Search Results (1,025)

Jujube (Ziziphus jujuba Mill.) cultivation in arid regions of China faces severe soil constraints, including high alkalinity, low organic matter content, and poor water retention. Although soil amendments have demonstrated potential for improving soil quality, their combined effects on soil–plant–microbe interactions in desert agroecosystems remain poorly understood. This study conducted a three-year field experiment in a desert jujube orchard in southern Xinjiang, China, to evaluate six nitrogen fertilizer management strategies: urea alone (CK) or combined with biochar (NB), bentonite (NP), graphene (NS), biochar plus bentonite (NBP), or microbial inoculants (NW). Soil physicochemical properties, enzyme activities, bacterial community structure, and jujube yield were analyzed. Structural equation modeling (SEM) was employed to elucidate the pathways linking soil amendments to crop productivity. Results showed that NBP was the most effective in improving soil physical structure, significantly reducing bulk density and enhancing water retention capacity compared to the control. The NBP treatment also enhanced soil organic matter (30% increase), available phosphorus (119% increase), and urease activity (44% increase), resulting in the highest jujube yield (7.14 kg per tree). Bacterial community analysis revealed that NBP significantly increased Shannon diversity and enriched Actinobacteriota and Proteobacteria. SEM analysis indicated that urease activity served as a significant mechanistic pathway linking soil organic matter improvements to enhanced crop productivity. These findings demonstrate that combined application of biochar and bentonite with nitrogen fertilizer represents an effective strategy for improving soil quality, enhancing microbial functionality, and increasing crop yield in desert jujube orchards, providing a practical and synergistic amendment combination for sustainable soil management and productivity enhancement in arid agroecosystems. Full article

This study explores the use of bentonite to enhance biological biogas upgrading in a bubble reactor (BR) operated under mesophilic conditions (39 ± 1 °C). The experimental setup consisted of a 2 L vertically oriented BR (height-to-diameter ratio 16:1) fed with a synthetic gas mixture (60% H₂, 15% CO₂, 25% CH₄, v/v) at a gas recirculation rate of 4 L L_R⁻¹ h⁻¹. The aim was to overcome hydrogen’s low gas–liquid mass transfer rate while avoiding the operational challenges typically associated with trickle-bed reactors (TBR). Bentonite increases the density and hydrostatic pressure of the liquid medium and likely alters its rheology, thereby extending the gas–liquid contact time without requiring elevated pressures or intensive gas recirculation. Additionally, bentonite is expected to provide microstructural support that promotes the formation of biofilm-like communities, creating favorable microenvironments for hydrogenotrophic methanogens. As a clay-based additive, bentonite may also contribute to improved process stability through adsorption of inhibitory compounds, enhanced biomass retention, and pH buffering. Under mesophilic conditions, the bentonite-modified BR achieved a methane production rate of 2.17 ± 0.06 LCH₄ L_R⁻¹ d⁻¹ at a gas retention time of 1.49 h, with methane purity reaching 96.25%. In comparison, a previously reported mesophilic BR operated under an identical reactor configuration and operating conditions but without bentonite exhibited substantially lower methane production rates, supporting the beneficial role of bentonite in biological methanation. The findings highlight bentonite’s potential dual role (physical and biological) in improving process efficiency and stability in biological methanation. Full article

To address the challenges of low strength and poor impermeability of soil–cement walls formed with ordinary cement materials when applying the CSM (Cutter Soil Mixing) method in highly weathered strata, this study carried out structural optimization by combining the CSM method with H–section steel. This optimization effectively resolves issues such as low efficiency and high cost associated with the CSM method integrated with cement–filled piles. Meanwhile, using ordinary Portland cement as the base material, basalt fiber, sodium bentonite, and fly ash were added to investigate the influence of each component on the performance of the new composite. A novel CSM material suitable for highly weathered strata was developed, which exhibits excellent mechanical strength and impermeability. The optimal mix proportion of the soil–cement material was determined as follows: basalt fiber 0.5%, fly ash 15%, and sodium bentonite 3%. This research provides a quantitative basis for the efficient and economical application of the CSM method in highly weathered strata. Full article

The impact of large boulders transported by debris flows is a primary cause of structural damage to mitigation works. However, quantitative modeling remains difficult because of the scarcity of field measurements and the complexity of the flow medium. In this study, a theoretical model for boulder impact force in debris flows is developed using dimensional analysis based on the Buckingham theorem, subsequently simplified to two dimensionless parameters, and then validated through a series of controlled laboratory experiments. Marble spheres were used as impactors and were released to strike a rigid steel plate under three types of media: clear water, bentonite slurry, and debris flows containing particles of different size classes. The experiments were designed to isolate and quantify the influence of the flow rheology and the suspended solid phase on impact forces. The results show that the impact coefficient c is strongly governed by the debris flow yield stress, bulk density, and the size of suspended particles, following the relationship c = 0.183[τ/(rgd₁)]^−0.1(d/d₀)^0.05. Based on this relationship, a generalized formula for calculating boulder impact forces in debris flows is proposed. The model is further evaluated using field monitoring data from Jiangjiagou, Yunnan Province. The back-calculated boulder diameters fall predominantly within the range of 0.1–0.3 m (76.3–86.8%), which is consistent with field observations. These results indicate that the proposed model captures the essential physical mechanisms governing boulder impacts and provides a rational basis for selecting design parameters in debris flow mitigation engineering. The array-type piezoelectric impact sensing system designed in this study achieves high-precision and high-stability measurement of the impact force of large boulders in debris flows, providing a new sensing technology for debris flow impact monitoring. Full article

This study aims to investigate the influence of clay mineral content on the rheological properties and long-term deformation stability of clays, and to establish a unified model capable of quantitatively describing the nonlinear rheological behavior of clays with different mineral compositions. Direct shear rheological tests were conducted on specimens prepared with different mixing ratios of bentonite, kaolin, and quartz. Combined with micro-mechanism analysis, the controlling factors of clay rheological behavior were explored. The experimental results show that the creep stress threshold, elastic viscosity, and average plastic viscosity decrease significantly with increasing clay mineral content. The rheological deformation exhibits distinct nonlinear characteristics, and clay mineral content plays a controlling role in the rheological behavior. Based on experimental and mechanistic analysis, a unified rheological model was established, which reflects the material origin of rheology and captures nonlinear rheological characteristics. This model can predict the entire time-history mechanical behavior of clays with different mineral compositions across the three stages of instantaneous deformation, decay rheology, and steady-state rheology under different shear stress levels using a single set of parameters. Validation was performed through direct shear rheological tests under 50 working conditions for five types of clay specimens, demonstrating good consistency between the model calculations and experimental results. The unified rheological model reveals the material origin and physical essence of clay rheology, demonstrates high universality, and advances the understanding of the influence of mineral composition on rheology from the current phenomenological qualitative description to quantitative calculation for the first time, significantly enhancing its engineering application value. This provides a more reliable tool for predicting long-term deformation and assessing the stability of clay foundations. Full article

The development of sustainable ceramic membranes remains a major challenge for advanced wastewater treatment, particularly regarding the trade-off between mechanical durability and the removal of dissolved micropollutants. While bentonite membranes offer high stability, they often lack the selective adsorption sites required for complex effluents, and the recovery of high-capacity powder adsorbents remains technically prohibitive. This paper addresses these gaps by developing an integrated hybrid system that combines eco-friendly bentonite-based tubular membranes with regenerable clam shell-derived adsorbents. The membranes were synthesized using natural plasticizers and binders with optimization at a sintering temperature of 1000 °C yielding an average pore size of 1.7 µm, a high flexural strength of 24.06 MPa, and a permeability of 525 L h⁻¹ m⁻² bar⁻¹. To enhance the performance, clam shell powder was integrated as a functional adsorbent layer. When applied to real textile effluent from a jeans washing plant, this integrated process achieved superior removal efficiencies: 85.6% COD, 86.5% BOD₅, 86.5% TSS, and 96.5% color. A key scientific contribution of this paper is the successful application of a photochemical regeneration approach, which ensures complete adsorbent recovery and maintains membrane flux, directly supporting circular economy objectives. These results demonstrate that combining low-cost ceramic scaffolds with marine waste-derived materials provides a unique, efficient, and green solution for the scalable treatment of industrial wastewater. Full article

Circular pipe-jacking construction in gravel strata faces significant technical challenges, including high frictional resistance, elevated permeability, and susceptibility to collapse. Optimizing the formulation of thixotropic slurry is crucial for improving the construction quality and efficiency of such projects. This study, based on the Ruyang Water Supply Project of the North Main Canal in the Qianping Irrigation Area, Henan Province, China, systematically investigated slurry formulation using bentonite, soda ash, sodium carboxymethyl cellulose (CMC), polyacrylamide (PAM), and shell powder as raw materials. An orthogonal experimental design was employed to optimize the mix proportions, and the friction-reduction performance was validated through drag-friction model tests. The results indicate that the optimal slurry formulation is: bentonite 8%, soda ash 0.3%, CMC 0.2%, PAM 0.15%, shell powder 4%, and water 87.35%. This formulation exhibits excellent fluidity and thixotropy, facilitating the formation of a stable slurry film. Consequently, the friction coefficient between concrete specimens and gravel soil was reduced by 35.6%. The inclusion of shell powder significantly enhanced the slurry’s cohesiveness and improved the anti-seepage capacity of the surrounding stratum due to its filling effect. The optimized thixotropic slurry effectively mitigates frictional resistance during pipe jacking in gravel strata and enhances the formation’s resistance to collapse. The findings of this study provide a viable technical reference for pipe-jacking projects under similar geological conditions. Full article

As global oil and gas exploration extends to deep and ultra-deep wells, high bottom-hole temperature is prone to deteriorating the gelation and rheological properties of water-based drilling fluids, which manifests as undesirable thickening or thinning at elevated temperatures. Therefore, the development of high-temperature resistant and stable drilling fluids is crucial for ensuring safe and efficient drilling operations, and the enhancement of high-temperature performance is typically achieved by adding drilling fluid treatment agents. The main objective of this study is to apply sodium acetate (SA) to drilling fluid systems, developing an economical and efficient non-polymer treatment agent with dual functions as a composite sodium-modifier and a rheological regulator. By-product sodium acetate (TRSA) is adopted to provide better cost-effectiveness while maintaining equivalent performance, and its universality across seven types of bentonites is verified. Three grades of sodium acetate were added to the bentonites as either composite sodium-modifiers or rheological regulators. After high-temperature aging, rheological parameters, including mud density, plastic viscosity (PV), yield point (YP), and gel strength, were measured in accordance with standard API methods. The results indicate that adding 2 wt.% TRSA to drilling fluid and subjecting it to hot rolling at 180 °C for 16 h keeps the viscosity at a high shear rate (1022 s⁻¹) nearly unchanged (from 36 mPa·s to 37.5 mPa·s), while increasing the viscosity at a low shear rate (5.11 s⁻¹) from 250 mPa·s to 1400 mPa·s, thereby effectively improving the shear thinning effect of the sodium-modified calcium-based bentonite water-based drilling fluid. Although TRSA increases the filtration loss from 21.8 mL to 30 mL, this can be reduced to 20–25 mL by co-extrusion sodium modification with sodium carbonate or by adding additional TRSA to sodium-modified bentonite. This study provides a novel perspective for significantly improving the gelation characteristics and rheological properties of bentonite suspensions at high temperatures through a special inorganic substance, while realizing resource reuse and cost reduction. Full article

To address the problem of excessive sulfur in high-sulfur magnetite concentrates when used directly, this study systematically investigated the desulfurization behavior and mechanism during oxidative roasting. Green pellets were prepared by mixing high-sulfur iron concentrate fines with 1% bentonite, followed by roasting experiments in air at 800–1200 °C. Thermogravimetric analysis (TG), real-time flue gas analysis (DOAS), X-ray diffraction (XRD), and scanning electron microscopy–energy dispersive spectroscopy (SEM–EDS) were employed to characterize the process and products. The results show that sulfur release is mainly concentrated in two stages: intensive oxidative decomposition of FeS/FeS₂ in the range of 480–580 °C and release of reacted sulfur originally encapsulated within the pellets in the range of 940–1080 °C. It was found that alkali metal oxides CaO and MgO in the feed can fix sulfur at a high temperature. They react with released SO₂ and iron oxides to form Ca/Mg sulfate–iron oxide composite phases, such as (Ca_0.75Mg_0.25)SO₄·0.38Fe₂O₃ and (Ca_0.91Mg_0.09)SO₄·3.66Fe₂O₃·1.47MgO, which slow the SO₂ emission rate. A desulfurization ratio above 99% can be achieved when roasting at 1100 °C and above. This study clarifies the sulfur migration mechanism during the roasting of high-sulfur iron concentrate pellets, providing a theoretical basis for optimizing the roasting process to achieve efficient desulfurization and recovery of iron resources. Full article

This study investigates the adsorption of ibuprofen (IBU) and diclofenac sodium (DS) using bentonite modified with varying amounts (50, 75, and 100% of cation exchange capacity—CEC) of two surfactants: octadecyl(dimethylbenzyl)ammonium (ODMBA) chloride and hexadecyltrimethylammonium (HDTMA) bromide. The resulting organobentonites were characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry/thermogravimetric analysis (DSC/TG), and zeta potential analysis. The results indicated that higher surfactant concentrations in organobentonites improved adsorption efficiencies for both drugs, while ODMBA-modified organobentonites exhibited notably larger adsorption capacities than HDTMA-modified samples. The adsorption isotherms fitted well to both the Langmuir and Freundlich models, with a better fit observed for the Freundlich model. The highest adsorption capacities were 102 mg/g for IBU and 160 mg/g for DS on sample OB-100 (organobentonite with 100% of ODMBA). Characterization of samples after drug adsorption, using FTIR, zeta potential and DSC/TG analysis, confirmed drug presence in organobentonites. Adsorption tests of DS in real river water (Danube and Sava rivers) showed that OB-100 demonstrated high removal capacity for DS. The findings suggest that organobentonites are low-cost adsorbents with potential for the removal of pharmaceutical contaminants from real aquatic environments. Full article

This paper presents the results of a laboratory-based treatability study conducted for a confidential former wood treating site heavily impacted by a creosote non-aqueous-phase liquid (NAPL) containing pentachlorophenol (PCP). PCP impacts in the silty sands extended to approximately 33 ft (10 m) below the ground surface (bgs), with discrete soil samples containing PCP concentrations up to 14,500 mg/kg, and groundwater PCP concentrations forming a main plume exceeding 1 mg/L over 2.16 acres (0.87 ha). Treatability testing was performed on unspiked and NAPL-spiked site soils with total PCP concentrations ranging from 10 to 100 mg/kg, respectively, and leachable PCP concentrations of approximately 3 to 8 mg/L. Stabilization/solidification (S/S) mix designs using 5 to 10 weight percent (wt%, dry-reagent-to-wet-soil mass basis) of a Portland cement (PC) blend and 1 wt% powdered bentonite met the minimum unconfined compressive strength (UCS) and maximum hydraulic conductivity (K) performance criteria of 50 lb/in2 (345 kPa) and 1 × 10⁻⁶ cm/s, respectively, within the specified 28-day cure time. Long-term semi-dynamic leach testing was performed on S/S-treated soils using a modified United States Environmental Protection Agency (EPA) Method 1315 test incorporating a polydimethylsiloxane (PDMS) liner to improve the data reliability for hydrocarbons. Results showed that adding 1 wt% organoclay (OC) to the S/S mix designs did not substantially reduce leaching of common semi-volatile organic compounds (SVOCs) such as naphthalene, acenaphthene, phenanthrene and benzo(a)anthracene compared to mixes using only the PC blend with bentonite, consistent with previous studies. However, the inclusion of OC had a decisive effect on PCP immobilization, providing an order-of-magnitude (10×) reduction in the cumulative mass release of PCP over the test duration. This benefit diminished with decreasing degree of chlorination for other phenolic compounds. Full article

During the construction of underwater shield tunnels (excavated using a slurry pressure balance shield machine), whether seawater (Sw) can be used to replace freshwater (Fw) in the preparation of cement–sodium silicate grout (CSG) has become a major concern in the engineering community. CSG is formed by mixing components A and B, where component A is a liquid prepared by mixing bentonite, cement, and water, and component B is a sodium silicate solution. In this paper, the CSG was prepared using Sw instead of part of Fw. The properties, including bleeding rate, initial and final setting time, gel time, compressive strength, and microscopic characteristics, were tested to investigate the influence of Sw on the performance of CSG and explore its impact mechanism. The results showed that when expanding bentonite with Sw, the bleeding rate of Component A exceeded 50%, failing to meet the engineering requirement of 10%. However, expanding bentonite with Fw, the seawater replacement ratio has almost no effect on Component A, with all values remaining below 10%. As the seawater replacement ratio increases, the setting time of CSG is significantly shortened. Although the inclusion of seawater results in a marginally lower 1-day strength for CSG, it notably boosts the strength at later ages. Specifically, at a 45% seawater replacement ratio, the 28-day strength showed a marked increase of 52% relative to the CSG without seawater. In the later stage of hydration, the positive effect of Cl⁻ in seawater, promoting the hydrolysis of C₃S and C₂S on strength, is significantly higher than the negative effect of sulfate ion erosion in seawater on strength. Therefore, seawater significantly increases the 28-day compressive strength of CSG. This study can provide reference and guidance for the application of seawater in the preparation of two-component grout for submarine shield tunnels. Full article

Model tests are effective for studying the entire deformation and evolution process of reservoir landslides. The sensitivity of similar materials to seepage effects is crucial to the accuracy of landslide model testing. Based on a fuzzy evaluation of in situ sliding zone soil, this study compared three similar materials, using shear tests and microscopic SEM to assess the similarity. The optimal similar material (sliding zone soil: bentonite: standard sand = 50%: 20%: 30%) with a water content of 13.5% and a permeability coefficient of 3.8 × 10⁻⁶ cm/s was identified, simultaneously matching physical–mechanical properties and seepage effects. When the proportion of in situ sliding zone soil exceeds that of bentonite, the in situ sliding zone soil dominates the strength. Cohesion depends on interparticle cementation force and water film viscosity. Bentonite modifies these forces in stages, leading to a trend where cohesion (c′) first increases and then decreases with rising water content, while the internal friction angle (φ’) decreases continuously. Model test results indicate the failure mode of reservoir landslides is a three-stage traction-braking failure, evolving from initial shallow deformation to deep progressive failure and finally to overall large-scale instability. The proposed similar material exhibits reliable physical–mechanical and seepage similarity and can be directly applied in physical model tests of reservoir-induced landslides to reproduce the hydro-mechanical coupling behavior of sliding zones. Full article

This study investigates the impact of multilayer structures and drying strategies on the barrier properties of high-speed starch/bentonite-coated paperboard. The study examines the impact of drying at a high machine speed of 400 m min⁻¹, addressing a key knowledge gap. The hypotheses were that thin multilayer coatings reduce oxygen permeability more effectively than thick single or double coatings and that gentle infrared (IR) drying would be required to achieve this effect. The experiments comprised up to six consecutive coating applications, each providing a dry coat weight between 0.5 and 1.5 g m⁻². The IR dryer power ranged from 207 kW to 829 kW, and different IR frame positions were tested. The results indicated that thin multilayer coatings resulted in fewer pinholes, lower oxygen transmission rates, and improved grease resistance compared with one or two thick layers. However, the effectiveness of the multilayer-coated paperboard was influenced by the employed drying strategy. Specifically, gentle IR drying reduced pinholes, lowered oxygen transmission rates and enhanced grease resistance. Full article

Geopolymers, a class of alkali-activated aluminosilicate binders, have emerged as a sustainable alternative for expansive soil stabilization. In this study, the swelling behavior of geopolymer-treated bentonite was systematically investigated using a Taguchi orthogonal design, complemented by XRD, FTIR, and SEM analyses to elucidate the underlying mechanisms. Specimens were compacted to an initial void ratio of e = 1.1, sealed, and cured under controlled conditions (22 ± 2 °C and 70 ± 2% relative humidity) prior to testing. The free swell ratio (FSR) was determined using a standardized free swelling test in accordance with GB/T 50123-2019, which is technically consistent with ISO 17892-13, under zero vertical surcharge. Each orthogonal condition was tested using a single specimen, and the reported values represent individual measurements. The results show that NaOH concentration is the dominant factor controlling swelling response, with a quantified contribution of 55.04%. The swelling behavior exhibits a distinct two-stage trend, characterized by an initial enhancement at low alkali concentrations followed by a significant suppression beyond a critical threshold of approximately 3 mol/dm³. Microstructural analyses reveal that this transition is governed by a progressive interlayer cation exchange, the structural dissolution of clay minerals, and the formation of geopolymer gel, which densifies the soil matrix and restricts interlayer expansion. These findings provide quantitative and mechanistic insight into the role of alkali activation in expansive clay stabilization and establish a practical concentration threshold for optimizing swelling suppression. Full article