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Keywords = cement plasticizers

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29 pages, 3167 KiB  
Article
A Comparative Evaluation of Polymer-Modified Rapid-Set Calcium Sulfoaluminate Concrete: Bridging the Gap Between Laboratory Shrinkage and the Field Strain Performance
by Daniel D. Akerele and Federico Aguayo
Buildings 2025, 15(15), 2759; https://doi.org/10.3390/buildings15152759 - 5 Aug 2025
Abstract
Rapid pavement repair demands materials that combine accelerated strength gains, dimensional stability, long-term durability, and sustainability. However, finding materials or formulations that offer these balances remains a critical challenge. This study systematically evaluates two polymer-modified belitic calcium sulfoaluminate (CSA) concretes—CSAP (powdered polymer) and [...] Read more.
Rapid pavement repair demands materials that combine accelerated strength gains, dimensional stability, long-term durability, and sustainability. However, finding materials or formulations that offer these balances remains a critical challenge. This study systematically evaluates two polymer-modified belitic calcium sulfoaluminate (CSA) concretes—CSAP (powdered polymer) and CSA-LLP (liquid polymer admixture)—against a traditional Type III Portland cement (OPC) control under both laboratory and realistic outdoor conditions. Laboratory specimens were tested for fresh properties, early-age and later-age compressive, flexural, and splitting tensile strengths, as well as drying shrinkage according to ASTM standards. Outdoor 5 × 4 × 12-inch slabs mimicking typical jointed plain concrete panels (JPCPs), instrumented with vibrating wire strain gauges and thermocouples, recorded the strain and temperature at 5 min intervals over 16 weeks, with 24 h wet-burlap curing to replicate field practices. Laboratory findings show that CSA mixes exceeded 3200 psi of compressive strength at 4 h, but cold outdoor casting (~48 °F) delayed the early-age strength development. The CSA-LLP exhibited the lowest drying shrinkage (0.036% at 16 weeks), and outdoor CSA slabs captured the initial ettringite-driven expansion, resulting in a net expansion (+200 µε) rather than contraction. Approximately 80% of the total strain evolved within the first 48 h, driven by autogenous and plastic effects. CSA mixes generated lower peak internal temperatures and reduced thermal strain amplitudes compared to the OPC, improving dimensional stability and mitigating restraint-induced cracking. These results underscore the necessity of field validation for shrinkage compensation mechanisms and highlight the critical roles of the polymer type and curing protocol in optimizing CSA-based repairs for durable, low-carbon pavement rehabilitation. Full article
(This article belongs to the Special Issue Study on Concrete Structures—2nd Edition)
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29 pages, 5505 KiB  
Article
Triaxial Response and Elastoplastic Constitutive Model for Artificially Cemented Granular Materials
by Xiaochun Yu, Yuchen Ye, Anyu Yang and Jie Yang
Buildings 2025, 15(15), 2721; https://doi.org/10.3390/buildings15152721 - 1 Aug 2025
Viewed by 123
Abstract
Because artificially cemented granular (ACG) materials employ diverse combinations of aggregates and binders—including cemented soil, low-cement-content cemented sand and gravel (LCSG), and concrete—their stress–strain responses vary widely. In LCSG, the binder dosage is typically limited to 40–80 kg/m3 and the sand–gravel skeleton [...] Read more.
Because artificially cemented granular (ACG) materials employ diverse combinations of aggregates and binders—including cemented soil, low-cement-content cemented sand and gravel (LCSG), and concrete—their stress–strain responses vary widely. In LCSG, the binder dosage is typically limited to 40–80 kg/m3 and the sand–gravel skeleton is often obtained directly from on-site or nearby excavation spoil, endowing the material with a markedly lower embodied carbon footprint and strong alignment with current low-carbon, green-construction objectives. Yet, such heterogeneity makes a single material-specific constitutive model inadequate for predicting the mechanical behavior of other ACG variants, thereby constraining broader applications in dam construction and foundation reinforcement. This study systematically summarizes and analyzes the stress–strain and volumetric strain–axial strain characteristics of ACG materials under conventional triaxial conditions. Generalized hyperbolic and parabolic equations are employed to describe these two families of curves, and closed-form expressions are proposed for key mechanical indices—peak strength, elastic modulus, and shear dilation behavior. Building on generalized plasticity theory, we derive the plastic flow direction vector, loading direction vector, and plastic modulus, and develop a concise, transferable elastoplastic model suitable for the full spectrum of ACG materials. Validation against triaxial data for rock-fill materials, LCSG, and cemented coal–gangue backfill shows that the model reproduces the stress and deformation paths of each material class with high accuracy. Quantitative evaluation of the peak values indicates that the proposed constitutive model predicts peak deviatoric stress with an error of 1.36% and peak volumetric strain with an error of 3.78%. The corresponding coefficients of determination R2 between the predicted and measured values are 0.997 for peak stress and 0.987 for peak volumetric strain, demonstrating the excellent engineering accuracy of the proposed model. The results provide a unified theoretical basis for deploying ACG—particularly its low-cement, locally sourced variants—in low-carbon dam construction, foundation rehabilitation, and other sustainable civil engineering projects. Full article
(This article belongs to the Special Issue Low Carbon and Green Materials in Construction—3rd Edition)
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17 pages, 6929 KiB  
Article
The Application and Effects of Aerogel in Ultra-Lightweight Mineralised Foams
by Tongyu Xu, Harald Garrecht, Chao Jiang and Chuanyuan Lu
Buildings 2025, 15(15), 2671; https://doi.org/10.3390/buildings15152671 - 28 Jul 2025
Viewed by 204
Abstract
This study aims to explore the potential of aerogel to optimise the thermal conductivity of mineralised foam materials. Experiments were conducted with (i) addition methods of aerogel, (ii) proportion of aerogels in cement slurry, and (iii) water/cement ratio as influencing parameters for mineralised [...] Read more.
This study aims to explore the potential of aerogel to optimise the thermal conductivity of mineralised foam materials. Experiments were conducted with (i) addition methods of aerogel, (ii) proportion of aerogels in cement slurry, and (iii) water/cement ratio as influencing parameters for mineralised foam. Additionally, mixed Ordinary Portland Cement (OPC)/Calcium Sulphoaluminate Cement (CSA) slurries were used to test whether a synergy could be achieved. In this study, the defoaming effect of the aerogel and its mitigation to a certain extent by pre-mixing the aerogel with cement slurry were confirmed. The thermal conductivity of the mineralised foams was reduced from 0.049 to 0.036 W/(m·K) when the aerogel was up to 10 wt.% of the cement. In the specimens prepared from the mixed OPC/CSA slurry, a homogeneous circular pore structure was observed under the microscope along with a reduction in the thermal conductivity. The use of aerogels and CSA cements can effectively reduce the thermal conductivity of ultra-low-density mineralised foams to levels comparable with certain plastic foams that dominate the building insulation market. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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22 pages, 3056 KiB  
Article
Recycled Glass and Plastic Waste in Sustainable Geopolymer Systems for Affordable Housing Solutions
by Zhao Qing Tang, Yat Choy Wong, Yali Li and Eryadi Kordi Masli
Recycling 2025, 10(4), 147; https://doi.org/10.3390/recycling10040147 - 27 Jul 2025
Viewed by 338
Abstract
The increasing demand for sustainable construction materials has driven research into low-carbon geopolymers that mitigate both cement-related emissions and plastic and glass waste accumulation. This study explores the development of geopolymer concrete incorporating fly ash (FA), slag (S), and FA + S blends, [...] Read more.
The increasing demand for sustainable construction materials has driven research into low-carbon geopolymers that mitigate both cement-related emissions and plastic and glass waste accumulation. This study explores the development of geopolymer concrete incorporating fly ash (FA), slag (S), and FA + S blends, with 10% recycled crushed glass (RCG) and recycled plastic waste (RPW) as partial coarse aggregate replacements. Compressive strength testing revealed that FA + S-based geopolymers (25FA + S) with 100% ordinary Portland cement (OPC) replacement achieved a 7-day strength of 24.6 MPa, representing a 98% improvement over control specimens. Slag-based geopolymers demonstrated water absorption properties comparable to OPC, indicating enhanced durability. Microstructural analyses using SEM, XRD, and EDS confirmed the formation of a dense aluminosilicate matrix, with slag promoting FA reactivity and reinforcing interfacial transition zone (ITZ). These effects contributed to superior mechanical performance and water resistance. Despite minor shrinkage-induced cracking, full OPC replacement with S or FA + S geopolymers outperformed control specimens, consistently exceeding the target strength of 15 MPa required for low-impact, single-story housing applications within seven days. These findings underscore the potential of geopolymer systems for rapid and sustainable construction, offering an effective solution for reducing carbon footprints and repurposing industrial waste. Full article
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27 pages, 19505 KiB  
Article
Analysis on the Ductility of One-Part Geopolymer-Stabilized Soil with PET Fibers: A Deep Learning Neural Network Approach
by Guo Hu, Junyi Zhang, Ying Tang and Jun Wu
Buildings 2025, 15(15), 2645; https://doi.org/10.3390/buildings15152645 - 27 Jul 2025
Viewed by 265
Abstract
Geopolymers, as an eco-friendly alternative construction material to ordinary Portland cement (OPC), exhibit superior performance in soil stabilization. However, their inherent brittleness limits engineering applications. To address this, polyethylene terephthalate (PET) fibers can be incorporated into a one-part geopolymer (OPG) binder to enhance [...] Read more.
Geopolymers, as an eco-friendly alternative construction material to ordinary Portland cement (OPC), exhibit superior performance in soil stabilization. However, their inherent brittleness limits engineering applications. To address this, polyethylene terephthalate (PET) fibers can be incorporated into a one-part geopolymer (OPG) binder to enhance ductility while promoting plastic waste recycling. However, the evaluation of ductile behavior of OPG-stabilized soil with PET fiber normally demands extensive laboratory and field experiments. Leveraging artificial intelligence, a predictive model can be developed for this purpose. In this study, data were collected from compressive and tensile tests performed on the OPG-stabilized soil with PET fiber. Four deep learning neural network models, namely ANN, BPNN, CNN, and LSTM, were then used to construct prediction models. The input parameters in the model included the fly ash (FA) dosage, dosage and length of the PET fiber, and the Curing Time. Results revealed that the LSTM model had the best performance in predicting the three ductile properties (i.e., the compressive strength index [UCS], strain energy index [CSE], and tensile strength index [TES]). The SHAP and 2D-PDP methods were further used to verify the rationality of the LSTM model. It is found that the Curing Time was the most important factor for the strength and ductile behavior. The appropriate addition of PET fiber of a certain length had a positive impact on the ductility index. Thus, for the OPG-stabilized soil, the optimal dosage and length of PET fiber were found to be 1.5% and 9 mm, respectively. Additionally, there was a synergistic effect between FA and PET on the ductility metric. This research provides theoretical support for the application of geopolymer and PET fiber in enhancing the ductility of the stabilized soil. Full article
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15 pages, 4613 KiB  
Article
Utilizing Cob–Earth and Sand-Filled Plastic Bottles to Address Environmental Challenges: A Sustainable Construction Solution
by Mayar Khairy, Zeinab Ahmed, Ahmed Abodonya, Omar Ahmed El Kadi, Khaled Tarabieh, Khaled Nassar and Ezzeldin Yazeed Sayed-Ahmed
Sustainability 2025, 17(15), 6784; https://doi.org/10.3390/su17156784 - 25 Jul 2025
Viewed by 365
Abstract
The construction industry is a major contributor to global carbon emissions, primarily due to its reliance on cement-based materials. Simultaneously, plastic bottle waste presents a significant environmental challenge. This study aims to address both issues by exploring the integration of plastic bottle waste [...] Read more.
The construction industry is a major contributor to global carbon emissions, primarily due to its reliance on cement-based materials. Simultaneously, plastic bottle waste presents a significant environmental challenge. This study aims to address both issues by exploring the integration of plastic bottle waste into cob–earth materials as a sustainable alternative to traditional concrete modules. The research involves testing various mixes with plastic bottles arranged in different patterns to assess their load-bearing capacity and distribution. The cob mix with bottles arranged in a modified pattern demonstrated the highest load resistance, bearing over 47.1 kN, making it suitable for prototype development. The study also investigates the potential of using cob as an exterior finishing layer, reducing the need for cement. The results show that using local earth materials significantly lowers embodied carbon, offering a more sustainable construction solution. This approach helps mitigate plastic waste and supports climate resilience by promoting low-carbon, locally sourced materials, aligning with Egypt’s national sustainability commitments. Full article
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37 pages, 3799 KiB  
Systematic Review
Improvement of Expansive Soils: A Review Focused on Applying Innovative and Sustainable Techniques in the Ecuadorian Coastal Soils
by Mariela Macías-Párraga, Francisco J. Torrijo Echarri, Olegario Alonso-Pandavenes and Julio Garzón-Roca
Appl. Sci. 2025, 15(15), 8184; https://doi.org/10.3390/app15158184 - 23 Jul 2025
Viewed by 219
Abstract
Traditional stabilization techniques, such as lime and cement, widely used for their effectiveness, albeit with economic and environmental limitations, are leading to the search for sustainable approaches that utilize agricultural and industrial waste, such as rice husk ash, bagasse, and natural fibers. These [...] Read more.
Traditional stabilization techniques, such as lime and cement, widely used for their effectiveness, albeit with economic and environmental limitations, are leading to the search for sustainable approaches that utilize agricultural and industrial waste, such as rice husk ash, bagasse, and natural fibers. These have been shown to improve key geotechnical properties, even under saturated conditions, significantly. In particular, the combination of rice husk ash and recycled ceramics has shown notable results in Ecuadorian coastal soils. The article emphasizes the importance of selecting techniques that balance effectiveness, cost, and sustainability and identifies existing limitations, such as the lack of long-term data (ten years) and predictive models adapted to the Ecuadorian climate. From a bibliographic perspective, this article analyzes the challenges posed by expansive soils in the western coastal region of Ecuador, whose high plasticity and instability to moisture negatively affect civil works such as roads and buildings. The Ecuadorian clay contained 30% kaolinite and only 1.73% CaO, limiting its chemical reactivity compared to soils such as Saudi Arabia, which contained 34.7% montmorillonite and 9.31% CaO. Natural fibers such as jute, with 85% cellulose, improved the soil’s mechanical strength, increasing the UCS by up to 130%. Rice husk ash (97.69% SiO2) and sugarcane bagasse improved the CBR by 90%, highlighting their potential as sustainable stabilizers. All of this is contextualized within Ecuador’s geoenvironmental conditions, which are influenced by climatic phenomena such as El Niño and La Niña, as well as global warming. Finally, it is proposed to promote multidisciplinary research that fosters more efficient and environmentally responsible solutions for stabilizing expansive soils. Full article
(This article belongs to the Section Civil Engineering)
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24 pages, 6323 KiB  
Article
Study on Creep Characteristics of High-Volume Fly Ash-Cement Backfill Considering Initial Damage
by Shuokang Wang, Jingjing Yan, Zihui Dong, Hua Guo, Yuanzhong Yang and Naseer Muhammad Khan
Minerals 2025, 15(7), 759; https://doi.org/10.3390/min15070759 - 19 Jul 2025
Viewed by 343
Abstract
To reveal the long-term deformation behavior of high-volume fly ash-based backfill under continuous mining and backfilling, a fly ash–cement backfill material with 73.0% fly ash content was developed, and creep characteristic tests considering initial damage were conducted. The results demonstrate that: (1) A [...] Read more.
To reveal the long-term deformation behavior of high-volume fly ash-based backfill under continuous mining and backfilling, a fly ash–cement backfill material with 73.0% fly ash content was developed, and creep characteristic tests considering initial damage were conducted. The results demonstrate that: (1) A calculation method for the initial damage of backfill based on stress–strain hysteresis loop cycles is proposed, with cumulative characteristics of initial damage across mining phases analyzed; (2) Creep behaviors of backfill affected by initial damage are investigated, revealing the weakening effect of initial damage on long-term bearing capacity; (3) An enhanced, nonlinear plastic damage element is developed, enabling the construction of an HKBN constitutive model capable of characterizing the complete creep behavior of backfill materials. The research establishes a theoretical framework for engineering applications of backfill materials with early-age strength below 5 MPa, while significantly enhancing the utilization efficiency of coal-based solid wastes. Full article
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16 pages, 2469 KiB  
Article
Application of Gelatin for Sustainable Stabilization of Low-Compressible Silt–Clay Mixtures: Geotechnical Behavior and Carbon Emission Considerations
by Evangelin Ramani Sujatha, Veera Ragavan Pratheeba, Jair De Jesus Arrieta Baldovino and Yamid E. Nunez de la Rosa
Polymers 2025, 17(14), 1954; https://doi.org/10.3390/polym17141954 - 17 Jul 2025
Viewed by 290
Abstract
Biopolymers, owing to their environmentally friendly and sustainable characteristics, have become a promising alternative for soil stabilization in geotechnical engineering. The application of protein-based biopolymers as binders for soil stabilization is less prevalent in geotechnical engineering compared to polysaccharide-based biopolymers. This study explores [...] Read more.
Biopolymers, owing to their environmentally friendly and sustainable characteristics, have become a promising alternative for soil stabilization in geotechnical engineering. The application of protein-based biopolymers as binders for soil stabilization is less prevalent in geotechnical engineering compared to polysaccharide-based biopolymers. This study explores the potential of gelatin, a protein-based biopolymer derived from animal collagen, for stabilizing silty sand and improving its geotechnical properties. Gelatin was mixed into the soil at concentrations ranging from 0.25% to 2% of the dry weight of soil, and its effects on various soil characteristics were evaluated. The tests conducted include liquid limit, plastic limit, compaction behavior, and unconfined compressive strength (UCS); the addition of 1% gelatin led to an approximate 1.69 times increase in the strength of the unamended soil. After 28 days of curing, the UCS improved by approximately 5.03 times compared to the untreated soil, and the treated soil exhibited increased resistance to deformation under load. Microstructural analysis using scanning electron microscopy (SEM) revealed that gelatin facilitated the formation of a cohesive matrix, enhancing particle bonding and reducing void spaces within the soil. Carbon footprint analysis (CFA) conducted on an isolated footing stabilized with gelatin showed that the carbon emissions were reduced by 99.8% and 99% compared to traditional stabilizers such as lime and cement. Additionally, the interaction between the biopolymer and the fine-grained soil is distinctly evident in the FTIR and XRD analysis through hydrogen bonding and the formation of cementitious compounds. Full article
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18 pages, 2154 KiB  
Article
Performance Limits of Hydraulic-Binder Stabilization for Dredged Sediments: Comparative Case Studies
by Abdeljalil Zri, Nor-Edine Abriak, Amine el Mahdi Safhi, Shima Pilehvar and Mahdi Kioumarsi
Buildings 2025, 15(14), 2484; https://doi.org/10.3390/buildings15142484 - 15 Jul 2025
Viewed by 381
Abstract
Maintenance dredging produces large volumes of fine sediments that are commonly discarded, despite increasing pressure for beneficial reuse. Lime–cement stabilization offers one pathway, yet field performance is highly variable. This study juxtaposes two French marine dredged sediments—DS-F (low plasticity, organic matter (OM) ≈ [...] Read more.
Maintenance dredging produces large volumes of fine sediments that are commonly discarded, despite increasing pressure for beneficial reuse. Lime–cement stabilization offers one pathway, yet field performance is highly variable. This study juxtaposes two French marine dredged sediments—DS-F (low plasticity, organic matter (OM) ≈ 2 wt.%) and DS-M (high plasticity, OM ≈ 18 wt.%)—treated with practical hydraulic road binder (HRB) dosages. This is the first French study that directly contrasts two different DS types under identical HRB treatment and proposes practical boundary thresholds. Physical indexes (particle size, methylene-blue value, Atterberg limits, OM) were measured; mixtures were compacted (Modified Proctor) and tested for immediate bearing index (IBI). IBI, unconfined compressive strength, indirect tensile strength, and elastic modulus were determined. DS-F reached IBI ≈ 90–125%, UCS ≈ 4.7–5.9 MPa, and ITS ≈ 0.40–0.47 MPa with only 6–8 wt.% HRB, satisfying LCPC-SETRA class S2–S3 requirements for road subgrades. DS-M never exceeded IBI ≈ 8%, despite 3 wt.% lime + 6 wt.% cement. A decision matrix distilled from these cases and recent literature shows that successful stabilization requires MBV < 3 g/100 g, plastic index < 25%, OM < 7 wt.%, and fine particles < 35%. These thresholds permit rapid screening of dredged lots before costly treatment. Highlighting both positive and negative evidence clarifies the realistic performance envelope of soil–cement reuse and supports circular-economy management of DS. Full article
(This article belongs to the Collection Advanced Concrete Materials in Construction)
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24 pages, 2179 KiB  
Article
Time-Dependent Rheological Behavior and MPS Simulation of Cement–Bentonite Slurries with Hydration Accelerators for Borehole Backfilling Applications
by Shinya Inazumi, Kazuhiko Tazuke and Seiya Kashima
J. Compos. Sci. 2025, 9(7), 361; https://doi.org/10.3390/jcs9070361 - 10 Jul 2025
Viewed by 563
Abstract
This study investigates cement–bentonite slurries with hydration accelerators for borehole backfilling applications in infrastructure reconstruction projects. Two formulations with different accelerator dosages (5 and 10 kg/m3) were evaluated through combined experimental testing and Moving Particle Semi-implicit (MPS) numerical modeling to optimize [...] Read more.
This study investigates cement–bentonite slurries with hydration accelerators for borehole backfilling applications in infrastructure reconstruction projects. Two formulations with different accelerator dosages (5 and 10 kg/m3) were evaluated through combined experimental testing and Moving Particle Semi-implicit (MPS) numerical modeling to optimize material performance. The research focuses on time-dependent rheological evolution and its impact on construction performance, particularly bleeding resistance and workability retention. Experimental flow tests revealed that both formulations maintained similar initial flowability (240–245 mm spread diameter), but the higher accelerator dosage resulted in 33% flow reduction after 60 min compared to 12% for the lower dosage. Bleeding tests demonstrated significant improvement in phase stability, with bleeding rates reduced from 2.5% to 1.5% when accelerator content was doubled. The MPS framework successfully reproduced experimental behavior with prediction accuracies within 3%, enabling quantitative analysis of time-dependent rheological parameters through inverse analysis. The study revealed that yield stress evolution governs both flow characteristics and bleeding resistance, with increases several hundred percent over 60 min while plastic viscosity remained relatively constant. Critically, simulations incorporating time-dependent viscosity changes accurately predicted bleeding behavior, while constant-viscosity models overestimated bleeding rates by 60–130%. The higher accelerator formulation (10 kg/m3) provided an optimal balance between initial workability and long-term stability for typical borehole backfilling operations. This integrated experimental–numerical approach provides practical insights for material optimization in infrastructure reconstruction projects, particularly relevant for aging infrastructure requiring proper foundation treatment. The methodology offers construction practitioners a robust framework for material selection and performance prediction in borehole backfilling applications, contributing to improved construction quality and reduced project risks. Full article
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21 pages, 15772 KiB  
Article
Impact of Inorganic Salts on Rheology, Strength, and Microstructure of Excess-Sulfate Phosphogypsum Slag Cement
by Zhe Chen, Zixin Xue, Yong Xia, Chunli Wu, Junming Mai, Weisen Liu, Yuan Feng and Jianhe Xie
Buildings 2025, 15(13), 2348; https://doi.org/10.3390/buildings15132348 - 4 Jul 2025
Viewed by 266
Abstract
Excess-sulfate phosphogypsum slag cement (EPSC), offering the potential for large-scale phosphogypsum (PG) utilization, has drawn significant attention. However, its susceptibility to salt erosion in marine/saline environments remains unquantified, hindering engineering applications. This study, therefore, systematically investigates the effect of various salts (NaCl, MgCl [...] Read more.
Excess-sulfate phosphogypsum slag cement (EPSC), offering the potential for large-scale phosphogypsum (PG) utilization, has drawn significant attention. However, its susceptibility to salt erosion in marine/saline environments remains unquantified, hindering engineering applications. This study, therefore, systematically investigates the effect of various salts (NaCl, MgCl2, KCl, and Na2SO4) at different concentrations (0.5–1.5%) on the hydration mechanism and performance of EPSC using rheometry, strength tests, and microstructural characterization (XRD/SEM-EDS). The findings reveal that EPSC exhibits low initial yield stress and plastic viscosity, both of which increase over time. The addition of Na+, Cl, and SO42− ions promotes hydration and flocculent structure formation in the EPSC paste, thereby enhancing the yield stress and plastic viscosity. In contrast, Mg2+ and K+ ions inhibit the hydration reaction, although Mg2+ temporarily increases the plastic viscosity by forming Mg(OH)2 during the initial stage of the reaction. Both Na2SO4 and NaCl improve mechanical properties when their concentrations are within the 0.5–1.0% range; however, excessive amounts (>1%) negatively impact these properties. Significantly, adding 0.5% NaCl significantly improves the mechanical properties of EPSC, achieving a 28-day compressive strength of 51.06 MPa—a 9.5% increase compared to the control group. XRD and SEM-EDX analyses reveal that NaCl enhances pore structure via Friedel’s salt formation, while Na2SO4 promotes the early nucleation of ettringite. However, excessive ettringite formation in the later stages of the hydration reaction due to Na2SO4 may negatively affect compressive strength due to the inherent abundance of SO42− in the EPSC system. Therefore, attention should be paid to the effect of excessive SO42− on the system. These results establish salt-type/dosage thresholds for EPSC design, enabling its rational use in coastal infrastructure where salt resistance is critical. Full article
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21 pages, 6305 KiB  
Article
Use of BOIvy Optimization Algorithm-Based Machine Learning Models in Predicting the Compressive Strength of Bentonite Plastic Concrete
by Shuai Huang, Chuanqi Li, Jian Zhou, Xiancheng Mei and Jiamin Zhang
Materials 2025, 18(13), 3123; https://doi.org/10.3390/ma18133123 - 1 Jul 2025
Viewed by 277
Abstract
The combination of bentonite and conventional plastic concrete is an effective method for projecting structures and adsorbing heavy metals. Determining the compressive strength (CS) is a crucial step in the design of bentonite plastic concrete (BPC). Traditional experimental analyses are resource-intensive, time-consuming, and [...] Read more.
The combination of bentonite and conventional plastic concrete is an effective method for projecting structures and adsorbing heavy metals. Determining the compressive strength (CS) is a crucial step in the design of bentonite plastic concrete (BPC). Traditional experimental analyses are resource-intensive, time-consuming, and prone to high uncertainties. To address these challenges, several machine learning (ML) models, including support vector regression (SVR), artificial neural network (ANN), and random forest (RF), are generated to forecast the CS of BPC materials. To improve the prediction accuracy, a meta-heuristic optimization, called the Ivy algorithm, is integrated with Bayesian optimization (BOIvy) to optimize the ML models. Several statistical indices, including the coefficient of determination (R2), root mean square error (RMSE), prediction accuracy (U1), prediction quality (U2), and variance accounted for (VAF), are adopted to evaluate the predictive performance of all models. Additionally, Shapley additive explanation (SHAP) and sensitivity analysis are conducted to enhance model interpretability. The results indicate that the best model is the BOIvy-ANN model, which achieves the optimal indices during the testing. Moreover, water, curing time, and cement are found to be more influential on the prediction of the CS of BPC than other features. This paper provides a strong example of applying artificial intelligence (AI) techniques to estimate the performance of BPC materials. Full article
(This article belongs to the Section Construction and Building Materials)
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21 pages, 3185 KiB  
Article
Sustainable Use of Gypsum Waste for Applications in Soil–Cement Bricks: Mechanical, Environmental, and Durability Performance
by Elvia Soraya Santos Nascimento, Herbet Alves de Oliveira, Cochiran Pereira dos Santos, Maria de Andrade Gomes, Mário Ernesto Giroldo Valerio and Zélia Soares Macedo
Ceramics 2025, 8(3), 83; https://doi.org/10.3390/ceramics8030083 - 1 Jul 2025
Viewed by 480
Abstract
This study investigates the use of gypsum waste from civil construction as a partial substitute for cement in soil–cement formulations, aiming to produce eco-friendly bricks aligned with circular economy principles. Formulations were prepared using a 1:8 cement–soil ratio, with gypsum replacing cement in [...] Read more.
This study investigates the use of gypsum waste from civil construction as a partial substitute for cement in soil–cement formulations, aiming to produce eco-friendly bricks aligned with circular economy principles. Formulations were prepared using a 1:8 cement–soil ratio, with gypsum replacing cement in proportions ranging from 5% to 40%. The raw materials were characterized in terms of chemical composition, crystalline phases, plasticity, and thermal behavior. Specimens, molded by uniaxial pressing into cylindrical bodies and cured for either 7 or 28 days, were evaluated for compressive strength, water absorption, durability, and microstructure. Water absorption remained below 20% in all samples, with an average value of 16.20%. Compressive strength after 7 days exhibited a slight reduction with increasing gypsum content, ranging from 16.36 MPa (standard formulation) to 13.74 MPa (40% gypsum), all meeting the quality standards. After 28 days of curing, the formulation containing 10% gypsum achieved the highest compressive strength (26.7 MPa), surpassing the reference sample (25.2 MPa). Mass loss during wetting–drying cycles remained within acceptable limits for formulations incorporating up to 20% gypsum. Notably, samples with 5% and 10% gypsum demonstrated superior mechanical performance, while the 20% formulation showed performance comparable to the standard formulation. These findings indicate that replacing up to 20% of cement with gypsum waste is a technically and environmentally viable approach, supporting sustainable development, circular economy, and reduction of construction-related environmental impacts. Full article
(This article belongs to the Special Issue Ceramics in the Circular Economy for a Sustainable World)
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24 pages, 18983 KiB  
Article
Multi-Factor Analysis and Graded Remediation Strategy for Goaf Stability in Underground Metal Mines: Fluid–Solid Coupling Simulation and Genetic Algorithm-Based Optimization Approach
by Xuzhao Yuan, Xiaoquan Li, Xuefeng Li, Tianlong Su, Han Du and Danhua Zhu
Symmetry 2025, 17(7), 1024; https://doi.org/10.3390/sym17071024 - 30 Jun 2025
Viewed by 283
Abstract
To ensure the green, safe, and efficient extraction of mineral resources and promote sustainability, the stability of mined-out areas has become a critical factor affecting safe production and ecological restoration in underground metal mines. The instability of underground goafs poses a significant threat [...] Read more.
To ensure the green, safe, and efficient extraction of mineral resources and promote sustainability, the stability of mined-out areas has become a critical factor affecting safe production and ecological restoration in underground metal mines. The instability of underground goafs poses a significant threat to mine safety, especially when irregular excavation patterns interact with high ground stress, exacerbating instability risks. Most existing studies lack a systematic and multidisciplinary integrated framework for comprehensive evaluation and management. This paper proposes a trinity research system of “assessment–optimization–governance”, integrating theoretical analysis, three-dimensional fluid–solid coupling numerical simulation, and a filling sequence optimization method based on genetic algorithms. An analysis of data measured from 243 pillars and 49 goafs indicates that approximately 20–30% of the pillars have a factor of safety (FoS) below 1.0, signaling immediate instability risks; additionally, 58% do not meet the threshold for long-term stability (FoS ≥ 1.5). Statistical and spatial analyses highlight that pillar width-to-height ratio (W/H) and cross-sectional area significantly influence stability; when W/H exceeds 1.5, FoS typically surpasses 2.0. Numerical simulations reveal pore water pressures of 1.4–1.8 MPa in deeper goafs, substantially reducing effective stress and accelerating plastic zone expansion. Stability classification categorizes the 49 goafs into 7 “poor”, 37 “moderate”, and 5 “good” zones. A genetic algorithm-optimized filling sequence prioritizes high-risk area remediation, reducing maximum principal stress by 60.96% and pore pressure by 28.6%. Cemented waste rock filling applied in high-risk areas, complemented by general waste rock filling in moderate-risk areas, significantly enhances overall stability. This integrated method provides a scientific foundation for stability assessment and dynamic remediation planning under complex hydrogeological conditions, offering a risk-informed and scenario-specific application of existing tools that improves engineering applicability. Full article
(This article belongs to the Section Mathematics)
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