Search Results (166)

This study presents the first successful integration of Fe₃O₄ and Li_0.5Cr_0.5Fe₂O₄ into a well-defined core/shell nanostructure through a two-step synthesis that combines co-precipitation and sol–gel auto-combustion methods. Unlike conventional composites, the core/shell design effectively suppresses the magnetic dead layer and promotes exchange coupling at the interface, leading to enhanced saturation magnetization, superior magnetic heating (specific absorption rate; SAR), and improved dielectric properties. Our research introduces a novel interfacial engineering strategy that simultaneously optimizes both magnetic and dielectric performance, offering a multifunctional platform for applications in magnetic hyperthermia, electromagnetic interference (EMI) shielding, and microwave devices. Full article

Polyethersulfone (PES) membranes are essential in separation processes; however, their inherent hydrophobicity can limit their effectiveness in water-intensive applications. This study aims to enhance PES membranes by modifying them with a NiFe₂O₄–nanoclay composite nanoparticle to improve both their hydrophilicity and photocatalytic potential as a photocatalytic membrane. The nanoparticles were synthesized using the sol–gel auto-combustion method and incorporated into PES membranes through mixed-matrix embedding (1 wt% and 3 wt%) and surface coating. X-ray diffraction confirmed the cubic spinel structure of the composite nanoparticles, which followed the second order kinetic reaction during the photodegradation–adsorption of crystal violet. The mixed-matrix membranes displayed a remarkable 170% increase in water flux and a 25% improvement in mechanical strength, accompanied by a slight decrease in contact angle at 1 wt% of nanoparticle loading. In contrast, the surface-coated membranes demonstrated a significant reduction in contact angle to 18°, indicating a highly hydrophilic surface and increased roughness. All membranes achieved high dye removal rates of 98–99%, but only the coated membrane system exhibited approximately 50% photocatalytic degradation, following mixed kinetics. These results highlight the critical importance of surface modification in advancing PES membranes, as it significantly reduces fouling and enhances water–material interaction qualities essential for future filtration and photocatalytic applications. Exploring hybrid strategies that combine both embedding and coating approaches may yield even greater synergies in membrane functionality. Full article

The measurement error of sound travel time, one of the most critical parameters in acoustic temperature measurement, is significantly affected by the type of sound source signal. In order to select more appropriate sound source signals, a sound source signal preference study of loose coal acoustic temperature measurement was performed and is described herein. The results showed that the absolute error of the swept signal and the pseudo-random signal both increased with increased acoustic wave propagation distance. The relative error of the swept signal showed a relatively stable upward trend; in comparison, the pseudo-random signal showed a general decrease with a large fluctuation in the middle section, and both the relative and absolute errors for the pseudo-random signal were larger than those of the swept signal. Therefore, the swept signal is expected to perform better than the pseudo-random signal in the loose coal medium. Based on the experimental results, the linear sweep signal was selected as the sound source signal for the loose coal temperature inversion experiments: the average error between the inverted temperature value and the actual value was 4.86%, the maximum temperature difference was 2.926 °C, and the average temperature difference was 1.5949 °C. Full article

Hydrogen–gasoline dual-fuel spark ignition (SI) engines represent a promising transitional solution toward cleaner combustion and reduced carbon emissions. In a previous study, a predictive engine model was developed to simulate the performance and combustion characteristics of such systems; however, its accuracy was constrained by the use of estimated combustion parameters. This study presents an experimental validation based on high-resolution in-cylinder pressure measurements performed on a naturally aspirated SI engine operating with a 20% hydrogen energy share. The objectives are twofold: (1) to refine the combustion model using empirically derived combustion metrics, and (2) to evaluate the feasibility of moderate hydrogen enrichment in a stock engine configuration. To facilitate a more accurate understanding of how key combustion parameters evolve under different operating conditions, Vibe function was fitted to the ensemble-averaged heat release rate curves computed from 100 consecutive engine cycles at each static full-load operating point. This approach enabled the extraction of stable and representative metrics, including the mass fraction burned at 50% (MFB50) and combustion duration, which were then used to recalibrate the predictive combustion model. In addition, cycle-to-cycle variation and combustion duration were also investigated in the dual-fuel mode. The combustion duration exhibited a consistent and substantial reduction across all of the examined operating points when compared to pure gasoline operation. Furthermore, the cycle-to-cycle variation difference remained statistically insignificant, indicating that the introduction of 20% hydrogen did not adversely affect combustion stability. In addition to improving model accuracy, this work investigates the occurrence of abnormal combustion phenomena—including backfiring, auto-ignition, and knock—under enriched conditions. The results confirm that 20% hydrogen blends can be safely utilized in standard engine architectures, yielding faster combustion and reduced burn durations. The validated model offers a reliable foundation for further dual-fuel optimization and supports the broader integration of hydrogen into conventional internal combustion platforms. Full article

Strongly driven fluid and combustion systems typically contain a few, nonlinearly coupled, major flow constituents. It is necessary to identify the flow constituents in order to establish the underlying dynamics and to control these complex flows. Due to non-trivial boundary condition in realistic systems and long-range coupling, it is often difficult to construct accurate models of large-scale reacting systems. The question then arises if these flow constituents can be identified and controlled through analysis of experimental data. The difficulties in such analyses originate in the presence of high levels of noise and irregularities in the flow. A typical time series contains high-frequency noise as well as low-frequency features originating from the near translational invariance of the underlying fluid systems. We propose a pair of approaches to study such data. The first is the use of auto and cross correlation functions. Auto-correlation functions of the time series from a single transducer can be used effectively to demonstrate the low dimensionality of the flow. Second, we show that multi-point time series from appropriately placed transducers can be used to establish spatial characteristics of these flow constituents. The novelty of the approaches lies in the establishment of geometric and dynamic features of the primary flow constituents based on sensor data only, without the need of expensive imaging tools. These methods can potentially identify changes in flow behavior within complex propulsion systems, such as aircraft engines, by utilizing data collected from embedded transducers. Full article

The anodic stability of tungsten carbide (WC) and iron oxide with a spinel structure (Fe₃O₄) were compared against similar data for nanostructured, boron-doped diamond (BDD), and the benchmark Vulcan XC72 carbon, in view of their eventual application as alternative supports for the anion exchange membrane electrolyzer anode. To this end, metal oxide composites were prepared by the in situ autocombustion (ISAC) method, and the anodic behavior of materials (composites as well as supports alone) was investigated in 1 M NaOH electrolyte by the rotating ring–disc electrode method, which enables the separation oxygen evolution reaction and materials’ degradation currents. Among all supports, BDD has proven to be the most stable, while Vulcan XC72 is the least stable under the anodic polarization, with Fe₃O₄ and WC demonstrating intermediate behavior. The Co₃O₄-BDD, -Fe₃O₄, -WC, and -Vulcan composites prepared by the ISAC method were then tested as catalysts of the oxygen evolution reaction. The Co₃O₄-BDD and Co₃O₄-Fe₃O₄ composites appear to be competitive electrocatalysts for the OER in alkaline medium, showing activity comparable to the literature and higher support stability towards oxidation, either in cyclic voltammetry or chronoamperometry stability tests. On the contrary, WC- and Vulcan-based composites are prone to degradation. Full article

This study presents the development of a deep drawing process under an indirect hot stamping method for manufacturing an automotive internal combustion engine oil pan from ultra-high-strength steel (UHSS) sheets, specifically 22MnB5. The forming process involves two stages—cold stamping followed by hot stamping—and is finalized with rapid quenching to achieve a martensitic microstructure. Finite element simulation using AutoForm R8 was conducted to determine optimal forming conditions. The simulation results guided the design of the forming tools and were validated through experimental trials. The final oil pan component exhibited no cracks or wrinkles, with maximum thinning below 18%, a hardness of 550.63 HV, and a fully martensitic phase. This research demonstrates a novel and effective solution for producing deep-drawn, high-strength components using indirect hot stamping, contributing to the advancement of automotive forming processes in Thailand. Full article

Ammonia is a carbon-free fuel with strong potential for emission reduction. However, its high auto-ignition temperature and low reactivity lead to poor ignitability and unstable combustion. In contrast, coal-to-liquid (CTL) fuel offers high cetane number, low sulfur content, and low aromaticity, making it a clean fuel with excellent ignition performance. Blending CTL with ammonia can effectively compensate for ammonia’s combustion limitations, offering a promising pathway toward low-carbon clean combustion. This study explores the effects of post-injection strategies on combustion and emission characteristics of a CTL–ammonia dual-fuel engine under different levels of ammonia energy fractions (AEFs). Results show that post-injection significantly improves combustion and emission performance by expanding ammonia’s the favorable reactivity range of ammonia and enhancing NH₃ oxidation, particularly under moderate AEF conditions (5–10%) where ammonia and CTL demonstrate strong synergy. For emissions, moderate post-injection notably reduces CO at low AEFs, while NO_X emissions consistently decrease with increasing post-injection quantity, with greater suppression observed at higher AEFs. Soot emissions are also effectively reduced under post-injection conditions. Although total hydrocarbon (THC) emissions increase due to ammonia’s low reactivity, post-injection mitigates this accumulation trend to some extent, demonstrating overall co-benefits for emission control. Comprehensive evaluation indicates that the combination of 5–10% AEF, 8–12 mg post-injection quantity, and post-injection timing of 10–15 °CA achieves the most favorable balance of combustion efficiency, emissions reduction, and reaction stability, confirming the potential of the CTL–ammonia dual-fuel system for clean and efficient combustion. Full article

In this study, praseodymium-doped cobalt ferrite nanoparticles (CoFe_2−yPr_yO₄, y = 0–0.2) were synthesized via sol-gel auto-combustion and systematically characterized to assess their structural, morphological, magnetic, and biological properties. X-ray diffraction (XRD) confirmed single-phase cubic cobalt ferrite formation for samples with y ≤ 0.05 and the emergence of a secondary orthorhombic PrFeO₃ phase at higher dopant concentrations. FTIR spectroscopy identified characteristic metal–oxygen vibrations and revealed a progressive shift of absorption bands with increasing praseodymium (Pr) content. Vibrating sample magnetometry (VSM) demonstrated a gradual decline in saturation (Ms) and remanent (Mr) magnetization with Pr doping, an effect further intensified by cyclodextrin surface coating. TEM analyses revealed a particle size increase correlated with dopant level, while SEM images displayed a porous morphology typical of combustion-synthesized ferrites. In vitro cell viability assays showed minimal toxicity in normal human keratinocytes (HaCaT), while significant antiproliferative activity was observed against human cancer cell lines A375 (melanoma), MCF-7 (breast adenocarcinoma), and HT-29 (colorectal adenocarcinoma), particularly in Pr 6-CD and Pr 7-CD samples. These findings suggest that Pr substitution and cyclodextrin coating can effectively modulate the physicochemical and anticancer properties of cobalt ferrite nanoparticles, making them promising candidates for future biomedical applications. Full article

Biodiesel and 2-methylfuran (MF) exhibit significant potential as alternative fuels due to advancements in their production techniques. Despite this potential, the low cetane number (CN) of biodiesel–MF (BMF) blends limits their practical use in diesel engines due to poor auto-ignition characteristics and extended ignition delays. This study addresses this issue by investigating the impact of the cetane improver 2-ethylhexyl nitrate (2-EHN) on the performance and emissions of a BMF30 blend. The blend consists of 70% biodiesel and 30% MF, with 2-EHN added at concentrations of 1% and 1.5% to enhance ignition properties. The experiments were conducted on a four-cylinder, four-stroke, direct-injection compression ignition (DICI) engine at a constant speed of 1800 rpm with brake mean effective pressures (BMEP) ranging from 0.13 to 1.13 MPa. The results showed that 2-EHN improved the CN of the BMF30 blend, leading to earlier combustion initiation and longer combustion duration. At low BMEP (0.13 MPa), 2-EHN increased the peak rate of heat release and in-cylinder pressure, whereas at higher BMEP (0.88 MPa), these parameters decreased. The key findings include a reduction in brake-specific fuel consumption (BSFC) by 5.49–7.33% and an increase in brake thermal efficiency (BTE) by 3.30–4.69%. Additionally, NOx emissions decreased by 9.4–17.48%, with the highest reduction observed at 1.5% 2-EHN. CO emissions were reduced by 45.1–85.5% and soot emissions also declined. Hydrocarbon (HC) emissions decreased by 14.56–24.90%. These findings demonstrate that adding 2-EHN to BMF30 blends enhances engine performance, reduces key emissions, and offers a promising alternative fuel for diesel engines. Full article

In this work, we synthesized the Co_0.85Bi_0.15Fe_1.9X_0.1O₄ (X = Ce³⁺, Sm³⁺, Ho³⁺, and Er³⁺) nanoparticles via the auto-combustion method. The cell viability against two breast cancer cells (MDA-MB-231 and T-47D cells) and the PC3 prostate cancer cells were carefully analyzed and correlated with the structural parameters and particle size values as well as the chemical composition. The produced compounds’ morphological and structural characteristics were performed using scanning transmission microscopy (TEM) and X-ray Diffraction (XRD). For all compounds, the analyses of the XRD experimental data revealed a structurally reversed cubic spinel with space group Fd-3m. All of the compounds had crystallites smaller than 45 nm which concorded well with the particle size values deduced from TEM images. Co_0.85Bi_0.15Fe_1.9Ho_0.1O₄ nanoparticles induced a high mortality of breast and prostate cancer cells (MDA-MB-231, T-47D, and PC3) while the Co_0.85Bi_0.15Fe_1.9Sm_0.1O₄ compound (higher particle size) reduced almost 35% of MDA-MB-231 cancer cells. With very low cytotoxicity against normal human cells, the Co_0.85Bi_0.15Fe_1.9Ho_0.1O₄ nanoparticles play a significant role in the elimination of cancer cells. Full article

In this study, copper ferrite nanoparticles, a type of ferrimagnetic spinel ferrite, were synthesized using the sol-gel auto-combustion method with three different fuels: citric acid, urea, and ethylene glycol. The crystal structures of the synthesized samples were analyzed using X-ray diffraction (XRD), and the growth of secondary phases like Fe₂O₃ and CuO for samples prepared with urea and ethylene glycol indicated the presence of impurities. Additionally, we observed that the particle size varied significantly with the type of fuel, being the smallest for citric acid and the largest for urea. The electrical and magnetic properties showed strong correlations with the particle size and the presence of impurities. In particular, the optical band gap values, derived from UV-Vis spectroscopy, varied significantly with the choice of fuel, ranging from 2.06 to 3.75 eV. The highest band gap of 3.75 eV was observed in samples synthesized with citric acid. Magnetic properties were measured using a vibrating sample magnetometer (VSM), and it was found that the copper ferrite synthesized with citric acid exhibited the highest values of magnetic saturation and coercivity. These findings demonstrate that the choice of fuel during the synthesis process has substantial impacts on the structural, optical, and magnetic properties of CuFe₂O₄ nanoparticles. Full article

As a zero-carbon fuel, ammonia can be directly employed in its liquid form. However, its unique physical and chemical properties pose challenges to its application in engines. The direct injection of liquid ammonia is considered a promising technique for internal combustion engines, yet its combustion behavior is still not well understood. In this work, the combustion characteristics of liquid ammonia direct injection under high-pressure conditions were investigated using direct numerical simulation (DNS) in a Eulerian–Lagrangian framework. The ammonia spray was injected via a circular nozzle and underwent combustion under high-temperature and high-pressure conditions, resulting in complex turbulent spray combustion. It was found that the peaks of mass fraction of important species, heat release rate, and gaseous temperature increase with increasing axial distance, and the peaks shifted to richer mixtures. The distribution of scalar dissipation rate at various locations is nearly log-normal. The budget analysis of species transport equations shows that the reaction term is much larger than the diffusion term, suggesting that auto-ignition plays a predominant role in turbulent ammonia spray flame stabilization. It can be observed that both non-premixed and premixed combustion modes co-exist in the ammonia spray combustion. Moreover, the contribution of premixed combustion becomes more significant as the axial distance increases. Full article

The vigorous development of marine engines fueled by natural gas can effectively support the reform of energy structures in the field of ship power, aligning with the global trend toward sustainable development and green shipping. However, the presence of knock significantly hinders the improvement of engine thermal efficiency. Therefore, studying the knock mechanism in natural gas engines is not only crucial for enhancing engine power and economy but also for advancing the transition to cleaner and more sustainable energy sources in the maritime industry. In this paper, via a 2D numerical model, the dominant role in the knock mechanism of stoichiometric methane combustion in a combustion chamber of a rapid compression machine (RCM) is revealed. It further establishes the association mechanism between constant-volume combustion and pressure wave suppression at high temperatures. The results show that the knock is caused by the end-gas auto-ignition. The increase in initial temperature can significantly change auto-ignition modes and combustion modes, but initial pressure has little effect on this. The increase in initial temperature will inhibit the strength of pressure waves, and the increase in initial pressure cannot significantly increase the strength of pressure waves. The main cause why auto-ignition occurs earlier is not due to the increase in the strength of pressure waves, but the decrease in the required increase in temperature to attain ignition temperature caused by the increase in initial temperature. The peak pressure is affected by the initial pressure on the left wall before auto-ignition and the increase in pressure on the left wall at low to medium initial temperature. The pressure oscillation amplitude is positively correlated to the increase in pressure on the left wall. Constant volume combustion will occur at a high initial temperature. The increase and decrease in pressure are very uniform which will lead to the decrease in the pressure oscillation amplitude. The peak pressure depends on the influence of initial temperature and pressure on the increase in pressure produced by constant volume combustion. Full article

Ba_1−xSr_xFe₁₂O₁₉ (x = 0.0, 0.5 and 1.0) hard-magnetic nanohexaferrites prepared by autocombustion were primarily investigated using Mössbauer spectroscopy and optical studies. Morphological examination by electron scanning microscopy revealed that the particles agglomerated into grains with a hexagonal shape. The grain size increases with the amount of Sr content, from ca. 490 nm (x = 0.0) to ca. 700 nm (x = 1.0). Room-temperature Mössbauer spectroscopy showed that the mean hyperfine field increased with the substitution of Ba²⁺ by Sr²⁺, consistent with magnetization results. The preferential sites occupied by Fe ions in the hexaferrite structure were determined. Optical studies revealed that all compounds absorb up to ca. 1000 nm, and that the bandgap energy decreases with increasing Sr content. Full article