Search Results (73)

The cigarette butt (CB) recycling process yields several byproducts, including cleaned filters, solid debris (mainly paper and tobacco), and wastewater. This study aimed to assess, for the first time, the long-term suitability of these recycled byproducts for turfgrass cultivation. Under controlled conditions, Paspalum vaginatum Swartz was grown in sand–peat substrate, either unmodified (control) or amended with small pieces of uncleaned CBs or solid byproducts from CB recycling at concentrations of 25% or 50% (v/v). In additional tests, turfgrass grown in unmodified substrate received wastewater instead of tap water once or twice weekly. Over 7 weeks, physiological and biometric parameters were assessed. Plants grown with solid debris showed traits comparable to the control. Those grown with intact CBs or cleaned filters had similar biomass and coverage as the control but accumulated more carotenoids and antioxidants. Wastewater significantly enhanced plant growth when applied once weekly, while becoming toxic when applied twice, reducing biomass and coverage. After scalping, turfgrass recovered well across all treatments, and in some cases biomass improved. Overall, recycled CB byproducts, particularly wastewater used at optimal concentrations, can be a sustainable resource for promoting turfgrass growth. Full article

Urban solid waste (USW) is a promising alternative source of valuable chemical compounds. It is considered an adsorbent material due to its chemical structure, porosity and electronic charge available to form chemical bonds and can be recovered or transformed for use in bioprocesses and industrial applications. This is the case with cigarette butts (CBs), which consist of thousands of substances that can be chemically converted for various purposes. This work showed high efficiency in the production of cellulose mass from the recycling of CBs, a patented technology in operation at the company Poiato Recicla—SP. The lignin-like solid (LLS)—a material obtained from the recycling of cigarette butts (CBs) by catalytic transfer hydrogenation (CTH), under non-rigorous conditions—showed high efficiency in its conversion into molecules of great interest. In the bio-oil obtained, characterized by analyses such as GCMS and RMN 2D HSQC, a mixture of predominantly hydrocarbons (many of them with cyclic and/or branched chains) was identified in almost all the experiments. This method demonstrates the potential of the TCH process for SSLs and completes the recycling chain designed for CBs, promoting their complete conversion into chemical compounds of greater interest. Full article

This research utilized recycled acetate fibers from discarded cigarette butts (CBs) as reinforcing materials, reducing solid waste and enhancing the properties of bitumen. The surface properties of the fibers significantly impacted the binder characteristics. The treatment of CB fibers with anhydrous ethanol was employed to remove the plasticizer glycerol triacetate (GTA), enabling the better homogeneity of the fibers in the binder. Thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) were used to assess the effectiveness of the fiber treatment. A dynamic shear rheometer (DSR) was used to explore the properties of bitumen with varying CB contents (0%, 0.25%, 0.75%, and 1.25% by weight). A whole life cycle analysis further confirmed the eco-efficiency of CB binders. The results show that the pretreatment effectively removed GTA, leading to a more homogeneous dispersion of fibers in the binder. Adding CBs can significantly improve bitumen properties, but this effect does not increase with higher dosages; when the CB content exceeded 1.25%, a reduction in fatigue resistance was observed. Among the tested dosages, the optimal amount was 0.75%, which improved the high-temperature performance of the binder by 2.7 times, the medium-temperature fatigue life by 1.78 times, and the low-temperature performance by 1.08 times. In terms of ecological benefits, the addition of CB fibers to bitumen pavement reduced carbon emissions by two-thirds compared to traditional bitumen pavement, resulting in a significant decrease in carbon emissions. This study provides valuable insights into the construction of sustainable transportation infrastructure. Full article

The rheological properties of fiber-reinforced binders are remarkable. The research on acetate fibers as reinforcing agents is scant. Acetate fibers exhibit more environmental benefits than lignocellulose and other fibers. In this study, acetate fibers were pretreated with anhydrous ethanol as the extractant to disperse the fibers uniformly in the bitumen and the high/medium-temperature fatigue properties of waste acetate fibers blended with binders were investigated. Infrared spectroscopy (FT-IR) tests showed that pretreatment was effective in removing plasticizers from CBs so that the fibers could be more uniformly dispersed in the binders. The roadworthiness and fatigue performance of the adhesives were tested based on frequency sweep (FS), multiple stress creep recovery (MSCR), and linear amplitude sweep (LAS) tests with different CB (cigarette butt) doping levels. Ultimately, CBs were added to effectively improve all aspects of bitumen performance, but this phenomenon was not enhanced with an increase in the amount of admixture—optimal covariance was 0.25%. Moreover, a further correlation analysis was performed for the three traditional predicted fatigue failure points. The best correlation was R² = 0.98 for a 50% decrease in dynamic shear modulus, followed by R² = 0.96 for peak stress–strain, and R² = 0.88 for fatigue factor. Full article

Cigarette butt (CB) waste is abundant and difficult to biodegrade, which is dangerous for both the environment and human health. The key reason CBs are littered is that people do not know much about the harm CBs pose to the environment. Recycling CBs in infrastructure construction can help raise people’s awareness. To promote the recycling of CB waste, this paper aimed to determine the feasibility of using CBs as a modifier for asphalt binders. In this research, CBs were preprocessed and mixed with virgin asphalt binder as a fiber modifier. Comprehensive laboratory investigations, including a softening point test, viscosity test, storage stability test, and temperature sweep test, were performed, along with a frequency sweep test, to evaluate the performance of the modified samples. During this investigation, samples were prepared with 1%, 2%, 3%, and 4% CBs. The results of the CB-modified samples were compared with the sample consisting of fresh bitumen (0% fiber). The results show that the physical and rheological properties of bitumen with incorporated CBs improved significantly, and CBs could be used instead of virgin cellulose fiber as a fiber modifier. However, CB-modified asphalt reduced the storage stability and low-temperature performance of the samples. Further research should focus on improving the storage stability and low-temperature performance of CB-modified asphalt binders to facilitate their application in asphalt pavements. Full article

Marine litter is a critical environmental issue, with beach litter being its most visible indicator. Despite severe pollution on Mediterranean beaches, Tunisia currently lacks a national beach litter monitoring program. To address this gap and support the development of such a program, particularly at pollution hotspots like urban beaches, we conducted a one-year study on six Tunisian beaches. We employed an innovative, accelerated multiple 10 m transect method tailored to highly polluted beaches, focusing on macro-litter (>2.5 cm). This method significantly reduces survey time compared to the standard 100 m approach while maintaining comparable pollution metrics, offering a practical and efficient solution for areas with high litter density. Our findings reveal an average litter density of 1.01 ± 1.08 pieces/m², with higher pollution in urban areas. Based on the Clean Coast Index (CCI), two beaches were classified as extremely dirty, one as dirty, two as moderately clean, and one as clean. Plastics (59.2%) and cigarette butts (21.1%) were the most prevalent pollutants, with single-use plastics comprising 52.5% ± 5.3% of total litter. Most of the litter (60.6%) originated from shoreline activities and poor waste management. These findings underscore the urgent need for a long-term national beach litter monitoring program. The integration of our accelerated transect method would enable efficient, effective surveys on highly polluted beaches, providing critical data to address litter sources and support targeted strategies for mitigating pollution and protecting Tunisia’s coastal ecosystems. Full article

Cigarette butts are an increasing environmental burden worldwide, and the quantities discarded each year could continue to rise. The chemical composition of cigarette butts, which comprises about 4000 different toxic chemicals, as well as their persistence in the environment and their potential negative effects pose a major threat to the environment as they regularly enter aquatic habitats and endanger water supplies and aquatic species. One effective way to reduce pollution is to recycle cigarette butts. The aim of this study is to evaluate the possibility of using extracts from cigarette butts (filter extract and extract from tobacco residues) as corrosion inhibitors for the Cu10Ni alloy in a 3.5% NaCl solution with a pH of 8 at different temperatures (12 °C, 20 °C and 25 °C). The determination of the electrochemical parameters, i.e., the corrosion behavior of the Cu10Ni alloy in a 3.5% NaCl solution and pH of 8, with and without modification of the alloy surface by cigarette butt extracts was tested using electrochemical measurements (electrochemical impedance spectroscopy and linear and potentiodynamic polarization methods). The surface properties of the Cu10Ni alloy modified with cigarette butt extracts were evaluated by goniometry, SEM analysis and FTIR spectrophotometry. The modification of the surface of the Cu10Ni alloy with an extract of tobacco residue and a filter extract separated from cigarette butts, whose presence on the surface was confirmed by the surface analysis methods, increased the corrosion resistance of the alloy, indicating that these substances have an inhibitory effect. The better inhibition properties (at all temperatures: 12 °C, 20 °C and 25 °C) were exhibited by the filter extract, and the highest inhibition effect was exhibited by the filter extract at 12 °C. Full article

Cigarette butts (CBs) are emerging soil contaminants, releasing chemicals upon contact with moisture. This study examined heavy metal concentrations leached from smoked and unsmoked CBs (Pall Mall, Philip Morris, and Marlboro) into OECD artificial soil and Vertisol soil and their accumulation in white mustard (Sinapis alba L.). Key physiological parameters, including germination rate, plant height, fresh weight, and dry weight, were analyzed, along with the uptake of heavy metals (Al, Fe, Mn, Zn, Ba, Ti, and Cu) and essential elements (Ca, Mg, Na, and K). Results showed that Mn had the highest bioaccumulation index (BAI = 1.10) in OECD soil, while Zn uptake was consistently high across soil types. Soil type significantly influenced plant height (χ² = 41.269, p < 0.01) and elemental composition, with Vertisol soil facilitating greater overall growth and heavy metal uptake than OECD soil. MANOVA revealed no three-way interaction among soil type, CB use, and CB brand on elemental uptake. However, two-way interactions, particularly between soil type and CB use (F (4, 39) = 40.233, p < 0.001, Wilk’Λ = 0.195), showed significant effects on heavy metal uptake. These findings highlight the complex interactions influencing plant contamination, underlining the ecological risks of CB pollution in soils. Full article

Cigarette butt littering poses a significant environmental challenge, with billions of butts discarded each year, fouling ecosystems with slow-to-decompose cellulose acetate filters that absorb and release harmful compounds. In response, an innovative, sustainable approach for valorizing ballot bin waste (BBW) by extracting high-quality cellulose acetate from cigarette butts was investigated. This green approach eliminates the need for hazardous acids and toxic solvents, resulting in a yield of 30% (w/w) and a degree of substitution (DS) of 2.0–2.5, which is comparable to pure cellulose acetate. The following four essential processes are involved in this process: filter separation, water washing to remove impurities, ethanol purification, and acetone precipitation of the cellulose acetate. This approach not only mitigates environmental harm, but also supports circular economy goals by transforming waste into valuable resources. Full article

This study demonstrated the biodegradation of two different brands of cigarette butts (CBs), which are primarily composed of cellulose acetate, by four distinct microorganisms. These included the white rot fungus Pleurotus ostreatus, the brown rot fungus Lentinus lepideus, and the bacteria Bacillus cereus and Pseudomonas putida. After 31 days of treatment, weight loss measurements revealed a mass loss of 24–34%, where B. cereus exhibited the greatest efficacy in terms of mass loss for both brands of CBs. Fourier-Transform Infrared Spectroscopy (FTIR), confocal microscopy, and scanning electron microscopy (SEM) confirmed changes in the surface of the CBs, attributable to structural wear and material breakdown, indicating effective biodegradation by the evaluated microorganisms. Furthermore, the analyses confirmed changes in the surface of the CBs, attributable to structural wear and material breakdown, indicating effective biodegradation by the evaluated microorganisms. Full article

Cigarette butts (CBs) are a major source of persistent pollution in coastal ecosystems, introducing harmful chemicals and microplastics into the environment. This study assesses the ecotoxicological impact of CB leachates on Marbella Beach, Chile, by analyzing the metal contamination and its phytotoxic effects on Lactuca sativa and Lolium perenne. Three scenarios were evaluated: CBs alone, CBs mixed with sand, and sand alone. Leachate analysis revealed significant concentrations of iron and zinc, with higher toxicity observed in scenarios involving CBs. Ecotoxicological assays demonstrated that cigarette butt leachates severely inhibited seed germination and plant growth, particularly in Lactuca sativa, which showed greater sensitivity compared to that of Lolium perenne. The results underscore the partial mitigating role of sand, although it was insufficient to prevent the toxic effects of CBs. The persistence of cellulose acetate in the environment and the continued release of hazardous chemicals highlight the ecological risks posed by cigarette butt pollution. These findings emphasize the need for improved waste management strategies and the development of biodegradable cigarette filters to reduce environmental contamination in coastal areas. Full article

This paper deals with beach litter presence on the Ionian coast of Albania, i.e., at Vlora Bay and the Albanian Riviera, which is the most famous coastal tourist destination in the country. Along 16 beaches surveyed in November–December 2022 was found a total amount of 6621 litter items (or 416 kg) belonging to 114 categories of the EU J−code list. Most of these were plastic fragments and items (82%), mainly linked to local tourist activities. Wastewaters were responsible for bringing different litter items to the urban beaches of Vlora Bay. The most commonly observed litter items were cigarette butts, plastic caps/lids, and medium-sized plastic fragments of non-foamed plastic. The cleanest beaches, quite often, were the ones where beach clubs implemented clean-up programs during and at the end of the summer season. The results of this paper constitute a baseline of the beach litter amount and content along the study coast, which has never been investigated before. Municipalities and beach clubs have to implement more frequent and efficient clean-up activities and educational initiatives to reduce beach pollution, with special attention paid to the presence of cigarette butts and other small plastic items. Full article

Cigarette butts (CBs) are non-biodegradable harmful residues of synthetic origin and are widespread in marine environments around the world. Although environmental factors are often primarily responsible for the fragmentation of microplastics in the marine environment, biotic factors have recently been shown to be equally important in plastic debris. This study evaluates the role of the Hediste diversicolor polychaete in the fragmentation of CBs in the marine environment. Polychaetes were exposed to three concentrations of CB (0 (as the control), 0.25, and 1 butt L⁻¹) at two different temperatures (15 °C and 23 °C) for 28 days. At each temperature, aquaria without polychaetes were used to study the effect of the burrowing activity of the polychaete on CB fragmentation. Toxicants analysed from exposed sediments increased their concentration in a dose-dependent manner to the CB concentration at a temperature of 15 °C but not at 23 °C. CBs did not directly decrease Hediste survival, but prolonged elevated temperatures increased the polychaetes’ susceptibility. The negative effects of CBs on burial success and burrowing behaviour could not be offset by the reduced start time caused by elevated temperatures. Regardless of temperature, both the weight loss and physical fragmentation of CBs buried in polychaete-contaminated sediments were significantly higher than those without Hediste, with no differences between the two concentrations tested. FTIR-ATR analysis used to evaluate CB degradation in relation to cellulose acetate decomposition showed a greater degradation of this compound in treatments with Hediste than in those without polychaetes (~2.75 times), but these differences were not significant. This study is a promising initial step for future research, as any factor that facilitates the fragmentation of this prevalent and hazardous waste must be carefully studied to extract the maximum benefit to help to reduce CBs in the marine environment. Full article

Cigarette butts, often discarded as litter, are considered a common form of waste, containing a variety of pollutants within this hazardous residue. This study, which was designed to assess the environmental release of certain metals from cigarette butts, investigates a variety of scenarios under varying climatic conditions. Thus, in order to assess the level of metal contamination, samples of cigarette butts were collected in urban areas from seven popular brands in China, smoked artificially, and examined through graphite furnace atomic absorption (GF-AAS). The findings indicated mean concentrations of 1.77 for Cr, 2.88 for Ni, 12.93 for Cu, 24.25 for Zn, and 1.77 µg/g for Pb in the case of newly smoked butts. The emission of each of the metals increases to 8–10% when cigarette butts remain in the environment for an extended period of time. Furthermore, rainfall can accelerate metal leaching, reaching values of 18–20% compared to the controlled scenario. The worst-case scenario releases 2129.31 kg/year of metals into the environment, while the best-case scenario sees a lower release of 844.97 kg/year. The data reflect variations in metal emissions across different scenarios. There was also a strong correlation between cigarette butts in public spaces and cities. This research highlights the need to educate smokers and increase urban maintenance efficiency to reduce this litter and the metals it leaches into the environment. Full article

As a cigarette butt falls onto the forest surface fuel, it first smolders the fuel, then ignites into flames, and spreads as forest fire under certain conditions. In this study, the needles under a typical stand of P. massoniana were used as the research object. Needle beds with different moisture content and packing ratios were constructed indoors. Cigarette butt-ignition experiments were conducted under different wind velocities, and 30 experiment cycles were conducted under different conditions. There was a total of 5 (packing ratio) × 4 (moisture content) × 6 (wind velocity) = 120 sets of conditions, and a total of 3600 ignition experiments were conducted. The results showed that (1) the total ignition probability of the cigarette butts was 2.36%, which only occurred when the fuelbed moisture content was <10% and the wind velocity was >1 m/s. The ignition time of cigarette butts ranged from 2.73 to 7.25 min. (2) The fuelbed moisture content and wind velocity significantly influenced the ignition probability and time. With an increase in moisture content, the ignition probability of cigarette butts decreased, while the time required for ignition showed an increasing trend. Wind velocity had a dual effect on ignition. The ignition effect was optimal at a wind velocity of 4 m/s. With an increase in wind velocity, the ignition probability first increased and then decreased, and the ignition time first decreased and then increased. (3) The packing ratio had no significant effect on the ignition probability; however, the ignition time significantly decreased as the packing ratio increased. (4) The logistic regression method (LRM), general linear method (GLM), and nonlinear regression method (NLM) were used to establish a prediction model of ignition probability. The prediction effect of GLM was the worst, followed by LRM, and the NLM had the best prediction effect. The GLM was selected to establish the ignition time model, and the error was also within the allowance range. This study elucidated the underlying mechanism of factors affecting cigarette butt-based fuel ignition. In addition, the established prediction model provides a reference for human-caused forest fires and is highly significant for forest fire prevention. Full article