Search Results (52)

Although asbestos has been banned in the European Union since 2005, asbestos-containing materials, such as brake pads and clutch linings, may still occur in waste streams due to the long service life of vehicles, legacy equipment, and international trade in spare parts. The persistence of these materials raises environmental and occupational health concerns, particularly in waste management systems. This study aims to assess the presence, temporal trends, and sectoral distribution of asbestos-containing friction materials in the Hungarian waste management system two decades after the EU ban, and to evaluate the associated regulatory and occupational risk implications. The analysis is based on national hazardous waste datasets classified under EWC code 16 01 11* (asbestos-containing brake pads), with a specific focus on this waste category rather than on the full range of asbestos-related waste streams recorded in the national database. The results indicate that asbestos-containing friction materials are still present in the waste stream, with measurable quantities recorded annually. Despite regulatory control, identification challenges and potential misclassification may contribute to underreporting. The continued occurrence of asbestos-containing materials highlights the persistence of legacy hazardous materials within circular economy systems. Strengthened monitoring, improved identification protocols, and enhanced occupational safety measures are necessary to mitigate residual exposure risks. The findings underline that asbestos is not merely a historical issue but remains a contemporary environmental and public health challenge. Full article

Urban environments in developing countries remain affected by legacy asbestos-containing materials, yet integrated assessments of multi-pathway asbestos release and environmental mobilization integrated with demographic distribution remain limited. This study aimed to develop a spatially explicit framework to assess environmental deterioration and asbestos-related environmental hazard where multiple asbestos release pathways converge in a post-ban urban setting, using Cartagena, Colombia, as a case study. A multi-pathway approach was implemented, combining source characterization of asbestos-cement (AC) roofs through microvacuum sampling, analysis of roof runoff and drinking water, spatial distribution of AC pipelines, and demographic data at the neighborhood scale. A total of 72 roof surface samples were collected, of which 92% showed detectable asbestos fibers, with concentrations reaching up to 326 × 10⁶ structures/cm². Runoff water analysis indicated 85% detection, with average concentrations of 3.5 ± 3.14 million fibers per liter (MFL). Drinking water samples showed 11% positivity, with lower concentrations (mean 1.01 ± 1.59 MFL). Spatial analysis revealed that approximately 9.5% of the urban area exhibited high airborne release potential and 3.1% exhibited high runoff-related hazard, while integrated spatial prioritization identified 5.59% of the city as high priority for intervention. Results indicated that less deteriorated roofs exhibited higher surface fiber availability, suggesting that emission potential is not directly proportional to visible degradation. The integration of environmental and demographic data supported the identification of critical hotspots where multiple asbestos release pathways converge. The proposed methodology provides a novel framework for multi-pathway asbestos spatial prioritization in urban environments and highlights the need for source-based monitoring approaches. These findings support the development of targeted mitigation strategies in cities with widespread legacy asbestos infrastructure. Full article

Asbestos, a group 1 carcinogen, has generated a serious health and environmental liability in Pedro Leopoldo/MG, Brazil, even after its national ban in 2017. This study aims to analyze the silent epidemic of asbestos-related diseases (ARDs) through the lens of social injustice. We used a qualitative, socio-historical, and clinical approach within the framework of an Expanded Research Community (ERC), based on ergology, with content analysis of interviews with workers and institutional documents. The evidence reveals a pattern of institutional silencing and omission, marked by corporate fraud, denial of risk, and medical underreporting, perpetuating occupational, domestic, and environmental exposure. In response, the Brazilian Association of Asbestos-Exposed Individuals of Minas Gerais (ABREA/MG) emerged as a central actor in the struggle for recognition and justice. It is concluded that overcoming this injustice requires structured public policies of recognition, integrated surveillance, historical reparation, and strengthening of the SUS (Unified Health System), with collective resistance being fundamental to transforming suffering into memory and social demands. Full article

Although asbestos use has been banned in many countries, including South Korea, the long latency period of asbestos-related diseases remains a serious public health concern. We conducted a nationwide, registry-based retrospective study to estimate the latency period of asbestosis and identify its determinants. We analyzed exposure history and demographics for 1110 asbestosis cases collected by the Ministry of Environment and the Environmental Health Center for Asbestos in Korea between 2009 and 2021. Mean latency was 45.3 years for asbestosis Grade 1 and 46.3 years for Grade 2. Patients with occupational exposure had shorter latency than those with environmental exposure: 44.4 vs. 46.0 years in Grade 1 (p = 0.010) and 45.0 vs. 47.0 years in Grade 2 (p < 0.001). Within occupations, production-type work showed the shortest latency; within environmental exposure, residence near asbestos-related industries showed the shortest latency, whereas residence near asbestos mines showed the longest. Longer exposure duration (occupational) was associated with shorter latency, and greater residential distance from the source (environmental) with longer latency. Priorities for further investigation include differences by asbestos fiber type and exposure intensity/modality, to inform strengthened occupational health monitoring and targeted surveillance for residents near industrial sources and legacy mines. Full article

Growing requirements in the field of environmental protection and waste management result in the need to search for new and effective methods of recycling various types of waste. From the perspective of technical and natural sciences, the disposal of hazardous waste, which can lead to environmental degradation, is of utmost importance. A particularly hazardous waste is asbestos, used until recently in many branches of the economy and industry. Despite the ban on the production and use of asbestos introduced in many countries, products containing it are still present in the environment and pose a real threat. This paper presents the results of research related to the process of asbestos neutralization, especially the chrysotile variety, by the thermal decomposition method. Changes in the mineralogical characteristics of asbestos waste were studied using the following methods: TG-DTA-EGA, XRD, SEM-EDS and XRF. The characteristics of the chrysotile asbestos sample were determined before and after thermal treatment at selected temperatures. The second part of the study focuses on the kinetic aspect of this process, where the chrysotile thermal decomposition process was measured by two techniques: ex situ and in situ. This study showed that the chrysotile structure collapsed at approximately 600–800 °C through dehydroxylation, and then the fibrous chrysotile asbestos was transformed into new mineral phases, such as forsterite and enstatite. The formation of forsterite was observed at temperatures below 1000 °C, while enstatite was created above this temperature. From the kinetic point of view, the chrysotile thermal decomposition process could be described by the Avrami–Erofeev model, and the calculated activation energy values were ~180 kJ mol⁻¹ and ~220 kJ mol⁻¹ for ex situ and in situ processes, respectively. The obtained results indicate that the thermal method can be successfully used to detoxify hazardous chrysotile asbestos fibers. Full article

For many years, countries around the world have been struggling with the problem of storing asbestos waste, especially in, those countries where the production and use of asbestos products have been legally banned. Following the adoption of plans for cleaning up asbestos waste, countries are struggling with the problem of its disposal, which mainly involves storing it in specialist landfills. At the same time, scientists are looking for alternatives to this type of “disposal” of asbestos by developing methods for degrading the harmful fibers. Particular attention has been paid to methods based on the thermal treatment of this waste, which results in hazardous asbestos fibers being thermally decomposed. This work focuses on the kinetic study of the thermal decomposition process of cement–asbestos using an exsitu thermal treatment. The results obtained made it possible to interpret this thermal transformation kinetically. Kinetic analysis of the isothermal data using an Avrami–Erofeev model yielded values for the overall reaction order. On this basis, the value of the apparent activation energy of the thermal decomposition process of the tested cement–asbestos samples was obtained, which was approximately 140–180 kJ mol⁻¹. Full article

Asbestos is a fibrous variety of certain minerals, some of which occur naturally as an accessory to a wide variety of mineral resources. Although asbestos itself has been historically mined for various useful properties, the negative health effects of asbestos dust have greatly diminished it as a useful earth material, as many countries have banned the use of these fibrous minerals based on those health concerns. Resulting regulations of asbestos have focused primarily on intentionally mined material used in product manufacturing, such as building materials made with beneficiated asbestos and their derivative exposures, e.g., airborne asbestos in schools with asbestos-containing materials. The hazards of asbestos as unintended byproducts have not been as extensively considered, although this “contamination” has been repeatedly observed in common earth materials including talc, vermiculite, sand, and gravel. This study reveals such contamination of ornamental and dimension stone commonly referred to as “marble”. Asbestos types that can be associated with certain Indian marble reserves include asbestiform tremolite, actinolite, anthophyllite, and chrysotile asbestos. This case reveals such contamination in a marble reserve in Rajsamand, Rajasthan. At this location, marble dust in slurry is disposed at waste collection points, unfortunately including a location now open to the public that has become a tourist destination. Using Transmission Electron Microscopy (TEM) in this study, dust from this location revealed abundant tremolite asbestos fibres in the disaggregated dust. This poses potential health risks to the workers, bystanders, and tourists that may be exposed to this recognized carcinogen, a known cause of mesothelioma, lung cancer, and other asbestos-related diseases. Full article

Objectives: Occupational respiratory diseases represent a major public health concern worldwide. This study analyses the hospitalization costs and characteristics of four major occupational respiratory diseases: malignant mesothelioma (MM), sinonasal cancer (SNC), pneumoconiosis (PN), and hypersensitivity pneumonitis (HP). The findings are situated within the context of Italy’s population trends and healthcare system, offering insights into the economic and clinical burden of these diseases. Study Design: This retrospective, population-based study examines Italian hospitalizations for MM, SNC, PN, and HP during the period 2010–2021. The primary outcomes were the number of hospitalizations, length of stay, and associated cost. Costs were derived from charges linked to diagnosis-related groups (version 24) and major diagnostic category coding systems. Results: Though the Italian population is rapidly aging, the annual number and rate of hospitalizations declined by 35% over the study period. SNC hospitalizations aligned with the overall trend, PN and MM experienced faster declines, whereas HP admissions remained steady. MM emerged as the most resource-intensive (EUR 25 million yearly, with 86% attributable to occupation), followed by PN (EUR 10 million, entirely occupational), SNC (EUR 5 million, with EUR 650,000 occupational), and HP (EUR 2 million, with EUR 370,000 occupational). All studied diseases had an average length of stay exceeding the national one. The SNC admissions were the shortest (6.5 days) and least expensive (EUR 3647). In contrast, MM, PN, and HP had a mean length of stay exceeding 10 days, with admission costs averaging EUR 4700 for MM and EUR 4000 for PN and HP. The median age was the highest for PN (78 years) and MM (71 years), while SNC and HP patients had a median age of approximately 65 years. Conclusions: Consistent with their anticipated benefits, Italian workplace health regulations over the last three decades, including the 1992 asbestos ban and D.lgs. 81/2008, are associated with significant reductions in the hospitalization burden and an increased median age at discharge for MM and PN. In contrast, fewer conclusions can be drawn for SNC and HP due to their lower occupational fractions (10–20%). This finding suggests adding an occupational exposure flag in hospital records for acknowledged occupational diseases to enhance surveillance. Finally, this study provides the first estimate of the occupational fraction of hospitalization costs for the studied diseases in Italy. Full article

Asbestos is a naturally occurring mineral renowned for its exceptional tensile strength, chemical resistance, and low thermal and electrical conductivity. Due to these properties, it has been widely used in various industries. However, asbestos exposure is strongly linked to severe health conditions, including lung cancer, mesothelioma, and asbestosis. Although over 70 countries have banned asbestos-containing materials, significant health risks persist due to ongoing use and poor management practices in many regions. To mitigate these risks, robust occupational health measures are essential. These include safe removal protocols, comprehensive worker training, proper use of personal protective equipment (PPE), regular exposure monitoring, rigorous compliance checks, and severe penalties for non-compliance. Moreover, effective asbestos waste management and the development of advanced disposal technologies are essential to reducing risks. Public awareness campaigns, regulatory enforcement, and a global ban on asbestos production, use, and export are also necessary, particularly in countries where asbestos is still in use. Lessons from asbestos management in Australia and New Zealand provide valuable insights for nations currently dealing with asbestos issues. This paper reviews current practices in asbestos surveying, removal, and disposal, comparing them to the stringent regulatory frameworks in Australia and New Zealand. It highlights strategies that can be adopted globally to ensure safer management and complete elimination of asbestos. Full article

Many years ago, asbestos fibers were banned and replaced by synthetic vitreous fibers because of their carcinogenicity. However, the toxicity of the latter fibers is still under debate, especially when it concerns the early fiber interactions with biological cell membranes. Here, we aimed to investigate the effects of a synthetic vitreous fiber named FAV173 on the Xenopus laevis oocyte membrane, the cell model we have already used to characterize the effect of crocidolite asbestos fiber exposure. Using an electrophysiological approach, we found that, similarly to crocidolite asbestos, FAV173 was able to stimulate a chloride outward current evoked by step membrane depolarizations, that was blocked by the potent and specific TMEM16A channel antagonist Ani9. Exposure to FAV173 fibers also altered the oocyte cell membrane microvilli morphology similarly to crocidolite fibers, most likely as a consequence of the TMEM16A protein interaction with actin. However, FAV173 only partially mimicked the crocidolite fibers effects, even at higher fiber suspension concentrations. As expected, the crocidolite fibers’ effect was more similar to that induced by the co-treatment with (Fe³⁺ + H₂O₂), since the iron content of asbestos fibers is known to trigger reactive oxygen species (ROS) production. Taken together, our findings suggest that FAV173 may be less harmful that crocidolite but not ineffective in altering cell membrane properties. Full article

Asbestos is a widely used name for natural silicate minerals with fibrous properties. Asbestos minerals were one of the most popular and cheapest raw materials used in the construction industry in the past when they was used in the form of cement–asbestos composite material. Nowadays, we know that asbestos possesses carcinogenic properties. Due to this fact, asbestos was banned in many countries including Lithuania. All asbestos-containing materials are considered waste and stored in special landfills, which causes significant environmental pollution. One of the methods proposed to solve the asbestos problem may be thermal treatment. In the present study, asbestos-containing wastes in the form of cement–asbestos materials were examined. These asbestos-containing materials were characterised via chemical analysis (XRF) connected with mineralogical phase analysis with powder X-ray diffraction (XRD) as well as scanning electron microscopy (SEM). The thermal decomposition of samples was studied via differential thermal analysis (DTA) and thermogravimetric measurements with evolved gas analysis (TG–EGA). It was found that thermal treatment is a possible way to destroy asbestos contained in cement–asbestos wastes and convert it into new mineral phases. The work also compared the obtained characteristics of asbestos waste with the characteristics of waste produced in other countries. Full article

Many countries banned asbestos due to its toxicity, but considering its colossal use, especially in the 1960s and 1970s, disposing of waste containing asbestos is the current problem. Today, many asbestos disposal technologies are known, but they usually involve colossal investment and operating expenses, and the end- and by-products of these methods negatively impact the environment. This paper identifies a unique modern direction in detoxifying asbestos minerals, which involves using microorganisms and plants and their metabolites. The work comprehensively focuses on the interactions between asbestos and plants, bacteria and fungi, including lichens and, for the first time, yeast. Biological treatment is a prospect for in situ land reclamation and under industrial conditions, which can be a viable alternative to landfilling and an environmentally friendly substitute or supplement to thermal, mechanical, and chemical methods, often characterized by high cost intensity. Plant and microbial metabolism products are part of the green chemistry trend, a central strategic pillar of global industrial and environmental development. Full article

As part of a surveillance plan active since the early 1990s, this study evaluates malignant mesothelioma (MM) mortality for the time-window 2010–2019 in Italy, a country that banned asbestos in 1992. National and regional mortality rates for MM, and municipal standardized mortality ratios (all mesotheliomas, pleural (MPM) and peritoneal (MPeM)), by gender and age group were calculated. A municipal clustering analysis was also performed. There were 15,446 deaths from MM (11,161 males, 3.8 × 100,000; 4285 females, 1.1 × 100,000), of which 12,496 were MPM and 661 were MPeM. In the study period, 266 people ≤50 years died from MM. A slightly decreasing rate among males since 2014 was observed. The areas at major risk hosted asbestos-cement plants, asbestos mines (chrysotile in Balangero), shipyards, petrochemical and chemical plants, and refineries. Female mortality excesses particularly were found in municipalities with a fluoro-edenite-contaminated mine (Biancavilla) and textile facilities. Excesses were also found in a region with the presence of natural asbestos fibres and in males living in two small islands. The Italian National Prevention Plan stated recommendations to eliminate asbestos exposures and to implement health surveillance and healthcare for people exposed to asbestos. Full article

In Brazil, with the ban on the production, sale, and use of chrysotile asbestos, the sector’s industry opted to replace asbestos with CRFS Technology—Cement Reinforced with Synthetic Wire (fiber cement); that is, another product to be disposed of in landfills. This work aimed to determine a composite based on clay, fiber cement powder, and cement that meets the technical specifications of Brazilian soil–cement application standards to contribute to a more sustainable treatment of the future disposal of fiber cement products. With the characterization analysis of the materials, we identified that the clay granulometry is heterogeneous and distributed from 0.1 µm to 25 µm. In comparison, 75% of the fiber cement powder has grains greater than 10 µm. For clay, the liquidity limit is 39.67%, the plasticity limit is 25.01%, and the plasticity index is 14.66%. In the semiquantitative chemical analysis, silicon oxide (SiO₂) and calcium oxide (CaO) stood out as the main oxides found, reflected in the mineralogy as quartz and calcium silicate. Therefore, we identified the percentage of organic matter in clay at 2%, using the result of the thermogravimetric analysis. The results described met the normative parameters foreseen for soil–cement applications. That said, the technological characterization was carried out by tests of linear retraction, water absorption, and simple mechanical compression on the specimens made under an axial pressure of 31.2 Mpa in the formulations defined in this work. The formulations with 10% cement and 20% and 30% fiber cement powder are suitable for use in soil–cement bricks, as they have volumetric shrinkage percentages from 2% to 2.5%, water absorption ranging from 18.66% to 19.39%, and simple compressions from 4.25 Mpa to 6.88 Mpa, meeting the requirements of Brazilian standards for soil–cement applications. It is concluded that the results showed that it is possible to produce soil–cement bricks with passive fiber cement products converted into powder, avoiding improper disposal and unwanted environmental impacts. Full article

Inhalation of asbestos fibres can cause lung inflammation and the later development of asbestosis, lung cancer, and mesothelioma, and the use of asbestos is banned in many countries. In most countries, large amounts of asbestos exists within building stock, buried in landfills, and in contaminated soil. Mechanical, thermal, and chemical treatment options do exist, but these are expensive, and they are not effective for contaminated soil, where only small numbers of asbestos fibres may be present in a large volume of soil. Research has been underway for the last 20 years into the potential use of microbial action to remove iron and other metal cations from the surface of asbestos fibres to reduce their toxicity. To access sufficient iron for metabolism, many bacteria and fungi produce organic acids, or iron-chelating siderophores, and in a growing number of experiments these have been found to degrade asbestos fibres in vitro. This paper uses the internal transcribed spacer (ITS) and 16S amplicon sequencing to investigate the fungal and bacterial diversity found on naturally-occurring asbestos minerals, asbestos-containing building materials, and asbestos-contaminated soils with a view to later selectively culturing promising species, screening them for siderophore production, and testing them with asbestos fibres in vitro. After filtering, 895 ITS and 1265 16S amplicon sequencing variants (ASVs) were detected across the 38 samples, corresponding to a range of fungal, bacteria, cyanobacterial, and lichenized fungal species. Samples from Auckland (North Island, New Zealand) asbestos cement, Auckland asbestos-contaminated soils, and raw asbestos rocks from Kahurangi National Park (South Island, New Zealand) were comprised of very different microbial communities. Five of the fungal species detected in this study are known to produce siderophores. Full article