Search Results (49)

Agricultural biomass ashes are increasingly used as sustainable supplementary cementitious materials (SCMs) to reduce cement-related carbon emissions and improve concrete performance. However, their effects on compressive strength depend on the SCM type, replacement level, and physical and chemical properties. These variables are often overlooked in machine learning studies focused on single SCM types and absolute strength prediction, limiting transferability across heterogeneous SCM datasets. This study develops an interpretable machine learning framework using a compiled dataset covering 18 agricultural biomass ash SCMs (bio-SCMs) used in concrete. Input features include concrete mixture proportions, the SCM replacement level, chemical composition, and specific surface area (SSA), while the target variable is the 28-day compressive-strength ratio relative to the companion control mixture. Among the five evaluated models, XGBoost achieved the best performance, with weighted 10-fold cross-validation R² values around 0.80. SHapley Additive exPlanations (SHAP) results were interpreted as model associations rather than causal mechanisms. Higher SCM SiO₂ content, pozzolanic oxide content, superplasticizer dosage, and baseline control mixture strength were associated with more favorable strength ratios; SCM SSA showed a mild positive tendency, whereas a higher SCM replacement level, water-to-binder ratio, and loss on ignition were associated with less favorable strength ratios. SCM-specific response analysis further identified literature-derived screening ranges based on observed and interpolated replacement levels rather than machine learning extrapolation. Full article

This study evaluates the performance of recycled, long-term-aged rubber-modified asphalt (RMA) mixtures rejuvenated with soybean oil. Crumb rubber is widely used in asphalt mixtures for its ability to enhance elasticity, crack resistance, and durability. However, long-term aging leads to oxidative hardening, increased stiffness, and reduced cracking resistance, creating a need for effective rejuvenation strategies. To simulate extended field aging, plant-produced RMA mixtures were conditioned at 85 °C for five and ten days and subsequently treated with 10% soybean oil by binder weight. Mechanical performance was assessed using the Disc-Shaped Compact Tension test, Indirect Tensile Asphalt Cracking Test, Hamburg Wheel Tracking Test, and Rapid Shear Rutting Test. Rejuvenation effectively reversed aging-related deterioration, increasing fracture energy by 137–211% and improving cracking tolerance indices by 22–104%, thereby restoring or surpassing the cracking performance of unaged RMA mixtures. This improvement in flexibility was accompanied by reduced rutting resistance, with rutting tolerance indices decreasing by 52–70%, consistent with the softening effect of bio-based oils. Performance space diagrams further illustrated the trade-off between enhanced cracking resistance and increased rut susceptibility. Overall, the results demonstrate that soybean oil provides strong restorative capabilities for aged RMA mixtures, but achieving balanced field performance requires optimization of rejuvenator dosage. Full article

In this study, lightweight geopolymer mortars with low environmental impact, high thermal insulation performance, and strong resistance to elevated temperatures were developed. Fly ash, expanded perlite, and bio-based hemp fibers were employed as the binder, aggregate, and reinforcement, respectively. Hemp fibers were prepared in lengths of 1, 2, and 3 cm and incorporated into the mixtures at dosages of 0.50%, 0.75%, and 1.00% by weight of binder. Sodium hydroxide was used as the activator, and specimens were heat-cured at 90 °C for 24–48–72 h. The workability, unit weight, UPV, flexural, and compressive strength of the geopolymer mortars were determined. In addition, thermal conductivity, high-temperature resistance, microstructural characteristics, and environmental impacts of selected mixtures were evaluated. The results demonstrated that lightweight geopolymer mortars could be successfully produced using expanded perlite aggregate and that hemp fibers significantly enhanced mechanical performance up to 48% at one day. Moreover, fiber reinforcement improved thermal insulation capability by up to 5.5% and high-temperature resistance. FESEM, EDX, elemental mapping, and XRD analyses supported the mechanical and physical findings through detailed microstructural evidence. Furthermore, LCA results revealed that fiber incorporation improved the environmental performance of geopolymer mortars, resulting in approximately a 21% reduction in global warming potential compared with the reference mixture. Full article

Integrating waste materials into road infrastructure is essential for environmental sustainability and resource efficiency. This study addresses the modification of short-term-aged 50/70-penetration-grade bitumen using two sustainable additives: waste toner powder and lignin. Waste toner was added at weight percentages of 4%, 8%, 12%, and 16%, while lignin was added at 15% and 20%. Since these modifiers have individual uses, this study examines how they may strengthen the oxidized binder. It focuses on extending the lifespan of the mixture by combining industrial and bio-based polymers. The main aim was to delineate the impact of these modifiers on the physical consistency, low-temperature flexibility, and microstructural morphology of the binder. The results show that both modifiers increase binder stiffness by reducing penetration at all modification rates. The resins in the waste toner enhance the polymer matrix, and the lignin’s aromatic structure increases the elastic components, improving high-temperature stability. However, ductility tests showed a reduction in elongation capability, suggesting a brittle state at lower temperatures. Also, waste toner additive is identified as the ideal modifier for high-temperature applications. SEM analysis illuminated the mechanisms underlying these performance modifications. Both additives had homogeneous distribution and good bitumen matrix interfacial bonding at lower concentrations. Full article

Asphalt binders that perform exceptionally well in resisting both rutting and cracking are highly desirable for withstanding the combined effects of extreme low temperatures and heavy vehicle loads. This work highlights the benefits of softening oils on the cracking performance of styrene–butadiene–styrene-modified asphalt (SBSMA). Additionally, the inherent correlations between cracking-performance parameters of binders and mixtures were thoroughly analyzed. A bio-based oil (bio-oil) and a petroleum-based oil (re-refined engine oil bottom, REOB) were selected as the softening oils. The benefit provided by softening oils was evaluated using various rheological indices, while the adverse effects of oxidative aging on cracking resistance were also considered. The cracking properties at intermediate temperatures were characterized by the modified Glover–Rowe (M G–R) parameter, δ_{8967 kPa}, and fatigue life (N_f). The low-temperature cracking properties of binders were evaluated by stiffness and m-value. The indirect tensile asphalt cracking (IDEAL-CT) test was conducted utilizing the CT-index and post-peak slope to estimate the fracture properties of the mixtures. The oxidative aging of binder and mixture samples was simulated and carried out based on lab aging methods; meanwhile, the carbonyl index obtained from the Fourier transform infrared (FTIR) scanning was used to track and evaluate the aging level of binders. The results show that the cracking performance could be greatly improved by the application of softening oils. Meanwhile, the bio-oils were found to operate with much higher efficiency than REOB, since the oil modification index (OMI) result showed that bio-oils exhibited four to six times the efficiency of REOB, in terms of improving the stress relaxation property. The correlations proved that the cracking-related parameters shared an inherent relationship with R² above 0.85, while these parameters consistently declined as the binder aged. The cracking performance of the mixtures at intermediate temperatures was mainly governed by the fatigue life of the binder, whereas thermal cracking performance was highly associated with the binder’s relaxation property. Full article

This study focuses on the development, characterization, and numerical simulation of novel composite materials based on natural vegetable fibers for applications in civil engineering. Three different bio-based composites were formulated using Alfa plant fibers, wood waste, and an equal mixture of both (50% Alfa, 50% wood), with polyvinyl acetate (PVAc), a non-polluting polymer matrix, as the binder. The performance of these composites is strongly influenced by the fiber morphology, structural characteristics, and the nature of the matrix. Thus, understanding and optimizing these parameters is crucial for tailoring materials to meet specific design requirements. The experimental approach began with the morphological and structural characterization of the raw and treated fibers, followed by the evaluation of the thermal a properties of the resulting composites. Furthermore, thermal conductivity simulations were performed using COMSOL Multiphysics to validate the experimental results and gain deeper insights into heat transfer behavior within the composites. A comparative analysis with conventional synthetic insulation materials revealed that the developed bio-composites offer competitive thermal performance while being more environmentally sustainable. These findings highlight the potential of Alfa and wood waste fibers as effective, eco-friendly alternatives for thermal insulation in building applications. Full article

Geopolymer concrete (GC) has become apparent as a promising and sustainable alternative to ordinary portland cement (OPC) concrete, presenting notable advantages in both environmental impact and mechanical performance. Despite these benefits, shrinkage remains a critical issue, influencing cracking susceptibility, long-term durability, and structural reliability. While previous investigations have focused on isolated parameters, such as activator concentration or curing techniques, this review provides a comprehensive analysis of the shrinkage behaviour of geopolymer concrete by exploring a broader range of influential factors. Key contributors—including precursor composition, alkali activator concentration, sodium silicate-to-sodium hydroxide ratio, liquid-to-solid ratio, pore structure, and curing conditions—are evaluated and mitigation strategies are discussed. Comparative evaluation of experimental studies reveals key patterns and mechanisms: heat curing around 60 °C consistently limits shrinkage, low-calcium binders outperform high-calcium systems, and chemical additives can reduce shrinkage by as much as 80%. The analysis also highlights emerging, bio-based additives that show promise for simultaneously controlling shrinkage and preserving mechanical performance. By integrating these diverse insights into a single framework, this paper provides a comprehensive reference for designing low-shrinkage GC mixtures. Full article

Additive manufacturing (AM) has brought significant breakthroughs to the construction sector, such as the ability to fabricate complex geometries, enhance efficiency, and reduce both material usage and construction waste. However, several challenges must still be addressed to fully transition from conventional construction practices to innovative and sustainable green alternatives. This study investigates the use of non-cementitious traditional mixtures for green construction applications through 3D printing using Liquid Deposition Modeling (LDM) technology. To explore the development of mixtures with enhanced physical and mechanical properties, natural pine and cypress wood shavings were added in varying proportions (1%, 3%, and 5%) as sustainable additives. The aim of this study is twofold: first, to demonstrate the printability of these eco-friendly mortars that can be used for conservation purposes and overcome the challenges of incorporating bio-products in 3D printing; and second, to develop sustainable composites that align with the objectives of the European Green Deal, offering low-emission construction solutions. The proposed mortars use hydrated lime and natural pozzolan as binders, river sand as an aggregate, and a polycarboxylate superplasticizer. While most studies with bio-products focus on traditional methods, this research provides proof of concept for their use in 3D printing. The study results indicate that, at low percentages, both additives had minimal effect on the physical and mechanical properties of the tested mortars, whereas higher percentages led to progressively more significant deterioration. Additionally, compared to molded specimens, the 3D-printed mortars exhibited slightly reduced mechanical strength and increased porosity, attributable to insufficient compaction during the printing process. Full article

In the search for eco-friendly and resource-efficient alternatives to conventional building materials, agricultural residues are gaining increasing attention as reinforcements in cement-based composites. This study investigates the potential of walnut shell particles (WSPs), a lignocellulosic bio-product, as a sustainable reinforcing agent in walnut shell cement boards (WSCBs). Using super white cement (SWC) as a binder, boards were manufactured with WSP content ranging from 10% to 50% by weight, targeting a density of 1300 kg/m³, a 10 mm thickness, and a water-to-cement ratio of 0.6:1. The mixtures were cold-pressed at ambient temperature using a hydraulic press at 3 MPa for 24 h, followed by curing for 28 days under ambient conditions. Physical properties such as density, water absorption, and thickness swelling were assessed, along with mechanical performance, through flexural testing. Fracture surfaces and internal microstructures were examined using scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS). Functional groups and chemical reactions were monitored using FTIR, while thermal analysis (TGA and DSC), as well as measurements of thermal conductivity and resistance, provided comprehensive insights into the thermal behavior, insulating performance, and energy efficiency potential of the boards. Results demonstrate that the board with 30% WSP exhibited an optimal balance of physical and mechanical properties, achieving a 24 h water absorption of 14.05% and a modulus of rupture (MOR) of 6.53 MPa, making it suitable for non-structural applications. The board with 50% WSP exhibited the best thermal insulation performance, with a low thermal conductivity of 0.079 W/m·K. These findings highlight the potential of recycled agricultural materials in enhancing building materials’ performance, contributing to sustainable, eco-friendly construction practices. Full article

The increasing demand for sustainable road construction materials necessitates innovative solutions to overcome the challenges of Recycled Asphalt Pavement (RAP), including aged binder brittleness, reduced flexibility, and durability concerns. Waste Plastic Aggregates (WPA) offer a promising alternative; however, their thermal aging behavior and interactions with RAP remain insufficiently understood. This study evaluates the performance of RAP-based asphalt mixtures, incorporating three types of WPA—Low-Density Polyethylene (LDPE), High-Density Polyethylene (HDPE), and Polypropylene (PP)—under three thermal aging conditions: mild (60 °C for 7 days), moderate (80 °C for 14 days), and severe (100 °C for 30 days). The mixtures were designed with 30% RAP content, 10% and 20% WPA by aggregate weight, and SBS-modified binder rejuvenated with 2% and 4% sewage sludge bio-oil by binder weight. It is considered that thermal aging may impact the performance of WPA in RAP mixtures; therefore, this study evaluates the durability and mechanical properties of RAP mixtures incorporating LDPE, HDPE, and PP under varying thermal aging conditions to address these challenges. The results showed that incorporating WPA and bio-oil significantly enhanced the mechanical performance, durability, and sustainability of asphalt mixtures. Marshall Stability increased by 12–23%, with values ranging from 12.6 to 13.2 kN for WPA-enhanced mixtures compared to 12.7 kN for the control. ITS improved by 15–20% in dry conditions (1.34–1.44 MPa) and 12–18% in wet conditions (1.15–1.19 MPa), with TSR values reaching up to 82.64%. Fatigue life was extended by 28–43%, with load cycles increasing from 295,600 for the control to 352,310 for PP mixtures. High-temperature performance showed a 12–18% improvement in softening point (57.3 °C to 61.2 °C) and a 23% increase in rutting resistance, with rut depths decreasing from 7.1 mm for the control to 5.45 mm for PP mixtures after 20,000 passes. These results demonstrate that combining RAP, WPA, and bio-oil produces sustainable asphalt mixtures with superior performance under aging and environmental stressors, offering robust solutions for high-demand applications in modern infrastructure. Full article

The viability of using Juncus acutus fibers as reinforcement material for developing lightweight sustainable non-structural construction materials in compliance with the valorization of local by-products has been investigated in this work. This study aims to investigate the effect of the chemical treatment of Juncus acutus fibers on the mechanical and hygric properties of bio-sourced clay–sand–Juncus acutus fiber composite. This lightweight specimen has been produced from a mixture of 60% natural clay and 40% sand by mass, as a matrix, and reinforced with different amounts of Juncus fibers. The fibers were used as a partial replacement of sand in the mixture by volume at 0% (control specimen), 5%, 10%, and 20%. In order to enhance interfacial bonding between the fibers and the binder matrix, which seriously limits the strength development of the composite, the fibers have undergone an NaOH alkali treatment with different concentrations of 1 and 2 wt. %. Morphological and elementary chemical component evaluations based on SEM micrographs and EDX analyses revealed that the 1 wt. % NaOH alkali treatment exhibited the most beneficial effect due to the removal of impurity deposits without significant surface damage to the fibers. This finding was highlighted through the tensile tests carried out which showed the tensile stress value of 81.97 MPa compared to those of the treated fibers with 2% NaOH (74.45 MPa) and the untreated fibers (70.24 MPa). However, mechanical test results, carried out according to the European Standard EN 196-1, highlighted the beneficial effect of the fiber alkali treatment on both the compressive and flexural strengths, particularly for the fiber contents of 5% and 10%, which corresponds to a strengthening rate of 25% and 30%, respectively. The examination of the hygroscopic properties of the samples, including capillary water absorption, water diffusivity, and moisture buffering capacity under the dynamic conditions have indicated that the specimen containing treated fibers exhibited a better moisture regulating property than that obtained with untreated fibers. However, the specimens with treated fibers are classified as excellent hygric regulators based on their moisture buffer values (MBV > 2 g/(m².%RH)), according to the NORDTEST classification. The results also indicated that the capillary water absorption and the apparent moisture diffusivity of composites were lowered due to high fiber-matrix interfacial bond after fiber treatment. Consequently, the composite with treated fibers is less diffusive compared to that with untreated fibers, and thus expected to be more durable in a humid environment. Full article

The availability of petroleum asphalt, derived from non-renewable natural sources, is steadily declining in tandem with dwindling petroleum reserves. To mitigate the reliance on petroleum, alternative renewable natural sources are being explored for use as both modifiers and replacements for petroleum asphalt, particularly as binders in asphalt mixtures. The development of bio-asphalt represents a significant innovation aimed at reducing or even eliminating the dependence on petroleum as a source of asphalt. This paper examines the chemical, rheological, and mechanical properties of Gopal (Gondorukem Asphalt), a bio-asphalt derived from Gondorukem (gum rosin) and CPO (Crude Palm Oil). Two types of Gopal, Gopal-GEM130 and Gopal-GEG90, were analyzed using FTIR (Fourier Transform Infra-Red) and EDX (Energy Dispersive X-ray) tests, with Pen 60 petroleum asphalt serving as a control for comparison. The results indicate that the chemical groups of Gopal-GEG90 and Gopal-GEM130 share 86% similarity with those of Pen 60 petroleum asphalt. Compared to Pen 60, Gopal-GEM130 is less toxic and less alkaline, while Gopal-GEG90 is also less toxic but more alkaline. Rheologically, Gopal-GEG90 and Gopal-GEM130 fall within the same classification as Pen 60, based on the Pen 60 classification grade of asphalt. Gopal-GEG90 exhibits slightly better stripping resistance and lower aging resistance than Pen 60, whereas Gopal-GEM130 demonstrates significantly better stripping resistance but lower aging resistance. Performance-wise, both Gopal variants belong to the same performance grade (PG64S) as Pen 60 petroleum asphalt. However, Gopal-GEG90 has slightly better rutting resistance compared to Pen 60 but lower than Gopal-GEM130, and it ages faster with lower fatigue resistance. Conversely, Gopal-GEM130 has superior rutting resistance but lower fatigue resistance and ages faster than Pen 60 petroleum asphalt. Full article

In North America and Europe, asphalt shingle waste created during the installation of roofing membranes and tear-off shingles retrieved at the end of the membrane’s life cycle are two major sources of municipal solid waste. Since almost 15–35% of recycled asphalt shingles (RAS) consist of an asphalt binder, the effective recycling of RAS into asphalt mixtures could also allow a reduction in the consumption of non-renewable resources such as asphalt binders. In this context, several studies investigating the use of RAS in asphalt mixtures can be found in the literature, although they exhibit widespread and sometimes conflicting information about the investigated materials, the mix preparation and testing methodologies and the experimental findings. Given this background, this review paper aims at summarizing the existing information and research gaps, providing a synthetic and rational picture of the current literature, where similar attempts cannot be found. In particular, different research studies show that the use of RAS in asphalt mixtures is an economical as well as an eco-friendly option. RAS with up to 20% by weight of binder or 5% by weight of aggregate/mixtures (eventually in combination with 15% reclaimed asphalt pavement aggregate) were found to be relatively suitable to improve the performance properties of asphalt mixtures, both in the laboratory and in the field. Adding RAS to asphalt mixtures could enhance their stiffness, strength and rutting resistance (i.e., high-temperature properties), while negatively affecting the mixtures’ fatigue and thermal cracking resistance. However, the addition of specific biomaterials (e.g., bio-binders, bio-oils) or additives to asphalt mixtures can mitigate such issues, resulting in lower brittleness and shear susceptibilities and thus improving the anti-cracking performance. On the other hand, the literature review revealed that several aspects still need to be studied in detail. As an example, RAS-modified porous asphalt mixtures (fatigue, rutting, moisture susceptibility and thermal cracking) need specific research, and there are no comprehensive research studies on the effects of the RAS mixing time, size and mixing temperature in asphalt mixtures. Moreover, the addition of waste cooking/engine oils (biomaterials) as asphalt binder rejuvenators in combination with RAS represents an attractive aspect to be studied in detail. Full article

Carbon-based electrodes have recently been most widely used in P-MFC due to their desirable properties such as biocompatibility, chemical stability, affordable price, corrosion resistance, and ease of regeneration. In general, carbon-based electrodes, particularly graphite, are produced using a complex process based on petroleum derivatives at very high temperatures. This study aims to produce electrodes from bio-pitch and charcoal powder as an alternative to graphite electrodes. The carbons used to manufacture the electrodes were obtained by the carbonisation of Robinia pseudoacacia and Azadirachta indica wood. These carbons were pulverised, sieved to 50 µm, and used as the raw materials for electrode manufacturing. The binder used was bio-pitch derived from coconut shells as the raw materials. The density and coking value of the bio-pitch revealed its potential as a good alternative to coal-tar pitch for electrode manufacturing. The electrodes were made by mixing 66.50% of each carbon powder and 33.50% of bio-pitch. The resulting mixture was moulded into a cylindrical tube 8 mm in diameter and 80 mm in length. The raw electrodes obtained were subjected to heat treatment at 800 °C or 1000 °C in an inert medium. The electrical resistivity obtained by the four-point method showed that N1000 has an electrical resistivity at least five times lower than all the electrodes developed and two times higher than that of G. Fourier-transform infrared spectroscopy (FTIR) was used to determine the compositional features of the samples and their surface roughness was characterised by atomic force microscopy (AFM). Charge transfer was determined by electrical impedance spectroscopy (EIS). The FTIR of the electrodes showed that N1000 has a spectrum that is more similar to that of G compared to the others. The EIS showed the high ionic mobility of the ions and therefore that N1000 has a higher charge transfer compared to G and the others. AFM analysis revealed that N1000 had the highest surface roughness in this study. Full article

The growing demand for sustainable building materials has boosted research on plant-based composite materials, including hemp shives bound with biodegradable binders. This study investigates the enhancement of potato-starch-based binders with sodium metasilicate and glycerol to produce eco-friendly bio-composites incorporating hemp shives. Potato starch, while renewable, often results in suboptimal mechanical properties and durability in its unmodified form. The addition of sodium metasilicate is known to improve the mechanical strength and thermal stability of starch-based materials, while glycerol acts as a plasticizer, potentially enhancing flexibility and workability. Bio-composites were produced with varying concentrations of sodium metasilicate (0–107% by mass of starch) and glycerol (0–133% by mass of starch), and their properties were evaluated through thermal analysis, density measurements, water absorption tests, compressive strength assessments, and thermal conductivity evaluations. The results demonstrate that sodium metasilicate significantly increases the bulk density, water resistance, and compressive strength of the bio-composites, with enhancements up to 19.3% in density and up to 2.3 times in compressive strength. Glycerol further improves flexibility and workability, though excessive amounts can reduce compressive strength. The combination of sodium metasilicate and glycerol provides optimal performance, achieving the best results with an 80% sodium metasilicate and 33% glycerol mixture by weight of starch. These modified bio-composites offer promising alternatives t2 o conventional building materials with improved mechanical properties and environmental benefits, making them suitable for sustainable construction applications. Full article