Search Results (313)

Quercus suber bark, known as cork, is an important fire-adaptive trait of this Mediterranean species. However, the increased frequency of wildfires and poor forest management practices can be significant challenges in managing the sustainable exploitation of cork oak stands. This study evaluates cork’s thermal behavior and organoleptic quality for commercial applications under three experimental fire scenarios: prescribed burn, low-intensity wildfire, and high-intensity wildfire. Bench-scale tests were conducted using a vertical mass loss calorimeter to simulate heat exposure levels, measuring temperature changes at four cork depths and quantifying heat-induced damage. Morphological traits—cork thickness, corkback thickness, and relative humidity—were recorded as predictor variables. Additionally, organoleptic and aromatic analyses were performed to assess the suitability of fire-exposed cork for wine stopper production. Results were consistent with the available literature, confirming that cork thickness significantly reduces the maximum temperature at the phellogen level. Specifically, mean cork thickness showed a significant negative effect on Tmax4 (β = −0.02, p < 0.001), indicating a consistent decrease in internal temperatures with increasing thickness across all heat flux levels. By contrast, cork consumption (mass loss) was primarily driven by heat flux intensity rather than cork structural traits. Aromatic profiling and organoleptic analysis revealed the presence of smoke-related compounds in cork samples exhibiting external carbonization. This effect was observed under higher heat flux exposure (particularly at 25 and 50 kW m⁻²), where visible charring occurred. Under these conditions, commercial quality may be partially compromised, whereas samples without external carbonization did not show comparable aromatic alteration. Further field validation is recommended. Full article

The determination of the arc rating of arc-resistant materials for the manufacture of personal protective clothing is conducted by measuring the incident and transmitted energies through calorimetry using thermocouples coupled to copper discs during the electric arc events. In this study, custom calorimeters were constructed by incorporating both a thermocouple wire and an embedded optical-fiber temperature sensor, and the arc ratings of different fabrics were determined in terms of their arc-thermal-performance value (ATPV). The results revealed differences between the measurements obtained with the two sensor types. Notably, the absence of electromagnetic interferences generated by the arc current and the enhanced time response achieved with the optical-fiber temperature sensor signal led to an ATPV arc rating approximately 27% lower than that measured with the thermocouple. These findings underscore the importance of investigating the current methodology used for determining arc ratings to ensure accurate measurement of incident and transmitted energy. Full article

The building-integrated photovoltaic (BIPV) system has advantages in construction and energy, but due to the use of flammable polymer packaging materials, it introduces complex fire safety-related challenges. Although polymer backboards are traditionally considered to be the main combustible components in photovoltaic modules, recent studies have shown that ethylene–vinyl acetate (EVA) packaging materials play a key role in the development of fires. This study investigated the fire behavior, optical properties and system-level fire effects of montmorillonite (MMT) nano-clay-modified EVA packaging materials. Through the 50 kW/m² conical calorimeter test, optical transmittance measurement and the accelerated aging test, pure EVA and EVA containing 3% MMT were evaluated, and the measured fire parameters were further incorporated into the simplified BIPV cavity fire model. The results show that MMT modification reduces the peak heat release rate of EVA by about 30%, delays the ignition time, and increases the formation of carbides, while maintaining the optical transmittance of more than 88%. At the system level, the reduction in heat release leads to a decrease in the cavity temperature and delays the ignition of adjacent insulation materials. These findings establish a direct link between material-level fire behavior and the fire performance of BIPV systems, indicating that nano-clay-modified EVA is a feasible strategy that can improve the fire safety of BIPV systems integrated into the facade without compromising optical or durability requirements. Full article

Heat is a crucial factor in all biological processes; therefore, measuring heat change can be a powerful tool for monitoring bioprocesses and metabolism, analyzing biomolecular interactions, and studying cells. The insights gained from thermal measurements can also aid healthcare applications, such as drug susceptibility testing and disease diagnosis. Calorimetry, the science of measuring heat, has seen many advances. However, the pressing need for miniaturization, combined with breakthroughs in micro- and nanofabrication, has led to the development of chip calorimeters and accelerated their innovation. In this comprehensive review, we discuss significant advances in chip calorimetry, including figures of merit, various applications, and key challenges. The review offers an overview of the current state of the art, highlighting prospects and opportunities. Full article

This study develops a kinetic model that captures poly-ether-ether-ketone (PEEK) crystallization over a temperature $T$ window from glass transition ($T_g$) to melting ($T_m$) temperature, and across cooling rates from 5 to ~10³ °C/min. The framework is a parallel dual-Nakamura formulation whose isokinetic parameters {$k_i\left(T\right),n_i,w_i\left(T\right)$} are obtained from a bi-level non-linear regression of isothermal crystallization tests conducted using a flash-differential scanning calorimeter (FSC). The weight $w_i\left(T\right)$ partitions the faster primary and slower secondary crystallization and is represented by a physics-based analytical function that captures its dome-shaped temperature dependence. A maximum isothermally achievable enthalpy function is introduced so that the model predicts enthalpy $\Delta H\left(t\right)$ natively under arbitrary thermal profiles. To extend this isothermal backbone to non-isothermal conditions, two explicit cooling-rate-dependent scalars are introduced, $\omega \left(\dot{T}\right)$ and $\chi \left(\dot{T}\right)$, which shift $w_i\left(T\right)$ and limit attainable crystallinity at high cooling rates respectively. Finally, a rate-dependent induction time relation is added to adjust the onset of crystallization. Calibrating these rate functions against non-isothermal experiments, while keeping the isokinetic parameters fixed, yields a single isothermal–non-isothermal model that predicts $\Delta H\left(t\right)$ under arbitrary $T\left(t\right)$ profiles. Model performance is validated using an interrupted FSC experiment with a multi-segment cooling program that mimics a local transient thermal history of PEEK during additive manufacturing. The sample is cooled through successive constant-rate segments with intermittent quench–remelt cycles to probe the accumulated crystallinity along the path. Without additional fitting, the model predicts the measured enthalpy evolution with R² ≈ 0.95. The framework thus provides a practical route for predicting polymer crystallinity under processing-relevant thermal histories. Full article

The NA64 experiment at the CERN H4 beamline recently started a high-energy positron-beam program to search for light dark matter particles through a thick-target, missing-energy measurement. To fulfill the energy resolution requirement of the physics measurement ${\sigma }_E/E\simeq 2.5\%/\sqrt{E\left[\mathrm{GeV}\right]}\oplus 0.5\%$ and cope with the constraints and performance requests of the NA64 setup, a new high-resolution homogeneous electromagnetic calorimeter PKR-CAL has been designed. The detector is based on PbWO₄ crystals, each read by multiple SiPM sensors to maximize the light collection. The PKR-CAL design has been optimized to mitigate and control unavoidable SiPM saturation effects at high light levels, as well as to minimize the gain fluctuations induced by instantaneous variations of the H4 beam intensity. The R&D program culminated in the construction of a small-scale prototype, POKERINO. In this work, we present the results from the experimental characterization campaign of the POKERINO, aiming at demonstrating that the obtained performances are compatible with the application requirements. Full article

The relaxation calorimeter option in the commercial Physical Property Measurement System (PPMS) has become widely used. Since its introduction, the capabilities of this technique for specific heat measurements have been critically discussed, particularly to avoid misinterpretation of data near phase transitions. Traditional methods rely on cooling curves after sample excitation, where sharp latent heat contributions during heating lead to clear deviations from the fitting model. However, subtle but extended enthalpy contributions (e.g., strain release) may mask these effects, allowing both heating and cooling curves to be well fitted using the standard PPMS protocol. In this work, we develop a procedure that assumes a constant extra power supplied due to subtle enthalpy contributions, enabling consistent interpretation of both heating and cooling curves. This procedure allows: (1) correction of specific heat measurements; and (2) quantification of the enthalpy involved in the transition. The procedure is applied to a magnetic-field-induced transformation in MnCo(Fe)Ge(Si) alloys. Two samples were studied: a single-phase austenite without any field-induced transition, used as a reference, and a mixed austenite-martensite sample, in which apparent deviations in the conductance of the wires evidence the presence of the anomaly. Full article

In this work, measurements of thermal diffusivity, heat capacity and thermal expansion of 40HM (42CrMo4, 1.7225, AISI 4140) steel manufactured conventionally and via Laser Powder Bed Fusion (L-PBF) were carried out in the temperature range from room temperature (RT) to 1000 °C. Thermophysical properties were tested using specialized test stands from NETZSCH. Thermal diffusivity was studied using both the LFA 427 laser flash apparatus and the LFA 467 xenon flash apparatus. Specific heat capacity was investigated using DSC 404 F1 Pegasus differential scanning calorimeter, and thermal expansion was investigated using the DIL 402 C. Inconel 600 and A310 steel were selected as the reference materials during the thermal diffusivity test using LFA467 in the RT÷500 °C range. The conventionally manufactured 40HM steel, in the form of hot-rolled bar stock, was subjected to standard heat treatment for this steel grade—quenching followed by high-temperature tempering. The additively manufactured 40HM steel was subjected to stress-relief annealing. The results revealed no significant differences between the thermophysical properties of the L-PBF-produced samples in the out-of-plane and in-plane build orientations. Furthermore, no substantial differences were observed between the thermophysical properties of the conventionally produced material and the material manufactured using the L-PBF technique. Full article

Melamine polyphosphate (MPP) is a widely employed additive-type flame retardant for polyamide 6. Generally, a higher loading of MPP leads to improved flame retardancy of polyamide 6 composites. Nevertheless, excessive addition tends to cause problems such as flame-retardant migration, leakage, and exudation. Against this background, this work focuses on covalently grafting melamine polyphosphate onto the surface of carbon nanotubes via a facile chemical reaction, with the aim of alleviating the migration and leakage of the flame retardant in the polyamide 6 matrix. Carbon nanotubes (CNTs) were surface modified with a silane coupling agent (KH560) to obtain CNTs bearing epoxy groups (CNT-KH560). Subsequently, a ring-opening addition reaction was conducted between the CNT-KH560 and melamine polyphosphate (MPP) yielding carbon nanotubes with surface-bonded flame-retardant MPP (CNTM). Polyamide 6 composite slices (PA6/CNTM) were prepared via twin-screw extrusion blending and compounding and then by hot-press molding into test specimens. The modified carbon nanotubes were characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analysis. The results confirmed the successful grafting of MPP onto the carbon nanotube surface, with a grafting degree of 9.1 g/100 g measured. The flame retardancy of the PA6/CNTM composites were evaluated through UL 94 vertical burning and limiting oxygen index (LOI) tests and cone calorimeter. These flame retardancy results indicated that when the content of flame-retardant-modified carbon nanotubes was 10 wt%, the PA6/CNTM10 composites achieved UL 94 V-2 and the limiting oxygen index increased from 24.5% of pure PA6 to 29.1%. The PHRR value of pure PA6 decreased from 750 kW/m² to 614 kW/m². This design of surface-grafted flame retardant provides a new strategy for the preparation and application of high-performance polyamide 6 flame-retardant composites. Full article

Failure to fully backfill the goaf may result in increased exposure of roof strata, significantly raising the risk of roof collapses in mining zones and potentially causing surface subsidence, thereby endangering the safety of mining personnel. To address this issue, expansive agents are utilized to produce active roof-contact backfill (ARCB) materials, which promote localized self-compaction of backfill materials in unroof-contact areas through hydration reactions. In this study, an isothermal calorimeter was employed to measure the ARCB hydration heat release rate curves of three types of expansive agents, CaO-based, MgO-based, and ettringite-based, at dosages ranging from 6% to 12%. Hydration kinetic parameters were calculated based on the Krstulovic–Dabic model. The influence of expansive agent type and dosage on these parameters was analyzed, and the hydration mechanism of ARCB materials was investigated. The results indicate that the hydration process of grouting materials using all three expansive agents follows five distinct stages: rapid reaction, induction, acceleration, deceleration, and decay. However, increasing the dosage of the CaO-based expansive agent will enhance heat release and prolong the duration of the acceleration stage. When the dosage is 12%, the total heat release reaches 327.4 J·g⁻¹. At the same dose, the sample doped with MgO-based expansive agent was only 254.3 J·g⁻¹, which was 22.3% lower than that of CaO-based, and the occurrence time of the second heat release peak was earlier. In contrast, the ettringite-based expansive agent shows a decreasing trend in heat release with increasing dosage. Furthermore, the use of CaO-based and MgO-based expansive agents allows the hydration process to bypass the phase boundary reaction (I) stage and directly enter the diffusion (D) stage. Ettringite-based expansive agents still undergo three stages, but exhibit a shortened nucleation and growth (NG) stage and an extended induction stage. Additionally, different expansive agents have varying effects on the crystal growth index (n), reaction rate constant, and degree of hydration. Full article

The accurate simulation of sub-GeV particle detectors is essential for interpreting experimental data and optimizing detector design. This work identifies and addresses several critical aspects in modeling such detectors, taking as a case study the High-Energy Particle Detector (HEPD-02), a space-borne instrument developed within the CSES-02 mission to measure electrons in the ∼3–100 MeV range, protons and light nuclei in the ∼30–200 MeV/n. The HEPD-02 instrument consists of a silicon tracker, plastic and LYSO scintillator calorimeters, and anticoincidence systems, making it a representative example of a complex low-energy particle detector operating in Low Earth Orbit. Key challenges arise from replicating intricate detector geometries derived from CAD models, selecting appropriate hadronic physics lists for low-energy interactions, and accurately describing the detector response—particularly quenching effects in scintillators and digitization in solid-state tracking planes. Particular attention is given to three critical aspects: the precise CAD-level geometry implementation, the impact of hadronic physics models on the detector response, and the parameterization of scintillation quenching. In this study, we present original solutions to these challenges and provide data–MC comparisons using data from HEPD-02 beam tests. Full article

The characteristics of litter combustion have a significant impact on the spread of surface fires in the central Yunnan Province, a high-risk forest fire zone. The burning behavior of individual and mixed-species litter samples from five dominant tree species (Pinus yunnanensis Franch., Keteleeria evelyniana Mast., Quercus variabilis Blume., Quercus aliena var. acutiserrata, and Alnus nepalensis D. Don.) was assessed in this study using cone calorimeter tests. Fern fronds and fine branches were included in additional tests to evaluate their effects on specific combustion parameters, such as Fire Performance Index (FPI), Flame Duration (FD), Time to Ignition (TTI), Mass Loss Rate (MLR), Residual Mass Fraction (RMF), Peak Heat Release Rate (PHRR), and Total Heat Release (THR). There were remarkable differences in the burning properties of the three types of litter (broadleaf, pine needles, and short pine needles). The THR and PHRR values of P. yunnanensis were the highest, whereas the PHRR of the other species varied very little. Short pine needle litter showed incomplete combustion and a long flame duration. When measured against pure pine needle litter, mixtures of P. yunnanensis and broadleaf litter showed lower PHRR. When set side by side to pure pine needle litter, P. yunnanensis and broadleaf litter showed lower PHRR. THR rose when fine branches were included, underlining the significance of fine woody fuels in fire behavior. The insertion of ferns increases the percentage of unburned biomass, prolongs TTI, and dramatically reduces PHRR. Full article

The hadron calorimeter is a central component of the CMS detector, vital for measuring hadron energies and reconstructing missing transverse momentum. This paper reviews its performance before and after the Phase 1 upgrade (completed in 2019), which upgraded both back-end and front-end electronics, including photodetectors and charge-integrating ADC with precise-timing TDC, as well as its depth segmentation in the barrel and endcaps. This paper describes energy reconstruction algorithms that suppress out-of-time signals, along with high-precision timing alignment and multi-step energy calibration procedures to mitigate radiation damage and improve energy resolution Performance evaluations using proton–proton collision data demonstrate that the upgraded detector and reconstruction techniques achieve good resolution and robust operation under high-luminosity conditions. Full article

The study of the antimatter component in cosmic rays is essential for the understanding of their acceleration and propagation mechanisms, and is one of the most powerful tools for the indirect search of dark matter. Current methods rely on magnetic spectrometers for charge-sign discrimination, but these are not suitable for extending measurements to the TeV region within a short timeframe of a few decades. Since most of present and upcoming high-energy space experiments use large calorimeters, it is crucial to develop an alternative charge-sign discrimination technique that can be integrated with them. The Electron/Positron Space Instrument (EPSI) project, a two-year R&D initiative launched in 2023 with EU recovery funds, aims to address this challenge. The basic idea is to exploit the synchrotron radiation emitted by charged particles moving through Earth’s magnetic field. The simultaneous detection of an electron/positron with an electromagnetic calorimeter and synchrotron photons with an X-ray detector is enough to discriminate between the two particles at the event level. The main challenge is to develop an X-ray detector with a very large active area, high X-ray detection efficiency, and a low-energy detection threshold, compliant with space applications. In this paper, we give an overview of the EPSI project, with a focus on the general idea of the detection principle, the concept of the space instrument, and the design of the X-ray detector. Full article

NUSES is a pathfinder satellite that will be deployed in a low Earth orbit, designed with new technologies for space-based detectors. Ziré is one of the payloads of NUSES and aims to measure the spectra of electrons, protons, and light nuclei in a kinetic energy range spanning from a few MeVs to several hundred MeVs, as well as photons in the energy range from 0.1 MeV to 30 MeV. Ziré consists of a Fiber TracKer (FTK), a Plastic Scintillator Tower (PST), a calorimeter (CALOg), an AntiCoincidence System (ACS) and a Low Energy Module (LEM). The FTK is based on thin scintillating fibers read out by Silicon Photomultiplier (SiPM) arrays. We assembled a prototype of Ziré (Zirettino) equipped with a single FTK layer, a reduced number of PST layers and a partially instrumented CALOg. A preliminary version of the Ziré custom Front-End Board (FEB) featuring the on-the-shelf ASIC CITIROC by OMEGA/Weeroc was used for the readout. We carried out several beam test campaigns at CERN’s PS facility and a dynamic qualification test. The performance of FTK will be presented and discussed. Full article