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Keywords = basalt fiber morphology

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27 pages, 15704 KiB  
Article
Study on Mechanical Properties of Composite Basalt Fiber 3D-Printed Concrete Based on 3D Meso-Structure
by Shengxuan Ding, Jiren Li and Mingqiang Wang
Materials 2025, 18(14), 3379; https://doi.org/10.3390/ma18143379 - 18 Jul 2025
Viewed by 441
Abstract
As 3D concrete printing emerges as a transformative construction method, its structural safety remains hindered by unresolved issues of mechanical anisotropy and interlayer defects. To address this, we systematically investigate the failure mechanisms and mechanical performance of basalt fiber-reinforced 3D-printed magnesite concrete. A [...] Read more.
As 3D concrete printing emerges as a transformative construction method, its structural safety remains hindered by unresolved issues of mechanical anisotropy and interlayer defects. To address this, we systematically investigate the failure mechanisms and mechanical performance of basalt fiber-reinforced 3D-printed magnesite concrete. A total of 30 cube specimens (50 mm × 50 mm × 50 mm)—comprising three types (Corner, Stripe, and R-a-p)—were fabricated and tested under compressive and splitting tensile loading along three orthogonal directions using a 2000 kN electro-hydraulic testing machine. The results indicate that 3D-printed concrete exhibits significantly lower strength than cast-in-place concrete, which is attributed to weak interfacial bonds and interlayer pores. Notably, the R-a-p specimen’s Z-direction compressive strength is 38.7% lower than its Y-direction counterpart. To complement the mechanical tests, DIC, CT scanning, and SEM analyses were conducted to explore crack development, internal defect morphology, and microstructure. A finite element model based on the experimental data successfully reproduced the observed failure processes. This study not only enhances our understanding of anisotropic behavior in 3D-printed concrete but also offers practical insights for print-path optimization and sustainable structural design. Full article
(This article belongs to the Special Issue 3D Printing Materials in Civil Engineering)
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27 pages, 5072 KiB  
Article
Study on the Mechanical Properties of Optimal Water-Containing Basalt Fiber-Reinforced Concrete Under Triaxial Stress Conditions
by Kaide Liu, Songxin Zhao, Yaru Guo, Wenping Yue, Chaowei Sun, Yu Xia, Qiyu Wang and Xinping Wang
Materials 2025, 18(14), 3358; https://doi.org/10.3390/ma18143358 - 17 Jul 2025
Viewed by 213
Abstract
In response to the high-performance requirements of concrete materials under complex triaxial stress states and water-containing environments in marine engineering, this study focuses on water-containing basalt fiber-reinforced concrete (BFRC). Uniaxial compression and splitting tensile tests were conducted on specimens with different fiber contents [...] Read more.
In response to the high-performance requirements of concrete materials under complex triaxial stress states and water-containing environments in marine engineering, this study focuses on water-containing basalt fiber-reinforced concrete (BFRC). Uniaxial compression and splitting tensile tests were conducted on specimens with different fiber contents (0.0%, 0.05%, 0.10%, 0.15%, and 0.20%) to determine the optimal fiber content of 0.1%. The compressive strength of the concrete with this fiber content increased by 13.5% compared to the control group without fiber, reaching 36.90 MPa, while the tensile strength increased by 15.9%, reaching 2.33 MPa. Subsequently, NMR and SEM techniques were employed to analyze the internal pore structure and micro-morphology of BFRC. It was found that an appropriate amount of basalt fiber (content of 0.1%) can optimize the pore structure and form a reticular three-dimensional structure. The pore grading was also improved, with the total porosity decreasing from 7.48% to 7.43%, the proportion of harmless pores increasing from 4.03% to 4.87%, and the proportion of harmful pores decreasing from 1.67% to 1.42%, thereby significantly enhancing the strength of the concrete. Further triaxial compression tests were conducted to investigate the mechanical properties of BFRC under different confining pressures (0, 3, and 6 MPa) and water contents (0%, 1%, 2%, and 4.16%). The results showed that the stress–strain curves primarily underwent four stages: initial crack compaction, elastic deformation, yielding, and failure. In terms of mechanical properties, when the confining pressure increased from 0 MPa to 6 MPa, taking dry sandstone as an example, the peak stress increased by 54.0%, the elastic modulus increased by 15.7%, the peak strain increased by 37.0%, and the peak volumetric strain increased by 80.0%. In contrast, when the water content increased from 0% to 4.16%, taking a confining pressure of 0 MPa as an example, the peak stress decreased by 27.4%, the elastic modulus decreased by 43.2%, the peak strain decreased by 59.3%, and the peak volumetric strain decreased by 106.7%. Regarding failure characteristics, the failure mode shifted from longitudinal splitting under no confining pressure to diagonal shear under confining pressure. Moreover, as the confining pressure increased, the degree of failure became more severe, with more extensive cracks. However, when the water content increased, the failure degree was relatively mild, but it gradually worsened with further increases in water content. Based on the CDP model, a numerical model for simulating the triaxial compression behavior of BFRC was developed. The simulation results exhibited strong consistency with the experimental data, thereby validating the accuracy and applicability of the model. Full article
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23 pages, 3120 KiB  
Article
An Experimental Study on the Effects of Basalt Fiber and Iron Ore Tailings on the Durability of Recycled Concrete
by Yang Zhang, Xu-Hui Wang and Xian-Jie Tang
Buildings 2025, 15(14), 2492; https://doi.org/10.3390/buildings15142492 - 16 Jul 2025
Viewed by 300
Abstract
To elucidate the effects of iron ore tailings (IOTs) and basalt fiber (BF) on the durability of recycled aggregate concrete (RAC) with different recycled aggregate replacement rates, this study used IOTs to replace natural sand at mass replacement rates of 0%, 20%, 40%, [...] Read more.
To elucidate the effects of iron ore tailings (IOTs) and basalt fiber (BF) on the durability of recycled aggregate concrete (RAC) with different recycled aggregate replacement rates, this study used IOTs to replace natural sand at mass replacement rates of 0%, 20%, 40%, 60%, 80%, and 100% and incorporated BF at volume fractions of 0%, 0.1%, 0.2%, and 0.3%. Carbonation and freeze–thaw cycle tests were conducted on C30 grade RAC. The carbonation depth and compressive strength of RAC at different carbonation ages and the mass loss rate, relative dynamic elastic modulus, and changes in compressive strength of RAC under different freeze–thaw cycle times were determined. Scanning electron microscopy (SEM) was utilized to meticulously observe the micro-morphological alterations of BF-IOT-RAC before and after carbonation. We then investigated the mechanisms by which BF and IOTs enhance the carbonation resistance of RAC. Utilizing the experimental data, we fitted relevant models to establish both a carbonation depth prediction model and a freeze–thaw damage prediction model specific to BF-IOT-RAC. Furthermore, we projected the service life of BF-IOT-RAC under conditions typical of northwest China. The results showed that as the dosages of the two materials increased, the carbonation resistance and frost resistance of RAC initially improved and then declined. Specifically, the optimal volume content of BF was ascertained to be 0.1%, while the optimal replacement rate of IOTs was determined to be 40%. Compared to using BF or IOTs individually, the composite incorporation of both materials significantly improves the durability of RAC while simultaneously enhancing the reuse of construction waste and mining solid waste, thereby contributing to environmental sustainability. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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24 pages, 7576 KiB  
Article
Study on the Damage Evolution Mechanism of FRP-Reinforced Concrete Subjected to Coupled Acid–Freeze Erosion
by Fei Li, Wei Li, Shenghao Jin, Dayang Wang, Peifeng Cheng and Meitong Piao
Coatings 2025, 15(7), 759; https://doi.org/10.3390/coatings15070759 - 26 Jun 2025
Viewed by 470
Abstract
Plain concrete specimens and FRP(Fiber Reinforced Polymer)-reinforced concrete specimens were fabricated to investigate concrete’s mechanical and surface degradation behaviors reinforced with carbon, basalt, glass, and aramid fiber-reinforced polymer under coupled sulfuric acid and freeze–thaw cycles. The compressive strength of fully wrapped FRP cylindrical [...] Read more.
Plain concrete specimens and FRP(Fiber Reinforced Polymer)-reinforced concrete specimens were fabricated to investigate concrete’s mechanical and surface degradation behaviors reinforced with carbon, basalt, glass, and aramid fiber-reinforced polymer under coupled sulfuric acid and freeze–thaw cycles. The compressive strength of fully wrapped FRP cylindrical specimens and the flexural load capacity of prismatic specimens with FRP reinforced to the pre-cracked surface, along with the dynamic elastic modulus and mass loss, were evaluated before and after acid–freeze cycles. The degradation mechanism of the specimens was elucidated through analysis of surface morphological changes captured in photographs, scanning electron microscopy (SEM) observations, and energy-dispersive spectroscopy (EDS) data. The experimental results revealed that after 50 cycles of coupled acid–freeze erosion, the plain cylindrical concrete specimens showed a mass gain of 0.01 kg. In contrast, after 100 cycles, a significant mass loss of 0.082 kg was recorded. The FRP-reinforced specimens initially demonstrated mass loss trends comparable to those of the plain concrete specimens. However, in the later stages, the FRP confinement effectively mitigated the surface spalling of the concrete, leading to a reversal in mass loss and subsequent mass gain. Notably, the GFRP(Glassfiber Reinforced Polymer)-reinforced specimens exhibited the most significant mass gain of 1.653%. During the initial 50 cycles of acid–freeze erosion, the prismatic and cylindrical specimens demonstrated comparable degradation patterns. However, in the subsequent stages, FRP reduced the exposed surface area-to-volume ratio of the specimens in contact with the acid solution, resulting in a marked improvement in their structural integrity. After 100 cycles of acid–freeze erosion, the compressive strength loss rate and flexural load capacity loss rate followed the ascending order: CFRP-reinforced < BFRP(Basalt Fiber Reinforced Polymer)-reinforced < AFRP(Aramid Fiber Reinforced Polymer)-reinforced < GFRP-reinforced < plain specimens. Conversely, the ductility ranking from highest to lowest was AFRP/GFRP > control group > BFRP/CFRP. A probabilistic analysis model was established to complement the experimental findings, encompassing the quantification of hazard levels and reliability indices. Full article
(This article belongs to the Special Issue Surface Treatments and Coatings for Asphalt and Concrete)
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20 pages, 14949 KiB  
Article
The Impact of Redox Atmosphere on the High-Temperature Melting Behavior of Basalt Materials
by Kaiwen Shi, Guanli Xu, Di Wu, Zhen Li, Hao Wang, Huaiming Liu, Jie Li and Jiangfan Liang
Minerals 2025, 15(6), 596; https://doi.org/10.3390/min15060596 - 2 Jun 2025
Viewed by 377
Abstract
This study systematically reveals the fundamental mechanisms controlling redox-induced phase transformations occurring in basalt melting processes via integrated high-temperature redox experiments combined with thermodynamic simulations. Our findings demonstrate that oxidizing conditions drive clinopyroxene dissolution and concurrent crystallization of refractory phases—hematite [(Fe,Ti,Al)2O [...] Read more.
This study systematically reveals the fundamental mechanisms controlling redox-induced phase transformations occurring in basalt melting processes via integrated high-temperature redox experiments combined with thermodynamic simulations. Our findings demonstrate that oxidizing conditions drive clinopyroxene dissolution and concurrent crystallization of refractory phases—hematite [(Fe,Ti,Al)2O3] and magnesioferrite [(Mg,Fe)(Fe,Al)2O4]—where distinct crystallization pathways govern magnesioferrite morphology evolution. Conversely, reducing environments suppress oxide mineral formation while promoting phase transformation from high-melting-point plagioclase to low-melting-point clinopyroxene solid solutions, thus lowering the system’s liquidus temperature to achieve full melting. This provides a theoretical basis for optimizing energy consumption in basalt fiber production and offers new insights into the effects of material melting temperature. Full article
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21 pages, 4445 KiB  
Article
The Mechanical Properties and Durability of the PE-BFRP Hybrid-Fiber-Engineered Cementitious Composite (ECC)
by Shasha Xu, Wei Li, Xuezhen Wang, Hongze Zhang, Ju Liu, Hui Jiang, Xuebin Wang, Hongke Ma, Jun Shi, Zhenyun Yu and Kuangyu Dai
Buildings 2025, 15(11), 1860; https://doi.org/10.3390/buildings15111860 - 28 May 2025
Viewed by 419
Abstract
This paper investigates the effects of the basalt-fiber-reinforced polymer (BFRP) and polyethylene (PE) hybrid fiber ratio on the mechanical properties and durability of engineered cementitious composites (ECC). First, four different PE-BFRP hybrid fiber ECC mixtures were systematically prepared by controlling the fiber volume [...] Read more.
This paper investigates the effects of the basalt-fiber-reinforced polymer (BFRP) and polyethylene (PE) hybrid fiber ratio on the mechanical properties and durability of engineered cementitious composites (ECC). First, four different PE-BFRP hybrid fiber ECC mixtures were systematically prepared by controlling the fiber volume ratio of PE and BFRP fibers. The workability and mechanical properties of the hybrid fiber ECC (HFECC) were then evaluated using flowability tests and multi-scale mechanical tests, including compressive strength, flexural strength, bending toughness, and tensile performance. After that, the durability of HFECC with different fiber ratios was comprehensively assessed through freeze–thaw cycle tests and rapid ion migration tests. Finally, the interface morphology of fibers within the matrix was observed using scanning electron microscopy (SEM). The results show that an appropriate hybrid of PE and BFRP fibers can synergistically enhance the crack resistance and toughness of ECC, improving its failure mode. The best performance in terms of flowability and mechanical properties was observed for the HFECC mixture with 1.30% PE fiber volume and 0.30% BFRP fiber volume. With the increase in BFRP fiber content, the freeze–thaw resistance and chloride ion erosion resistance of HFECC were gradually enhanced. This study provides experimental and theoretical support for the design and engineering application of high-performance hybrid fiber ECC materials. Full article
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13 pages, 1887 KiB  
Article
Polymer-Based Thermal Protective Composites: The Role of Reinforcement and Matrix in Providing Strength and Fire Resistance
by Mohammed Meiirbekov, Assem Kuandyk, Mukhammed Sadykov, Meiir Nurzhanov, Nurmakhan Yesbolov, Berdiyar Baiserikov, Ilyas Ablakatov, Laura Mustafa, Botagoz Medyanova, Arman Kulbekov, Sunkar Orazbek and Abussaid Yermekov
Polymers 2025, 17(10), 1419; https://doi.org/10.3390/polym17101419 - 21 May 2025
Viewed by 593
Abstract
This study addresses the need for thermomechanically robust materials for high-temperature environments by investigating fabric-reinforced composites produced through polymer infiltration and thermal pressing using phenol-formaldehyde (PF) and epoxy (ER) resins. Experimental validation was required due to the lack of comparative data across different [...] Read more.
This study addresses the need for thermomechanically robust materials for high-temperature environments by investigating fabric-reinforced composites produced through polymer infiltration and thermal pressing using phenol-formaldehyde (PF) and epoxy (ER) resins. Experimental validation was required due to the lack of comparative data across different textile reinforcements under identical conditions. Seven technical fabrics—carbon, aramid, basalt, silica, fiberglass, asbestos, and a carbon/aramid hybrid—were used as reinforcements. Mechanical testing revealed that carbon- and hybrid fiber composites exhibited the highest tensile (up to 465 MPa) and compressive strengths (up to 301 MPa), particularly when combined with ER. Conversely, the use of PF generally resulted in a 30–50% reduction in mechanical strength. However, PF-based composites demonstrated superior thermal resistance, with the silica/PF combination showing the lowest back-face temperature (401 °C), up to 37% lower than other pairings. Thermal conductivity ranged from 0.041 to 0.51 W/m·K, with PF-based systems offering 6–12% lower values on average compared to ER-based analogs. Morphological analysis confirmed better interfacial bonding in ER composites, while PF systems showed higher structural integrity under thermal loading. Overall, the results emphasize the trade-offs between mechanical strength and thermal protection depending on the fabric–resin combination. Among all variants, the silica fabric with PF demonstrated the most balanced performance, making it a promising candidate for thermomechanical applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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23 pages, 17695 KiB  
Article
Exploring Pore Structure Features, Crack Propagation and Failure Behavior of Fiber Reinforced Foam Tail Fill by CT Imaging and 3D Reconstruction
by Tingting Jiang, Shuai Cao and Erol Yilmaz
Minerals 2025, 15(4), 354; https://doi.org/10.3390/min15040354 - 28 Mar 2025
Cited by 1 | Viewed by 555
Abstract
Fiber-reinforced foam tail fill (FRFTF) has been widely investigated in the field of foamed backfill because of its high strength and toughness. However, the fiber enhancement and damage mechanism of FRFTF still need to be further explored. The pore crack growth and particle [...] Read more.
Fiber-reinforced foam tail fill (FRFTF) has been widely investigated in the field of foamed backfill because of its high strength and toughness. However, the fiber enhancement and damage mechanism of FRFTF still need to be further explored. The pore crack growth and particle structure distribution features of three kinds of basalt (B), polypropylene (PP), and glass (G) fibers on FRFTF were explored. The porosity, fracture, sphericity, and fractal dimension of FRFTF were quantitatively probed by X-ray micro-computed tomography combined with uniaxial compression (UCS) and SEM, while the spatial distribution of porosity and fracture of FRFTF was analyzed by 3D reconstruction technology. Laboratory findings demonstrate that the porosity of glass fiber increases from 1.46% to 4.74% with the increase of fiber content from 0.3% to 0.9%. This is related to the weak adhesion between the backfill and the fiber. Adding fiber and blowing agents could well enhance the pore distribution and morphology of FRFTF, reduce the number of principal cracks trapped within backfill specimens, and maintain the structure’s integrity. The relationship between FRFTF’s UCS value and porosity/fracture is closely related to the nature and quantity of fibers, and the overall performance of glass fiber is the best among others. As the quality of glass fiber shifts from 0.3% to 0.9%, the fill specimen’s UCS value is adversely correlated with the porosity. In the current study, the internal connection and damage mechanism of FRFTFs are studied microscopically. The combination of macro-mechanical strength and microscopic mechanism provides a new research idea for FRFTF materials during the implementation of the fully mechanized mining technology in hard rock mines. Full article
(This article belongs to the Special Issue Cemented Mine Waste Backfill: Experiment and Modelling: 2nd Edition)
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17 pages, 6327 KiB  
Article
Enhanced Mechanical and Acoustic Properties of Basalt Fiber/Polyurethane Composites by Silane Coupling Agents
by Mengchen Ge, Xiaodong Li, Fei Han, Xing Su, Hao Jiang, Youhao Liu, Yangwei Wang and Meishuai Zou
Polymers 2025, 17(1), 61; https://doi.org/10.3390/polym17010061 - 29 Dec 2024
Cited by 7 | Viewed by 1565
Abstract
Modified basalt microfiber-reinforced polyurethane elastomer composites were prepared by a semi-prepolymer method with two different silane coupling agents (KH550 and KH560) in this study. Infrared spectroscopy was used to quantify the degree of microphase separation and analyze the formation of hydrogen bonding in [...] Read more.
Modified basalt microfiber-reinforced polyurethane elastomer composites were prepared by a semi-prepolymer method with two different silane coupling agents (KH550 and KH560) in this study. Infrared spectroscopy was used to quantify the degree of microphase separation and analyze the formation of hydrogen bonding in polyurethane. The interfacial surface and the morphology of fibers and composites from tensile fracture were examined by a scanning electron microscope. Further measurements were performed on an electronic universal testing machine for characterizing the mechanical properties of composites. Moreover, the loss factor and transmission loss of composite materials were obtained from dynamic thermomechanical analysis and acoustic impedance tube, respectively. The suitable concentrations in the modification of basalt fibers were established at 1% for KH550 and 1.5% for KH560. The best overall performance was obtained in KH550-BMF/PUE group, as the properties increased by 31% in tensile strength, 37% in elongation at break, and 21% in acoustic insulation. Full article
(This article belongs to the Special Issue Processing, Characterization and Modeling of Polymer Nanocomposites)
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17 pages, 6382 KiB  
Article
Tribological Performance of Short Fibers Reinforced Thermoplastic Polyurethane Composite Materials Under Water-Lubricated Condition
by Yicong Yu, Pan Jiang, Wei Yu and Zhiwei Guo
Polymers 2025, 17(1), 30; https://doi.org/10.3390/polym17010030 - 26 Dec 2024
Viewed by 949
Abstract
The water-lubricated bearing plays a crucial role in the ship propulsion system, significantly impacting vessel safety. However, under the harsh working conditions of low-speed and heavy-load, the lubrication state of water-lubricated bearings is usually poor, leading to serious friction and wear. To improve [...] Read more.
The water-lubricated bearing plays a crucial role in the ship propulsion system, significantly impacting vessel safety. However, under the harsh working conditions of low-speed and heavy-load, the lubrication state of water-lubricated bearings is usually poor, leading to serious friction and wear. To improve the tribological performance of composites and reduce friction, three short fibers (ultra-high-molecular-weight polyethylene fibers, basalt fibers, and bamboo fibers) with the same mass fraction (5%) were added into the melted thermoplastic polyurethane (TPU). The tribological behavior of these three composites under different loads and rotation speeds was investigated using the CBZ-1 friction and wear tester. Through the comprehensive analysis of the friction coefficient, the wear mass loss, and the surface morphology, it was confirmed that the filled fiber positively affected the tribological performance of thermoplastic polyurethane materials. The experimental results indicated that basalt fiber significantly improved the tribological performance of TPU, and the friction coefficient of the sample was only 0.088 under the working conditions of 0.5 MPa and 250 r/min, which was 70.57% lower than that of pure TPU material. And in all the tests, the minimum wear of the basalt fiber-reinforced composite is only 0.4 mg, which is also the smallest of all the materials under all conditions, and a decrease of 98.69% compared to TPU. Under high loads, ultra-high-molecular-weight polyethylene fiber and bamboo fiber-reinforced composites have smoother surfaces and exhibit better tribological properties. This study provides an experimental foundation for tribological performance enhancement for environmentally friendly, water-lubricated bearing composites. Full article
(This article belongs to the Special Issue Advances in Functional Rubber and Elastomer Composites II)
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19 pages, 7044 KiB  
Article
Analysis of Tensile Failure Behavior of Metal Fiber Laminates Under Different Temperature Environments
by Hongbin Lu, Dongfa Sheng, Yuting Fang, Hongquan Yu and Fan Yang
Polymers 2024, 16(23), 3319; https://doi.org/10.3390/polym16233319 - 27 Nov 2024
Cited by 3 | Viewed by 1024
Abstract
The tensile properties of fiber metal laminates were examined at temperatures ranging from 30 °C to 180 °C in this paper through the integration of numerical simulation techniques, experimental measurements, and digital image correlation techniques. The laminates were initially modeled using finite elements, [...] Read more.
The tensile properties of fiber metal laminates were examined at temperatures ranging from 30 °C to 180 °C in this paper through the integration of numerical simulation techniques, experimental measurements, and digital image correlation techniques. The laminates were initially modeled using finite elements, and the failure behavior of porous basalt-fiber-reinforced aluminum alloy plates was numerically simulated. Consequently, metal fiber laminate stress–strain responses were varied by numerous tensile experiments conducted at varying temperatures. Simultaneously, a scanning electron microscope was used to scan a porous basalt-fiber-reinforced aluminum alloy laminate at different temperatures to determine the tensile mechanical behavior and micro-damage morphology. Lastly, the laminate’s dynamic response to the tensile process was observed through digital image correlation technology. The stress distribution was determined to be concentrated around circular openings through analysis. The strain distribution graph exhibited a “band” shape as the number of perforations increased. The findings indicate that fiber metal laminates lose tensile strength as temperatures increase. The ultimate tensile strength of the laminate decreases as the number of perforations increases at the same temperature. Complex damage mechanisms, including matrix debonding, fiber withdrawal, and matrix fracture, can be captured through scanning electron microscopy at varying temperatures. The tensile behavior and damage mechanisms of laminates with hole-containing structures under thermal conditions are examined, and the results can be used to inform the design and utilization of laminate structures. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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19 pages, 6344 KiB  
Article
Influence of Basalt Fiber Morphology on the Properties of Asphalt Binders and Mixtures
by Chenhao Cai, Keke Lou, Fuxin Qian and Peng Xiao
Materials 2024, 17(21), 5358; https://doi.org/10.3390/ma17215358 - 1 Nov 2024
Cited by 4 | Viewed by 1272
Abstract
Basalt fiber (BF) has been proven to be an effective additive for improving the properties of asphalt mixtures. However, the influence of basalt fiber morphology on the properties of asphalt binders and mixtures remains inadequately explored. In this study, chopped basalt fiber (CBF) [...] Read more.
Basalt fiber (BF) has been proven to be an effective additive for improving the properties of asphalt mixtures. However, the influence of basalt fiber morphology on the properties of asphalt binders and mixtures remains inadequately explored. In this study, chopped basalt fiber (CBF) and flocculent basalt fiber (FBF) were selected to make samples for testing the influence of the two types of basalt fibers on asphalt materials. Fluorescence microscopy was used to obtain the dispersion of fiber in asphalt binders. Then, a temperature sweep test and a multiple stress creep recovery (MSCR) test were carried out to appraise the rheological characteristics of the binder. Moreover, the performance of the fiber-reinforced asphalt mixture was evaluated by a wheel tracking test, a uniaxial penetration test, an indirect tensile asphalt cracking test (IDEAL-CT), a low-temperature bending test, a water-immersion stability test, and a freeze–thaw splitting test. The results indicate that the rheological behavior of asphalt binders could be enhanced by both types of fibers. Notably, FBFs exhibit a larger contact area with asphalt mortar compared to CBFs, resulting in improved resistance to deformation under identical shear conditions. Meanwhile, the performance of the asphalt mixture underwent different levels of enhancement with the incorporation of two morphologies of basalt fiber. Specifically, as for the road property indices with FBFs, the enhancement extent of DS in the wheel tracking test, that of RT in the uniaxial penetration test, that of the CTindex in the IDEAL-CT test, and that of εB in the low-temperature trabecular bending test was 3.1%, 6.8%, 15.1%, and 6.5%, respectively, when compared to the CBF-reinforced mixtures. Compared with CBFs, FBFs significantly enhanced the elasticity and deformation recovery ability of asphalt mixtures, demonstrating greater resistance to high-temperature deformation and a more pronounced effect in delaying the onset of middle- and low-temperature cracking. Additionally, the volume of the air void for asphalt mixtures containing FBFs was lower than that containing CBFs, thereby reducing the likelihood of water damage due to excessive voids. Consequently, the moisture susceptibility enhancement of CBFs to asphalt mixture was not obvious, while FBFs could improve moisture susceptibility by more than 20%. Overall, the impact of basalt fibers with different morphologies on the properties of asphalt pavement materials varies significantly, and the research results may provide reference values for the choice of engineering fibers. Full article
(This article belongs to the Special Issue Mechanical Property Research of Advanced Asphalt-Based Materials)
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20 pages, 8018 KiB  
Article
Extrusion Parameters Optimization and Mechanical Properties of Bio-Polyamide 11-Based Biocomposites Reinforced with Short Basalt Fibers
by Vito Gigante, Francesca Cartoni, Bianca Dal Pont and Laura Aliotta
Polymers 2024, 16(21), 3092; https://doi.org/10.3390/polym16213092 - 31 Oct 2024
Cited by 3 | Viewed by 2083
Abstract
The increasing demand for sustainable materials in high-value applications, particularly in the automotive industry, has prompted the development of biocomposites based on renewable or recyclable matrices and natural fibers as reinforcements. In this context, this paper aimed to produce composites with improved mechanical [...] Read more.
The increasing demand for sustainable materials in high-value applications, particularly in the automotive industry, has prompted the development of biocomposites based on renewable or recyclable matrices and natural fibers as reinforcements. In this context, this paper aimed to produce composites with improved mechanical and thermal properties (tensile, flexural, and heat deflection temperature) through an optimized process pathway using a biobased polyamide reinforced with short basalt fibers. This study emphasizes the critical impact of fiber length, matrix adhesion, and the variation in matrix properties with increasing fiber content. These factors influence the properties of short-fiber composites produced via primary processing using extrusion and shaped through injection molding. The aim of this work was to optimize extrusion conditions using a 1D simulation software to minimize excessive fiber fragmentation during the extrusion process. The predictive model’s capacity to forecast fiber degradation and the extent of additional fiber breakage during extrusion was evaluated. Furthermore, the impact of injection molding on these conditions was investigated. Moreover, a comprehensive thermomechanical characterization of the composites, comprising 10%, 20%, and 30% fiber content, was carried out, focusing on the correlation with morphology and processing using SEM and micro-CT analyses. In particular, how the extrusion process parameters adopted can influence fiber breakage and how injection molding can influence the fiber orientation were investigated, highlighting their influence in determining the final mechanical properties of short fiber composites. By optimizing the process parameters, an increment with respect to bio-PA11 in the tensile strength of 38%, stiffness of 140%, and HDT of 77% compared to the matrix were obtained. Full article
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16 pages, 4643 KiB  
Article
Investigating the Mechanical Characteristics and Fracture Morphologies of Basalt Fiber Concrete: Insights from Uniaxial Compression Tests and Meshless Numerical Simulations
by Chuan Zhao, Guoxin Jiang, Junli Guo, Shuyang Yu, Zelong Ma, Chunyi Zhuang, Youbin Lei and Zilin Liang
Materials 2024, 17(21), 5258; https://doi.org/10.3390/ma17215258 - 29 Oct 2024
Cited by 3 | Viewed by 997
Abstract
To explore the mechanical properties and fracture modes of basalt fiber-reinforced concrete, single-doped and hybrid-doped basalt fiber-reinforced concrete was prepared, and uniaxial failure tests under different basalt fiber-reinforced concrete contents were carried out. At the same time, the smooth kernel function in the [...] Read more.
To explore the mechanical properties and fracture modes of basalt fiber-reinforced concrete, single-doped and hybrid-doped basalt fiber-reinforced concrete was prepared, and uniaxial failure tests under different basalt fiber-reinforced concrete contents were carried out. At the same time, the smooth kernel function in the traditional SPH method was improved, and the basalt fiber random generation algorithm was embedded in the SPH program to realize the simulation of the progressive failure of basalt fiber-reinforced concrete. The results show that under the circumstance with no basalt fiber, the specimen final failure mode is damage on the upper and lower surface, as well as the side edge, while the interior of the specimen center is basically intact, indicating that there is an obvious stress concentration phenomenon on the upper and lower surface when the specimen is compressed. Under the circumstance with basalt fiber, longitudinal cracks begin to appear inside the specimen. With the increase in the content, the crack location gradually develops from the edge to the middle, and the crack number gradually increases. This indicates that appropriately increasing the fiber content in concrete may improve the stress state of concrete, change the eccentric compression to axial compression, and indirectly increase the compressive strength of concrete. The numerical simulation results are consistent with the test results, verifying the rationality of the numerical simulation algorithm. For the concrete model without the basalt fiber, shear cracks are generated around the model. For the concrete model with basalt fiber, in addition to shear cracks, the tensile cracks generated at the basalt fiber inside the model eventually lead to the splitting failure of the model. The strength of concrete samples with basalt content of 0.1%, 0.2%, and 0.3% is increased by 1.69%, 5.10%, and 4.31%, respectively, compared to the concrete sample without basalt fiber. It can be seen that with the increase in the content of single-doped basalt fiber, the concrete strength is improved to a certain extent, but the improvement degree is not high; For hybrid-doped basalt fiber-reinforced concrete, the strength of concrete samples with basalt content of 0.1%, 0.2%, and 0.3% is increased by 14.51%, 15.02%, and 30.31%, respectively, compared to the concrete sample without basalt fiber. Therefore, compared with the single-doped basalt fiber process, hybrid doping is easier to improve the strength of concrete. Full article
(This article belongs to the Special Issue Sustainable and Advanced Cementitious Materials)
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15 pages, 3383 KiB  
Article
Improvement of Mechanical and Acoustic Characteristics of Halloysite Nanotube-Reinforced Polyurethane Elastomer Composites and Their Applications
by Mengchen Ge, Xiaodong Li, Xing Su, Hao Jiang, Yangwei Wang, Fei Han and Meishuai Zou
Polymers 2024, 16(21), 3025; https://doi.org/10.3390/polym16213025 - 28 Oct 2024
Cited by 3 | Viewed by 1475
Abstract
Polyurethane incorporated with nanofillers such as carbon nanotubes, basalt fibers, and clay nanoparticles has presented remarkable potential for improving the performance of the polymeric composites. In this study, the halloysite nanofiller-reinforced polyurethane elastomer composites were prepared via the semi-prepolymer method. The impact of [...] Read more.
Polyurethane incorporated with nanofillers such as carbon nanotubes, basalt fibers, and clay nanoparticles has presented remarkable potential for improving the performance of the polymeric composites. In this study, the halloysite nanofiller-reinforced polyurethane elastomer composites were prepared via the semi-prepolymer method. The impact of different halloysites (halloysite nanotubes and halloysite nanoplates) in polyurethane composites was investigated. Scanning electron microscopy, X-ray diffraction, infrared spectroscopy, electronic universal tensile testing, and acoustic impedance tube testing were employed to characterize the morphology, composition, phase separation, mechanical properties, and sound insulation of the samples. The composite fabricated with 0.5 wt% of halloysite nanotubes introduced during quasi-prepolymer preparation exhibited the highest tensile strength (22.92 ± 0.84 MPa) and elongation at break (576.67 ± 17.99%) among all the prepared samples. Also, the incorporation of 2 wt% halloysite nanotubes into the polyurethane matrix resulted in the most significant overall improvements, particularly in terms of tensile strength (~44%), elongation at break (~40%), and sound insulation (~25%) within the low-frequency range of 50 to 1600 Hz. The attainment of these impressive mechanical and acoustic characteristics could be attributed to the unique lumen structure of the halloysite nanotubes, good dispersion of the halloysites in the polyurethane, and the interfacial bonding between the matrix and halloysite fillers. Full article
(This article belongs to the Special Issue Processing, Characterization and Modeling of Polymer Nanocomposites)
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