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33 pages, 5541 KB  
Article
Multiscale Dynamics Organizing Heavy Precipitation During Tropical Cyclone Hilary’s (2023) Remnant Passage over the Southwestern U.S.
by Jackson T. Wiles, Michael L. Kaplan and Yuh-Lang Lin
Atmosphere 2026, 17(1), 82; https://doi.org/10.3390/atmos17010082 - 14 Jan 2026
Abstract
The Weather Research and Forecasting Model (WRF-ARW) version 4.5 was used to simulate the synoptic to mesoscale evolving atmosphere of Tropical Cyclone (TC) Hilary’s (2023) remnant passage over the southwestern United States. The atmospheric dynamic processes conducive to the precursor rain events were [...] Read more.
The Weather Research and Forecasting Model (WRF-ARW) version 4.5 was used to simulate the synoptic to mesoscale evolving atmosphere of Tropical Cyclone (TC) Hilary’s (2023) remnant passage over the southwestern United States. The atmospheric dynamic processes conducive to the precursor rain events were extensively studied to determine the effects of mid-level jetogenesis. Concurrently, the dynamics of mesoscale processes related to the interaction of TC Hilary over the complex topography of the western United States were studied with several sensitivity simulations on a nested 2 km × 2 km grid. The differential surface heating between the cloudy California coast and clear/elevated Great Basin plateau had a profound impact on the lower-mid-tropospheric mass field resulting in mid-level jetogenesis. Diagnostic analyses of the ageostrophic flow support the importance of both isallobaric and inertial advective forcing of the mid-level jetogenesis in response to differential surface sensible heating. This ageostrophic mesoscale jet ultimately transported tropical moisture in multiple plumes more than 1000 km poleward beyond the location of the extratropical transition of the storm, resulting in anomalous flooding precipitation within a massive arid western plateau. Full article
(This article belongs to the Section Meteorology)
28 pages, 2958 KB  
Article
Spatiotemporal Wind Speed Changes Along the Yangtze River Waterway (1979–2018)
by Lei Bai, Ming Shang, Chenxiao Shi, Yao Bian, Lilun Liu, Junbin Zhang and Qian Li
Atmosphere 2026, 17(1), 81; https://doi.org/10.3390/atmos17010081 - 14 Jan 2026
Abstract
Long-term wind speed changes over the Yangtze River waterway have critical implications for inland shipping efficiency, emission dispersion, and renewable energy potential. This study utilizes a high-resolution 5 km gridded reanalysis dataset spanning 1979–2018 to conduct a comprehensive spatiotemporal analysis of surface wind [...] Read more.
Long-term wind speed changes over the Yangtze River waterway have critical implications for inland shipping efficiency, emission dispersion, and renewable energy potential. This study utilizes a high-resolution 5 km gridded reanalysis dataset spanning 1979–2018 to conduct a comprehensive spatiotemporal analysis of surface wind climatology, variability, and trends along China’s primary inland waterway. A pivotal regime shift was identified around 2000, marking a transition from terrestrial stilling to a recovery phase characterized by wind speed intensification. Multiple change-point detection algorithms consistently identify 2000 as a pivotal turning point, marking a transition from the late 20th century “terrestrial stilling” to a recovery phase characterized by wind speed intensification. Post-2000 trends reveal pronounced spatial heterogeneity: the upstream section exhibits sustained strengthening (+0.02 m/s per decade, p = 0.03), the midstream shows weak or non-significant trends with localized afternoon stilling in complex terrain (−0.08 m/s per decade), while the downstream coastal zone demonstrates robust intensification exceeding +0.10 m/s per decade during spring–autumn daytime hours. Three distinct wind regimes emerge along the 3000 km corridor: a high-energy maritime-influenced downstream sector (annual means > 3.9 m/s, diurnal peaks > 6.0 m/s) dominated by sea breeze circulation, a transitional midstream zone (2.3–2.7 m/s) exhibiting bimodal spatial structure and unique summer-afternoon thermal enhancement, and a topographically suppressed upstream region (<2.0 m/s) punctuated by pronounced channeling effects through the Three Gorges constriction. Critically, the observed recovery contradicts widespread basin greening (97.9% of points showing significant positive NDVI trends), which theoretically should enhance surface roughness and suppress wind speeds. Correlation analysis reveals that wind variability is systematically controlled by large-scale atmospheric circulation patterns, including the Northern Hemisphere Polar Vortex (r ≈ 0.35), Western Pacific Subtropical High (r ≈ 0.38), and East Asian monsoon systems (r > 0.60), with distinct seasonal phase-locking between baroclinic spring dynamics and monsoon-thermal summer forcing. These findings establish a comprehensive, fine-scale climatological baseline essential for optimizing pollutant dispersion modeling, and evaluating wind-assisted propulsion feasibility to support shipping decarbonization goals along the Yangtze Waterway. Full article
(This article belongs to the Section Meteorology)
24 pages, 2004 KB  
Article
A New Antenna Pattern Correction Method for a Cross-Track Scanning Microwave Sounder with Full-Circular Sampling
by Guohong Fan and Zhenzhan Wang
Remote Sens. 2026, 18(2), 277; https://doi.org/10.3390/rs18020277 - 14 Jan 2026
Abstract
The measured antenna temperature of microwave radiometers differs from the true brightness temperature due to antenna pattern effects. Corrections for the antenna pattern effects constitutes an essential component of microwave radiometer calibration. The Compact Atmospheric Microwave Sounder (CAMS) is a cross-track scanning microwave [...] Read more.
The measured antenna temperature of microwave radiometers differs from the true brightness temperature due to antenna pattern effects. Corrections for the antenna pattern effects constitutes an essential component of microwave radiometer calibration. The Compact Atmospheric Microwave Sounder (CAMS) is a cross-track scanning microwave designed for small satellites. It adopts full-circle sampling on the scan plane. Leveraging its special scan geometry, a new method of antenna pattern correction (APC) is developed. This method utilizes adjacent samplings from consecutive scans to obtain APC coefficients, and correct antenna temperature to the pixel level brightness temperature. For the first time, real samplings from beyond the Earth swath are introduced to assist APC near the swath edges. The performance of the method are analyzed through scenarios of coastlines and Earth swath edges. Analysis in the coastline scenarios demonstrates that the proposed method is more effective in correcting antenna pattern effects and detecting brightness temperature variations than traditional APC approaches in heterogeneous Earth scenarios. Comparative analysis of the method at Earth swath edges demonstrates that the introduction of samplings outside the swath effectively enhances the precision of corrected brightness temperature at swath edges. This method provides a reference for antenna pattern correction and sampling strategy in other microwave radiometers. Full article
(This article belongs to the Section Atmospheric Remote Sensing)
19 pages, 4319 KB  
Article
Numerical Simulation of Tritiated Water Transfer by Moist Air in Nuclear Power Station
by Yifan Cheng, Xi Xu, Kefeng Lyu, Yang Li, Kun Hu, Yongfang Xia and Xudan Ma
Processes 2026, 14(2), 286; https://doi.org/10.3390/pr14020286 - 14 Jan 2026
Abstract
This study investigates the dispersion and condensation behavior of tritiated water vapor released into the atmosphere using moist air as a carrier, with an emphasis on safety optimization for nuclear power plant effluent discharge. A coupled heat and mass transfer model was developed [...] Read more.
This study investigates the dispersion and condensation behavior of tritiated water vapor released into the atmosphere using moist air as a carrier, with an emphasis on safety optimization for nuclear power plant effluent discharge. A coupled heat and mass transfer model was developed and implemented in CFD simulations to analyze the evolution of temperature and relative humidity during the mixing of exhaust moist air with ambient air. The effects of key atmospheric and operational parameters—including the ambient wind speed, turbulence intensity, ambient temperature, relative humidity, and exhaust velocity—were systematically examined. The results indicate that the temperature difference between the exhaust gas and ambient air is the primary factor governing condensation risk. Low wind speeds and weak turbulence favor near-field humidity accumulation, while higher wind speeds and turbulence intensities enhance mixing and dilution, thereby reducing local humidity peaks but extending the downwind impact range. Increasing exhaust velocity strengthens plume rise and long-range transport due to enhanced momentum and latent heat release, mitigating accumulation near the chimney outlet. Furthermore, high ambient temperatures significantly increase the air’s moisture-holding capacity, allowing higher exhaust humidity without inducing condensation. Full article
(This article belongs to the Section Process Safety and Risk Management)
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30 pages, 7793 KB  
Article
A New Sea Ice Concentration (SIC) Retrieval Algorithm for Spaceborne L-Band Brightness Temperature (TB) Data
by Yin Hu, Shaoning Lv, Zhijin Li, Yijian Zeng, Xiehui Li, Yijun Zhang and Jun Wen
Remote Sens. 2026, 18(2), 265; https://doi.org/10.3390/rs18020265 - 14 Jan 2026
Abstract
Sea ice concentration (SIC) is crucial to the global climate. In this study, a new single-channel SIC retrieval algorithm utilizing spaceborne L-band brightness temperature (TB) measurements is developed based on a microwave radiative transfer model. Additionally, its four uncertainties are quantified [...] Read more.
Sea ice concentration (SIC) is crucial to the global climate. In this study, a new single-channel SIC retrieval algorithm utilizing spaceborne L-band brightness temperature (TB) measurements is developed based on a microwave radiative transfer model. Additionally, its four uncertainties are quantified and constrained: (1) variations in seawater reference TB under warm water conditions, (2) variations in sea ice reference TB under extremely low-temperature conditions, (3) the freeze–thaw dynamics of sea ice captured by Diurnal Amplitude Variation (DAV) signals, and (4) Land mask imperfections. It is found that DAV has the most pronounced effect: eliminating its influence reduces RMSE from 10.51% to 8.43%, increases R from 0.92 to 0.94, and minimizes Bias from -0.68 to 0.13. Suppressing all four uncertainties lowers RMSE to 7.42% (a 3% improvement). Furthermore, the algorithm exhibits robust agreement with the seasonal variability of SSM/I SIC, with R mostly exceeding 0.9, RMSE mostly below 10%, and Biases mostly within 5% throughout the year. Compared to ship-based and SAR SIC data, the new L-band algorithm’s Bias and RMSE are only 2% and 2% (ship-based)/2% and 1% (SAR) higher, respectively, than those of the SSM/I product. Future algorithms can integrate the DAV signal more effectively to better understand sea ice freeze–thaw processes and ice-atmosphere interactions. Full article
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21 pages, 1231 KB  
Article
Undervalued Contribution of OVOCs to Atmospheric Activity: A Case Study in Beijing
by Kaitao Chen, Ziyan Chen, Fang Yang, Xingru Li and Fangkun Wu
Toxics 2026, 14(1), 77; https://doi.org/10.3390/toxics14010077 - 14 Jan 2026
Abstract
VOCs are significant precursors for the formation of O3 and SOA, directly impacting human health. This study employs multiple approaches to analyzing atmospheric VOCs by focusing on OVOCs including aldehydes, ketones, and phenols, with a case study in Beijing, China. We analyzed [...] Read more.
VOCs are significant precursors for the formation of O3 and SOA, directly impacting human health. This study employs multiple approaches to analyzing atmospheric VOCs by focusing on OVOCs including aldehydes, ketones, and phenols, with a case study in Beijing, China. We analyzed the concentration levels and compositions of VOCs and their atmospheric activities, offering a new perspective on VOCs. This analysis was conducted through offline measurements of volatile phenols and carbonyl compounds, complemented by online VOC observations during the summer period of high O3 levels. The total atmospheric VOCs concentration was found to be 51.29 ± 10.01 ppbv, with phenols contributing the most (38.87 ± 11.57%), followed by carbonyls (34.91 ± 6.85%), and aromatics (2.70 ± 1.03%, each compound is assigned to only one category based on its primary functional group, with no double counting). Carbonyls were the largest contributors to the OFP at 59.03 ± 14.69%, followed by phenols (19.94 ± 4.27%). The contribution of phenols to the SOAFP (43.37 ± 9.53%) and the LOH (67.74 ± 16.72%) is dominant. Among all quantified VOC species, phenol and formaldehyde exhibited the highest species-level contributions to atmospheric reactivity metrics, including LOH, OFP and SOAFP, owing to their combination of elevated concentrations and large kinetic or MIR coefficients. Using the PMF model for source analysis, six main sources of volatile organic compounds were identified. Solvent use and organic chemicals production were found to be the primary contributors, accounting for 31.76% of the total VOCs emissions, followed by diesel vehicle exhaust (17.80%) and biogenic sources (15.51%). This study introduces important OVOCs such as phenols, re-evaluates the importance of OVOCs and their role in atmospheric chemical processes, and provides new insights into atmospheric VOCs. These findings are crucial for developing effective air pollution control strategies and improving air quality. This study emphasizes the importance of OVOCs, especially aldehydes and phenols, in the mechanism of summer O3 generation. Full article
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22 pages, 8822 KB  
Article
Potential Recovery and Recycling of Condensate Water from Atlas Copco ZR315 FF Industrial Air Compressors
by Ali Benmoussa, Zakaria Chalhe, Benaissa Elfahime and Mohammed Radouani
Inventions 2026, 11(1), 10; https://doi.org/10.3390/inventions11010010 - 14 Jan 2026
Abstract
This research examines the feasibility of recovering and recycling condensate water, a waste byproduct generated by Atlas Copco ZR315 FF industrial air compressors utilizing oil-free rotary screw technology with integrated dryers. Given the growing severity of global water scarcity, finding alternative water sources [...] Read more.
This research examines the feasibility of recovering and recycling condensate water, a waste byproduct generated by Atlas Copco ZR315 FF industrial air compressors utilizing oil-free rotary screw technology with integrated dryers. Given the growing severity of global water scarcity, finding alternative water sources is essential for sustainable industrial practices. This study specifically evaluates the potential of capturing and treating compressed air condensate as a viable method for water recovery. The investigation analyzes both the quantity and quality of condensate water produced by the ZR315 FF unit. It contrasts this recovery approach with traditional water production methods, such as desalination and atmospheric water generation (AWG) via dehumidification. The findings demonstrate that recovering condensate water from industrial air compressors is a cost-effective and energy-efficient substitute for conventional water production, especially in water-stressed areas like Morocco. The results show a significant opportunity to reduce industrial water usage and provide a sustainable source of process water. This research therefore supports the application of circular economy principles in industrial water management and offers practical solutions for overcoming water scarcity challenges within manufacturing environments. Full article
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16 pages, 9276 KB  
Article
Study of Co-Combustion of Pellets and Briquettes from Lignin in a Mixture with Sewage Sludge
by Andrey Zhuikov, Tatyana Pyanykh, Mikhail Kolosov, Irina Grishina, Olga Fetisova, Petr Kuznetsov and Stanislav Chicherin
Energies 2026, 19(2), 397; https://doi.org/10.3390/en19020397 - 14 Jan 2026
Abstract
Improving the thermal utilisation of organic production waste to generate energy is integral to solving one of the most pressing issues of our time: transitioning away from fossil fuels. In this context, the thermal utilisation of organic waste, particularly sewage sludge (SS) and [...] Read more.
Improving the thermal utilisation of organic production waste to generate energy is integral to solving one of the most pressing issues of our time: transitioning away from fossil fuels. In this context, the thermal utilisation of organic waste, particularly sewage sludge (SS) and lignin-containing by-products from the biochemical industry, is of considerable scientific and practical interest. This study provides a thorough analysis of the co-combustion processes involving SS, lignin-based pellets and briquettes, and their mixtures with various component ratios. The aim of the work is to evaluate the fuel properties, thermokinetic characteristics, and potential for synergistic interactions during joint fuel combustion, considering the mechanical impact on lignin during granulation. The aim is to optimise conditions for the thermal utilisation of industrial waste. The study employed standard analytical methods: the thermophysical properties of the fuels were determined; morphological analysis of the particle surface was conducted using scanning electron microscopy; and X-ray fluorescence analysis was performed to identify the inorganic oxide phase. It has been established that lignin briquettes have the highest lower heating value, exceeding that of lignin pellets and sewage sludge by 7% and 27%, respectively. Thermogravimetric analysis (TGA) in an oxidising atmosphere (air, heating rate of 10 °C/min) made it possible to determine the following key combustion parameters: the ignition temperature of the coke residue (Ti); the temperature at which oxidation is complete (Tb); the maximum combustion rate (Rmax); and the combustion efficiency index (Q). The ignition temperature of the coke residue was 262.1 °C for SS, 291.8 °C for lignin pellets, and 290.0 °C for lignin briquettes. Analysis of co-combustion revealed non-linear behaviour in the thermograms, indicating synergistic effects, which are manifested by a decrease in the maximum combustion rate compared to the additive prediction, particularly in mixtures with a moderate lignin content (25–50%). It was established that the main synergistic interactions between the mixture components occurred during moisture evaporation and the combustion of coke residue. These results are valuable for designing and operating power plants that focus on co-combusting industrial organic waste, and they contribute to the development of thermal utilisation technologies within closed production cycles. Full article
(This article belongs to the Section I2: Energy and Combustion Science)
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22 pages, 3058 KB  
Article
Concurrent Decadal Trend Transitions of Sea Ice Concentration and Sea Surface pCO2 in the Beaufort Sea
by Shangbin Chi and Meibing Jin
Remote Sens. 2026, 18(2), 257; https://doi.org/10.3390/rs18020257 - 13 Jan 2026
Abstract
Interannual climate changes and increasing atmospheric CO2 (AtmCO2) have significantly altered sea surface partial pressure of CO2 (pCO2) in the Beaufort Sea (BS). Yet, their decadal variability and underlying mechanisms remain inadequately understood. Using observational [...] Read more.
Interannual climate changes and increasing atmospheric CO2 (AtmCO2) have significantly altered sea surface partial pressure of CO2 (pCO2) in the Beaufort Sea (BS). Yet, their decadal variability and underlying mechanisms remain inadequately understood. Using observational data and the Regional Arctic System Model (RASM), a decreasing trend transition of the BS summer surface pCO2 was identified at around 2010–2012. Sensitivity cases reveal that the decadal trend transition in surface pCO2 (early: 4.12 ± 0.80 μatm/yr, p < 0.05 and late: 1.23 ± 2.22 μatm/yr, p > 0.05) is driven by interannual climate changes. While the long-term increase in AtmCO2 does not directly drive surface pCO2 trend transition, it reduces its magnitude. The sensitivity experiment with no interannual AtmCO2 changes from 1990 reveals that the statistically significant contributor of the decadal trend transition in surface pCO2 is the concurrent transition in sea ice concentration (SIC, early: −0.0120 ± 0.0037/yr, p < 0.05 and late: 0.0101 ± 0.0063/yr, p > 0.05). The decadal trend transitions in the subsurface and deep layer pCO2 are negligible compared to that in the sea surface pCO2 due to the insignificant influence of interannual climate changes on subsurface and deep layer pCO2. The surface pCO2 decadal trend transition is significantly correlated with a trend transition of CO2 sink. On seasonal timescales, the effects of SIC on the decadal trend transition of pCO2 occur primarily within the duration of open-water (DOW), and align with the decadal trend transitions in the open-water start day, end day, and DOW. The magnitude of sea surface pCO2 trend transition increases as the magnitude of the DOW trend transition increases. Full article
(This article belongs to the Special Issue Remote Sensing for Monitoring Water and Carbon Cycles)
28 pages, 604 KB  
Review
Remote Sensing Effects and Invariants in Land Surface Studies
by Hongliang Fang
Remote Sens. 2026, 18(2), 248; https://doi.org/10.3390/rs18020248 - 13 Jan 2026
Abstract
Remote sensing is a technique to acquire information from a distance. Remote sensing effects refer to any factors that need to be considered in remote sensing processes, while remote sensing invariants represent features that remain stable throughout these processes. Both remote sensing effects [...] Read more.
Remote sensing is a technique to acquire information from a distance. Remote sensing effects refer to any factors that need to be considered in remote sensing processes, while remote sensing invariants represent features that remain stable throughout these processes. Both remote sensing effects and invariants are fundamental to the study of remote sensing systems, methods, algorithms, products, and applications. Many studies have explored different effects and invariants independently, yet these studies are scattered across the literature and a comprehensive synthesis is lacking within the community. This paper intends to synthesize various remote sensing effects and invariants under a unified framework. The characterization, underlying principles, and potential applications of a selected group of remote sensing effects were first examined. Subsequently, a suite of nine key effects, atmospheric effects, background effects, clumping effects, directional effects, heterogeneity effects, saturation effects, scaling effects, temporal effects, and topographic effects, were addressed. Furthermore, a list of remote sensing invariants, including spectral, spatial, temporal, directional, and thematical invariants, were analyzed. Potential directions for future studies were further discussed. This synthesis represents a concerted effort to advance the theoretical understanding of fundamental principles in remote sensing science. Full article
(This article belongs to the Section AI Remote Sensing)
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23 pages, 14617 KB  
Article
Quantitative Study of Urban Ventilation Corridors’ Impact on the Atmospheric Environment Based on Circuit Theory
by Chong Liu, Mingsong Zhan, Xuefeng Zhao, Jianbing Wei, Yuanman Hu, Chunlin Li, Yaqi Chu and Fengyuan Sun
Buildings 2026, 16(2), 329; https://doi.org/10.3390/buildings16020329 - 13 Jan 2026
Abstract
Urbanization and industrialization have led to the coexistence of winter haze and summer heat island in some cities in northern China, but the mitigation effect of ventilation corridors is lack of quantitative evaluation. This paper introduces circuit theory into urban climate research. Taking [...] Read more.
Urbanization and industrialization have led to the coexistence of winter haze and summer heat island in some cities in northern China, but the mitigation effect of ventilation corridors is lack of quantitative evaluation. This paper introduces circuit theory into urban climate research. Taking Shenyang as a case study, it comprehensively employs three-dimensional urban landscape pattern indices (including SVF, FAD, and Z0) to guide ventilation corridor construction, establishes an analytical framework for PM2.5 and LST, and quantifies the environmental benefits of ventilation corridors. The results show that the corridor generated by circuit theory can make 65.14% of path PM lower than the average level of the city; Among the 7 exit paths of wind corridors, the surface temperature of 4 channels is lower than the average level of the city. FAD is positively correlated with Z0 (R2 = 0.7) and negatively correlated with SVF (R2 = 0.61). Meanwhile, the circuit theory model identifies eight pinch points along ventilation paths. CFD software is employed to simulate atmospheric environments for six typical building layouts to guide subsequent urban planning. Therefore, the reasonable layout of urban morphology indicators and the construction of reasonable ventilation corridors can effectively control the atmospheric particulate pollution and the heat island effect in summer. Full article
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16 pages, 2284 KB  
Communication
Embedding Rhetorical Competence in Medical Education: A Communication-Focused Course Innovation for Medical Students
by József L. Szentpéteri, Roland Hetényi, Dávid Fellenbeck, Kinga Dávid, Kata Kumli and Péter Szabó
Educ. Sci. 2026, 16(1), 111; https://doi.org/10.3390/educsci16010111 - 13 Jan 2026
Abstract
Effective communication is essential for professional practice, yet medical curricula rarely incorporate systematic, performance-based training. The Sell Yourself!—Presentation Techniques course was developed to address this gap through a two-day, practice-oriented program integrating rhetorical training, evolutionary psychology, and structured peer feedback. We examined anonymized [...] Read more.
Effective communication is essential for professional practice, yet medical curricula rarely incorporate systematic, performance-based training. The Sell Yourself!—Presentation Techniques course was developed to address this gap through a two-day, practice-oriented program integrating rhetorical training, evolutionary psychology, and structured peer feedback. We examined anonymized institutional evaluations from 450 medical students using descriptive statistics and combined inductive–deductive thematic and content coding to gauge the perceived educational utility of the course. The course received a mean satisfaction rating of 9.6/10, with approximately 74% of students assigning the maximum score. Inductive analysis identified interactivity (143 mentions), practical usefulness (76), feedback and improvement (75), positive atmosphere (51), instructor quality (47), and multimedia examples (37) as key strengths, while critiques primarily concerned breaks and scheduling (62), course length and intensity (59), and smaller concerns regarding feedback processes, content structure, and technical issues. Deductive coding indicated perceived improvements across five predefined dimensions: increased confidence, rhetorical fluency, feedback quality, peer recognition, and cultural inclusivity. Structured rhetorical training appears to be well received by learners and may provide a feasible model for embedding communication competence in medical education. These findings also offer a transferable template for integrating performance-based communication training into other programs. However, conclusions are limited by reliance on self-reported perceptions and the absence of a control group or direct assessment of applied communication outcomes. Full article
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22 pages, 2707 KB  
Article
Substituent and Ring-Number Effects on the Kinetics of PAH + OH Reactions: A QSAR–DOE Approach with Tunneling Corrections
by Cezary Parzych, Maciej Baradyn and Artur Ratkiewicz
Molecules 2026, 31(2), 265; https://doi.org/10.3390/molecules31020265 - 13 Jan 2026
Abstract
The reactions of hydrogen transfer by hydroxyl radicals involving polycyclic aromatic hydrocarbons (PAH) are important, because these compounds contribute to environmental pollution and negatively affect human health. Hydroxyl radicals play a key role in atmospheric processes. This study analyzed the influence of the [...] Read more.
The reactions of hydrogen transfer by hydroxyl radicals involving polycyclic aromatic hydrocarbons (PAH) are important, because these compounds contribute to environmental pollution and negatively affect human health. Hydroxyl radicals play a key role in atmospheric processes. This study analyzed the influence of the substituent and the number of aromatic rings in the compound on the kinetics of the hydrogen-transfer reaction. This work proposes for the first time a quantitative structure–activity relationship-based statistical framework combining design of experiments and tunneling corrections to predict PAH + ·OH kinetics. The main objective of this research was to identify which molecular features and substituent effects most strongly govern tunneling and reactivity, thereby enabling the rational prediction of PAH behavior in atmospheric and combustion environments. For this purpose, a quantitative structure–activity relationship model was developed using 22 descriptors, and their relationship with the kinetic parameters of the reaction was determined using statistical tools such as design of experiments and partial least squares. Full article
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24 pages, 4343 KB  
Article
Preparation of CO2-Adsorbing Fire-Extinguishing Gel and Study on Inhibition of Coal Spontaneous Combustion
by Jianguo Wang, Zhenzhen Zhang and Conghui Li
Gels 2026, 12(1), 68; https://doi.org/10.3390/gels12010068 - 12 Jan 2026
Viewed by 14
Abstract
Spontaneous coal combustion accounts for more than 90% of mine fires, and at the same time, the ‘dual carbon’ strategy requires fire prevention and extinguishing materials to have both low-carbon and environmentally friendly functions. To meet on-site application needs, a composite gel with [...] Read more.
Spontaneous coal combustion accounts for more than 90% of mine fires, and at the same time, the ‘dual carbon’ strategy requires fire prevention and extinguishing materials to have both low-carbon and environmentally friendly functions. To meet on-site application needs, a composite gel with fast injection, flame retardant, and CO2 adsorption functions was developed. PVA-PEI-PAC materials were selected as the gel raw materials, and an orthogonal test with three factors and three levels was used to optimize the gelation time parameters to identify the optimal formulation. The microstructure of the gel, CO2 adsorption performance, as well as its inhibition rate of CO, a marker gas of coal spontaneous combustion, and its effect on activation energy were systematically characterized through SEM, isothermal/temperature-programmed/cyclic adsorption experiments, and temperature-programmed gas chromatography. The results show that the optimal gel formulation is 14% PVA, 7% PEI, and 5.5% PAC. The gel microstructure is continuous, dense, and rich in pores, with a CO2 adsorption capacity at 30 °C and atmospheric pressure of 0.86 cm3/g, maintaining over 76% efficiency after five cycles. Compared with raw coal, a 10% gel addition reduces CO release at 170 °C by 25.97%, and the temperature-programmed experiment shows an average CO inhibition rate of 25% throughout, with apparent activation energy increased by 14.96%. The gel prepared exhibited controllable gelation time, can deeply encapsulate coal, and can efficiently adsorb CO2, significantly raising the coal–oxygen reaction energy barrier, providing an integrated technical solution for mine fire prevention and extinguishing with both safety and carbon reduction functions. Full article
(This article belongs to the Special Issue Gels for Adsorption and Separation)
16 pages, 2169 KB  
Article
Concentrations and Estimation of Sources of Ultrafine Particles in the City of Belgrade at Ada Marina Urban Background Site
by Željko Ćirović, Danka B. Stojanović, Miloš Davidović, Antonije Onjia, Meritxell Garcia-Marlès, Noemí Pérez Lozano, Andres Alastuey and Milena Jovašević-Stojanović
Environments 2026, 13(1), 47; https://doi.org/10.3390/environments13010047 - 12 Jan 2026
Viewed by 102
Abstract
Particulate matter is widely known as a significant air pollutant due to its proven detrimental impact on human health. Furthermore, ultrafine particles (UFPs) are those with diameters smaller than 100 nm, which can cause numerous serious health effects. Thus, identifying the sources of [...] Read more.
Particulate matter is widely known as a significant air pollutant due to its proven detrimental impact on human health. Furthermore, ultrafine particles (UFPs) are those with diameters smaller than 100 nm, which can cause numerous serious health effects. Thus, identifying the sources of UFPs is essential for formulating effective mitigation strategies. Quantifying the contributions of particle sources can be performed by measuring particle number size distributions (PNSDs) for specific size ranges. This study was conducted in the city of Belgrade, the capital of Serbia, and one of the largest cities in the Balkans peninsula, which, within the European framework, belongs to a region and urban area characterized by high levels of atmospheric particulate matter pollution. In addition, there is a lack of studies addressing UFP levels and their sources in Serbia, including Belgrade. Several criteria pollutants were measured, together with the UFPs and equivalent black carbon (BC) at the urban background site in the city of Belgrade, Serbia, for the period from February to August 2024. The particle sources were analyzed using Positive Matrix Factorization (PMF) of PNSDs along with equivalent BC, PM10, PM2.5, O3, SO2, NO, NO2 and NOx. Seven source types were identified, characterized, and quantified, including two traffic sources (separated into traffic 1 and traffic 2), mixed traffic, an urban diffuse source, nucleation and nucleation growth sources, and a biomass burning source. Traffic-related sources were found to have the most significant contribution at around 40% of total particles emitted, followed by nucleation-related sources (24%) and biomass burning (20%). This is the first study performed in Serbia and Belgrade that addresses source apportionment of PNSD, for particles in the range 10–400 nm. Full article
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