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23 pages, 930 KiB  
Article
One-Dimensional Shallow Water Equations Ill-Posedness
by Tew-Fik Mahdi
Mathematics 2025, 13(15), 2476; https://doi.org/10.3390/math13152476 - 1 Aug 2025
Viewed by 142
Abstract
In 2071, the Hydraulic community will commemorate the second centenary of the Baré de Saint-Venant equations, also known as the Shallow Water Equations (SWE). These equations are fundamental to the study of open-channel flow. As non-linear partial differential equations, their solutions were largely [...] Read more.
In 2071, the Hydraulic community will commemorate the second centenary of the Baré de Saint-Venant equations, also known as the Shallow Water Equations (SWE). These equations are fundamental to the study of open-channel flow. As non-linear partial differential equations, their solutions were largely unattainable until the development of computers and numerical methods. Following 1960, various numerical schemes emerged, with Preissmann’s scheme becoming the most widely employed in many software applications. In the 1990s, some researchers identified a significant limitation in existing software and codes: the inability to simulate transcritical flow. At that time, Preissmann’s scheme was the dominant method employed in hydraulics tools, leading the research community to conclude that this scheme could not handle transcritical flow due to suspected instability. In response to this concern, several researchers suggested modifications to Preissmann’s scheme to enable the simulation of transcritical flow. This paper will demonstrate that these accusations against the Preissmann scheme are unfounded and that the proposed improvements are unnecessary. The observed instability is not due to the numerical method itself, but rather a mathematical instability inherent to the SWE, which can lead to ill-posed conditions if a specific derived condition is not met. In the context of a friction slope formula based on Manning or Chézy types, the condition for ill-posedness of the 1D shallow water equations simplifies to the Vedernikov number condition, which is necessary for roll waves to develop in uniform flow. This derived condition is also relevant for the formation of roll waves in unsteady flow when the 1D shallow water equations become ill-posed. Full article
(This article belongs to the Special Issue Computational Fluid Dynamics, 3rd Edition)
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24 pages, 32703 KiB  
Article
Spatiotemporal Evolution of Carbon Storage and Driving Factors in Major Sugarcane-Producing Regions of Guangxi, China
by Jianing Ma, Jun Wen, Shirui Du, Chuanmin Yan and Chuntian Pan
Agronomy 2025, 15(8), 1817; https://doi.org/10.3390/agronomy15081817 - 27 Jul 2025
Viewed by 224
Abstract
Objectives: The major sugarcane-producing regions of Guangxi represent a critical agricultural zone in China. Investigating the mechanisms of land use change and carbon storage dynamics in this area is essential for optimizing regional ecological security and promoting sustainable development. Methods: Employing the land [...] Read more.
Objectives: The major sugarcane-producing regions of Guangxi represent a critical agricultural zone in China. Investigating the mechanisms of land use change and carbon storage dynamics in this area is essential for optimizing regional ecological security and promoting sustainable development. Methods: Employing the land use transfer matrix, the InVEST model and the Geodetector model to analyze carbon storage changes and identify key driving factors and their interactive effects. Results: (1) From 2011 to 2022, Guangxi’s major sugarcane-producing regions experienced significant land use changes: reductions in cultivated land, grassland and water bodies alongside expansions of forest, bare land and construction land. (2) The total carbon storage in Guangxi’s major sugarcane-producing regions has increased from 2011 to 2018 by 0.99%, representing 1627.03 and 1643.10 million tons, while it has decreased by 0.1% in 2022 (1641.47 million tons) compared to 2018. (3) Cultivated land proportion and forest coverage rate were the primary drivers of spatial heterogeneity, followed by average slope and land urbanization rate. (4) Interaction analysis revealed strong synergistic effects among cultivated land proportion, forest coverage rate, NDVI and average slope, confirming multi-factor control over carbon storage changes. Conclusions: Carbon storage in the Guangxi sugarcane-producing regions is shaped by land use patterns and multi-factor interactions. Future strategies should optimize land use structures and balance urbanization with ecological protection to enhance regional carbon sequestration. Full article
(This article belongs to the Section Agroecology Innovation: Achieving System Resilience)
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16 pages, 1049 KiB  
Article
Limited Short-Term Impact of Annual Cover Crops on Soil Carbon and Soil Enzyme Activity in Subtropical Tree Crop Systems
by Abraham J. Gibson, Lee J. Kearney, Karina Griffin, Michael T. Rose and Terry J. Rose
Agronomy 2025, 15(7), 1750; https://doi.org/10.3390/agronomy15071750 - 21 Jul 2025
Viewed by 272
Abstract
In wet subtropical environments, perennial groundcovers are common in horticultural plantations to protect the soil from erosion. However, there has been little investigation into whether seeding annual cover crops into the perennial groundcovers provides additional soil services including carbon and nutrient cycling in [...] Read more.
In wet subtropical environments, perennial groundcovers are common in horticultural plantations to protect the soil from erosion. However, there has been little investigation into whether seeding annual cover crops into the perennial groundcovers provides additional soil services including carbon and nutrient cycling in these systems. To investigate this, farmer participatory field trials were conducted in commercial avocado, macadamia, and coffee plantations in the wet Australian subtropics. Cover crops were direct-seeded into existing inter-row groundcovers in winter (cool season cover crops), and into the same plots the following summer (warm season cover crops). Inter-row biomass was quantified at the end of winter and summer in the control (no cover crop) and cover crops treatments. Soil carbon and nutrient cycling parameters including hot water extractable carbon, water soluble carbon, autoclavable citrate-extractable protein and soil enzyme activities were quantified every two months from early spring (September) 2021 to late autumn (May) 2022. Seeded cover crops produced 500 to 800 kg ha−1 more total inter-row biomass over winter at the avocado coffee sites, and 3000 kg ha−1 biomass in summer at the coffee site. However, they had no effect on biomass production in either season at the macadamia site. Soil functional parameters changed with season (i.e., time of sampling), with few significant effects of cover crop treatments on soil function parameters across the three sits. Growing a highly productive annual summer cover crop at the coffee site led to suppression and death of perennial groundcovers, exposing bare soil in the inter-row by 3 weeks after termination of the summer cover crop. Annual cover crops seeded into existing perennial groundcovers in tree crop systems had few significant impacts on soil biological function over the 12-month period, and their integration needs careful management to avoid investment losses and exacerbating the risk of soil erosion on sloping lands in the wet subtropics. Full article
(This article belongs to the Section Farming Sustainability)
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21 pages, 12821 KiB  
Article
The Identification and Diagnosis of ‘Hidden Ice’ in the Mountain Domain
by Brian Whalley
Glacies 2025, 2(3), 8; https://doi.org/10.3390/glacies2030008 - 15 Jul 2025
Viewed by 252
Abstract
Morphological problems for distinguishing between glacier ice, glacier ice with a debris cover (debris-covered glaciers), and rock glaciers are outlined with respect to recognising and mapping these features. Decimal latitude–longitude [dLL] values are used for geolocation. One model for rock glacier formation and [...] Read more.
Morphological problems for distinguishing between glacier ice, glacier ice with a debris cover (debris-covered glaciers), and rock glaciers are outlined with respect to recognising and mapping these features. Decimal latitude–longitude [dLL] values are used for geolocation. One model for rock glacier formation and flow discusses the idea that they consist of ‘mountain permafrost’. However, signs of permafrost-derived ice, such as flow features, have not been identified in these landsystems; talus slopes in the neighbourhoods of glaciers and rock glaciers. An alternative view, whereby rock glaciers are derived from glacier ice rather than permafrost, is demonstrated with examples from various locations in the mountain domain, 𝔻𝕞. A Google Earth and field examination of many rock glaciers shows glacier ice exposed below a rock debris mantle. Ice exposure sites provide ground truth for observations and interpretations stating that rock glaciers are indeed formed from glacier ice. Exposure sites include bare ice at the headwalls of cirques and above debris-covered glaciers; additionally, ice cliffs on the sides of meltwater pools are visible at various locations along the lengths of rock glaciers. Inspection using Google Earth shows that these pools can be traced downslope and their sizes can be monitored between images. Meltwater pools occur in rock glaciers that have been previously identified in inventories as being indictive of permafrost in the mountain domain. Glaciers with a thick rock debris cover exhibit ‘hidden ice’ and are shown to be geomorphological units mapped as rock glaciers. Full article
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22 pages, 4476 KiB  
Article
A Method for Identifying Key Areas of Ecological Restoration, Zoning Ecological Conservation, and Restoration
by Shuaiqi Chen, Zhengzhou Ji and Longhui Lu
Land 2025, 14(7), 1439; https://doi.org/10.3390/land14071439 - 10 Jul 2025
Viewed by 314
Abstract
Ecological security patterns (ESPs) are fundamental to safeguarding regional ecological integrity and enhancing human well-being. Consequently, research on conservation and restoration in critical regions is vital for ensuring ecological security and optimizing territorial ecological spatial configurations. Focusing on the Henan section of the [...] Read more.
Ecological security patterns (ESPs) are fundamental to safeguarding regional ecological integrity and enhancing human well-being. Consequently, research on conservation and restoration in critical regions is vital for ensuring ecological security and optimizing territorial ecological spatial configurations. Focusing on the Henan section of the Yellow River Basin, this study established the regional ESP and conservation–restoration framework through an integrated approach: (1) assessing four key ecosystem services—soil conservation, water retention, carbon sequestration, and habitat quality; (2) identifying ecological sources based on ecosystem service importance classification; (3) calculating a comprehensive resistance surface using the entropy weight method, incorporating key factors (land cover type, NDVI, topographic relief, and slope); (4) delineating ecological corridors and nodes using Linkage Mapper and the minimum cumulative resistance (MCR) theory; and (5) integrating ecological functional zoning to synthesize the final spatial conservation and restoration strategy. Key findings reveal: (1) 20 ecological sources, totaling 8947 km2 (20.9% of the study area), and 43 ecological corridors, spanning 778.24 km, were delineated within the basin. Nineteen ecological barriers (predominantly located in farmland, bare land, construction land, and low-coverage grassland) and twenty-one ecological pinch points (primarily clustered in forestland, grassland, water bodies, and wetlands) were identified. Collectively, these elements form the Henan section’s Ecological Security Pattern (ESP), integrating source areas, a corridor network, and key regional nodes for ecological conservation and restoration. (2) Building upon the ESP and the ecological baseline, and informed by ecological functional zoning, we identified a spatial framework for conservation and restoration characterized by “one axis, two cores, and multiple zones”. Tailored conservation and restoration strategies were subsequently proposed. This study provides critical data support for reconciling ecological security and economic development in the Henan Yellow River Basin, offering a scientific foundation and practical guidance for regional territorial spatial ecological restoration planning and implementation. Full article
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22 pages, 2022 KiB  
Article
Impact of Slow-Forming Terraces on Erosion Control and Landscape Restoration in Central Africa’s Steep Slopes
by Jean Marie Vianney Nsabiyumva, Ciro Apollonio, Giulio Castelli, Elena Bresci, Andrea Petroselli, Mohamed Sabir, Cyrille Hicintuka and Federico Preti
Land 2025, 14(7), 1419; https://doi.org/10.3390/land14071419 - 6 Jul 2025
Viewed by 616
Abstract
Large-scale land restoration projects require on-the-ground monitoring and evidence-based evaluation. This study, part of the World Bank Burundi Landscape Restoration and Resilience Project (in French: Projet de Restauration et de Résilience du Paysage du Burundi-PRRPB), examines the impact of slow-forming terraces on surface [...] Read more.
Large-scale land restoration projects require on-the-ground monitoring and evidence-based evaluation. This study, part of the World Bank Burundi Landscape Restoration and Resilience Project (in French: Projet de Restauration et de Résilience du Paysage du Burundi-PRRPB), examines the impact of slow-forming terraces on surface conditions and erosion in Isare (Mumirwa) and Buhinyuza (Eastern Depressions), Burundi. Slow-forming, or progressive, terraces were installed on 16 December 2022 (Isare) and 30 December 2022 (Buhinyuza), featuring ditches and soil bunds to enhance soil and water conservation. Twelve plots were established, with 132 measurement pins, of which 72 were in non-terraced plots (n_PT) and 60 were in terraced plots (PT). Monthly measurements, conducted until May 2023, assessed erosion reduction, surface conditions, roughness, and soil thickness. Terracing reduced soil loss by 54% in Isare and 9% in Buhinyuza, though sediment accumulation in ditches was excessive, especially in n_PT. Anti-erosion ditches improved surface stability by reducing slope length, lowering erosion and runoff. Covered Surface (CoS%) exceeded 95%, while Opened Surface (OS%) and Bare Surface (BS%) declined significantly. At Isare, OS% dropped from 97% to 80%, and BS% from 96% to 3% in PT. Similar trends appeared in Buhinyuza. Findings highlight PRRPB effectiveness in this short-term timeframe, and provide insights for soil conservation in steep-slope regions of Central Africa. Full article
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27 pages, 4125 KiB  
Article
Monitoring Gypsiferous Soils by Leveraging Advanced Spaceborne Hyperspectral Imagery via Spectral Indices and a Machine Learning Approach
by Najmeh Rasooli, Saham Mirzaei and Stefano Pignatti
Remote Sens. 2025, 17(11), 1914; https://doi.org/10.3390/rs17111914 - 31 May 2025
Viewed by 781
Abstract
Enhancing the spatial resolution of gypsiferous soil detection, as a valuable baseline information layer, is beneficial for investigating agroecological processes and tackling land degradation in semi-arid environments. This study evaluates the performance of PRISMA (PRecursore IperSpettrale della Missione Applicativa) and EnMAP (Environmental Mapping [...] Read more.
Enhancing the spatial resolution of gypsiferous soil detection, as a valuable baseline information layer, is beneficial for investigating agroecological processes and tackling land degradation in semi-arid environments. This study evaluates the performance of PRISMA (PRecursore IperSpettrale della Missione Applicativa) and EnMAP (Environmental Mapping and Analysis Program) satellites in estimating soil gypsum content and compares models trained on satellite imagery versus lab data. To this end, 242 bare-soil samples were collected from southeast Iran. Gypsum content was measured using acetone precipitation, and spectral reflectance was acquired using the ASD (Analytical Spectral Devices)-Fieldspec 3 spectroradiometer. The gypsum content was retrieved by optical data using three approaches: narrowband indices, spectral absorption features, and machine learning (ML) algorithms. Four machine learning algorithms, including PLSR (Partial Least Squares Regression), RF (Random Forest), SVR (Support Vector Regression), and GPR (Gaussian Process Regression), achieved excellent performance (RPD > 2.5). The results showcased that the difference soil index (DSI) achieved the highest R2 scores of 0.96 (ASD), 0.79 (PRISMA), and 0.84 (EnMAP), slightly outperforming the normalized difference gypsum ratio (NDGI) and ratio soil index (RSI). Comparing the shape indices’, the slope parameter (SLP) index outperformed the half-area parameter (HAP) index. PRISMA, with SVR (R2 ≥ 0.83), and EnMAP, with PLSR (R2 ≥ 0.85), demonstrated that hyperspectral satellites proved reliable in detecting gypsum content, yielding results comparable to ASD with detailed algorithms. Full article
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23 pages, 7153 KiB  
Article
ASTER GDEM Correction Based on Stacked Ensemble Learning and ICEsat-2/ATL08: A Case Study from the Qilian Mountains
by Qi Wei, Yanli Zhang, Yalong Ma, Ruirui Yang and Kairui Lei
Remote Sens. 2025, 17(11), 1839; https://doi.org/10.3390/rs17111839 - 24 May 2025
Viewed by 404
Abstract
ASTER GDEM provides the fundamental data for remote sensing identification of snow cover in mountainous areas. Due to its elevation accuracy being easily affected by optical stereo images and local terrain, many studies have utilized machine learning (ML) models for correction. However, most [...] Read more.
ASTER GDEM provides the fundamental data for remote sensing identification of snow cover in mountainous areas. Due to its elevation accuracy being easily affected by optical stereo images and local terrain, many studies have utilized machine learning (ML) models for correction. However, most correction methods rely on a single ML model, which limits the improvement of DEM accuracy. Stacked ensemble learning (SEL) is a newly developed method of improving model performance by combining multiple ML models. This study proposes a DEM correction method based on SEL and ICESatand affiliations. -2/ATL08 products. Taking the Babao River Basin in Qilian Mountains as the study area, five ML models with good DEM correction effects (XGBoost, AdaBoost, LightGBM, BPNN, and CatBoost) were selected and trained using land cover and various terrain factors to obtain DEM errors, respectively. Then, the SEL algorithm was used to integrate the DEM errors of the five ML models and correct GDEM. Using 740 CORS measurements and 48,000 ATL08 points for accuracy validation, the results showed that the SEL achieved higher DEM accuracy than any single ML model. The root mean square error (RMSE) of the corrected GDEM decreased from 7.15 m to 4.13 m, while the mean absolute error (MAE) and mean bias error (MBE) values both decreased about by 38%. Furthermore, unmanned aerial vehicle (UAV) DEM data from five sample areas were selected for profile analysis, and it was found that the corrected GDEM was closer to the real surface. Further analysis revealed that the influence of slope, aspect, and land cover types on corrected DEM was weakened, with the most significant improvement in DEM accuracy observed in areas with slope ≥5°, north orientation, and bare land. This study can provide high-precision DEM scientific data for quantitative remote sensing, flood prediction, and other research. Full article
(This article belongs to the Special Issue Application of Remote Sensing in Snow and Ice Monitoring)
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18 pages, 5360 KiB  
Article
Analysis of the Distribution Pattern and Driving Factors of Bald Patches in Black Soil Beach Degraded Grasslands in the Three-River-Source Region
by Weitao Jing, Zhou Wang, Guowei Pang, Yongqing Long, Lei Wang, Qinke Yang and Jinxi Song
Land 2025, 14(5), 1050; https://doi.org/10.3390/land14051050 - 12 May 2025
Viewed by 459
Abstract
The degradation of ‘black soil beach’ (BSB) ecosystems in the Three-River-Source region, characterized by widespread bald patches and severe soil erosion, poses a critical threat to regional ecological security and sustainable pastoralism. This study aims to elucidate the spatial distribution patterns and driving [...] Read more.
The degradation of ‘black soil beach’ (BSB) ecosystems in the Three-River-Source region, characterized by widespread bald patches and severe soil erosion, poses a critical threat to regional ecological security and sustainable pastoralism. This study aims to elucidate the spatial distribution patterns and driving factors of bald patches in BSB degraded grasslands within the Guoluo Tibetan Autonomous Prefecture, providing a scientific basis for targeted restoration strategies. Utilizing multi-source remote sensing data (Landsat 8–9 OLI, UAV imagery, and Google Earth), we employed the Multiple Endmember Spectral Mixture Analysis (MESMA) method to identify bald patches, combined with the landscape pattern index and spatial autocorrelation to quantify their spatial heterogeneity. Geographical detector analysis was applied to assess the influence of natural and anthropogenic factors. The results indicate the following: (1) The patches are bounded by the Yellow River, showing a distribution pattern of ‘high in the west and low in the east’. The total area of patches reached 32,222.11 km2, accounting for 43.43% of the total area of Guoluo Prefecture, among which Maduo County and Dari County had the highest degradation rate. (2) With the aggravation of degradation, the patch density of each county increased first and then decreased, while the aggregation index and landscape shape index continued to decrease. (3) Spatial autocorrelation of bare patches strengthens with degradation severity (Moran’s I index 0.6543→0.7999). LISA identified two clusters: the high–high agglomeration area in the north of Maduo–Dari and the low–low agglomeration area in the southeast of Jiuzhi–Banma, revealing the spatial heterogeneity of the degradation process. (4) The spatial distribution pattern of bare patches was mainly affected by the annual average precipitation and actual stocking capacity, and the synergistic effect was significantly higher than that of a single factor. The combination of a 4491–4708 m high altitude area, 0–5° gentle slope zone, and soil texture (clay 27–31%, silt 43–100%) has the highest degradation risk. This multi-factor coupling effect explains the limitations of traditional single factor analysis and provides a new perspective for accurate repair. Full article
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13 pages, 3220 KiB  
Article
CoMo/SS Cathode Catalyst for Enhanced Hydrogen Production in Microbial Electrolysis Cells
by Gao Lei, Yaoqiang Wang, Gang Xiao and Haijia Su
Catalysts 2025, 15(5), 439; https://doi.org/10.3390/catal15050439 - 30 Apr 2025
Viewed by 687
Abstract
Hydrogen energy has emerged as a pivotal clean energy solution due to its sustainability and zero-emission potential. Microbial electrolysis cells are a promising technology for renewable hydrogen production, typically relying on expensive and unstable Pt/C catalysts for the hydrogen evolution reaction (HER). To [...] Read more.
Hydrogen energy has emerged as a pivotal clean energy solution due to its sustainability and zero-emission potential. Microbial electrolysis cells are a promising technology for renewable hydrogen production, typically relying on expensive and unstable Pt/C catalysts for the hydrogen evolution reaction (HER). To address these limitations, this study develops a cost-effective and durable alternative approach. A cobalt–molybdenum (Co-Mo) alloy catalyst (denoted as CoMo/SS) was synthesized via a one-step electrodeposition method on 1000-mesh 316L stainless steel at a current density of 30 mA·cm−2 for 80 min, using an electrolyte with a Co-to-Mo ratio of 1:1. The electrochemical properties and hydrogen evolution performance of this catalyst in a microbial electrolysis cell were evaluated. Key results demonstrate that the CoMo/SS catalyst achieves a good catalytic performance of hydrogen evolution. The CoMo/SS cathode catalyst only requires an overpotential of 91.70 mV (vs. RHE) to reach a current density of 10 mA·cm−2 in 1 mol·L−1 KOH, with favorable kinetics, evidenced by a reduced Tafel slope of 104.10 mV·dec−1, enhanced charge transfer with a charge transfer resistance of 4.56 Ω, and a double-layer capacitance of 34.73 mF·cm−2. Under an applied voltage of 0.90 V, the CoMo/SS cathode exhibited a hydrogen production rate of 1.12 m3·m−3·d−1, representing a 33.33% improvement over bare SS mesh. This performance highlights the catalyst’s potential as a viable Pt/C substitute for scalable MEC applications. Full article
(This article belongs to the Section Electrocatalysis)
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21 pages, 3377 KiB  
Article
Study on the Effectiveness of Temporary Vegetation Measures on the Regulation of Runoff, Sediment Yield and Hydraulic Characteristics on the Spoil Heaps
by Jian Pu, Jianming Li, Wenlong Wang, Zhigang Wang, Jiale Wang, Ke Wang, Xiao Li, Xiudi Zhu, Wensheng Xu and Jigen Liu
Land 2025, 14(5), 951; https://doi.org/10.3390/land14050951 - 28 Apr 2025
Viewed by 404
Abstract
Temporary vegetation measures are the most common methods for reducing soil erosion of spoil heaps during construction; however, their regulatory mechanisms on soil and water loss have not been sufficiently studied. This study compared the impacts of five temporary vegetation measures (turfing 300 [...] Read more.
Temporary vegetation measures are the most common methods for reducing soil erosion of spoil heaps during construction; however, their regulatory mechanisms on soil and water loss have not been sufficiently studied. This study compared the impacts of five temporary vegetation measures (turfing 300 cm (TF-300 cm), turfing 75 cm (TF-75 cm), grass seeding 300 cm (GS-300 cm), grass seeding 75 cm (GS-75 cm), and synthetic turf (ST)) on the dynamic processes of runoff and sediment yield as well as hydraulic parameters under simulated rainfall experiments. A 30° bare slope (BS) was set up as the control. The results indicated that (1) all measures delayed the onset of runoff by 57–233%, effectively decreasing the runoff rate and the average erosion rate by 45–49% and 91–99%, respectively; (2) these measures reduced the average Reynolds number by 45–52% and diminished both the average runoff shear force and runoff power by 44–60%; and (3) the effectiveness in reducing runoff and sediment loss ranked as follows: turfing > synthetic turf > grass seeding, When these measures are applied locally to the bottom 25% of the slope, the efficiency of runoff and sediment reduction can exceed 89% for the entire slope. Our findings provide valuable insights for designing temporary vegetation measures in construction. Full article
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23 pages, 7346 KiB  
Article
A Comparison of the AHP and BWM Models for the Flash Flood Susceptibility Assessment: A Case Study of the Ibar River Basin in Montenegro
by Filip Vujović, Aleksandar Valjarević, Uroš Durlević, Cezar Morar, Vasile Grama, Velibor Spalević, Miško Milanović, Dejan Filipović, Golub Ćulafić, Milan Gazdić, Natalija Batoćanin, Goran Barović, Jelena Golijanin, Dragan Radovanović, Nikola Bačević and Ante Šiljeg
Water 2025, 17(6), 844; https://doi.org/10.3390/w17060844 - 14 Mar 2025
Cited by 2 | Viewed by 1261
Abstract
Assessing flash flood susceptibility is crucial for disaster management, yet Montenegro lacks research using geoinformation technologies. In northeastern Montenegro, the Ibar River Basin, mainly in Rožaje, has a well-developed hydrological network with torrential streams prone to flash flooding. This study compares two multi-criteria [...] Read more.
Assessing flash flood susceptibility is crucial for disaster management, yet Montenegro lacks research using geoinformation technologies. In northeastern Montenegro, the Ibar River Basin, mainly in Rožaje, has a well-developed hydrological network with torrential streams prone to flash flooding. This study compares two multi-criteria GIS decision analysis (GIS–MCDA) methodologies, the Analytic Hierarchy Process (AHP) and the Best-Worst Method (BWM), for assessing flood susceptibility. The analysis uses the Flash Flood Susceptibility Index (FFSI), integrating geoenvironmental and climatic factors. The geoenvironmental criteria considered include terrain slope, distance from the drainage network, geology, land cover, drainage density, bare soil index, and the BIO16 variable, which represents the mean monthly precipitation of the wettest quarter to enhance precipitation pattern assessment. The AHP model classifies 2.78% of the area as high to very high susceptibility, while the BWM model identifies 3.21% in these categories. Both models perform excellently based on AUC values, with minor, non-significant differences. Sensitivity analysis shows AHP provides a more stable weight distribution, whereas BWM is more sensitive to weight changes, emphasizing dominant criteria more strongly. This study introduces BWM for the first time in flash flood modeling, demonstrating its suitability for susceptibility assessment. The key novelty lies in its comparative analysis with AHP, highlighting differences in weight distribution and model stability. Full article
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11 pages, 6138 KiB  
Article
Facile Synthesis of MoP and Its Composite Structure with Ru as an Efficient Electrocatalyst for Hydrogen Evolution Reaction in Both Acidic and Alkaline Conditions
by Pinyun Ren, Rui Wang, Yujie Yang, Tianyu Wang, Yilun Hong, Yi Zheng, Qianying Zheng, Xianpei Ren and Zhili Jia
Materials 2025, 18(5), 1184; https://doi.org/10.3390/ma18051184 - 6 Mar 2025
Viewed by 901
Abstract
Developing low-cost electrocatalysts for efficient hydrogen evolution in both acidic and alkaline conditions is crucial for water-electrolytic hydrogen applications. Herein, MoP was synthesized via a simple, low-cost, and green phosphorization route. More importantly, the Ru/MoP composite prepared using the as-synthesized MoP as a [...] Read more.
Developing low-cost electrocatalysts for efficient hydrogen evolution in both acidic and alkaline conditions is crucial for water-electrolytic hydrogen applications. Herein, MoP was synthesized via a simple, low-cost, and green phosphorization route. More importantly, the Ru/MoP composite prepared using the as-synthesized MoP as a reactant, which exhibited excellent catalytic activity for the hydrogen evolution reaction. It showed lower overpotentials of 108 and 55 mV at 10 mA·cm−2 in acidic and alkaline solutions, respectively, which are superior to those of bare Ru and pristine MoP as well as comparable or even better than those of previously reported excellent Ru- or MoP-based catalysts. In addition, it also demonstrated small Tafel slopes of 52.6 mV dec−1 and 67.9 mV dec−1 in acidic and alkaline solutions, respectively, along with long-term stability. This work provides an effective and feasible route to design high-efficient MoP-based electrocatalysts for hydrogen evolution reaction. Full article
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24 pages, 1668 KiB  
Review
Progress and Prospects of Research on Physical Soil Crust
by Huiyun Xu, Xuchao Zhu and Meixia Mi
Soil Syst. 2025, 9(1), 23; https://doi.org/10.3390/soilsystems9010023 - 4 Mar 2025
Viewed by 1147
Abstract
Physical soil crust (PSC) is a dense structural layer formed on the surface of bare or very low-cover land due to raindrop splashes or runoff. The formation of crust changes the properties of the soil and strongly affects water infiltration and runoff and [...] Read more.
Physical soil crust (PSC) is a dense structural layer formed on the surface of bare or very low-cover land due to raindrop splashes or runoff. The formation of crust changes the properties of the soil and strongly affects water infiltration and runoff and sediment production processes on slopes. The irrational use of soil and water resources and frequent human production activity under the influence of urbanization increase the possibility of inducing erosion. Studying the formation and structural characteristics of PSC to predict terrestrial hydrological processes and improve models for predicting erosion is very important. Many studies of PSC have been carried out in China and abroad, but they are mainly unilateral discussions of the basic properties and characteristics of crust and its effects on runoff and sediment yield on slopes. Studies systematically analyzing and synthesizing the progress of crust research, however, are lacking. By reading the literature and analyzing the developmental history of PSC, we provide a comprehensive review of the following: (1) the meaning, main types, and classification of PSC, (2) the mechanism of formation and the characteristics and dynamic development of crust, (3) the factors affecting the formation of crust, including natural and anthropogenic factors and comprehensive effects, and (4) the development and formation of crust in the soil environment, i.e., hydrological processes and erosion. We also summarize the potential directions for future research on PSC: (1) studying the dynamics of soil structure during the development of crust, (2) developing an objective and standardized quantitative method for studying crust formation, (3) using models of erosion influenced by crust development, (4) improving the scale of the degree of crust development and structural characteristics, and (5) rationalizing the management of crust to optimize land structure and increase crop yield. Full article
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22 pages, 3240 KiB  
Article
Influence of Sugarcane on Runoff and Sediment Yield in Sloping Laterite Soils During High-Intensity Rainfall
by Changhong Yu, Haiyan Yang, Jiuhao Li and Cong Li
Agronomy 2025, 15(3), 596; https://doi.org/10.3390/agronomy15030596 - 27 Feb 2025
Viewed by 646
Abstract
Laterite is the predominant zonal soil in China’s southernmost tropical rainforest and monsoon forest regions, where typhoons are the primary source of precipitation. These storms pose significant risks of land and soil degradation due to heavy rainfall. In recent years, a substantial area [...] Read more.
Laterite is the predominant zonal soil in China’s southernmost tropical rainforest and monsoon forest regions, where typhoons are the primary source of precipitation. These storms pose significant risks of land and soil degradation due to heavy rainfall. In recent years, a substantial area of sloping land has been converted to agricultural use in these regions, predominantly for the cultivation of crops grown in laterite soil. These activities contribute to soil erosion, exacerbate environmental challenges, and hinder the pursuit of sustainable development. There is a paucity of research reports on the processes and mechanisms of runoff and sediment on sugarcane-cropped slopes in regions with laterite soil under heavy rainfall conditions. In this study, four different heavy rainfall scenarios of 75, 100, 125, and 150 mm/h were designed to assess the impact on sugarcane growth at four key stages and to measure the resulting effects on initial runoff time, surface runoff, and sediment yield from laterite soil slopes under controlled laboratory conditions. The results showed that the Horton model explained much of the variation in infiltration rate on the sugarcane-cropped laterite slopes. The cumulative sediment yield on the sugarcane-cropped laterite slopes followed a second-degree polynomial function. The initial runoff time, infiltration intensity, runoff intensity, and sediment yield were all linearly related to the leaf area index (LAI) and rainfall intensity on the sugarcane-cropped slope surface. The leaf area index exerted a greater influence on the initial runoff time and infiltration intensity than rainfall intensity. However, rainfall intensity exerted a greater influence on the runoff intensity and sediment yield than the leaf area index. Compared with the bare sloping land, the average sediment yield was reduced by 12.2, 33.1, 58.2, and 64.9% with the sugarcane growth stages of seedling, tillering, elongation, and maturity, respectively. Full article
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