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19 pages, 30180 KiB  
Article
Evaluating Distributed Hydrologic Modeling to Assess Coastal Highway Vulnerability to High Water Tables
by Bruno Jose de Oliveira Sousa, Luiz M. Morgado and Jose G. Vasconcelos
Water 2025, 17(15), 2327; https://doi.org/10.3390/w17152327 - 5 Aug 2025
Viewed by 2
Abstract
Due to increased precipitation intensity and sea-level rise, low-lying coastal roads are increasingly vulnerable to subbase saturation. Widely applied lumped hydrological approaches cannot accurately represent time and space-varying groundwater levels in some highly conductive coastal soils, calling for more sophisticated tools. This study [...] Read more.
Due to increased precipitation intensity and sea-level rise, low-lying coastal roads are increasingly vulnerable to subbase saturation. Widely applied lumped hydrological approaches cannot accurately represent time and space-varying groundwater levels in some highly conductive coastal soils, calling for more sophisticated tools. This study assesses the suitability of the Gridded Surface Subsurface Hydrologic Analysis model (GSSHA) for representing hydrological processes and groundwater dynamics in a unique coastal roadway setting in Alabama. A high-resolution model was developed to assess a 2 km road segment and was calibrated for hydraulic conductivity and aquifer bottom levels using observed groundwater level (GWL) data. The model configuration included a fixed groundwater tidal boundary representing Mobile Bay, a refined land cover classification, and an extreme precipitation event simulation representing Hurricane Sally. Results indicated good agreement between modeled and observed groundwater levels, particularly during short-duration high-intensity events, with NSE values reaching up to 0.83. However, the absence of dynamic tidal forcing limited its ability to replicate certain fine-scale groundwater fluctuations. During the Hurricane Sally simulation, over two-thirds of the segment remained saturated for over 6 h, and some locations exceeded 48 h of pavement saturation. The findings underscore the importance of incorporating shallow groundwater processes in hydrologic modeling for coastal roads. This replicable modeling framework may assist DOTs in identifying critical roadway segments to improve drainage infrastructure in order to increase resiliency. Full article
(This article belongs to the Topic Natural Hazards and Disaster Risks Reduction, 2nd Edition)
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18 pages, 4250 KiB  
Article
A Novel Carbon Fiber Composite Material for the Simulation of Damage Evolution in Thick Aquifers
by Bozhi Zhao, Xing Gao, Weibing Zhu, Jiaxing Ding and Pengjun Gao
Appl. Sci. 2025, 15(13), 7314; https://doi.org/10.3390/app15137314 - 29 Jun 2025
Viewed by 295
Abstract
Simulation experiments are a crucial method for investigating overburden failure, strata movement, and strata control during coal mining. However, traditional similar materials struggle to effectively monitor internal damage, fracturing, and dynamic development processes within the strata during mining. To address this issue, carbon [...] Read more.
Simulation experiments are a crucial method for investigating overburden failure, strata movement, and strata control during coal mining. However, traditional similar materials struggle to effectively monitor internal damage, fracturing, and dynamic development processes within the strata during mining. To address this issue, carbon fibers were introduced into the field of similar material simulation experiments for mining. Leveraging the excellent conductivity and the sensitive feedback of resistivity changes in response to damage of this composite material enabled real-time monitoring of internal damage and fracture patterns within the mining strata during similar simulation experiments, leading to the development of a carbon fiber similar simulation composite material with damage self-sensing properties. This study found that as the carbon fiber content increased, the evolution patterns of the electrical resistance change rate and the damage coefficient of the similar material tended to coincide. When the carbon fiber content in the similar material exceeded 2%, the electrical resistance change rate and the damage coefficient consistently exhibited synchronized growth with identical increments. A similar simulation experiment revealed that after the completion of workface mining, the thick sandstone aquifer did not develop significant cracks and remained stable. In the early stages of mining, damage rapidly accumulated at the bottom of the thick aquifer, approaching the failure threshold. In the middle layers, a step-like increase in the damage coefficient occurred after mining reached a certain width, while the top region was less affected by mining activities, resulting in less significant damage development. The research findings offer new experimental insights into rock layer movement and control studies, providing theoretical guidance for the prediction, early warning, and prevention of dynamic disasters in mines with thick key layers. Full article
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17 pages, 1753 KiB  
Article
Demulsification Kinetics of Water-in-Oil Emulsions of Ecuadorian Crude Oil: Influence of Temperature and Salinity
by Jordy Sarmas-Farfan, Antonio Diaz-Barrios, Teresa E. Lehmann and Vladimir Alvarado
Energies 2025, 18(12), 3115; https://doi.org/10.3390/en18123115 - 13 Jun 2025
Viewed by 374
Abstract
This work focuses on the stability analysis of water-in-oil macroemulsions with a crude oil from the Sacha Field in Ecuador. This field is an important hydrocarbon resource in Ecuador with a typical bottom freshwater drive. The comprehensive stability analysis includes coalescence, water resolution [...] Read more.
This work focuses on the stability analysis of water-in-oil macroemulsions with a crude oil from the Sacha Field in Ecuador. This field is an important hydrocarbon resource in Ecuador with a typical bottom freshwater drive. The comprehensive stability analysis includes coalescence, water resolution or phase separation, and water–oil interfacial tension and interfacial dilatational viscoelastic modulus measurements over time. Two main parameters, due to their relevance, were controlled in these experiments: water salinity and temperature. The analysis reported here is the first focused on this important resource in Ecuador. Findings shed light on which mechanisms more likely control the stability of these water-in-oil macroemulsions. Results herein suggest that regardless of temperature, low-salinity water favors emulsion stability, likely due to the tendency of a stiffer interface formation at low-ionic strength, as interfacial viscoelasticity measurements show. This implies that the low-ionic strength water from the aquifer can enable the formation of stable emulsions. In contrast, water resolution depends significantly on temperature, possibly due to higher sedimentation rates. The implication is that if emulsions do not break up before cooling off, the emulsion can become more stable. Finally, analysis of the interface buildup rates could explain the observed increase in emulsion stability over time. Full article
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14 pages, 6670 KiB  
Article
Numerical Simulation of Horizontal Barrier in Controlling Groundwater and Deformation During Foundation Pit Dewatering
by Ruonan Kuang, Changjie Xu, Chaofeng Zeng, Xiuli Xue, Youwu Zhao, Bin Li and Lijuan Yi
Water 2025, 17(12), 1763; https://doi.org/10.3390/w17121763 - 12 Jun 2025
Cited by 1 | Viewed by 410
Abstract
In water-rich strata, a traditional vertical barrier exhibits certain limitations when applied to deep foundation pit construction under complex geological conditions, such as it is difficult to completely cut off deep and thick aquifer, which may pose potential risks during pit dewatering. To [...] Read more.
In water-rich strata, a traditional vertical barrier exhibits certain limitations when applied to deep foundation pit construction under complex geological conditions, such as it is difficult to completely cut off deep and thick aquifer, which may pose potential risks during pit dewatering. To address the above challenge, this study introduced a mixed barrier system in which the horizontal barrier (HB) was set at the bottom of the foundation pit and was combined with the enclosure wall to collectively retard groundwater seepage into the pit. Based on an actual project in Tianjin, this study established HB models with varying numbers of its layers using ABAQUS 6.14 software. It systematically investigated the effect of HB on groundwater drawdown, ground surface settlement, and enclosure deflection during foundation pit dewatering. The research shows that HB can significantly reduce the magnitude of external water level drawdown by altering groundwater seepage paths while effectively controlling soil settlement. Furthermore, it exhibits favorable overall restraining effects on wall deformation. Varying the number of horizontal barrier layers (L) exhibits an insignificant effect on water-blocking and subsidence-control performance. However, the constraint effect on the enclosure shows a correlation with L. Full article
(This article belongs to the Section Hydrogeology)
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22 pages, 2798 KiB  
Article
Effects of Parameter Variations Generated by Pumping on LNAPL Migration in the Aquitard: An Analytical and Experimental Study
by Yue Su, Yong Huang, Huan Shen, Xiaosong Dong, Xiaochang Sun and Zhimin Fu
Toxics 2025, 13(6), 471; https://doi.org/10.3390/toxics13060471 - 2 Jun 2025
Viewed by 456
Abstract
The parameter variations in the aquitard have an important influence on the migration laws of contaminants in the aquitard. In order to study the influence of dynamic changes in parameters during pumping on the migration laws of Light Non-aqueous Phase Liquid (LNAPL) in [...] Read more.
The parameter variations in the aquitard have an important influence on the migration laws of contaminants in the aquitard. In order to study the influence of dynamic changes in parameters during pumping on the migration laws of Light Non-aqueous Phase Liquid (LNAPL) in the aquitard, the one-dimensional consolidation and groundwater flow equations for the aquitard were employed to derive the governing equations for the migration of LNAPL in the aquitard. A self-designed experimental platform was developed to investigate the effects of the pore water pressure, consolidation deformation, and pumping rate on LNAPL migration during pumping. The laboratory experimental results indicated that during pumping, the migration behavior of LNAPL in the aquitard typically exhibited a trend toward the pumping well and the overlying aquifer. The closer to the pumping well, the greater the change in the pore water pressure, the greater the amount of consolidation deformation, the earlier the state of densification, and the slower the migration rate of LNAPL in the aquitard. The nearer to the bottom of the aquitard, the larger the amount of consolidation deformation in the aquitard and the slower the migration rate of LNAPL in the aquitard. Also, the pumping rate had an important influence on groundwater flow movement and contaminant migration. The characteristics of parameter variations in the aquitard and laws of LNAPL migration during pumping were systematically studied and analyzed; these research results can provide a reference for the prediction and remediation of LNAPL in contaminated sites. Full article
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14 pages, 8083 KiB  
Article
Aerial Imagery and Surface Water and Ocean Topography for High-Resolution Mapping for Water Availability Assessments of Small Waterbodies on the Coast
by Cuizhen Wang, Charles Alex Pellett, Haofeng Tan and Tanner Arrington
Environments 2025, 12(5), 168; https://doi.org/10.3390/environments12050168 - 20 May 2025
Viewed by 538
Abstract
Surface water is the primary freshwater supply for Earth. Small lakes and ponds provide important ecological and economic services to society but are often left undocumented, or their documentation is outdated, due to their small sizes and temporal dynamics. This study tested the [...] Read more.
Surface water is the primary freshwater supply for Earth. Small lakes and ponds provide important ecological and economic services to society but are often left undocumented, or their documentation is outdated, due to their small sizes and temporal dynamics. This study tested the feasibility of the new Surface Water and Ocean Topography (SWOT) mission regarding the 3D documentation of small waterbodies in a coastal area of South Carolina, USA. Via deep learning using a recent 15 cm aerial image, small waterbodies (>0.02 ha) were extracted at an average precision score of 0.81. The water surface elevation (WSE) of each waterbody was extracted using the SWOT Level-2 Water Mask Pixel Cloud (PIXC) product, with the data collected on 1 June 2023. Using a statistical noise-removal approach, the average WSE values of small waterbodies revealed a significant correlation (Pearson’s r = 0.64) with their bottom elevations. Via spatial interpolation, the water levels of small waterbodies across the study area were generally aligned with the state-reported Cone of Depression of ground water surfaces in underlying aquifers. While the WSE measurements of SWOT pixel points are noisy due to the land–water interactions in small waterbodies, this study indicates that the SWOT PIXC product could provide a valuable resource for assessing freshwater availability to assist in water-use decision-making. Full article
(This article belongs to the Special Issue Hydrological Modeling and Sustainable Water Resources Management)
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18 pages, 6257 KiB  
Article
Submarine Groundwater Discharge in the Nice Airport Landslide Area
by Christoph Witt and Achim Kopf
J. Mar. Sci. Eng. 2025, 13(5), 909; https://doi.org/10.3390/jmse13050909 - 3 May 2025
Cited by 1 | Viewed by 481
Abstract
Natural radioactivity was measured and analyzed at the Nice Slope for over a month using radon daughters in order to trace groundwater movement from a coastal aquifer to a nearshore continental shelf. Such groundwater movement may have resulted in submarine groundwater discharge (SGD) [...] Read more.
Natural radioactivity was measured and analyzed at the Nice Slope for over a month using radon daughters in order to trace groundwater movement from a coastal aquifer to a nearshore continental shelf. Such groundwater movement may have resulted in submarine groundwater discharge (SGD) and potentially sediment weakening and slope failure. The relationship among major hydrological parameters (precipitation, Var discharge, groundwater level, salinity and water origin) in the area is demonstrated in this study. Time series analyses also helped to detect tidal fluctuations in freshwater input, highlighting the crucial role SGD plays in the slope stability of the still failure-prone Nice Slope, parts of which collapsed in a tsunamigenic submarine landslide in 1979. Earlier deployments of the underwater mass spectrometer KATERINA showed that SGD is limited to the region of the 1979 landslide scar, suggesting that the spatially heterogenous lithologies do not support widespread groundwater charging. The calculated volumetric activities from groundwater tracing isotopes revealed peaks up to ca. 150 counts 214Bi, which is similar to those measured at other prominent SGD sites along the Mediterranean shoreline. Therefore, this rare long-term radioisotope dataset is a valuable contribution to the collaborative research at the Nice Slope and may not remain restricted to the unconfined landslide scar but may charge permeable sub-bottom areas nearby. Hence, it has to be taken into account for further slope stability studies. Full article
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17 pages, 6693 KiB  
Article
A Comparative Study on Leakage Magnitude Occurred in Reservoir While Passing a Tunnel Beneath Reservoir
by Tao Chen, Liyuan Zhao, Zhou Ya, Zihao Yu and Guozhu Zhang
Water 2025, 17(7), 1068; https://doi.org/10.3390/w17071068 - 3 Apr 2025
Viewed by 333
Abstract
To prevent a decrease in the water level of the reservoir caused by water surges and seepage from the tunnel beneath the reservoir, it is essential to clarify the hydraulic connection between the reservoir and the underpass tunnel. A MODFLOW three-dimensional grid model [...] Read more.
To prevent a decrease in the water level of the reservoir caused by water surges and seepage from the tunnel beneath the reservoir, it is essential to clarify the hydraulic connection between the reservoir and the underpass tunnel. A MODFLOW three-dimensional grid model was developed using GMS 10.6 software to examine this hydraulic connection. The model focused on the section of the tunnel beneath the reservoir, investigating the effects of factors such as the permeability coefficient of the stratum, rainfall recharge, fault permeability, aquifer thickness, and the silt layer at the reservoir’s bottom on tunnel water inflow. Additionally, the relationship between tunnel water inflow and reservoir water levels was analyzed. The results indicate that the presence of faults enhances the hydraulic connection between the tunnel and the reservoir. An increase in fault permeability leads to greater water inflow into the tunnel at the fault location. As the permeability coefficient of the stratum increases, the decline in reservoir water levels follows an S-shaped curve. The silt layer at the bottom of the reservoir helps mitigate the drop in water levels caused by tunnel water inflow. When the water influx is below 0.4 m3/d, the reservoir water level remains unaffected. However, when the influx exceeds 0.7 m3/d, the water level decreases rapidly as the influx increases. At an influx near 1 m3/d, the reservoir level drops by approximately 7 m. The reservoir is particularly susceptible to leakage when the fault penetrates the bottom of the reservoir and forms a hydraulic connection with the tunnel. This study provides a predictive method for assessing reservoir water level reductions caused by tunnel surges, which can aid in mitigating such effects in the future. Full article
(This article belongs to the Section Hydraulics and Hydrodynamics)
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22 pages, 5895 KiB  
Article
Hydro-Mechanical Numerical Analysis of a Double-Wall Deep Excavation in a Multi-Aquifer Strata Considering Soil–Structure Interaction
by Yinhang Zhu, Weidong Wang, Zhonghua Xu, Jinjian Chen and Ji Zhang
Buildings 2025, 15(6), 989; https://doi.org/10.3390/buildings15060989 - 20 Mar 2025
Cited by 2 | Viewed by 421
Abstract
In order to exploit the deep underground space, the construction of ultra-deep excavation in Shanghai is growing rapidly. In multi-aquifer strata, deep excavations typically require dewatering of confined aquifers to ensure engineering safety. However, existing studies have seldom conducted in-depth analysis on the [...] Read more.
In order to exploit the deep underground space, the construction of ultra-deep excavation in Shanghai is growing rapidly. In multi-aquifer strata, deep excavations typically require dewatering of confined aquifers to ensure engineering safety. However, existing studies have seldom conducted in-depth analysis on the influence of the soil parameters and construction measures on the deformation of retaining structures. In this study, a three-dimensional hydro-mechanical numerical model was developed to evaluate the performances of excavation and dewatering of the foundation pit. The model was validated by comparing the calculated and measured wall deflections and groundwater drawdowns of a 45 m ultra-deep double-wall excavation in Shanghai. According to the characteristics of soil stratification and construction activities, three parameters were selected for subsequent analysis, including the hydraulic conductivity of aquitard below the bottom of the pit, the pumping rate in the second confined aquifer and the construction of TRD wall. The stress distributions on both sides of the diaphragm wall were examined to elucidate the deformation mechanism. The results indicate that the aquitard hydraulic conductivity directly affects the effective stress of the overlying aquifer, which plays a crucial role in resisting wall deflection. An increase in the hydraulic conductivity leads to smaller effective stress, greater wall deflection and larger ground settlement. While an appropriately increased pumping rate enhances effective stress, over-pumping may induce excessive wall deflection at depth and disproportionate ground settlement. The TRD wall is quite useful in terms of waterproofing but the effect on deformation control is limited. The findings of this study provide valuable insights for engineering practices and the optimization of deep excavation construction measures in multi-aquifer strata. Full article
(This article belongs to the Special Issue Advances in Soil-Structure Interaction for Building Structures)
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13 pages, 2159 KiB  
Article
New Method for Calculating Rock Compressibility, Dynamic Reserves, and Aquifer Size for Fractured–Vuggy Reservoirs with Bottom Aquifer
by Bo Fang, Yuwei Jiao, Qi Zhang, Yajie Tian, Baozhu Li and Wei Yu
Processes 2025, 13(3), 684; https://doi.org/10.3390/pr13030684 - 27 Feb 2025
Cited by 1 | Viewed by 555
Abstract
Due to the complex reservoir types and strong heterogeneity of fractured–vuggy reservoirs with aquifers, evaluating such reservoirs’ dynamic reserves and aquifer size is challenging. This paper established a segmented elastic-drive material balance equation based on the material balance principle by combining the functional [...] Read more.
Due to the complex reservoir types and strong heterogeneity of fractured–vuggy reservoirs with aquifers, evaluating such reservoirs’ dynamic reserves and aquifer size is challenging. This paper established a segmented elastic-drive material balance equation based on the material balance principle by combining the functional relationships among the crude oil volume factor, crude oil compressibility, and formation pressure. The PELT algorithm was used to segment the water invasion stages, and nonlinear least squares fitting was employed to determine the rock compressibility, dynamic reserves, and aquifer size of fractured–vuggy reservoirs. This study shows that production in fractured–vuggy reservoirs with aquifers can be divided into three stages: no water invasion, initial water invasion, and full water invasion. Rock compressibility and dynamic reserves can be calculated using production data from the no water invasion stage, while the aquifer size can be determined from data in the water invasion stage. Influenced by connectivity and production regulations, aquifers may not be fully affected by pressure waves, causing the aquifer size to increase gradually until stabilization. Compared with numerical simulation data, the method presented in this paper achieves errors of 0.34%, 0.67%, and 1.19% for rock compressibility, dynamic reserves, and aquifer size, respectively. Full article
(This article belongs to the Section Energy Systems)
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12 pages, 2781 KiB  
Article
Quantile-Based Approach for Improving the Identification of Preferential Groundwater Networks
by Massimiliano Schiavo
Water 2025, 17(2), 282; https://doi.org/10.3390/w17020282 - 20 Jan 2025
Cited by 7 | Viewed by 1076
Abstract
Identifying preferential paths for groundwater flow is one of the basics for understanding aquifer systems. Shallow free-surface aquifers often have flow directions (locally) similar to those of their surface counterparts, especially if surface and groundwater bodies are directly connected. This work proposes a [...] Read more.
Identifying preferential paths for groundwater flow is one of the basics for understanding aquifer systems. Shallow free-surface aquifers often have flow directions (locally) similar to those of their surface counterparts, especially if surface and groundwater bodies are directly connected. This work proposes a novel and simple framework to improve the identification of Preferential Groundwater Networks in free-surface aquifers. This is possible by proposing a quantile mapping procedure borrowed from stochastic hydrology, usually employed to adjust rainfall simulations (for example, achieved via climate models) upon available gauge-based data. This well-known procedure is applied to redistribute simulations of the aquifer bottom elevation for a real case study in Lombardy, Northern Italy. The result is a spatial redistribution of the elevation quantiles that leads to aquifer bottom surfaces carved with Preferential Groundwater Networks that are spatially consistent with the surface river network. This way, groundwater flow directions are redistributed to mimic their surface counterparts, but aquifer bottom elevations and slopes are far gentler as they were previously simulated from borehole data information. Furthermore, the errors in the spatial reframing of borehole data and the discrepancy of variogram structures before and after the redistribution procedure are not dramatically dissimilar. Full article
(This article belongs to the Section Hydrogeology)
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21 pages, 18639 KiB  
Article
CO2 Sequestration in a Carbonate Saline Aquifer: An Investigation into the Roles of Natural Fractures and Well Placement
by Abdulrahim K. Al Mulhim, Mojdeh Delshad and Kamy Sepehrnoori
Energies 2025, 18(2), 242; https://doi.org/10.3390/en18020242 - 8 Jan 2025
Viewed by 972
Abstract
CO2 sequestration is considered one of the main pillars in achieving the ongoing decarbonization efforts. A myriad of CO2 sequestration projects targeted sandstone reservoirs since carbonate reservoirs appeared to be unpropitious due to their geological complexity and unfavorable mineralogy and properties. [...] Read more.
CO2 sequestration is considered one of the main pillars in achieving the ongoing decarbonization efforts. A myriad of CO2 sequestration projects targeted sandstone reservoirs since carbonate reservoirs appeared to be unpropitious due to their geological complexity and unfavorable mineralogy and properties. This study investigates CO2 sequestration potential in a carbonate saline aquifer while considering various geological complexities by capitalizing on numerical simulation. A synthetic anticline reservoir model examined the optimum well location and landing zone for CO2 sequestration. Additionally, the model evaluated the role of natural fractures in the migration path of CO2 plume and geochemical reactions throughout the storage process. The study demonstrates that placing the injection well away from the top of the structure in a low-dip region while injecting in the bottom interval would yield the optimum design. After applying a plethora of analyses, geological complexity could impede the migration path of CO2 but eventually produce a similar path when injected in a similar region. The geochemical interactions between the injected CO2 and reservoir fluids and minerals reduce the free and trapped CO2 quantities by dissolving calcite and precipitating dolomite. Furthermore, natural fractures impact the CO2 quantities during early times only when the fractures cross the top layers. Similarly, the CO2 migration differs due to the higher permeability within the fractures, resulting in slightly different CO2 plumes. Consequently, the role of natural fractures should be limited in carbon storage projects, specifically if they do not cross the top of the reservoir. This study reflects a unique perspective on sequestering CO2 while capturing the roles of natural fractures and well placement in depicting the migration path of the CO2 plume. A similar systematic workflow and holistic approach can be utilized to optimize the subsurface storage process for potential formations. Full article
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14 pages, 6455 KiB  
Article
Application of NIPOS-SVM Model for Evaluation of Water Richness of Coal Seam Roof Aquifer—A Case Study of the Xinhu Coal Mine in Huaibei, China
by Maolin Xing, Qiqing Wang, Jie Xu and Wenping Li
Water 2024, 16(24), 3670; https://doi.org/10.3390/w16243670 - 20 Dec 2024
Cited by 1 | Viewed by 827
Abstract
The sandstone roof of coal seams, with its high porosity and developed fissures, serves as a favorable reservoir for groundwater. Predicting and assessing the water-bearing capacity of the sandstone roof in coal seams is crucial for the rational development of coal tunnels, ensuring [...] Read more.
The sandstone roof of coal seams, with its high porosity and developed fissures, serves as a favorable reservoir for groundwater. Predicting and assessing the water-bearing capacity of the sandstone roof in coal seams is crucial for the rational development of coal tunnels, ensuring safe and efficient production in mining areas. This study targets the Cenozoic bottom aquifer of the No. 81 mining area of the Xinhu Coal Mine. By analyzing the geological and hydrogeological conditions of the mining area, it was found that the primary water-bearing strata of the coal seam roof are the Permian sandstone fracture waters. Key factors for evaluating the water richness of the sandstone aquifer were identified as aquifer thickness, aquifer depth, core recovery rate, coal seam dip angle, brittleness–plasticity ratio, and the sand–mud interlayer index. A novel particle swarm optimization algorithm incorporating improved sine chaos mapping (NIPSO) to enhance the support vector machine (SVM), thereby constructing the NIPSO-SVM model, was applied for quantitative evaluation of water richness in the study area. Experimental results indicated that the NIPSO-SVM model has high accuracy and practical engineering application value in predicting water richness, which is significant for ensuring the safe production of coal mines. Full article
(This article belongs to the Section Hydrogeology)
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23 pages, 8695 KiB  
Article
Corrosion Inhibition of Carbon Steel Immersed in Standardized Reconstituted Geothermal Water and Individually Treated with Four New Biosourced Oxazoline Molecules
by Chahinez Helali, Stephanie Betelu, Romain Valentin, Sophie Thiebaud-Roux and Ioannis Ignatiadis
Metals 2024, 14(12), 1439; https://doi.org/10.3390/met14121439 - 16 Dec 2024
Viewed by 1077
Abstract
The current demand for heat production via geothermal energy is increasingly rising amid concerns surrounding non-renewable forms of energy. The Dogger aquifer in the Paris Basin (DAPB) in France produces saline geothermal waters (GWs), which are as hot as 70–85 °C, anaerobic, slightly [...] Read more.
The current demand for heat production via geothermal energy is increasingly rising amid concerns surrounding non-renewable forms of energy. The Dogger aquifer in the Paris Basin (DAPB) in France produces saline geothermal waters (GWs), which are as hot as 70–85 °C, anaerobic, slightly acidic (pH 6.1–6.4), and characterized mainly by the presence of Cl, SO42−, CO2/HCO3, and H2S/HS. These GWs are corrosive, and the casings of all geothermal wells are carbon steel. Since 1989, these GWs have been progressively treated using petrosourced organic corrosion inhibitors (PS–OCI) at the bottom of the production wells. Currently, there is a great need to test not only new PS–OCIs but also, and above all, biosourced organic corrosion inhibitors (BS–OCIs) to improve the efficiency and environmental friendliness of this carbon-free geothermal energy source. The main objective of this study is to evaluate the potential performance of biosourced corrosion inhibitor candidates (BS–CICs) in terms of their inhibition efficiency (IE) for carbon steel corrosion. This was achieved using a previously established geochemical and electrochemical method to study the mechanisms and kinetics of the corrosion/scaling of carbon steel and optimize short-term corrosion inhibition in standardized reconstituted geothermal water (SRGW) representative of the DAPB’s waters. Four new molecules from the 2-oxazoline family were evaluated individually and compared based on their behavior and inhibition efficiency. These molecules exhibited a mixed nature (i.e., anodic and cathodic inhibitors), with a slight anodic predominance, and showed a significant IE at a concentration of at 10 mg/L during the first hours of immersion of CS-XC38 in SRGW. The average IEs, obtained via the three electrochemical techniques used for the determination of corrosion current densities, i.e., Jcorr(Rp), Jcorr(Tafel), and Jcorr(Rw), are 51%, 79%, 96%, and 93% for Decenox (C10:1), Decanox (C10:0), Undecanox (C11:0), and Tridecanox (C13:0), respectively. Full article
(This article belongs to the Special Issue Recent Advances in Corrosion and Protection of Metallic Materials)
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29 pages, 9698 KiB  
Article
Study on the Application Method of Aquifer Depth Distribution Patterns as Model Input on the Performance of a Physically Based Distributed Hydrologic Model
by Jeawhan Shin, Bonwoong Koo, Jonghwan Jang, Sunho Choi and Changhwan Jang
Water 2024, 16(23), 3518; https://doi.org/10.3390/w16233518 - 6 Dec 2024
Viewed by 944
Abstract
Groundwater discharge is critical for maintaining river flow during dry seasons, especially in lowland areas. Despite its significance, groundwater resources have often been overlooked highlighting the need for comprehensive studies amidst growing pressure to develop new water resources. This study focuses on the [...] Read more.
Groundwater discharge is critical for maintaining river flow during dry seasons, especially in lowland areas. Despite its significance, groundwater resources have often been overlooked highlighting the need for comprehensive studies amidst growing pressure to develop new water resources. This study focuses on the Soyang River Basin, South Korea, including its ungauged northern regions, the nearby DMZ (Demilitarized Zone), using the physically based Gridded Surface Subsurface Hydrologic Analysis (GSSHA) model. A three-year simulation was conducted to examine variable aquifer depth distribution patterns by assuming an inverse relationship between surface elevation and aquifer bottom depth. Three case studies (i.e., equal distribution, linear regression, and logarithmic regression) were evaluated and compared. The method to identity optimal aquifer depth distributions to enhance groundwater simulation accuracy in regions with significant topographical variation was incorporated. Groundwater levels at six monitoring sites showed that altitude-based variable aquifer depths outperformed the equal distribution case. The results showed strong agreement between simulated and observed values, particularly in the linear regression case with an R-squared statistic of 0.858 and Nash–Sutcliffe Efficiency index of 0.789, indicating that linear regression-based aquifer depth estimation can significantly improves long-term runoff modeling and groundwater simulation accuracy. The logarithmic regression case had the lowest relative peak error in peak flow. These findings highlight the importance of adjusting aquifer depth distributions in physically based hydrologic models to better reflect real-world conditions. Overall, this study contributes to advance groundwater modeling by integrating variable aquifer depth distributions into a physically based hydrologic model for large scale watersheds. Full article
(This article belongs to the Section Hydrology)
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