Search Results (3,945)

Passive daytime radiative cooling (PDRC) technology with high solar reflectance and high infrared emissivity has been increasingly applied in green buildings. However, current PDRC designs are either high-cost or require additional multi-step fabrication processes, and both factors hinder their broader industrial application. Here, we present a low-cost, easy-to-process, scalable and uncomplicated porous epoxy-based radiative cooling coating via a simple Pickering high-internal-phase-emulsion (HIPE) approach. The obtained porous epoxy-based coating has micro- and submicropores. These hierarchical porous microstructures enable a synergistic interaction between the filler and the porous microstructure, thus enhancing the radiative cooling performance. As a result, the obtained porous epoxy-base polymer with alumina as fillers (PEP-A) coating presents a high solar reflectance of 95.6% in the wavelength range of 0.3–2.5 μm and a high infrared emissivity of 96.3% in the wavelength range of 8–14 μm, as well as a maximum subambient cooling temperature of 3.4 ℃ and an average cooling power of 105.6 W·m⁻² under solar shortwave radiation of 123.01–134.67 W·m⁻². Furthermore, the PEP-A coating can be easily applied via roll-coating, blade-coating, or brush-coating, and self-cures on diverse substrates like aluminum sheets, steel plates, polypropylene sheets, bricks, and wall surfaces without any additional template-extraction process. In particular, the cost of the raw materials for the PEP-A coating is 0.2–1.3% of that of previously reported radiative cooling coatings (e.g., Poly(vinylidenefluoride-co-hexafluoropropylene) and polydimethylsiloxane). The extraction-free nature, easy processability, self-curing ability, and low cost of the PEP-A coating make it very promising for large-scale PDRC production and applications. Full article

Climate change is altering soil organic carbon stocks and the associated carbon fluxes of cropland ecosystems—including organic matter mineralization, microbial respiration rates, and CO₂ emissions—through shifts in temperature and moisture regimes. Ecosystem respiration, the main pathway linking terrestrial carbon pools to atmospheric CO₂, directly governs the carbon source–sink balance of croplands. As integral components of the agroecosystem, soil microorganisms directly participate in ecosystem respiration and organic carbon transformation: they contribute to heterotrophic respiration through the decomposition of organic matter, while also synthesizing new organic compounds, forming microbial biomass, and promoting organic carbon stabilization, with their community composition and metabolic activity adjusting to changing environmental conditions. To synthesize research progress and clarify how the field has evolved over the past three decades, we analyzed 290 publications (1991–2025) from the Web of Science Core Collection, combining bibliometric tools (CiteSpace 7.0, VOSviewer 1.6.20) with a structured evidence synthesis to map the research landscape, knowledge structure, hotspot evolution, and mechanistic understanding of the microbial processes underlying cropland ecosystem respiration. Publication output has grown steadily, led by China (161 publications; 55.5%) and the United States (47; 16.2%), which together account for 71.7% of the sample. The knowledge structure has coalesced around five core themes (ecosystem respiration, soil microbial communities, soil organic carbon, carbon cycling, and agricultural management), corresponding to 14 major thematic clusters (Q = 0.668, S = 0.778). Rather than strictly sequential stages, these thematic areas developed largely in parallel, with a gradual shift in research emphasis over time: early work centered on fundamental carbon-cycle processes, including soil respiration flux, organic matter decomposition, and CO₂ release, whereas later research increasingly emphasized microbial community structure, functional mechanisms, carbon use efficiency, soil organic carbon stabilization, carbon sequestration, fungal communities, and ecological stoichiometry. The responses of cropland respiration to climate change are context-dependent: under specific conditions their direction and magnitude may be dominated by a single limiting factor, whereas overall they emerge from the coordinated interplay of temperature, moisture, substrate supply, and agricultural management, within which microbial processes play a central but still incompletely resolved role. Future research should prioritize long-term in situ observations, multi-factor coupling experiments, and functional validation of microbial processes, and integrate microbial mechanisms into ecosystem models to strengthen predictions of cropland carbon cycling and support agricultural emission reduction, carbon sequestration, and sustainable management. Full article

To support in situ lunar regolith resource utilization for a lunar base Controlled Ecological Life Support System (CELSS), this study selected the nitrogen-fixing cyanobacterium Nostoc commune and halophyte Suaeda salsa (L.) Pall. based on extremophile soil amelioration theory. Three cultivation treatments were established: Nostoc commune monoculture (Group A), co-culture of N. commune and S. salsa (Group B), and S. salsa monoculture (Group C). Stratified sampling (0–0.5 cm surface, 1–1.5 cm middle, 2–3 cm deep) was conducted on day 45 to quantify pH, electrical conductivity (EC), organic matter, total nitrogen, available macro/meso/trace elements, and elemental correlation of plant residues. The results showed that both species survived in lunar regolith simulant; co-culture generated significant synergistic growth promotion for S. salsa. All treatments significantly reduced initial alkaline pH (8.80 ± 0.1). Group A neutralized surface/middle layers most effectively and maximized surface available N/K; Group C exhibited superior surface available P activation; Group B achieved uniform vertical pH/EC regulation and stable carbon–nitrogen residue accumulation. Residual biomass acted as a stable C/N reservoir and altered medium/trace element bioavailability via adsorption and complexation. Group A is suitable for N/K-deficient regolith, Group C for P-limited substrates, and Group B provides comprehensive long-term balanced nutrient supply matching CELSS demands. This study verifies extremophile-based lunar regolith bioremediation and provides differentiated amelioration strategies for lunar in situ resource utilization. Full article

Aerobic co-composting of spent mushroom substrate (SMS) and cattle manure is a vital technology for agricultural waste recycling. However, high refractory lignocellulose content and low indigenous microbial activity usually hinder compost heating and maturation. Exogenous inoculation and raw material sterilization are common microbiome regulation strategies, while their divergent functional mechanisms and the contributions of native versus exogenous microbiota remain unclear. Herein, three treatments (control with intact indigenous microbiota, sterilization pretreatment, and 0.5% w/w fungal–bacterial inoculation) were established to explore their effects on composting performance and fungal community succession over 34 days. Compost stability and maturity were evaluated via thermophilic duration and germination index (GI), with fungal communities analyzed by ITS high-throughput sequencing. The results revealed that sterilization severely suppressed composting, causing delayed heating, a low peak temperature of 55.2 °C, inhibited lignocellulose degradation, and disordered fungal community structure with increased richness but decreased evenness due to random colonization by weak degraders. In contrast, microbial inoculation prominently improved composting efficiency, with a peak temperature of 67.5 °C, eight days of sustained high temperature, and a final GI of 89.67%. The degradation rates of cellulose, hemicellulose and lignin reached 68.32%, 72.15% and 35.28%, respectively. Inoculation directionally enriched core lignocellulose-degrading fungi (Chaetomium, Aspergillus fumigatus, Thermoascus) and maintained functional community balance. Core fungal genera dominated lignocellulose decomposition and humification driven by environmental factors. This study clarifies that indigenous microbiota underpin spontaneous composting, while targeted inoculation optimizes functional microbiota, and single sterilization impairs composting. It provides mechanistic guidance for efficient agricultural waste composting. Full article

National estimates of the bioenergy potential of livestock manure still rest on static inventories that apply conversion yields to the gross mass of manure, ignoring the fraction that is actually recoverable under each production system and the substrate-specific nature of anaerobic co-digestion. This study develops a category-level predictive model of the technical biogas potential of livestock manure in Peru, projected to 2030, resolving seven livestock categories: dairy and non-dairy cattle, broilers and layers, swine, guinea pigs (Cavia porcellus) and goats. Recoverability is formulated as a time-dependent factor tracking the progressive confinement of production systems; the technical potential is bounded between a mono-digestion floor and a co-digestion ceiling constrained by a co-location criterion that admits synergy only when the co-substrate originates within the same production system; and a greenhouse-gas layer quantifies avoided emissions from methane conversion factors. All coefficients are reported as intervals and propagated jointly by Monte Carlo simulation. Two yield hypotheses are carried throughout: experimental biochemical methane potential and the IPCC-consistent digester ceiling. The national net technical potential is 1975 ${\mathrm{GWh}}_{\mathrm{p}}$${\mathrm{yr}}^{-1}$ under mono-digestion (731 ${\mathrm{GWh}}_{\mathrm{e}}$; 95% credible interval 1628–2404 ${\mathrm{GWh}}_{\mathrm{p}}$, Monte Carlo $N=\mathrm{100,000}$) and 2093 ${\mathrm{GWh}}_{\mathrm{p}}$${\mathrm{yr}}^{-1}$ under co-digestion. The gross approach exceeds the recoverable resource by a factor of 3.94, equivalently a contraction of 74.6% (95% CI 68.9–79.1%), and a symmetric Shapley decomposition attributes 76.1% of that contraction to recoverability rather than to conversion yield—a share that is stable across both yield hypotheses. The greenhouse-gas layer yields a result that reverses the expected policy ordering: broilers rank first by recoverable energy but last by avoided methane, whereas swine rank first by mitigation because liquid slurry storage is the only baseline system emitting enough methane for anaerobic digestion to displace. Below a digester leakage of 4.6%, methane abatement is negative at the national scale. Full article

Laccases are multicopper oxidases capable of oxidizing a wide range of substrates using molecular oxygen as the terminal electron acceptor, producing water as the sole by-product. High-redox potential fungal laccases, such as those from Trametes versicolor, are particularly attractive for industrial and environmental applications, although their use is often limited by sensitivity to operational conditions. Enzyme immobilization represents an effective strategy to enhance laccase stability and reusability. In this work, magnetic nanoparticles (MNPs) were investigated as support for laccase immobilization due to their high surface area, biocompatibility, and ease of magnetic recovery. Two modified co-precipitation synthetic routes were systematically evaluated, and the size, morphology, and chemical composition of the products were characterized by microscopy, light scattering, and spectroscopic methods, while both adsorption and covalent immobilization strategies were explored. The MNP surface was found to be highly reactive toward radical species generated during laccase-catalyzed reactions, especially in the presence of small Fe²⁺ excess. While this can enhance the enzyme catalytic activity, it challenges the inertness of the support and promotes, in some cases, strong interactions between reaction products and the nanoparticle surface. These findings highlight a previously unexplored role of magnetic supports in laccase-based biocatalytic systems. Full article

As a renewable aromatic carbon reservoir, lignin exhibits great potential for the synthesis of sustainable fuels and high-value chemicals. Nevertheless, its intricate skeletons, irregular bond distribution, and abundant oxygenated functional groups complicate hydrodeoxygenation (HDO), resulting in inferior product selectivity and limited catalytic durability. Centered on structure–activity relationships, this review systematically correlates lignin structural features, catalytic performance, hydrogen supply modes, and HDO mechanisms. Impacts of linkage types, functional group distribution, and pretreatment-induced structural evolution on substrate adsorption and C–O bond cleavage are analyzed. The structure-performance rules of monometallic, bifunctional, atomic-scale, and carbon-based catalysts are clarified. Regulatory effects of various hydrogen supply strategies on active hydrogen generation and competitive direct deoxygenation/hydrogenation deoxygenation (DDO/HYD) pathways are elaborated. Critical bottlenecks restricting practical lignin conversion are summarized, and prospects for rational catalyst design and green biorefinery development are proposed. Full article

Complex hollow metallic microstructures are essential for microelectromechanical systems (MEMS), lab-on-a-chip microfluidics, and bio-integrated devices, yet their fabrication remains challenging because geometric complexity, microscale precision, and high aspect ratios must be satisfied simultaneously. This study proposes filament-guided electrolyte–column electrodeposition (FG-ECD), which couples a removable filament template with a nozzle-confined electrolyte column to define internal channels in situ during localized metal growth, thereby avoiding the collapse risks associated with conventional template removal routes. A two-dimensional axisymmetric multiphysics model reveals that the embedded filament reorganizes the electrolyte into a stable annular flow and shifts the cathodic current density maximum from the substrate toward the advancing dome front, establishing a self-consistent, quasi-stable localized reaction zone, while a parametric sweep shows that the total current scales the current density magnitude without altering its spatial profile. Experiments demonstrate that a current of 3.6 mA produces smooth dome front growth at approximately 20 μm/min, whereas 5.5 mA triggers sustained hydrogen evolution and a transition to cellular deposition. Under optimized conditions, straight, 540° spiral, and R-shaped dual-channel hollow nickel microstructures were fabricated with continuous, collapse-free internal channels of 50 ± 5 μm, aspect ratios exceeding 10:1, and dimensional accuracy within ±35 μm. FG-ECD provides a low-temperature processing route for complex hollow metallic architectures and offers process regulation principles based on co-regulation of the flow field and current density for electrochemical microfabrication. Full article

The intensification of poultry production in Poland generates enormous quantities of excreta and associated biomass. While these constitute valuable sources of macro- and micronutrients, inadequate waste management leads to environmental pollution, nutrient leaching, and ammonia emissions. This paper analyses the fertilising potential of avian excreta, the legal provisions governing their application, and modern management technologies within the context of the circular economy. The study addresses two global threats—antimicrobial resistance (AMR) and the eutrophication of aquatic ecosystems—evaluating mitigation strategies and advanced biotechnological processing methods. Industrial farming turns excreta into a reservoir of active antibiotics, leading to the contamination of soils, waters, and crops. As a preventative strategy to reduce reliance on veterinary antibiotics—thereby indirectly mitigating the environmental dissemination of AMR—the dietary application of phytobiotics is highlighted. To counteract eutrophication, supplementing feed with exogenous microbial phytase plays a pivotal role, improving phytate phosphorus absorption and reducing its excretion by up to 50%. Furthermore, anaerobic co-digestion with carbon-rich substrates enhances methane yield, while advanced recovery systems (struvite precipitation, electrodialysis, bioelectrochemical concentration, and membrane techniques) show significant potential for safer nutrient concentration. An integrated technological approach to waste processing constitutes the foundation of sustainable agricultural production. Full article

Magnetic molecular thin films provide a platform for nanoscale control of spin density, morphology and low-dimensional magnetism. We use co-deposition of closely isostructural iron phthalocyanine (FePc) and metal-free phthalocyanine (H₂Pc) onto heated substrates to prepare diluted thin films with systematically varied Fe spin densities. Structural and surface characterization shows that H₂Pc incorporation modifies film growth, producing a monotonic dependence of surface roughness on dilution and a grain size minimum for mixed FePc:H₂Pc films. Vibrating sample magnetometry reveals a nonlinear suppression of the magnetic response with increasing H₂Pc content, exceeding the reduction expected from FePc concentration alone. Below 5 K, the saturation magnetization is markedly reduced in diluted films compared with undiluted FePc, suggesting that molecular packing, Fe chain length and nanoscale morphology influence the magnetic coupling strength. These findings provide insight into FePc:H₂Pc co-deposition as a route to chemically tunable magnetic molecular nanomaterials and highlight the importance of structurally compatible molecular dilution for magnetic sensing applications. Full article

The spread of Bursaphelenchus xylophilus has caused a critical shortage of traditional Poria cocos cultivation materials, making bag-based substrates an urgent alternative. Yet, how substrate stoichiometry shapes nutritional quality remains unclear. Using non-targeted metabolomics combined with redundancy analysis (RDA) and weighted gene co-expression network analysis (WGCNA), we profiled P. cocos cultivated on four substrates: healthy pine logs, pine wilt wood bags, oak bags, and pine needle/branch bags. Bag-cultivated P. cocos showed significantly elevated total amino acids, poria cocos acid, and total triterpenoids, with pine wilt wood bags (P1) performing best overall. Nitrogen, phosphorus, and the N/P ratio independently drove metabolomic variation (pairwise overlap < 5%). Nitrogen-line hub metabolites were negatively correlated with amino acid content, suggesting that suppressed lipid metabolism may free carbon skeletons for the accumulation of nitrogenous nutrients. Phosphorus-line hub metabolites were positively associated with polysaccharide indices, whereas the N/P ratio in line lipid amides showed strong negative correlations with polysaccharides under phosphorus limitation. These correlational patterns are consistent with a stoichiometric resource allocation model, although direct validation through controlled-element experiments is required. These findings provide quantitative guidance for optimizing bag-substrate formulations in P. cocos cultivation. Full article

Gut microbiota regulate the intestinal expression of drug-metabolizing enzymes, transporters, and barrier properties that determine oral drug absorption and disposition. This study compares germ-free Swiss Webster mice to mice colonized with fecal microbiota from a single human donor, evaluating microbiota-driven differences in colonic gene expression and P-gp protein expression, as well as small intestinal mucosal permeability. Transcriptomic analysis of colonic tissue revealed microbiota-induced upregulation of genes encoding P-gp and other drug transporters, including MCT1 and OCTN2. Immunofluorescence also indicated greater P-gp expression and apical localization in colonized mice. Gene expression of drug-metabolizing enzymes was also higher in colonized mice, including phase I enzymes (carboxylesterase 2 paralogs), phase II enzymes (UDP-glucuronosyltransferases and glutathione S-transferases), and enzymes responsible for synthesizing their co-substrates, UDP-glucuronic acid and glutathione. Small intestinal mucosal explants demonstrated lower permeability to ¹⁴C-labeled polyethylene glycol 4000 in colonized mice compared to germ-free mice. In the colon, transcriptomic analysis identified microbiota-dependent changes in genes regulating paracellular tight junctions and actomyosin contractility. These results show that human-derived gut microbiota alter gene expression in the mouse colon, identifying candidate microbiota-responsive genes relevant to oral drug absorption and disposition. Full article

Titanium alloys are widely used in clinical settings due to their excellent mechanical properties and biocompatibility. However, the biologically inert surface of titanium alloys limits interfacial bioactivity and bone integration, which may compromise long-term implant stability. Therefore, this study innovatively proposes a synergistic “composition design and process adaptation” strategy. Specifically, borosilicate bioactive glasses (BSBGs) with a high B₂O₃ content (36 mol%), co-doped with strontium (Sr) and magnesium (Mg), were designed and systematically compared with Sr/Mg-doped silicate bioactive glasses (SBGs). Both glasses were subsequently deposited onto Ti6Al4V substrates using atmospheric plasma spraying. The results showed that the BSBG coating exhibited an initial boron release concentration of up to 116 mg/L but exhibited excellent cytocompatibility, which is likely related to the synergistic regulation of Sr, Mg, and B ions. Moreover, the BSBG coating induced Ca-P compound mineralization within 24 h, significantly faster than the SBG coating, which required a minimum of 3 days, confirming superior biomineralization kinetics. Both coatings achieved a bonding strength of 30 MPa, meeting clinical requirements. In vivo experiments confirmed that the BSBG coating significantly promoted new bone regeneration and implant osseointegration. This work not only delivers experimental validation supporting the implementation of high-boron-content bioactive glass coatings but also provides a practical method for designing rapidly degradable and highly bioactive coatings to facilitate improved osseointegration. Full article

Anode materials play a pivotal role in a wide range of electrochemical applications, including electrolysis, energy storage, corrosion protection, and industrial oxidation processes. This review provides a comprehensive analysis of recent advances in anode materials, with particular emphasis on their structural characteristics and major preparation methods, including thermal decomposition, electrochemical deposition, sol–gel processing, and magnetron sputtering. The degradation behaviour of anodes under electrochemical operating conditions is also critically discussed, together with strategies for improving their durability and overall performance. Particular attention is given to metal oxide-coated anodes, especially those based on ruthenium oxide (RuO₂) and iridium oxide (IrO₂), which remain the most representative systems in dimensionally stable anode (DSA) research and industrial applications. Emerging coating materials, including Co₃O₄- and carbon-based catalysts, are also reviewed as promising alternatives for reducing noble metal usage while maintaining acceptable electrochemical performance. In addition, the role of intermediate layers in titanium-based anodes is examined, with emphasis on their contribution to coating adhesion, conductivity, interfacial stability, and long-term electrode performance. This review further discusses the applications of anode materials in chlorine- and oxygen-related electrochemical industries and evaluates the performance of DSAs in relation to substrate selection, coating composition, and operational requirements. Alternative furnace technologies for anode baking are also reviewed, including conventional furnace heating, laser heating, and microwave heating, together with representative industrial furnace systems such as muffle, continuous, and vacuum furnaces. Overall, this review provides an integrated overview of the current progress in anode material research and development, while highlighting the key challenges and future directions for improving anode efficiency, durability, and sustainability in industrial electrochemical applications. Full article

In this work, Cu₂CoSnS₄ (CCTS) thin films were deposited on glass substrates by thermal evaporation and investigated for photovoltaic applications. The influence of substrate temperature, varied from 25 °C to 200 °C, on the structural, morphological, and optical properties of the films was experimentally studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence (PL) measurements. XRD analysis confirmed the formation of crystalline CCTS with a stannite structure and a preferential orientation along the (112) plane. SEM observations revealed rough and non-uniform surfaces accompanied by an increase in grain size with increasing substrate temperature. Room-temperature PL measurements indicated a band-gap energy of approximately 1.3 eV, suitable for photovoltaic applications, and confirmed the presence of secondary phases in the p-type stannite CCTS films. Despite the promising photovoltaic properties of CCTS, numerical studies on CCTS-based solar cells remain scarce in the literature. In this context, a numerical study of the CCTS-based solar structure grown on glass was also performed using SCAPS-1D, showing good agreement with experimental photovoltaic results and validating the simulation model. Replacing the glass substrate with silicon improved the device efficiency to 5.77%. Further optimization of the series and shunt resistances significantly enhanced the photovoltaic performance, achieving a power conversion efficiency of 16.77%, with FF = 52.94%, V_oc = 0.89 V and J_sc = 35.19 mA/cm². Full article