Search Results (40)

Current scheduling strategies for energy storage batteries in agricultural parks generally overlook the issue of battery lifespan degradation, which significantly undermines the system’s economic efficiency and long-term reliability. To address this problem, this paper proposes an optimal scheduling method for integrated energy systems in agricultural parks that takes into account the operational reliability of energy storage batteries. First, a battery capacity degradation model integrating both cycle aging and calendar aging is established, and the reliability of multiple components within the energy storage system is evaluated using Monte Carlo simulation. On this basis, an optimization scheduling model aimed at minimizing the total system operating cost is developed, dynamically balancing economic performance and battery service life. Finally, the proposed method is validated through a practical case study of a facility-based agricultural industrial park. The results demonstrate that, while ensuring stable system operation, the approach effectively extends the service life of energy storage equipment by 8–9 years, reduces the average daily operating cost by 61.94 yuan, and increases the power supply reliability rate to 99.921%. Full article

This work investigated the impact of vehicle-to-grid (V2G) cycling on the service life of lithium-ion cells, using real-world V2G data from commercial electric vehicle (EV) battery chargers. Commercially available cylindrical lithium-ion cells were subjected to long-term storage and V2G cycling under varying state of charge (SOC), depth of discharge (DOD), and temperature conditions. The ageing results demonstrate that elevated temperature (40 °C) is the dominant factor accelerating degradation, particularly at a high storage SOC (>80% SOC) and increased cycle depths (30–80% SOC, 30–95% SOC). A comparison between V2G cycling and calendar ageing over a similar storage period revealed that shallow V2G cycling (30–50% SOC) leads to comparable capacity fade to storage at a high SOC (≥80% SOC). The comparative analysis indicated that 62% of a full equivalent cycle (FEC) of V2G cycling can be achieved daily, without compromising the cell’s lifetime, demonstrating the viability of V2G adoption during EV idle/charging periods, which can offer potential operational benefits in terms of cost reduction and emissions savings. Furthermore, this work introduced the concept of a V2X capability metric as a novel cell-level specification, along with a corresponding experimental evaluation method. Full article

This paper compares two common dispatch policies—Load-Following (LF) and Cycle-Charging (CC)—for a photovoltaic Battery Energy Storage System (PV–BESS) microgrid (MG) with a 12 kW diesel generator, using a full-year of real 15 min PV and load data from an industrial use case in Germany. A forward time-step simulation enforces the battery State-of-Energy (SoE) window (total basis [20, 100] %, DoD = 80%) and computes curtailment, generator use, and unmet energy. Feasible designs satisfy a Loss of Power Supply Probability (LPSP) ≤ 0.03. Economic evaluation follows an Equivalent Annual Cost (EUAC) model with PV and BESS Capital Expenditure/Operation and Maintenance (CAPEX/O&M) (cycle life dependent on DoD and 15-year calendar life), generator costs, and fuel via SFC and diesel price. A value of lost load (VOLL) can be applied to unserved energy, with an optional curtailment penalty. Across the design space, a clear cost valley appears toward moderate storage and modest PV, with the baseline optimum at ≈56 kWp PV and 200 kWh BESS (DoD = 80%). Both policies meet the reliability target (in our runs LPSP ≈ 0), and their SoE trajectories are nearly identical; CC only lifts the SoE slightly after generator-ON events by using headroom to charge, while LF supplies just the residual deficit. Sensitivity analyses show that the optimum is most affected by diesel price and discount rate, with smaller shifts for ±10% changes in SFC. The study provides a transparent, reproducible workflow—grounded in real data—for controller selection and capacity planning. Full article

Digital twins represent a transformative innovation for battery energy storage systems (BESS), offering real-time virtual replicas of physical batteries that enable accurate monitoring, predictive analytics, and advanced control strategies. These capabilities promise to significantly enhance system efficiency, reliability, and lifespan. Yet, despite the clear technical potential, large-scale deployment of digital twin-enabled battery systems faces critical governance barriers. This study identifies three major challenges: fragmented standards and lack of interoperability, weak or misaligned market incentives, and insufficient cybersecurity safeguards for interconnected systems. The central contribution of this research is the development of a comprehensive governance framework that aligns these three pillars—standards, market and regulatory incentives, and cybersecurity—into an integrated model. Findings indicate that harmonized standards reduce integration costs and build trust across vendors and operators, while supportive regulatory and market mechanisms can explicitly reward the benefits of digital twins, including improved reliability, extended battery life, and enhanced participation in energy markets. For example, simulation-based evidence suggests that digital twin-guided thermal and operational strategies can extend usable battery capacity by up to five percent, providing both technical and economic benefits. At the same time, embedding robust cybersecurity practices ensures that the adoption of digital twins does not introduce vulnerabilities that could threaten grid stability. Beyond identifying governance gaps, this study proposes an actionable implementation roadmap categorized into short-, medium-, and long-term strategies rather than fixed calendar dates, ensuring adaptability across different jurisdictions. Short-term actions include establishing terminology standards and piloting incentive programs. Medium-term measures involve mandating interoperability protocols and embedding digital twin requirements in market rules, and long-term strategies focus on achieving global harmonization and universal plug-and-play interoperability. International examples from Europe, North America, and Asia–Pacific illustrate how coordinated governance can accelerate adoption while safeguarding energy infrastructure. By combining technical analysis with policy and governance insights, this study advances both the scholarly and practical understanding of digital twin deployment in BESSs. The findings provide policymakers, regulators, industry leaders, and system operators with a clear framework to close governance gaps, maximize the value of digital twins, and enable more secure, reliable, and sustainable integration of energy storage into future power systems. Full article

This study presents a comprehensive life-cycle assessment of Vehicle-to-Grid (V2G) economic viability, explicitly integrating the costs of both battery cycling degradation and calendar aging. While V2G offers revenue through energy arbitrage, its net profitability is critically dependent on regional electricity price differentials and the associated battery degradation costs. We develop a dynamic cost–benefit model, validated over a 10-year horizon across five diverse regions (Shanghai, Chengdu, the U.S., the U.K., and Australia). The results reveal stark regional disparities: Chengdu (0.65 USD/kWh peak–valley gap) and Australia (0.53 USD/kWh) achieve substantial net revenues of up to USD 25,000 per vehicle, whereas Shanghai’s narrow price differential (0.03 USD/kWh) renders V2G unprofitable. Sensitivity analysis quantifies critical break-even price differentials, varying by EV model and annual mileage (e.g., 0.12 USD/kWh minimum for Tesla Model Y). Crucially, calendar aging emerged as the dominant degradation cost (67% at 10,000 km/year), indicating significant battery underutilization potential. Policy insights emphasize the necessity of targeted interventions, such as Chengdu’s discharge incentives (0.69 USD/kWh), to bridge profitability gaps. This research provides actionable guidance for policymakers, grid operators, and EV owners by quantifying the trade-offs between V2G revenue and battery longevity, enabling optimized deployment strategies. Full article

The worldwide commitment to the electrification of road transport will require a broad overhaul of equipment and infrastructure. Heavy-duty trucks account for over one-third of on-road energy use. Electrified roadways (e-Hwys) are an emerging technology where electric vehicles receive electricity while driving via dynamic wireless power transfer (DWPT), which is becoming highly efficient, and can bypass the battery to directly serve the motor. A modeling study was undertaken to compare long-haul trucks on e-Hwys with conventional battery technology requiring off-road recharging to assess the most favorable pathway to electrification. Detailed data taken from on-road driving trips from five diesel transport trucks were obtained for this study. This on-road data provided the simulations with both real-life duty cycles as well as performance targets for electric trucks, enabling an assessment and comparison of their performance on e-Hwys or with fast recharging. Battery-only trucks were found to have lifetimes down to 60% original battery capacity (60% SOH) of up to 9 years with 1600 kWh packs, and were similar to conventional diesel truck performance. On e-Hwys smaller pack sizes in the 500 to 900 kWh capacity range were sufficient for the driving duty, and showed lifetimes upwards of 20 years, comparing favorably to the battery calendar life limit of about 26 years. For a 535 kWh battery pack, an e-Hwy DWPT level of 250 kW was sufficient for a 36 tonne truck to complete all the daily driving as defined by the diesel reference trucks, and reach a battery pack end of life point of 60% SOH. Full article

The increasing number of electric vehicles (EVs) on the roads has led to a rise in the number of batteries reaching the end of their first life. Such batteries, however, still have a capacity of 75–80% remaining, creating an opportunity for a second life in less power-intensive applications. Utilising these second-life batteries (SLBs) requires specific preparation, including grading the batteries based on their State of Health (SoH); repackaging, considering the end-use requirements; and the development of an accurate battery-management system (BMS) based on validated theoretical models. In this paper, we conduct a technical review of mathematical modelling and experimental analyses of SLBs to address existing challenges in BMS development. Our review reveals that most of the recent research focuses on environmental and economic aspects rather than technical challenges. The review suggests the use of equivalent-circuit models with 2RCs and 3RCs, which exhibit good accuracy for estimating the performance of lithium-ion batteries during their second life. Furthermore, electrochemical impedance spectroscopy (EIS) tests provide valuable information about the SLBs’ degradation history and conditions. For addressing calendar-ageing mechanisms, electrochemical models are suggested over empirical models due to their effectiveness and efficiency. Additionally, generating cycle-ageing test profiles based on real application scenarios using synthetic load data is recommended for reliable predictions. Artificial intelligence algorithms show promise in predicting SLB cycle-ageing fading parameters, offering significant time-saving benefits for lab testing. Our study emphasises the importance of focusing on technical challenges to facilitate the effective utilisation of SLBs in stationary applications, such as building energy-storage systems and EV charging stations. Full article

The aging process of lithium-ion batteries is an extremely complex process, and the prediction of the calendar life of the lithium-ion battery is important to further guide battery maintenance, extend the battery life and reduce the risk of battery use. In the uninterruptible power supply (UPS) system, the battery is in a floating state for a long time, so the aging of the battery is approximated by calendar aging, and its decay rate is slow and difficult to estimate accurately. This paper proposes a particle filtering-based algorithm for battery state-of-health (SOH) and remaining useful life (RUL) predictions. First, the calendar aging modeling for the batteries used in the UPS system for the Shanghai rail transportation energy storage power station is presented. Then, the particle filtering algorithm is employed for the SOH estimation and RUL prediction for the single-cell battery calendar aging model. Finally, the single-cell SOH and RUL estimation algorithm is expanded to the pack and group scales estimation. The experimental results indicate that the proposed method can achieve accurate SOH estimation and RUL prediction results. Full article

Due to their high energy density, long calendar life, and environmental protection, lithium-ion batteries have found widespread use in a variety of areas of human life, including portable electronic devices, electric vehicles, and electric ships, among others. However, there are safety issues with lithium-ion batteries themselves that must be emphasized. The safety of lithium-ion batteries is receiving increasing amounts of attention as incidents such as fires and explosions caused by thermal runaway have caused significant property damage and fatalities. Thermal runaway can easily occur when lithium-ion batteries experience issues such as electrical abuse and thermal abuse. This study compares various monitoring, warning, and protection techniques, summarizes the current safety warning techniques for thermal runaway of lithium-ion batteries, and combines the knowledge related to thermal runaway. It also analyzes and forecasts the future trends of battery thermal runaway monitoring, warning, and protection. Full article

Due to their low cost, suitable working potential and high stability, carbon materials have become an irreplaceable anode material for alkali ion batteries, such as lithium ion batteries, sodium ion batteries and potassium ion batteries. During the initial charge, electrolyte is reduced to form a solid electrolyte interphase (SEI) on the carbon anode surface, which is an electron insulator but a good ion conductor. Thus, a stable surface passivation is obtained, preventing the decomposition of electrolyte in the following cycles. It has been widely accepted that SEI is essential for the long-term performance of batteries, such as calendar life and cycle life. Additionally, the initial coulombic efficiency, rate capability as well as safety of the batteries are dramatically influenced by the SEI. Extensive research efforts have been made to develop advanced SEI on carbon materials via optimization of electrolytes, including solutes, solvents and additives, etc. However, SEI is produced via the catalytic decomposition of electrolyte by the surface of electrode materials. The surface structure of the carbon material is another important aspect that determines the structure and property of SEI, which little attention has been paid to in previous years. Hence, this review is dedicated to summarizing the impact of the surface structure of carbon materials on the composition, structure and electrochemical performance of the SEI in terms of surface atoms exposed, surface functionalization, specific surface area and pore structure. Some insights into the future development of SEI from the perspective of carbon surface are also offered. Full article

Battery aging is one of the key challenges that electrochemical energy storage faces. Models for both cycling and calendar aging are valuable for quantitatively assessing their contribution to overall capacity loss. Since batteries are stored and employed under varying conditions of temperature and state of charge in their real-life operation, the availability of a suitable model to anticipate the outcome of calendar aging in lithium-ion batteries under dynamic conditions is of great interest. In this article, we extend a novel model to predict the capacity loss due to calendar aging by using variable-order fractional calculus. For this purpose, some theoretical difficulties posed by variable-order definitions are discussed and compared by applying them to fit experimental results with a multi-parameter optimization procedure. We show that employing a variable-order model allows for a significant improvement in accuracy and predictive ability with respect to its constant-order counterpart. We conclude that variable-order models constitute an interesting alternative for reproducing complex behavior in dynamical systems, such as aging in lithium-ion batteries. Full article

Instead of storing the energy produced by photovoltaic panels in batteries for later use to power electric loads, green hydrogen can also be produced and used in transportation, heating, and as a natural gas alternative. Green hydrogen is produced in a process called electrolysis. Generally, the electrolyser can generate hydrogen from a fluctuating power supply such as renewables. However, due to the startup time of the electrolyser and electrolyser degradation accelerated by multiple shutdowns, an idle mode is required. When in idle mode, the electrolyser uses 10% of the rated electrolyser load. An energy management system (EMS) shall be applied, where a storage technology such as a lithium-ion capacitor or lithium-ion battery is used. This paper uses a state-machine EMS of PV microgrid for green hydrogen production and energy storage to manage the hydrogen production during the morning from solar power and in the night using the stored energy in the energy storage, which is sized for different scenarios using a lithium-ion capacitor and lithium-ion battery. The mission profile and life expectancy of the lithium-ion capacitor and lithium-ion battery are evaluated considering the system’s local irradiance and temperature conditions in the Australian climate. A tradeoff between storage size and cutoffs of hydrogen production as variables of the cost function is evaluated for different scenarios. The lithium-ion capacitor and lithium-ion battery are compared for each tested scenario for an optimum lifetime. It was found that a lithium-ion battery on average is 140% oversized compared to a lithium-ion capacitor, but a lithium-ion capacitor has a smaller remaining capacity of 80.2% after ten years of operation due to its higher calendar aging, while LiB has 86%. It was also noticed that LiB is more affected by cycling aging while LiC is affected by calendar aging. However, the average internal resistance after 10 years for the lithium-ion capacitor is 264% of the initial internal resistance, while for lithium-ion battery is 346%, making lithium-ion capacitor a better candidate for energy storage if it is used for grid regulation, as it requires maintaining a lower internal resistance over the lifetime of the storage. Full article

Battery lifetime is an important parameter in the life cycle assessment (LCA) of a plug-in hybrid-electric vehicle (PHEV). This paper aims to study the impact of various parameters on the battery aging of a PHEV. For this purpose, model-based use cases are generated, the outputs of which are the daily driven distances for a period of one year, recharge scenarios, and battery temperature. A combined aging model (calendar and cycling aging) is used to calculate the capacity lost by the battery at the end of one year of use. The thermal model of the battery is using an electro-thermal coupling equation, for which the ambient temperature is modeled using daily minimum and maximum temperature data varying throughout the year for different cities. Finally, a sensitivity analysis is carried out using the conditioned variance method to identify the most important input parameters which largely affect the output of this study. The results of this study show that battery size, annual mileage, external temperature, and charging behavior are the most important parameters to be considered in the aging study of the battery of a PHEV personal car. Full article

Several electrode materials have been developed to provide high energy density and a long calendar life at a low cost for lithium-ion batteries (LIBs). Iron (III) vanadate (FeVO₄), a semiconductor material that follows insertion/extraction chemistry with a redox reaction and provides high theoretical capacity, is an auspicious choice of anode material for LIBs. The correlation is investigated between calcination temperatures, morphology, particle size, physicochemical properties, and their effect on the electrochemical performance of FeVO₄ under different binders. The crystallite size, particle size, and tap density increase while the specific surface area (S_BET) decreases upon increasing the calcination temperature (500 °C, 600 °C, and 700 °C). The specific capacities are reduced by increasing the calcination temperature and particle size. Furthermore, FeVO₄ fabricated with different binders (35 wt.% PAA and 5 wt.% PVDF) and their electrochemical performance for LIBs was explored regarding the effectiveness of the PAA binder. FV500 (PAA and PVDF) initially delivered higher discharge/charge capacities of 1046.23/771.692 mAhg⁻¹ and 1051.21/661.849 mAhg⁻¹ compared to FV600 and FV700 at the current densities of 100 mAg⁻¹, respectively. The intrinsic defects and presence of oxygen vacancy along with high surface area and smaller particle sizes efficiently enhanced the ionic and electronic conductivities and delivered high discharge/charge capacities for FeVO₄ as an anode for LIBs. Full article

In this paper, capacity fade of LiFeYPO₄/graphite commercial cells during 116 cycles under different temperatures is studied. The cells were discharged in two modes, during Drive Cycle (DrC) discharge cycles the cell was discharged with current waveform calculated for example battery electric vehicle (BEV) under WLTC 3b drive cycle conditions, whereas during Constant Current (CC) discharge cycles the cell was discharged with a constant current of the same root mean square of the current, as the WLTC 3b current waveform and with the same depth of discharge. All the cells were charged in constant current/constant voltage mode. Two fresh cells were used for each discharge mode at 25 °C and as the results were similar, only one cell per discharge mode was used at the other temperatures 5 °C and 45 °C. Furthermore, simulation P2D model of calendar and cycle life was calibrated based on experimental data. SoC floating was observed during cycling for both discharge modes, accompanied with slight increase in end discharge voltage and growth of energy efficiency. Concluding the results for 25 °C, not waveform character, but the amount of electric charge in combination with calendar aging has the most effect on the cycle life, which is also proved by the simulation. For 5 °C, the capacity fade is milder for DrC discharge cycles, but simulation results do not prove that, which would demand further investigation. The results for 45 °C are apparently dependent on a higher amount of discharged and charged electric charge and influenced by calendar life, simulated capacity fade corresponds quite well to the experiment. The best State of Health (SoH) simulation results are for temperature 45 °C, RMSE is 0.10% SoH, for the other temperatures RMSE is 0.20 and 0.93% SoH for 25 and 5 °C, respectively. Full article