Search Results (1,041)

This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal to pure biomass. The results show that Scenario B (100% rice husk) achieved the best overall environmental performance, with the lowest global warming potential (300 kg CO₂ equivalent), eutrophication potential (4.742 kg PO₄ equivalent), and smog formation potential (0.012 kg C₂H₄ equivalent). Additionally, Scenario F (15% biomass mix) recorded the lowest acidification potential (57.39 kg SO₂ eq), indicating that even partial substitution can yield significant environmental benefits. In contrast, Scenario C (100% coal) exhibited the highest acidification (164.08 kg SO₂ eq) and eutrophication (8.82 kg PO₄ eq) potential. Overall, the results demonstrate that co-firing biomass waste significantly reduces pollutant emissions compared to burning coal alone. This study highlights the effectiveness of biomass waste co-firing in mitigating environmental impacts, promoting resource recovery, and supporting a sustainable energy transition within a circular economy framework. Full article

Understanding the differential impacts of emission sources of volatile organic compounds (VOCs) on formaldehyde (HCHO) levels is pivotal to effectively mitigating key photochemical radical precursors, thereby enhancing the regulation of atmospheric oxidation capacity (AOC) and ozone formation. This investigation systematically selected and analyzed year-long VOC measurements across three urban zones in Shenzhen, China. Photochemical age correction methods were implemented to develop the initial concentrations of VOCs before source apportionment; then Positive Matrix Factorization (PMF) modeling resolved six primary sources: solvent usage (28.6–47.9%), vehicle exhaust (24.2–31.2%), biogenic emission (13.8–18.1%), natural gas (8.5–16.3%), gasoline evaporation (3.2–8.9%), and biomass burning (0.3–2.4%). A machine learning (ML) framework incorporating Shapley Additive Explanations (SHAP) was subsequently applied to evaluate the influence of six emission sources on HCHO concentrations while accounting for reaction time adjustments. This machine learning-driven nonlinear analysis demonstrated that vehicle exhaust nearly always emerged as the primary anthropogenic contributor in diverse functional zones and different seasons, with gasoline evaporation as another key contributor, while the traditional reactivity metric method, ozone formation potential (OFP), tended to underestimate the role of the two sources. This study highlights the primacy of strengthening emission reduction of transportation sectors to mitigate HCHO pollution in megacities. Full article

Biochar is an amendment that can enhance both soil fertility and sequester carbon. However, its historical applications continue to be underexplored. In this overview, we investigate the formiguer method of burning woody biomass to create agricultural biochar for use as fertilizer in Catalonia, Spain, within the context of historical biochar use. A literature review targeted searches of scholarly databases to compare the formiguer method to Amazonian terra preta and other traditional biochar use. We identified sources covering biochar properties, soil impacts, and historical agricultural practices within the Iberian Peninsula and briefly described the main methods or treatments used during this process. Past research demonstrates that the formiguer method, which involves pyrolytic combustion of biomass within soil mounds, improves microbial activity, increases soil phosphorus and potassium availability from soil structure, and leads to long-term carbon stabilization, even though it can result in short-term decreases in soil organic carbon and nitrogen losses. Despite being abandoned in Europe with the rise of chemical fertilizers, the use of formiguers exemplifies a decentralized approach to nutrient and agroecosystem management. The literature highlights the relevance that these traditional biochar practices can have in informing modern soil management and sustainable agricultural strategies. Understanding the formiguer can offer critical insights to optimize contemporary biochar applications and historical techniques into future sustainability frameworks. Full article

This study aimed to investigate the effect of wildfire episodes on air quality in terms of particulate matter (PM) and carbonaceous compound concentration in ambient air, and to assess deviations from typical annual patterns. The sampling was performed at a rural background site near the Adriatic coast in Croatia through 2024. To better understand contributions caused by fire events, the levels of organic carbon (OC), elemental carbon (EC), black carbon (BC), pyrolytic carbon (PyrC), optical carbon (OptC), water-soluble organic carbon (WSOC), levoglucosan (LG), mannosan (MNS), and galactosan (GA) were determined in PM₁₀ and PM_2.5 fractions (particles smaller than 10 µm and 2.5 µm, respectively). The annual mean concentrations of PM₁₀ and PM_2.5 were 14 µg/m³ and 8 µg/m³, respectively. During the fire episode, the PM_2.5 mass contribution to the total PM₁₀ mass exceeded 65%. Total carbon (TC) and OC increased by a factor of 7, EC and BC by 12, PyrC by 8, and WSOC by 12. The concentration of LG reached 1.219 μg/m³ in the PM₁₀ fractions and 0.954 μg/m³ in the PM_2.5 fractions, representing a 200-fold increase during the fire episode. Meteorological data were integrated to assess atmospheric conditions during the fire episode, and the specific ratios between fire-related compounds were analyzed. Full article

Long-term source apportionment of PM_2.5 during high-pollution periods is essential for achieving sustained reductions in both PM_2.5 levels and their health impacts. This study conducted PM_2.5 sampling in Shenzhen from January to March over the years 2021–2024 to investigate the long-term impact of coronavirus disease 2019 and the short-term impact of the Spring Festival on PM_2.5 levels. The measured average PM_2.5 concentration during the research period was 22.5 μg/m³, with organic matter (OM) being the dominant component. Vehicle emissions, secondary sulfate, secondary nitrate, and secondary organic aerosol were identified by receptor model as the primary sources of PM_2.5 during the observational periods. The pandemic led to a decrease of between 30% and 50% in the contributions of most anthropogenic sources in 2022 compared to 2021, followed by a rebound. PM_2.5 levels in January–March 2024 dropped by 1.4 μg/m³ compared to 2021, mainly due to reduced vehicle emissions, secondary sulfate, fugitive dust, biomass burning, and industrial emissions, reflecting Shenzhen’s and nearby cities’ effective control measures. However, secondary nitrate and fireworks-related emissions rose significantly. During the Spring Festival, PM_2.5 concentrations were 23% lower than before the festival, but the contributions of fireworks burning exhibited a marked increase in both 2023 and 2024. Specifically, during intense peak events, fireworks burning triggered sharp, short-term spikes in characteristic metal concentrations, accounting for over 50% of PM_2.5 on those peak days. In the future, strict control over vehicle emissions and enhanced management of fireworks burning during special periods like the Spring Festival are necessary to reduce PM_2.5 concentration and improve air quality. Full article

This study describes a quite special and interesting atmospheric event characterized by the simultaneous presence of fresh and aged smoke layers. These peculiar conditions occurred on 16 July 2024 at the CNR-IMAA atmospheric observatory (CIAO) in Potenza (Italy), and represent an ideal case for the evaluation of the impact of aging and transport mechanisms on both the optical and microphysical properties of biomass burning aerosol. The fresh smoke was originated by a local wildfire about 2 km from the measurement site and observed about one hour after its ignition. The other smoke layer was due to a wide wildfire occurring in Canada that, according to backward trajectory analysis, traveled for about 5–6 days before reaching the observatory. Synergetic use of lidar, ceilometer, radar, and microwave radiometer measurements revealed that particles from the local wildfire, located at about 3 km a.s.l., acted as condensation nuclei for cloud formation as a result of high humidity concentrations at this altitude range. Optical characterization of the fresh smoke layer based on Raman lidar measurements provided lidar ratio (LR) values of 46 ± 4 sr and 34 ± 3 sr, at 355 and 532 nm, respectively. The particle linear depolarization ratio (PLDR) at 532 nm was 0.067 ± 0.002, while backscatter-related Ångström exponent (AEβ) values were 1.21 ± 0.03, 1.23 ± 0.03, and 1.22 ± 0.04 in the spectral ranges of 355–532 nm, 355–1064 nm and 532–1064 nm, respectively. Microphysical inversion caused by these intensive optical parameters indicates a low contribution of black carbon (BC) and, despite their small size, particles remained outside the ultrafine range. Moreover, a combined use of CIAO remote sensing and in situ instrumentation shows that the particle properties are affected by humidity variations, thus suggesting a marked particle hygroscopic behavior. In contrast, the smoke plume from the Canadian wildfire traveled at altitudes between 6 and 8 km a.s.l., remaining unaffected by local humidity. Absorption in this case was higher, and, as observed in other aged wildfires, the LR at 532 nm was larger than that at 355 nm. Specifically, the LR at 355 nm was 55 ± 2 sr, while at 532 nm it was 82 ± 3 sr. The AEβ values were 1.77 ± 0.13 and 1.41 ± 0.07 at 355–532 nm and 532–1064 nm, respectively and the PLDR at 532 nm was 0.040 ± 0.003. Microphysical analysis suggests the presence of larger, yet much more absorbent particles. This analysis indicates that both optical and microphysical properties of smoke can vary significantly depending on its origin, persistence, and transport in the atmosphere. These factors that must be carefully incorporated into future climate models, especially considering the frequent occurrences of fire events worldwide. Full article

This study assessed the influence of meteorological conditions on particulate matter (PM) concentrations in Campo Grande, Brazil, from May to December 2021. Using statistical analyses, including Pearson’s correlation coefficient and multivariate regression, we analyzed secondary data on PM2.5 and PM10 concentrations and meteorological variables from the Federal University of Mato Grosso do Sul’s Physics Department. Daily PM concentrations complied with Brazil’s National Ambient Air Quality Standards (PQAr). The PM2.5/PM10 ratios averaged 0.436 (hourly) and 0.442 (daily), indicating a mix of fine and coarse particles. Significant positive correlations were found with temperature, while relative humidity showed a negative correlation, reducing PM levels through deposition. Wind speed had no significant impact. Meteorological influences suggest that air quality management should be tailored to regional conditions, particularly addressing local emission sources like vehicular traffic and biomass burning. Full article

Biomass burning processes affect many semi-rural areas in the Mediterranean, but there is a lack of long-term datasets focusing on their classification, obtained by monitoring carbonaceous particle concentrations and optical properties variations. To address this issue, a campaign to measure equivalent black carbon (eBC) and particle number size distributions (0.3–10 μm) was carried out from August 2019 to November 2020 at a coastal semi-rural site in the Basilicata region of Southern Italy. Long-term datasets were useful for aerosol characterization, helping to clearly identify traffic as a constant eBC source. For a shorter period, PM_2.5 mass concentrations were also measured, allowing the estimation of elemental and organic carbon (EC and OC), and chemical and SEM (scanning electron microscope) analysis of aerosols collected on filters. This multi-instrumental approach enabled the discrimination among different biomass burning (BB) processes, and the analysis of three case studies related to domestic heating, regional smoke plume transport, and a local smoldering process. The AAE (Ångström absorption exponent) daily pattern was characterized as having a peak late in the morning and mean hourly values that were always higher than 1.3. Full article

The updated MODIS Collection 6.1 (C6.1) Dark Target (DT) aerosol optical depth (AOD) is extensively utilized in aerosol-climate studies in China. Nevertheless, the long-term accuracy of this data remains under-evaluated, especially for the forested areas. This study was undertaken to substantiate the accuracy of MODIS Terra (MOD04) and Aqua (MYD04) at 3 km resolution AOD retrievals at six forested sites in China from 2004 to 2022. The results revealed that MODIS C6.1 DT MOD04 and MYD04 datasets display good correlation (R = 0.75), low RMSE (0.20, 0.18), but significant underestimation, with only 53.57% (Terra) and 52.20% (Aqua) of retrievals within expected error (EE). Both the Terra and Aqua struggled in complex terrain (Gongga Mt.) and high aerosol loads (AOD > 1). In northern sites, MOD04 outperformed MYD04 with better correlation and a relatively high number of retrievals percentage within EE. In contrast, MYD04 outperformed MOD04 in central region with better R (0.69 vs. 0.62), and high percentage within EE (68.70% vs. 63.62%). Since both products perform well in the central region, MODIS C6.1 DT products are recommended for this region. In southern sites, MOD04 product performs relatively better than MYD04 with a marginally higher percentage within EE. However, MYD04 shows better correlation, although a higher number of retrievals fall below EE compared to MOD04. Seasonal biases, driven by snow and dust, were pronounced at northern sites during winter and spring. Southern sites faced issues during biomass burning seasons and complex terrain further degraded accuracy. MOD04 demonstrated a marginally superior performance compared to MYD04, yet both failed to achieve the global validation benchmark (66% within). The proposed results highlight critical limitations of current aerosol retrieval algorithms in forest and mountainous landscapes, necessitating methodological refinements to improve satellite-based derived AOD accuracy in ecological sensitive areas. Full article

The Metropolitan Area of Queretaro (MAQ) is a significant industrial hub in central Mexico whose air quality, including high concentrations of particulate matter (PM), poses a risk to the population. However, there have not been many studies on the sources and processes that influence the concentration of atmospheric pollutants. We used aerosol chemical composition and meteorological data from 1 January to 15 May 2022, along with back-trajectory modeling, to investigate emission sources not previously described in the region and the impact of local and regional meteorology on the chemical composition of aerosols. Furthermore, this study presents the first quantitative analysis of nitroaromatic compounds (NACs) in particulate matter in the MAQ using ultra-performance liquid chromatography coupled with high-resolution mass spectrometry. The NAC concentrations ranged from 0.086 to 3.618 ng m⁻³, with the highest concentrations occurring during a period of atmospheric stability. The secondary inorganic and organic fractions of the PM were the most abundant (50%) of the PM concentration throughout the campaign. Local and regional meteorology played a significant role in the variability of PM chemical composition, as it influenced oxidation and transport processes. The results reveal that emissions from biomass burning are a recurrent PM source, and regional emissions significantly impact the organic fraction of the PM. These results underscore the importance of considering both local and regional sources in assessing air pollution in the region. Full article

This study presents a global aerosol climatology derived from six years (October 2018–October 2024) of the Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) observations, using a U-Net Convolutional Neural Network (CNN) machine learning algorithm for Cloud–Aerosol Discrimination (CAD). Despite ICESat-2’s design primarily as an altimetry mission with a single-wavelength, low-power, high-repetition-rate laser, ICESat-2 effectively captures global aerosol distribution patterns and can provide valuable insights to bridge the observational gap between the Cloud–Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) and Earth Cloud, Aerosol and Radiation Explorer (EarthCARE) missions to support future spaceborne lidar mission design. The machine learning approach outperforms traditional thresholding methods, particularly in complex conditions of cloud embedded in aerosol, owing to a finer spatiotemporal resolution. Our results show that annually, between 60°S and 60°N, 78.4%, 17.0%, and 4.5% of aerosols are located within the 0–2 km, 2–4 km, and 4–6 km altitude ranges, respectively. Regional analyses cover the Arabian Sea (ARS), Arabian Peninsula (ARP), South Asia (SAS), East Asia (EAS), Southeast Asia (SEA), the Americas, and tropical oceans. Vertical aerosol structures reveal strong trans-Atlantic dust transport from the Sahara in summer and biomass burning smoke transport from the Savanna during dry seasons. Marine aerosol belts are most prominent in the tropics, contrasting with earlier reports of the Southern Ocean maxima. This work highlights the importance of vertical aerosol distributions needed for more accurate quantification of the aerosol–cloud interaction influence on radiative forcing for improving global climate models. Full article

Understanding indoor black carbon (BC) dynamics is important for assessing human exposure and informing air quality management in residential settings. This study presents a high-resolution, multi-sensor dataset collected over 24 days in a semi-occupied home in Zagreb, Croatia, designed to characterize the temporal behavior and sources of indoor BC. Indoor BC concentrations were measured at 1 min resolution using a dual-spot aethalometer, with source apportionment into biomass burning and fossil fuel components. Complementary contextual data including motion detection, door and window states, and traffic activity were collected in parallel using smart sensors and annotated experimental logs. Across the monitoring period, daily mean BC concentrations ranged from 174.7 and 1053.1 ng/m³ for biomass burning BC and between 53.2 and 880.3 ng/m³ for fossil fuel component. Statistical analyses revealed significant increases in BC concentrations during direct combustion-related activities, including scented candle burning and gas burner use. Additional BC elevations were associated with mechanical heat sources and nearby vehicle traffic, particularly affecting the fossil fuel BC component. In contrast, non-combustion activities such as brief human presence exhibited minor or inconsistent effects on indoor BC levels. This study elucidates the primary role of combustion-based indoor activities in influencing short-term BC exposure and highlights the importance of synchronized, high-resolution datasets for indoor air quality research. Full article

Peat fires are a major hazard to human and animal health and can negatively impact livelihoods. Once peat fires start to burn, they are difficult to extinguish and can continue to burn for months, destroying biomass and contributing to carbon emissions globally. In areas with limited accessibility and periods of thick haze and fog, these fires are difficult to detect, localize, and tackle. To address this problem, thermal infrared cameras mounted on drones can provide a potential solution since they allow large areas to be surveyed relatively quickly and can detect thermal radiation from fires above and below the peat surface. This paper describes a deep learning pipeline that detects and segments peat fires in thermal images. Controlled peat fires were constructed under varying environmental conditions and thermal images were taken to form a dataset for our pipeline. A semi-automated approach was adopted to label images using Otsu’s adaptive thresholding technique, which significantly reduces the required effort often needed to tag objects in images. The proposed method uses a pre-trained ResNet-50 model as a backbone (encoder) for feature extraction and is augmented with a set of up-sampling layers and skip connections, like the UNet architecture. The experimental results show that the model can achieve an IOU score of 87.6% on an unseen test set of thermal images containing peat fires. In comparison, a MobileNetV2 model trained under the same experimental conditions achieved an IOU score of 57.9%. In addition, the model is robust to false positives, which is indicated by a precision equal to 94.2%. To demonstrate its practical utility, the model was also tested on real peat wildfires, and the results are promising, as indicated by a high IOU score of 90%. Finally, a geolocation algorithm is presented to identify the GNSS location of these fires once they are detected in an image to aid fire-fighting responses. The proposed scheme was built using a web-based platform that performs offline detection and allows peat fires to be geolocated. Full article

There is currently a growing need for energy, which, combined with climate change, has increased the focus on renewable energies. Among them, biomass energy takes the lion’s share, and this can create forestry pressures or lead to the excessive consumption of resources. To mitigate this situation, residual biomass from agroforestry has emerged as a valuable resource, supporting energy transition and mitigating these challenges. However, this biomass is traditionally burned, leading to large fires, as a result of the high logistical costs associated with the lack of information/coordination between those involved in the chain. Therefore, the primary objective of this work is to address this gap by presenting an information management model based on a web application, which aims to increase transparency, integrate stakeholders, and improve logistical decisions. In methodological terms, this study follows the principles of human-centered design, as well as an agile software development methodology. The results include the creation of a new, flexible information management ecosystem, which allows each stakeholder to take on different roles according to their needs in the chain. In addition, lean information management principles have been included in order to reduce waste in information content and flow. Full article

Prescribed fire has become an increasingly important strategy for removing biomass from forests and mitigating the risk of severe wildfire. When considering where and to what extent prescribed fire should be applied, land resource managers must consider a host of concerns including biomass density, moisture content, and meteorological conditions. These variables will not only affect how effective the burn will be, but also what sort of smoke is produced by the prescribed fire and how that smoke impacts individuals and local communities. After briefly summarizing how prescribed fire practices have evolved, this review describes how the properties of prescribed fire smoke depend on prescribed fire conditions and the methods used to measure molecular and particulate species in prescribed fire smoke. The closing section of this review identifies areas where advances in smoke monitoring and characterization can continue to improve our understanding of prescribed fire behavior. Full article