Search Results (61)

Molybdenum alloys as refractory alloys can provide strength levels at operating temperatures higher than that of Ni-base superalloys, yet their ductility is usually inferior to Ni-base alloys. Currently, commercialized Mo alloys are much fewer than Ni alloys. The motivation of this work is to explore opportunities of discovering useful alloys from the usually less investigated binary Mo-X systems (X = alloying element). With computational thermodynamics (CALPHAD), first-principles calculation, and mechanistic modeling combined, in this work a large number of Mo-X binary systems are investigated in terms of thermodynamic features and mechanical properties (yield strength, ductility, ductile-brittle transition temperature, creep resistance, and stress-strain relationship). The applicability of the alloy systems as solution-strengthened or precipitation-strengthened alloys is investigated. Starting from 92 Mo-X systems, a down-selection process is implemented, the results of which include three candidate systems for precipitation strengthening (Mo-B, Mo-C, Mo-Si) and one system (Mo-Re) for solid-solution strengthened alloy. In a composition optimization of Mo alloys to reach the properties of Ni-base superalloys, improving ductility is of top priority, for which Re plays a unique role. The presented workflow is also applicable to other bcc refractory alloy systems. Full article

The cast nickel-based superalloy K417G exhibits excellent high-temperature strength, but non-equilibrium solidification during casting can cause defects such as irreparable interdendritic microporosity, which significantly degrades its fatigue and creep properties. This study uses hot isostatic pressing (HIP) to eliminate internal flaws such as porosity in the K417G alloy, aiming to improve its mechanical properties. We investigated the microstructure and mechanical properties of K417G under two thermal conditions: solution heat treatment (SHT) and hot isostatic pressing (HIP). The results indicate that HIP significantly reduces microporosity. Compared to SHT, HIP improves the mechanical performance of K417G. The creep fracture mechanism shifts from intergranular brittle fracture (SHT) to ductile fracture (HIP). Consequently, HIP increases the alloy′s creep life approximately threefold and raises its fatigue limit by about 20 MPa. This improvement is attributed to pore density reduction, which decreases stress concentration zones and homogenizes the microstructure, thereby impeding fatigue crack nucleation and extending the crack incubation period. Full article

To broaden clean asphalt modification methods, this study employs a composite polymer of maleic anhydride-grafted styrene-butadiene-styrene (MA-g-SBS) and styrene-butadiene-styrene (SBS) as a modifier. The composite is formulated into polymer latex and used to modify emulsified asphalt. Routine performance tests were conducted on MA-g-SBS/SBS composite latex-modified emulsified asphalt (MSMEA) with varying ratios to determine the optimal composition. The ideal ratio was found to be MA-g-SBS:SBS = 1:4. Subsequently, conventional property tests, rheological analyses, microphase structure observations, and bending beam creep tests were conducted on MSMEA with the optimal ratio to assess the impact of the composite latex on asphalt performance. Findings indicated that increasing the latex content significantly enhanced the softening point and ductility while reducing penetration. These macroscopic improvements were notably superior to those achieved with single SBS latex modification. Fluorescence microscopy revealed that at low dosages, the MA-g-SBS/SBS composite dispersed uniformly as point-like structures within the asphalt. At higher dosages (above 5%), a distinct network structure emerged. The addition of the composite latex raised the complex shear modulus and rutting factor while reducing the phase angle, with pronounced fluctuations observed between 4% and 5% dosages. This suggests a substantial enhancement in the high-temperature performance of the emulsified asphalt, attributed to the formation of the network structure. FT-IR results confirmed that a chemical reaction occurred during the modification process. Additionally, the bending beam creep test demonstrated that the composite latex reduced asphalt brittleness and improved its low-temperature performance. Full article

Fire safety design for steel beams is crucial in the construction of steel structures. However, there remains a significant gap in the fire resistance testing of insulated steel beams. This study focuses on full-scale experimental research examining the fire resistance performance of steel beams with varying fire protection methods, cross-sectional dimensions, and heating curves. During the tests, the furnace temperature, specimen temperature, and deflection at mid-span were measured. The test results indicated that specimens mainly failed in lateral–torsional buckling. Additionally, a markedly non-uniform temperature distribution was observed across the cross-section, and the predictions made by GB 51249-2017 were found to be unsafe. The use of fiber cement board for fire protection may be ineffective, as it tends to become brittle at elevated temperatures, making it susceptible to breakage and detachment when the beams begin to bend. Furthermore, due to potential creep deformation, specimens subjected to longer heating durations exhibited lower critical temperatures compared to those with shorter heating durations. Finally, the design method outlined in BS EN 1993-1-2 and ANSI/AISC 360-22 was evaluated against the test results, indicating an accurate prediction of these methods for specimens with shorter heating durations, but an unconservative prediction for specimens with longer heating durations due to ignorance of creep deformation. Full article

With the further implementation and development of the Western Development Strategy, studying the mechanical behavior and deformation characteristics of deep-buried tunnels in layered hard rock under high ground stress conditions holds considerable engineering significance. To study the mechanical properties and long-term deformation and failure characteristics of different bedding stratified rocks, this research employed an MTS815 electro-hydraulic servo rock testing system and a French TOP rheometer. Triaxial compression tests, rheological property tests, and long-term cyclic and unloading tests were conducted on shale samples under varying confining pressures and bedding angles. The results indicate that (1) under triaxial compression, shale demonstrates pronounced anisotropic behavior. When the confining pressure is constant, the peak strength of the rock sample exhibits a “U”-shaped variation with the bedding angle (its minimum value at 60°). For a fixed bedding angle, the peak strength of the rock sample progressively increases as the confining pressure rises. (2) The mode of shale failure varies with the angle: at 0°, shale exhibits conjugate shear failure; at 30°, shear slip failure along the bedding is controlled by the bedding weak plane; at 60° and 90°, failure occurs through the bedding. (3) During the creep process of layered shale, brittle failure characteristics are evident, with microcracks within the sample gradually failing at stress concentration points. The decelerated and stable creep stages are prominent; while the accelerated creep stage is less noticeable, the creep rate increases with increasing stress level. (4) Under low confining pressure, the peak strength during cyclic loading and unloading creep processes is lower than that of conventional triaxial tests when the bedding plane dip angles are 0° and 30°, which is the opposite at 60° and 90°. (5) In the cyclic loading and unloading process, Poisson’s ratio gradually increases, whereas the elastic modulus, shear modulus, and bulk modulus gradually decrease. Full article

This article evaluates the possibility of replacing creep-resistant magnesium Mg-Zn-RE-Zr alloys (EZ33) with Mg-Al-Ca-Sr alloys. (1) Background: Mg alloys with RE metals show excellent properties. Due to their high cost, new, more economical Mg alloys are being developed. Replacing RE metals with cheaper elements such as Al and Ca allows us to obtain high mechanical properties at elevated temperatures due to the tendency to form stable intermetallic phases. (2) Methods: Microstructure analysis (LM, SEM, TEM, and XRD) was performed and mechanical properties were tested at ambient and elevated temperatures. (3) Results: Increasing the Ca content and decreasing the Al content leads to the formation of a continuous skeleton of high-melting and brittle Ca-rich Laves phases and Sr-rich intermetallic phases and the formation of plate-like precipitates of the C15 phase inside the α-Mg solid solution. The crystallographic orientation of plate-like precipitates contributes to the blocking of dislocations in slip systems activated at elevated temperatures. Increasing the Ca and Sr content allows for the regulation of the Al concentration in the α-Mg, providing solution strengthening and stability of the α-Mg solid solution. These factors contribute to a significant improvement in creep resistance of Mg-Al-Ca-Sr alloys. (4) Conclusions: The strength properties and elongation at ambient temperature of the Mg alloys with Ca and Sr addition are comparable to those of the EZ33 alloy, and due to the presence of lighter alloying elements, a better specific strength is achieved. Ca-rich Mg-Al-Ca-Sr alloys exhibit better creep resistance at temperatures of up to 200 °C compared to the EZ33 alloy. Full article

Technological issues with the production of gluten-free rice crackers with spirulina powder were examined in this work through their rheological, textural, color, sensory, and nutritional aspects. A part of gluten-free whole-grain rice flour was replaced with 5, 10, and 15% spirulina powder in an appropriate recipe for crackers. The rheological analysis presented obtained dough samples as viscoelastic systems with dominant elastic components (G′ > G″ and Tan δ = G″/G′ is less than 0). The addition of spirulina contributed to a softer dough consistency according to a statistically significant (p < 0.5) decrease of Newtonian viscosity during the creep phase for a maximum of 43.37%, compared to the control dough. The 10 and 15% quantities of spirulina powder led to a statistically significant (p < 0.5) increase in the viscoelastic parameter J_max, which indicated a greater dough adaptability to stress. The textural determination of the dough pointed statistically significantly (p < 0.05) to decreased dough hardness and improved dough extensibility and confirmed all rheological measurements with high correlation coefficients, indicating good physical dough properties during processing. Spirulina certainly affected the change in the color of the dough from a yellow-white to intense green, which also had a significant impact on the sensory quality of the baked crackers. Many sensory properties of the crackers were improved by the addition of and increasing amounts of spirulina (appearance, brittleness, hardness, graininess, and stickiness). The results for the dough and for the final crackers pointed to very good technological aspects for the development of a gluten-free bakery product with high nutritional value, such as increased polyphenolic content (with the majority of catechins), protein, total dietary fibers, and mineral content compared to the control sample. Full article

The TNM alloy, a β_o-phase-containing TiAl alloy, has been withdrawn from use as a last-stage turbine blade in commercial jet engines as it suffered frequent impact fractures in service, raising doubts regarding the necessity of the β_o-phase in practical TiAl alloys. Here, we evaluate the practical properties required for jet engine blades for various TiAl alloys and investigate the effects of the β_o-phase thereupon. First, we explore the influence of the β_o-phase content on the impact resistance and machinability for forged Ti–43.5Al–xCr and cast Ti–46.0Al–xCr alloys; the properties deteriorate significantly at increasing β_o-phase contents. Subsequently, two practical TiAl alloys—TNM alloy and TiAl4822—were prepared with and without the β_o-phase by varying the heat treatment temperature for the former and the Cr concentration for the latter. In addition to impact resistance and machinability, the creep strength is significantly reduced by the presence of the β_o-phase. Overall, these findings suggest that the β_o-phase is an undesirable phase in practical TiAl alloys, especially those used for jet engine blades, because, although the disordered β-phase is soft at high temperatures, it changes to significantly more brittle and harder β_o-phase after cooling. Full article

In this study, a masonry panel under a high compressive stress to strength ratio is considered. The panel is modeled as a composite structure by considering a repeated unit cell of mortar and brick. Load redistributions due to creep in mortar and brick as composite materials are accounted for. A step-by-step in-time analysis is performed to calculate the load redistribution in the composite masonry. Time-dependent system reliability analysis of the masonry panel is performed by defining the component and system limit state functions at each time step. While the reliability index of ductile materials depends on the load level in each part of masonry, the reliability index of brittle materials depends only on the overall load. By proposing the reliability index of quasi-brittle materials being between these two reliability index bounds, the reliability index of quasi-brittle materials depends on both the load level in each part and the overall load. Using the proposed reliability index of quasi-brittle materials, partial safety factors for masonry panel design considering creep and damage are calibrated based on the Hasofer and Lind method. A design example using the proposed partial safety factor is presented. Full article

A thermodynamic constitutive damage model for plain concrete, and other quasi-brittle aging materials, under creep relaxation is developed. The model accounts for the anisotropic damage induced through a second-order tensor damage variable. The aging viscoelasticity of the material is considered through the theory of solidification for aging solidifying materials. The material is considered a viscoelastic-damageable material. The Helmholtz free energy, utilized in the formulation, is treated based on the representation theorem of coupled damage strain tensors and Volterra integral equations. The model can analyze time-dependent damage (tertiary creep) under constant loading and can account for damage due to cyclic creep. Theoretical case studies are considered to illustrate the applicability of the model. The determination of the functions and constants, representing the material behavior, as well as any experimental companion is proposed for further research. Full article

Ultramylonites are among the most extreme fault rocks that commonly occur in the mid-crustal brittle–plastic transition and are mainly characterized by intensely sheared fine-grained microstructures and well-mixed mineral phases. Although the deformation mechanism of ultramylonites is key to understanding the rheological behavior of the mid-crustal shear zone, their microstructural development is still controversial owing to their intensely fine-grained textures. To investigate the possible crustal deformation mechanisms, we studied 13 mylonites obtained from the Kashio shear zone along the Median Tectonic Line that is the largest strike-slip fault in Japan. In particular, we investigated various mixed quartz–plagioclase layers developed within tonalitic mylonite, which are representative of the common mean grain size and crystal fabric of quartz among the studied samples. A high-quality phase-orientation map obtained by electron backscattered diffraction showed not only a wide range of quartz–plagioclase mixing (10%–80% in quartz modal composition) but also revealed a correlation between grain size reduction and crystal fabric weakening in quartz, indicating a change in the deformation mechanism from dislocation creep to grain-size-sensitive creep in the mixed quartz-plagioclase layers. In contrast, plagioclase showed an almost consistent fine grain size and weak to random crystal fabrics regardless of modal composition, indicating that grain size-sensitive creep is dominant. Combined with laboratory-determined flow laws, our results show that the Kashio shear zone could have developed under deformation mechanisms in which the viscosities of quartz and plagioclase are nearly comparable, effectively within 10¹⁷–10¹⁹ Pa·s, thereby possibly enabling extensive shearing along the Median Tectonic Line. Full article

A model to rationalize the effects of test temperature and microstructural variables on the creep crack growth (CCG) and creep-fatigue crack growth (CFCG) rates in ferritic steels is described. The model predicts that as the average spacing between grain boundary particles that initiate creep cavities decrease, the CCG and CFCG rates increase. Further, the CCG data at several temperatures collapse into a single trend when a temperature compensated CCG rate derived from the model is used. The CCG and CFCG behavior measured at different temperatures is used to assess the effects of variables such as the differences between the base metal (BM), weld metal (WM), and heat-affected zone (HAZ) regions. The model is demonstrated for Grade 22 and Grade 91 steels using data from literature. It is shown that differences between the CCG behavior of the Grade 22 steel in new and ex-service conditions are negligible in the BM and WM regions but not in the HAZ region. The CCG behavior of the Grade 91 steels can be separated into creep-ductile and creep-brittle regions. The creep-brittle tendency is linked to the presence of excess trace element concentrations in the material chemistry. Significant differences found in the CCG rates between the BM, WM, and HAZ regions of the Grade 91 steel are explained. Full article

AZ91 is one of the most broadly used Mg alloys because of its good castability and reasonable mechanical properties. Strengthening AZ91 with carbon short fibers aims to increase tensile and fatigue strength, creep, and wear resistance. One of the proposed applications of reinforced AZ91 is the production of pistons for trucks. Such reciprocating parts are subjected to alternating fatigue loads which can lead to fatigue failure. In this respect, studying the tensile and fatigue behavior of materials subjected to such loading conditions is of great interest. The alternating low-cycle fatigue (LCF) and high-cycle fatigue (HCF) of unreinforced AZ91 and carbon fiber-reinforced AZ91 (AZ91-C) were investigated at 20 °C and 250 °C. Tensile tests were carried out at the same testing temperature to find the appropriate fatigue testing stress and strain for stress-controlled and strain-controlled tests, respectively. The fatigue curves of stress against the number of cycles (S–N) revealed that the composite AZ91-C’s fatigue strength was 55 MPa under HCF, while that of the matrix alloy AZ91 was only 37 MPa at 250 °C. Fracture investigations were conducted on the broken test samples. The fracture approach in the matrix material (AZ91) is mixed ductile/brittle containing fatigue serration, fiber fracture, and separation in the reinforced material (AZ91-C). Full article

This paper focused on determining the increased tendency of cracking after the die forging process of high nickel and chromium steel. The increase in carbon content in austenitic nickel–chromium steel promoted the tendency of valve forgings to forging intergranular crack on the valve head. Attention was paid to issues related to the chemical composition of the material to be considered when hot forming nickel–chromium steel components. Optical and scanning electron microscopies were used to examine the microstructure and fracture features of the samples removed from a fractured valve head. The embrittlement was due to microcavity formation at grain boundaries. Creep theory at grain boundaries was used to explain crack formation. The tensile behavior was interpreted from the evolution of the microstructure during deformation and referred to intermediate brittleness to explain the effect of carbon. It was found that the increased carbon content of the nickel–chromium steel and the strong undercooling observed at the edges of the valve head are factors that promote a reduction in grain boundary cohesion and enhance intermediate temperature embrittlement. Finally, it was found that the formation of a heterogeneous structure manifested by the presence of grain boundary M₂₃C₆-type carbides in the austenitic matrix was most likely related to the occurring brittleness. Full article

High-strength concrete (HSC) has been broadly applied to various civil structures for its advantages including high compressive strength and excellent durability and creep resistance. However, the brittleness of HSC raises concern about its use in practice. So far study on continuous reinforced HSC beams is limited. This work investigates the structural response of reinforced HSC continuous beams, and the results are compared with those of the counterparts made of normal-strength concrete (NSC). By applying a finite element method verified by experimental data, a comprehensive assessment is performed on two-span reinforced NSC and HSC (compressive strengths of 30, 60 and 90 MPa) continuous beams. A wide range of flexural reinforcement ratios are used to cover both under-reinforced and over-reinforced beams. The results show that reinforced HSC beams exhibit better flexural performance in terms of ultimate load, deformation, flexural ductility and moment redistribution, when compared to reinforced NSC beams. Formulae relating flexural ductility and moment redistribution with either neutral axis depth or tensile steel strain are suggested. Full article