Search Results (102)

This study evaluated birch and oak ash extracts as alternative extractants for isolating humic substances (HSs) from peat and lignite. The effects of ultrasound intensity, extraction time, and temperature were optimized using a Box–Behnken design and validated statistically. The highest HSs yields were obtained from peat with oak ash extract (pH 13.18), compared to birch ash extract (pH 12.09). Optimal process parameters varied by variant, falling within 309–391 mW∙cm⁻², 116–142 min, and 67–79 °C. HSs extracted under optimal conditions were fractionated into humic acids (HAs) and fulvic acids (FAs), and then analyzed by elemental analysis, Fourier Transform Infrared Spectroscopy (FTIR), and Cross-Polarization Magic Angle Spinning Carbon-13 Nuclear Magnetic Resonance Spectroscopy (CP/MAS ¹³C NMR). The main differences in HSs quality were influenced by raw material and fraction type. However, the use of birch ash extract consistently resulted in a higher proportion of carboxylic structures across all fractions. Overall, wood ash extract, especially from oak, offers a sustainable and effective alternative to conventional extractants, particularly for HSs isolation from lignite. Notably, HSs yield from lignite with oak ash extract (29.13%) was only slightly lower than that achieved with 0.5 M NaOH (31.02%), highlighting its practical potential in environmentally friendly extraction technologies. Full article

As pet owners become increasingly mindful of pet health and sustainability, labeling plays a crucial role in shaping informed purchasing decisions for pet food. This study evaluated the nutritional adequacy and pricing of plant-based, hybrid, and animal-based dog foods. Using the Mintel database, we analyzed product labels, ingredient compositions, and marketing claims for various dog food categories. The findings revealed notable differences in key nutrients, such as protein, fiber, fat, ash, and moisture content. Plant-based dog foods generally offer higher fiber and ash content but often fall short in protein and fat levels, particularly in snacks and treats, which may impact their suitability for meeting the dietary needs of canines. Hybrid dog foods, which blend plant and animal ingredients, show greater variability, with some achieving balanced protein and fat content, while fiber levels depend on the plant-based proportion. Animal-based foods tend to excel in protein and fat content, particularly in wet and dry formats, while being lower in fiber and ash content. A key concern is the reliance on additives, particularly in plant-based and hybrid options, which raises questions about the long-term health impacts on pets. Pricing trends indicate that plant-based dog foods are generally more expensive than hybrid and animal-based options, although the cost varies widely across all categories. Full article

The combustion of hard coal and lignite in power and combined heat and power plants generates significant amounts of coal fly ash (CFA), a waste material with variable properties. CFA naturally contains radionuclides, specifically naturally occurring radioactive materials (NORMs), which pose potential radiological risks to the environment and human health during their storage and utilization, including their incorporation into building materials. Although global research on the radionuclide content in CFA is available, there is a clear gap in detailed and current data specific to Central and Eastern Europe and notably, a lack of a systematic analysis investigating the influence of installed power plant capacity on the concentration profile of these radionuclides in the generated ash. This study aimed to fill this gap and provide crucial data for the Polish energy and environmental context. The objective was to evaluate the concentrations of selected radionuclides (²³²Th, ²²⁶Ra, and ⁴⁰K) in coal fly ash samples collected between 2020 and 2023 from 19 Polish power and combined heat and power plants with varying capacities (categorized into four groups: S1–S4) and to assess the associated radiological risk. Radionuclide concentrations were determined using gamma spectrometry, and differences between groups were analyzed using non-parametric statistical methods, including PERMANOVA. The results demonstrated that plant capacity has a statistically significant influence on the concentration profiles of thorium and potassium but not radium. Calculated radiological hazard assessment factors (Ra_eq, H_ex, H_in, IAED) revealed that although most samples fall near regulatory limits (e.g., 370 Bq kg⁻¹ for Ra_eq), some exceed these limits, particularly in groups S1 (plants with a capacity less than 300 MW) and S4 (plants with a capacity higher than 300 MW). It was also found that the frequency of exceeding the annual effective dose limits (IAEDs) showed an increasing trend with the increasing installed capacity of the facility. These findings underscore the importance of plant capacity as a key factor to consider in the radiological risk assessment associated with coal fly ash. This study’s outcomes are crucial for informing environmental risk management strategies, guiding safe waste processing practices, and shaping environmental policies within the energy sector in Central and Eastern European countries, including Poland. Full article

Due to the high yield potential, suitable agrotechnical properties, and nutritional value of the grain, the interest in growing triticale is increasing due to the high yield potential, suitable agrotechnical properties, and nutritional value. This species is primarily grown for fodder purposes, but numerous studies suggest its potential for human consumption, including bread production. Additionally, triticale is known for its greater resistance to adverse environmental conditions compared to other crops, even under varying agronomic practices. A field experiment was conducted in southeastern Poland from 2019 to 2022. The study involved two cultivation systems (conventional and integrated) as one factor and three winter triticale cultivars (Belcanto, Meloman, and Panteon) as the other. The conventional system is based on the intensive cultivation of plants through the use of large amounts of fertilizers and crop protection products. The integrated system of cultivation is an alternative to the conventional system. This system aims to reduce the use of industrial inputs and, as a result, minimize the negative impact of agriculture on the natural environment. Cultivation under the conventional system resulted in higher grain yields and improved physiological parameter values. There was an increase in the leaf area index (LAI), relative chlorophyll content, chlorophyll fluorescence parameters, and gas exchange parameters (photosynthetic rate (Pn) and transpiration rate (E)). The highest yields were achieved with the cv-Panteon and cv-Belcanto under the conventional system. The yields of these cultivars in the integrated system did not differ significantly from those of cv-Meloman under the conventional system. In the 2021/2022 season, the weather conditions were the most favorable during the triticale vegetation period, which resulted in the highest grain yield. The conventional system also resulted in higher thousand-grain weight (TGW), crude protein content, and grain test weight while lowering the falling number (FN) value. However, the cultivation systems did not significantly affect the grain uniformity, crude fat, fiber, or ash content, as well as wet gluten and gluten index (GI). The cv-Panteon exhibited the highest level of crude protein, crude fiber, and crude ash in its grain, suggesting its strong nutritional value and potential for use in human consumption. The cultivation of triticale in the integrated system, although associated with lower yields, causes less environmental pollution than cultivation in the conventional system. The appropriate selection of efficient cultivars grown in the integrated system allows for high grain yields with good quality parameters. Full article

Medical tubing, particularly cardiovascular tubing, is a critical area of research where continuous improvements are necessary to advance medical devices and improve patient care. While polymers are fundamental for these applications, on their own they present several limitations such as insufficient X-ray contrasting capabilities. As such, polymer composites utilizing radiopaque fillers are a necessity for this application. For medical tubing in vivo, radiopacity is a crucial parameter that virgin polymers alone fall short in achieving due to limited X-ray absorption. To address this shortcoming, inorganic radiopaque fillers such as barium sulphate (BaSO₄) and bismuth oxychloride (BiOCl) are incorporated into polymer matrices to increase the X-ray contrast of the manufactured tubing. It is also known, however, that the incorporation of these fillers can affect the mechanical, physical, and thermal properties of the finished product. This research evaluated the impact of incorporating the two aforementioned fillers into Pebax^® 6333 SA01 MED at three different loading levels (10, 20, and 30 wt.%) on the physical, thermal, and mechanical properties of the composite. Composites were prepared by twin screw extrusion and injection molding followed by characterization of the mechanical (tensile, impact, and flexural), thermal (DSC), rheological (MFI), and physical (density and ash content) properties. The performed analysis shows that BiOCl enhanced the aesthetic properties, increased stiffness, and maintained flexibility while having minimal impact on the tensile and impact properties. When comparing BiOCl to BaSO₄-filled composites, it was clear that depending on the application of the polymer composite, BiOCl may provide more desirable properties. The study highlights the importance of optimizing filler concentration and processing conditions to achieve desired composite properties for specific medical applications. Full article

The fall armyworm, Spodoptera frugiperda, is a major migratory polyphagous insect pest of various crops. The essential nutrient and mineral profile of the host plants determines the feeding fitness of herbivorous insects. As a result, the growth and development of insects is affected. To determine the effect of the nutrient and mineral profile of different host plants (maize, castor bean, cotton, cabbage, okra, and sugarcane) on the growth and development of S. frugiperda, biological parameters like larval weight, pupal weight (male/female), and feeding and growth indices were calculated. The proximate compositions such as crude protein, crude fat, crude fibre, and ash and mineral contents of the tested host plants showed significant differences (p < 0.05). The feeding indices on these host plants also differed significantly (p < 0.05). The maximum relative growth rate (RGR), relative consumption rate (RCR), and consumption index (CI) were recorded in S. frugiperda larvae that fed on maize and castor bean leaves. The crude protein, dry matter, and ash contents in maize and castor bean were significantly higher and positively correlated with the RGR and RCR of S. frugiperda larvae. The larval, male and female pupal weights were the maximum in the larvae feeding on the castor bean host plant. These findings provide novel information based on nutritional ecology to develop sustainable integrated pest management strategies using selective crop rotation. Full article

This study presents the first U-Pb (CA-ID-TIMS) radioisotopic dating of zircon grains extracted from tonsteins within the uppermost Permian coal interval of the Minusinsk Coal Basin (Siberia, Russia). Petrographic, structural, and mineralogical analyses confirm the volcanic ash origin of the tonsteins. The parent pyroclastic materials are identified as rhyolite–pantellerite for tonstein I-22 and dacite–rhyodacite for tonstein I-12. Morphological analysis of zircon crystals, along with cathodoluminescence and melt inclusion studies, confirms their volcanic origin and crystallisation temperatures of 700–900 °C. New radioisotopic dates of 261.4 ± 0.7 Ma and 261.3 ± 0.4 Ma clarify the age of the Izykh Formation, enabling its direct correlation with the Capitanian Stage of the International Chronostratigraphic Chart. The results emphasise the possible discontinuity of the coal-bearing succession of Siberian palaeocontinent and highlight the potential for further stratigraphic refinement through continued radioisotopic dating of tonsteins. Full article

This paper examines the properties of sewage sludge ashes (SSAs) from the incineration of sewage sludge with added limestone for toxic gas treatment. It also evaluates the potential valorization of SSA in cement composites as supplementary cementitious materials (SCMs). The work involves a thorough characterization of four SSAs, including physical, chemical, and mineralogical properties. It also includes assessing the behavior of SSA in water solution through electrical conductivity measurements. The reactivity of ashes was evaluated using the R³ method and mechanical properties. The results revealed that all SSAs present comparable mineralogical and chemical properties, with varying proportions. Major elements such as Ca, Si, Fe, P, and S are predominant in the ashes, with traces of heavy metals. In an aqueous solution, a gradual formation of ettringite was detected only for two SSA. The heavy metal leachability was negligible, confirming that SSA is a non-hazardous waste. Finally, the reactivity and strength activity index assessments revealed a low and slow reactivity of SSA compared to metakaolin or slag. The SSA that favored ettringite formation in aqueous solution presented the lowest compressive strength at 28 days after incorporation in mortar. Despite originating from different incineration sites, these ashes fall under the same category of SCM reactivity. Full article

Background: Sudden volcanic eruptions can lead to volcanic ash entering the eyes, causing severe discomfort and complicating evacuation efforts. The specific effects of volcanic ash on ocular tissues, especially when wearing soft contact lenses (SCLs), are not well documented, prompting this experimental investigation. Methods: White rabbits with normal eyes were randomly divided into three groups: (1) a bare eye group: bare eye + volcanic ash exposure + eye washing, (2) an SCL group: SCL-wearing eye + volcanic ash exposure + eye washing, and (3) a control group: eye washing only. In groups 1 and 2, volcanic ash was applied to one eye under topical anesthesia, followed by immediate saline rinsing. Slit-lamp microscopy and histopathological analysis were conducted after euthanasia. Results: Slit-lamp and histopathological examinations revealed more significant corneal and conjunctival erosion in the bare eye group compared to the SCL group, which showed limited damage. The control group displayed no ocular damage. Conclusions: Guidelines from the “Volcanic Ash Health Effects: A Guide for the Public” by the National Research Institute for Earth Science and Disaster Resilience recommend removing SCLs during ashfall. Our findings suggest that the damage to the corneal and conjunctival epithelium is less severe in SCL-wearing eyes than in bare eyes, recommending that SCL wearers prioritize evacuation over lens removal during sudden ashfall. Full article

The quality of coking coal is vital in steelmaking, impacting final product quality and process efficiency. Conventional forecasting methods often rely on empirical models and expert judgment, which may lack accuracy and scalability. Previous research has explored various methods for forecasting coking coal quality parameters, yet these conventional methods frequently fall short in terms of accuracy and adaptability to different mining conditions. Existing forecasting techniques for coking coal quality are limited in their precision and scalability, necessitating the development of more accurate and efficient methods. This study aims to enhance the accuracy and efficiency of forecasting coking coal quality parameters by employing neural networks and artificial intelligence algorithms, specifically in the context of Knurow and Szczyglowice mines. The research involves gathering historical data on various coking coal quality parameters, including a proximate and ultimate analysis, to train and test neural network models using the Group Method of Data Handling (GMDH). Real-world data from Knurow and Szczyglowice mines’ coal production facilities form the basis of this case study. The integration of neural networks and artificial intelligence techniques significantly improves the accuracy of predicting key quality parameters such as ash content, sulfur content, volatile matter, and calorific value. This study also examines the impact of these quality indicators on operational costs and highlights the importance of final indicators like the Coke Reactivity Index (CRI) and Coke Strength after Reaction (CSR) in expanding industrial reserve concepts. Model performance is evaluated using metrics such as mean absolute error (MAE), root mean square error (RMSE), and coefficient of determination (R²). The findings demonstrate the effectiveness of these advanced techniques in enhancing predictive modeling in the mining industry, optimizing production processes, and improving overall operational efficiency. Additionally, this research offers insights into the practical implementation of advanced analytics tools for predictive maintenance and decision-making support within the mining sector. Full article

High-quality pellets are typically produced from coniferous sawdust. However, achieving comparable quality from alternative feedstocks, such as broadleaf wood, often necessitates pre-treatments or additives. Yet, within the framework of small-scale pellet production, local forest enterprises may lack the resources for such treatments and usually produce pellets from the whole trees, including branches, leaves and tops. This can have an impact on the quality of the pellets obtained in this manner. To be classified as high-quality pellets (A1 class), the specific features of the pellet must be higher or fall below the thresholds specified in the EN ISO 17225 standard. In this study, we developed an alternative statistical approach to evaluate pellet quality in comparison to the constant thresholds reported in the technical standard. We applied such an approach to evaluate the quality of pellets produced from the broadleaved species common in the Mediterranean forestry, including European beech (Fagus sylvatica L.), Turkey oak (Quercus cerris L.), Eucalyptus (clone Eucalyptus camaldulensis x C. bicostata), and Poplar clone AF6. In particular, we focused on three variables that are generally the most troublesome for the production of high-quality pellets from the broadleaved species, namely bulk density, ash content, and lower heating value. We found that the beech pellets showed satisfactory bulk density (average effect size of −1.2, with no statistical difference in comparison to the standard’s threshold) and ash content (average effect size of about −5 and significantly lower than the standard’s threshold), but the heating value was significantly lower than the threshold required by the standard (average effect size of about −3). Conversely, other investigated species exhibited notable deficiencies, with turkey oak pellets displaying acceptable heating values. We found a significant improvement in ash content and heating value with increasing stem age within the same species thus suggesting that material derived from thinning interventions might be preferable over coppice-derived biomass for high-quality pellet production. We suggest that future research on the topic should focus on investigating pellets produced from blends of beech and turkey oak biomass. We further recommend a wider application of the proposed statistical approach, considering that it is clear and easy to interpret, and allows for a statistical comparison of the obtained values against the requirements of the technical standard. Full article

Fly ash microspheres, also called cenospheres, have many valuable properties that allow them to be widely used. Some of its most important properties are its mechanical and thermal strength as well as its chemical stability. These features constitute an important commercial parameter. Refining processes aim to select the highest quality product from raw materials that meets the expectations of recipients. Generally, preparing a final product involves selecting the appropriate sequence and parameters of the grain separation process. However, the key to the optimal selection of these parameters is knowledge of the specificity of the processed raw material. Microspheres are materials that are created spontaneously, uncontrolled, and without the possibility of intentionally influencing their properties. Therefore, due to the potential directions of microsphere use, it is justified to study the relationship between density, grain size, and mechanical strength. Understanding these relationships in microspheres from various sources is particularly important at the stage of planning refining processes. This paper presents the results of research on microspheres from two different sources. The tested raw materials (microspheres) are subjected to densiometric and grain analysis. Also, mechanical strength was determined for the separated density fractions and grain classes. The test results did not show significant correlations between the tested features of the microspheres. In the case of both raw materials, the highest density was observed in the smallest grain classes, and the highest mechanical strength was determined for microspheres with grain sizes in the range of 75–100 µm. For this grain size range, the value of mechanical strength is 26 for raw Material 1 and 38 for raw Material 2. The shares of this grain fraction in the microsphere stream are 11.2% and 16%, respectively. An important difference that may significantly affect the efficiency of the refining process is the method of distribution of the primary falling parts, which affects the mechanical strength of the tested raw materials. Full article

The aim of this research is to investigate the quality of different triticale cultivars (Ingen 35, Ingen 33, Ingen 93, Ingen 54, Ingen 40, Fanica and Costel) cultivated in the Republic of Moldova from the point of view of the flour, dough, and bread quality characteristics. This research may be of great importance for producers and consumers due to the high production capacity, wide adaptability, economic significance in human foods and nutritional value of triticale cultivars. The triticale flours were analyzed for moisture, ash, protein, wet gluten, fat, carbohydrates, acidity and color parameters (L*, a* and b* values). According to the chemical values, the triticale flours were suitable for breadmaking. The moisture content was less than 14% for all triticale varieties, indicating a long shelf life during its storage and the lowest protein content of 13.1%. The mixing, pasting and fermentation characteristics of triticale dough were analyzed using Mixolab, falling number, dynamic rheometer, alveograph and rheofermentometer devices. All triticale flours presented high levels of α-amylase, with falling number values being less than 70 s. The bread quality characteristics analyzed were the loaf volume, porosity, acidity, and sensory characteristics, and the textural parameters examined were the hardness, gumminess, chewiness, cohesiveness, and resilience. Our data showed large differences in breadmaking quality parameters. However, according to the sensory data, all the bread samples except those obtained from the Costel variety were of a very good quality, being within a total sensory range of 25.26–29.85 points. According to the relationships between flour, dough and bread characteristics obtained through principal component analysis, it may be concluded that the triticale varieties Costel, Ingen 33, Ingen 93 and Fanica, and Ingen 35 were more closely associated with each other. Significant differences were found between the triticale variety samples Ingen 40, Fanica, and Ingen 35 and between Ingen 54, Ingen 33, Costel, and Ingen 93. Full article

Cadmium (Cd²⁺) pollution in soil and water bodies is a significant environmental concern, necessitating effective remediation strategies. Traditional methods often fall short in efficiency, cost-effectiveness, and environmental sustainability. This study develops and evaluates the effectiveness of chitosan–gelatin–hydroxypropyl methylcellulose (CS-GEL-HPMC) membranes for Cd²⁺ removal from polluted environments. CS-GEL-HPMC membranes were synthesized with varying HPMC concentrations. Their structural and morphological characteristics were analyzed using UV–visible absorption spectroscopy and FT-IR. The membranes’ stability across different pH levels and their morphological traits were assessed. The adsorption efficiency for Cd²⁺ ions was evaluated in both aqueous solutions and soil environments under varying conditions of pH, initial ion concentration, and contact time. The CS-GEL-HPMC membranes demonstrated significant structural integrity and stability, especially at higher HPMC concentrations. UV–visible and FT-IR analyses confirmed the successful integration of HPMC into the CS-GEL matrix. In aqueous solutions, the membranes exhibited efficient Cd²⁺ adsorption, with the best performance observed for the CS30-GEL30-HPMC40 membrane. The adsorption capacity was influenced by contact time, initial Cd²⁺ concentration, and pH. In soil treatments, the membranes effectively reduced Cd²⁺ concentrations, with higher membrane dosages yielding better results. The incorporation of additives like (hydroxyapatite) HAP, fly ash (FA), and cement further enhanced the remediation efficiency. In summary, CS-GEL-HPMC membranes, particularly when combined with additives, emerge as a promising, sustainable solution for Cd²⁺ remediation in both soil and water bodies. This study highlights the potential of biopolymer-based composites in environmental clean-up efforts, offering a novel approach that is both effective and eco-friendly. Full article

Soil stabilization problems like liquefaction, bearing capacity, permeability, excessive settlement and swelling can be solved by improving soil’s engineering properties by using various methods. The use of fly ash as a stabilizer has become popular in recent years since it is eco-friendly and effective on soil stabilization, especially for fine-grained soils. This study investigated the reuse of fly ash as a stabilizer (5–25% by weight) and cement (constant 3% by weight) as an activator to enhance the geotechnical properties of poorly graded sand (SP). Standard proctor tests were conducted to determine optimum water content and maximum dry unit weight, followed by direct shear box, falling head permeability and CBR tests at the determined optimum water content. Direct shear box experiments were carried out at two relative densities (30% and 80%) and CBR experiments were performed after 7 and 28 days of curing time. The results demonstrated that the addition of fly ash and cement improved the geotechnical properties, including shear strength, permeability and bearing capacity of the fine sand soil. Full article