respectively. Fire suppression tests revealed that the gel rapidly cools high-temperature coal seams and effectively prevents reignition. Mechanistic investigations indicate that the CMC-PCDI cross-linked network synergizes with the APP-ZB phosphorus–boron flame-retardant system: the three-dimensional gel architecture provides physical encapsulation and water retention, while the intumescent char layer formed by APP-ZB offers efficient oxygen barrier protection. This study provides a reliable gel-based technical solution for the integrated prevention and control of coal dust pollution and spontaneous combustion disasters in underground mines. Full article
(This article belongs to the Special Issue Gels for Energy Applications)
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19 pages, 1188 KB  
Review
Dynamic Modeling of Circulating Fluidized Bed Power Plants for Flexible Operation: Progress, Challenges and Future
by Xiannan Hu, Haowen Wu, Ruiqi Bai, Tong Wang, Tuo Zhou, Man Zhang and Hairui Yang
Energies 2026, 19(17), 3953; https://doi.org/10.3390/en19173953 - 22 Aug 2026
Viewed by 218
Abstract
The increasing penetration of renewable energy has significantly intensified the demand for flexible operation of thermal power plants, making dynamic simulation an essential tool for understanding transient behaviors and developing advanced operational strategies for circulating fluidized bed (CFB) power plants. This review critically [...] Read more.
The increasing penetration of renewable energy has significantly intensified the demand for flexible operation of thermal power plants, making dynamic simulation an essential tool for understanding transient behaviors and developing advanced operational strategies for circulating fluidized bed (CFB) power plants. This review critically examines the existing dynamic modeling approaches for industrial-scale CFB power plants, with particular emphasis on their applicability to flexibility studies. Existing CFB flue-gas side models are systematically classified into three categories: 3D physics-based CFD models, behavioral/data-driven models, and semi-empirical mechanistic models. Their characteristics are critically compared in terms of spatial and temporal scales, empirical dependence, model generality, computational and implementation burden, and applicability to CFB flexibility studies. Dynamic modeling of the steam–water cycle is also reviewed, showing that it has reached a relatively mature stage owing to well-established thermo-hydraulic theories and standardized modeling platforms. The current research bottleneck is therefore identified as the dynamic coupling between the flue-gas side and the steam–water cycle for integrated CFB whole-plant simulation. Based on the comparative analysis, semi-empirical mechanistic models are identified as a particularly suitable framework for industrial-scale CFB flexibility studies requiring minute-to-hour transient simulation, physical interpretability, and whole-plant coupling. Finally, future research directions are discussed, highlighting how integrated dynamic models can support CFB flexibility-enhancement technologies and the development of new-generation coal-fired power plants. Full article
(This article belongs to the Section B2: Clean Energy)
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19 pages, 2196 KB  
Article
Operational Optimization of Mercury Control in a Coal-Fired SCR-WFGD System Through Front-End Speciation Steering and Back-End Re-Emission Suppression
by Jiao Liu, Jiaxin Wang, Shoubao Duan, Congyang Gu, Wanzhu Wu, Xiaoli She, Wenrui Li and Qiangqiang Ren
Fuels 2026, 7(3), 54; https://doi.org/10.3390/fuels7030054 - 21 Aug 2026
Viewed by 217
Abstract
Coal-fired power plants equipped with selective catalytic reduction (SCR) and wet flue-gas desulfurization (WFGD) can co-control mercury, but performance is limited by incomplete upstream Hg0 oxidation and downstream re-emission. This study evaluated a 660 MW unit using gas-, liquid-, and solid-phase measurements [...] Read more.
Coal-fired power plants equipped with selective catalytic reduction (SCR) and wet flue-gas desulfurization (WFGD) can co-control mercury, but performance is limited by incomplete upstream Hg0 oxidation and downstream re-emission. This study evaluated a 660 MW unit using gas-, liquid-, and solid-phase measurements and coordinated single-factor and coupled operating tests. Under baseline conditions, SCR Hg0 oxidation was 31.66%, WFGD Hg2+ capture was 73.79%, and net mercury removal was 31.08%, with a stack HgT concentration of 4.70 µg/Nm3. Coupled optimization increased SCR Hg0 oxidation to 69.76% and WFGD Hg2+ capture to 96.05%, reduced the re-emission index from 0.596 to 0.250, and raised net removal to 70.83%. SCR inlet temperature, equivalent space velocity, and catalyst health were the dominant upstream factors, while S(IV), oxidation–reduction potential (ORP), slurry pH, and oxidation air supply governed downstream stabilization. A practical operating window was identified near 340 °C, with a normalized stoichiometric ratio (NSR) of approximately 1.0, high ammonia injection uniformity, pH of 5.5–6.0, ORP of approximately 200 mV, and S(IV) of approximately 2 mmol/L. The results show that coordinated operation of existing SCR–WFGD equipment can substantially reduce stack mercury without dedicated mercury-control hardware, provided that NH3 slip, SO3-related risk, catalyst condition, and absorber stability are simultaneously constrained. Full article
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19 pages, 23579 KB  
Article
Investigation on Characteristics of Typical Pollutants Generated from Coal Fires: A Case Study of Sulabulak, Xinjiang, China
by Xinrong Du, Zhicheng Yang and Qiang Zeng
Fire 2026, 9(8), 360; https://doi.org/10.3390/fire9080360 - 21 Aug 2026
Viewed by 445
Abstract
Coal fires are a significant source of greenhouse gas emissions and ecological pollutants, yet their emission characteristics and carbon accounting remain poorly constrained. To reveal the pollutant generation characteristics and carbon emission levels of the typical underground coal fire area in Sulabulak, Xinjiang, [...] Read more.
Coal fires are a significant source of greenhouse gas emissions and ecological pollutants, yet their emission characteristics and carbon accounting remain poorly constrained. To reveal the pollutant generation characteristics and carbon emission levels of the typical underground coal fire area in Sulabulak, Xinjiang, this study integrated laboratory simulation, multi-source remote sensing inversion, and in situ field monitoring. Thermogravimetric analysis, a high-temperature tube furnace, HSC thermodynamic simulation, and multi-source remote sensing data from Landsat-8/9 and Sentinel-1A were employed to investigate the gaseous products and heavy metal migration mechanisms at different combustion stages, and to delineate the spatial extent of different combustion states in the fire area. A coal loss model was then constructed by coupling experimentally determined carbon emission factors with remote sensing-derived areas and was compared with an emission flux model based on field measurements. The results show that the coal oxidation process proceeds through three distinct stages, with indicator gas ratios (CO2/CO and C2H4/C2H6) serving as effective indicators for combustion state identification. Heavy metal partitioning is governed by elemental volatility and redox conditions: As and Se partition predominantly into the gas phase, while Zn becomes enriched in fly ash. Remote sensing time series analysis documents continuous fire expansion accompanied by progressive surface subsidence. By cross-validating the indirect coal loss model (constrained by remote sensing area) against the direct emission flux model (constrained by field measurements), we estimate the current annual GHG emission of the Sulabulak fire area at approximately 0.65 × 104 t CO2 equivalent. This study proposes a coupled “micro-experiment–macro-remote sensing–field measurement” approach for carbon emission accounting, providing reliable data support for environmental pollution control and the development of carbon inventories for coal fires in arid regions. Full article
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20 pages, 3952 KB  
Article
Comparative Technical and Economic Analysis of Heating Schemes for Rural Buildings
by Dan Wu, Shuangli Hua, Qi Qin, Yue Zhao and Long Gao
Processes 2026, 14(16), 2662; https://doi.org/10.3390/pr14162662 - 20 Aug 2026
Viewed by 391
Abstract
Currently, heating supply in rural areas of China still predominantly relies on conventional coal-fired heating, which suffers from poor thermal insulation performance and severe environmental pollution. To address the issues of energy waste and environmental pollution associated with traditional heating methods in rural [...] Read more.
Currently, heating supply in rural areas of China still predominantly relies on conventional coal-fired heating, which suffers from poor thermal insulation performance and severe environmental pollution. To address the issues of energy waste and environmental pollution associated with traditional heating methods in rural China, this study selects a detached rural residential building in Jilin City as the research object. A building thermal load calculation model incorporating phase-change material (PCM) walls and dynamic simulation models for five clean heating coupling systems are developed using TRNSYS software, so as to analyze the influence of PCM placement at different positions within the wall assembly on the building’s thermal load, as well as the technical and economic performance of the five heating systems. The results show that, when PCM is placed on the inner side of the building envelope, the peak heating load is reduced from 15,234.2 W to 11,266.5 W, and the cumulative heating load drops from 33,744.3 kWh to 25,688.9 kWh. Compared with the conventional PV (photovoltaic) system, the PVT (photovoltaic–thermal) system achieves an 11% improvement in power generation efficiency. Among the five clean heating systems, the PVT–ground-source heat pump system exhibits the lowest energy consumption, while the PVT–biomass boiler system records the highest energy consumption. Based on life-cycle cost analysis, the PVT–biomass boiler system delivers the optimal economic performance, with a equivalent annual cost of 9285.48 CNY. Full article
(This article belongs to the Special Issue Innovative Technologies and Processes in Geothermal Energy Systems)
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28 pages, 5281 KB  
Article
Study on Combustion Characteristics and NOX Emissions of a 600 MW Opposed Wall-Fired Boiler Under Deep Peak Shaving
by Xingyang Fu, Hao Lu and Wenjun Zhao
Processes 2026, 14(16), 2645; https://doi.org/10.3390/pr14162645 - 19 Aug 2026
Viewed by 358
Abstract
In the context of the new power system, coal-fired units are transitioning into peaking units. This study investigates the combustion characteristics and NOX emissions of a 600 MW opposed wall-fired boiler within a load range of 50% to 20%, and further analyzes [...] Read more.
In the context of the new power system, coal-fired units are transitioning into peaking units. This study investigates the combustion characteristics and NOX emissions of a 600 MW opposed wall-fired boiler within a load range of 50% to 20%, and further analyzes the impact of burner operation modes on boiler performance at the 20% ultra-low load. The results indicate that as the boiler load decreases from 50% to 20%, the average temperature in the primary combustion zone drops from 1634.3 K to 1457.0 K, and the ignition distance extends from 0.228 m to 0.260 m, leading to a significant decline in combustion stability. Notably, at the 20% ultra-low load, although the drop in temperature suppresses the formation of thermal NOX, the flow short-circuiting caused by the shrinking of the recirculation zone results in pulverized coal particles missing the optimal reduction window; the formation pathway dominated by fuel NOX causes the NOX concentration at the furnace outlet to surge to 670.6 mg/m3. Furthermore, the burner operation modes significantly influence boiler performance at the 20% ultra-low load. While ensuring combustion stability, operating the lower-tier burners effectively reduces NOX emissions by up to 21.6%. Considering both combustion stability and NOX emissions, prioritizing the operation of lower-tier burners is recommended. This study reveals the underlying mechanisms behind the surge in NOX concentrations at ultra-low loads of 20% and proposes optimal burner operation strategies, providing a theoretical foundation for the clean and stable operation of boilers during deep peak shaving. Full article
(This article belongs to the Section Energy Systems)
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27 pages, 8497 KB  
Article
Microenvironment Regulation and Plant Growth Responses Under Different Photovoltaic Tilt Angles for Sustainable Utilization of an Ash Storage Yard
by Daorina Bao, Guangqiang Yu, Qianqian Huang, Yuang Tang, Yanqiang Di, Xiaohu Ao and Chuanjiu Zhang
Sustainability 2026, 18(16), 8465; https://doi.org/10.3390/su18168465 - 18 Aug 2026
Viewed by 336
Abstract
Degraded industrial sites in arid and semi-arid regions often suffer from loose surface substrates, weak water-retention capacity, high wind-erosion risk, and poor early vegetation establishment. Combining photovoltaic (PV) deployment with ecological utilization may improve near-surface habitats by shading, reducing wind speed, and regulating [...] Read more.
Degraded industrial sites in arid and semi-arid regions often suffer from loose surface substrates, weak water-retention capacity, high wind-erosion risk, and poor early vegetation establishment. Combining photovoltaic (PV) deployment with ecological utilization may improve near-surface habitats by shading, reducing wind speed, and regulating soil heat and moisture. This study investigated an ash storage yard of a coal-fired power plant in Ordos, Inner Mongolia, China, by comparing soil temperature, soil moisture, and near-surface wind-speed responses under three representative fixed PV tilt angles of 36°, 43°, and 50°, together with the corresponding early plant-growth suitability. A multi-physics model coupling near-surface airflow, water-vapor transport, and porous-media hydrothermal migration was established. A Gaussian suitability function combined with AHP-CRITIC weighting was used to construct a model-based comprehensive growth index (CGI) from soil temperature and moisture, while short-term field monitoring was used to validate afternoon soil hydrothermal trends. Among the three scenarios, the 36° configuration produced the widest horizontal heat–moisture-affected zone and the highest CGI values for alfalfa and Elymus nutans, reaching 0.7741 and 0.6875, respectively. Relative to the outside reference area, the rear PV zone reduced the near-surface wind speed by 33–40% and increased the plant heights of alfalfa and Elymus nutans by 49.4% and 37.8%, respectively. A first-order PVsyst assessment showed that the 43° configuration achieved the highest specific energy yield of 1814 kWh kWp−1 year−1, whereas the annual grid-connected output at 36° was only 0.59% lower. These findings indicate that the 36° configuration may provide a favorable compromise between early vegetation establishment and photovoltaic electricity generation among the tested scenarios. By linking renewable-energy production with microenvironment regulation and early vegetation establishment, the proposed framework provides a decision basis for the multifunctional and sustainable reuse of degraded industrial land. Nevertheless, the results represent a site-specific, single-season assessment and should not be interpreted as a universal optimum. Full article
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