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22 pages, 2798 KiB  
Article
Effects of Parameter Variations Generated by Pumping on LNAPL Migration in the Aquitard: An Analytical and Experimental Study
by Yue Su, Yong Huang, Huan Shen, Xiaosong Dong, Xiaochang Sun and Zhimin Fu
Toxics 2025, 13(6), 471; https://doi.org/10.3390/toxics13060471 - 2 Jun 2025
Viewed by 446
Abstract
The parameter variations in the aquitard have an important influence on the migration laws of contaminants in the aquitard. In order to study the influence of dynamic changes in parameters during pumping on the migration laws of Light Non-aqueous Phase Liquid (LNAPL) in [...] Read more.
The parameter variations in the aquitard have an important influence on the migration laws of contaminants in the aquitard. In order to study the influence of dynamic changes in parameters during pumping on the migration laws of Light Non-aqueous Phase Liquid (LNAPL) in the aquitard, the one-dimensional consolidation and groundwater flow equations for the aquitard were employed to derive the governing equations for the migration of LNAPL in the aquitard. A self-designed experimental platform was developed to investigate the effects of the pore water pressure, consolidation deformation, and pumping rate on LNAPL migration during pumping. The laboratory experimental results indicated that during pumping, the migration behavior of LNAPL in the aquitard typically exhibited a trend toward the pumping well and the overlying aquifer. The closer to the pumping well, the greater the change in the pore water pressure, the greater the amount of consolidation deformation, the earlier the state of densification, and the slower the migration rate of LNAPL in the aquitard. The nearer to the bottom of the aquitard, the larger the amount of consolidation deformation in the aquitard and the slower the migration rate of LNAPL in the aquitard. Also, the pumping rate had an important influence on groundwater flow movement and contaminant migration. The characteristics of parameter variations in the aquitard and laws of LNAPL migration during pumping were systematically studied and analyzed; these research results can provide a reference for the prediction and remediation of LNAPL in contaminated sites. Full article
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24 pages, 9917 KiB  
Article
Experimental Investigation of Soil Settlement Mechanisms Induced by Staged Dewatering and Excavation in Alternating Multi-Aquifer–Aquitard Systems
by Cheng Zhao, Yimei Cheng, Guohong Zeng, Guoyun Lu and Yuwen Ju
Buildings 2025, 15(9), 1534; https://doi.org/10.3390/buildings15091534 - 2 May 2025
Viewed by 455
Abstract
Dewatering and excavation are fundamental processes influencing soil deformation in deep foundation pit construction. Excavation causes stress redistribution through unloading, while dewatering lowers the groundwater level, increases effective stress, and generates seepage forces and compressive deformation in the surrounding soil. To systematically investigate [...] Read more.
Dewatering and excavation are fundamental processes influencing soil deformation in deep foundation pit construction. Excavation causes stress redistribution through unloading, while dewatering lowers the groundwater level, increases effective stress, and generates seepage forces and compressive deformation in the surrounding soil. To systematically investigate their combined influence, this study conducted a scaled physical model test under staged excavation and dewatering conditions within a layered multi-aquifer–aquitard system. Throughout the experiment, soil settlement, groundwater head, and pore water pressure were continuously monitored. Two dimensionless parameters were introduced to quantify the contributions of dewatering and excavation: the total dewatering settlement rate ηdw and the cyclic dewatering settlement rate ηdw,i. Under different experimental conditions, ηdw ranges from 0.35 to 0.63, while ηdw,i varies between 0.32 and 0.82. Both settlement rates decrease with increasing diaphragm wall insertion depth and increase with greater dewatering depth inside the pit and higher soil permeability. An analytical formula for dewatering-induced soil settlement was developed using a modified layered summation method that accounts for deformation coordination between soil layers and includes correction factors for unsaturated zones. Although this approach is limited by scale effects and simplified boundary conditions, the findings offer valuable insights into soil deformation mechanisms under the combined influence of excavation and dewatering. These results provide practical guidance for improving deformation control strategies in complex hydrogeological environments. Full article
(This article belongs to the Special Issue Advances in Foundation Engineering for Building Structures)
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20 pages, 14671 KiB  
Article
Field Pumping and Recharge Test Study for Confined Aquifers in Super-Large Deep Foundation Pit Group Sites
by Shuo Wang, Weidong Wang, Zhonghua Xu, Qingjun Song and Jiangu Qian
Buildings 2025, 15(8), 1383; https://doi.org/10.3390/buildings15081383 - 21 Apr 2025
Viewed by 475
Abstract
To ensure the stability of deep foundation pits in confined aquifers, dewatering is often required. However, pumping from confined aquifers in large deep foundation pit groups may lead to significant environmental deformations. Therefore, field pumping and recharge tests are required to guide design [...] Read more.
To ensure the stability of deep foundation pits in confined aquifers, dewatering is often required. However, pumping from confined aquifers in large deep foundation pit groups may lead to significant environmental deformations. Therefore, field pumping and recharge tests are required to guide design of groundwater and environmental deformation control scheme. Focusing on a super-large deep foundation pit group in Shanghai, single-well pumping, multi-well pumping, and recharge tests were conducted in distinct geological zones (normally consolidated area and paleochannel zone). The hydraulic connectivity and spatiotemporal patterns of groundwater drawdown and soil settlement were systematically analyzed. The results show that: (1) There exists a certain hydraulic connection between the first and second confined aquifers. In the paleochannel area, the aquitard between the micro-confined and the first confined aquifer is insufficient to completely block hydraulic connectivity. (2) The ratio of ground surface settlement to groundwater drawdown is about 3.4 mm/m, and the deep soil settlement is significantly or even greater than the surface settlement, so it is necessary to strengthen the monitoring of deep settlement. (3) Recharge can elevate the groundwater and reduce settlement; however, it is difficult to eliminate the variation in settlement along the vertical direction. Full article
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22 pages, 5895 KiB  
Article
Hydro-Mechanical Numerical Analysis of a Double-Wall Deep Excavation in a Multi-Aquifer Strata Considering Soil–Structure Interaction
by Yinhang Zhu, Weidong Wang, Zhonghua Xu, Jinjian Chen and Ji Zhang
Buildings 2025, 15(6), 989; https://doi.org/10.3390/buildings15060989 - 20 Mar 2025
Cited by 2 | Viewed by 414
Abstract
In order to exploit the deep underground space, the construction of ultra-deep excavation in Shanghai is growing rapidly. In multi-aquifer strata, deep excavations typically require dewatering of confined aquifers to ensure engineering safety. However, existing studies have seldom conducted in-depth analysis on the [...] Read more.
In order to exploit the deep underground space, the construction of ultra-deep excavation in Shanghai is growing rapidly. In multi-aquifer strata, deep excavations typically require dewatering of confined aquifers to ensure engineering safety. However, existing studies have seldom conducted in-depth analysis on the influence of the soil parameters and construction measures on the deformation of retaining structures. In this study, a three-dimensional hydro-mechanical numerical model was developed to evaluate the performances of excavation and dewatering of the foundation pit. The model was validated by comparing the calculated and measured wall deflections and groundwater drawdowns of a 45 m ultra-deep double-wall excavation in Shanghai. According to the characteristics of soil stratification and construction activities, three parameters were selected for subsequent analysis, including the hydraulic conductivity of aquitard below the bottom of the pit, the pumping rate in the second confined aquifer and the construction of TRD wall. The stress distributions on both sides of the diaphragm wall were examined to elucidate the deformation mechanism. The results indicate that the aquitard hydraulic conductivity directly affects the effective stress of the overlying aquifer, which plays a crucial role in resisting wall deflection. An increase in the hydraulic conductivity leads to smaller effective stress, greater wall deflection and larger ground settlement. While an appropriately increased pumping rate enhances effective stress, over-pumping may induce excessive wall deflection at depth and disproportionate ground settlement. The TRD wall is quite useful in terms of waterproofing but the effect on deformation control is limited. The findings of this study provide valuable insights for engineering practices and the optimization of deep excavation construction measures in multi-aquifer strata. Full article
(This article belongs to the Special Issue Advances in Soil-Structure Interaction for Building Structures)
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18 pages, 3086 KiB  
Article
Earth Fissures During Groundwater Depletion and Recovery: A Case Study at Shitangwan, Wuxi, Jiangsu, China
by Guang-Ya Wang, Jin-Qi Zhu, Greg G. You, Dan Zhang, Jun Yu, Fu-Gang Gou and Jian-Qiang Wu
Hydrology 2025, 12(3), 62; https://doi.org/10.3390/hydrology12030062 - 19 Mar 2025
Viewed by 582
Abstract
The Shitangwan earth fissure is a resultant geological hazard due to prolonged groundwater depletion and land subsidence in Wuxi, China, since the 1980s. Initially observed in 1991, the earth fissure experienced continuous development over the next several decades. Employing a diverse array of [...] Read more.
The Shitangwan earth fissure is a resultant geological hazard due to prolonged groundwater depletion and land subsidence in Wuxi, China, since the 1980s. Initially observed in 1991, the earth fissure experienced continuous development over the next several decades. Employing a diverse array of techniques, including field monitoring via multilayered borehole extensometers, earth fissure monitoring for lateral and vertical movements, advanced geophysical exploration, and conventional geological investigations, this study aims to mitigate the risks associated with land subsidence and earth fissures. It is found that the groundwater has recovered to the levels in the 1980s, land subsidence and earth fissuring have ceased, and the earth fissuring is closely linked to the land subsidence. A bedrock ridge and a river course are underlying porous Quaternary sediments beneath the earth fissure. The formation of the earth fissure is the result of a combination of factors, including spatial and temporal variations in strata compression, rugged bedrock terrain, and the heterogeneity of the strata profile. Land subsidence is primarily attributed to the deep pumping aquifer and its adjacent aquitards, which are responsive to groundwater recovery with a time lag of a decade, and the land rebound accounts for 2% of the accumulated land subsidence. Estimations suggest that the depth of the earth fissure may have reached the bedrock ridge. The mechanism of the earth fissuring is the coupled effect of tension from the rotation of shallow soil strata along the bedrock ridge and shearing of strata driven by the differential compression of deep strata below the ridge level. Full article
(This article belongs to the Section Soil and Hydrology)
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25 pages, 9985 KiB  
Article
Water Resources Availability on a River Watershed in a Relevant Mineral Province (Minas Gerais, Brazil): An Integrated Approach to Water Resources Management
by Alex Rodrigues de Freitas, Rodrigo Sérgio de Paula and Isabel Margarida Horta Ribeiro Antunes
Water 2025, 17(4), 532; https://doi.org/10.3390/w17040532 - 13 Feb 2025
Viewed by 905
Abstract
The watershed of the Peixe River lies in central Minas Gerais state, close to Belo Horizonte city, a densely populated area. The area is located in the geological context of Quadrilátero Ferrífero, one of the most prominent mineral provinces in Brazil. To better [...] Read more.
The watershed of the Peixe River lies in central Minas Gerais state, close to Belo Horizonte city, a densely populated area. The area is located in the geological context of Quadrilátero Ferrífero, one of the most prominent mineral provinces in Brazil. To better recognize surface and groundwater availability, some methodologies have been applied to evaluate the minimal surface flow rates, groundwater recharge, and water reserves. The basin includes three main aquifer systems: Cauê (porous and fissured aquifer), related to iron formations; Gandarela, related to karst-fissured rocks; and Cercadinho, related to metapelite rocks. The Cauê aquifer presented the highest effective porosity and hydraulic conductivity. In contrast, the Cercadinho aquitard shows the lowest hydrodynamic parameters. Data between the years of 2004 and 2024 from 21 pumping tests from wells associated with the three aquifer systems were obtained to estimate the respective recharge rate. The recharge was evaluated by numeric recursive filter and recession-curve displacement methods. The recharge results with the numeric filter method showed underestimated values. Regarding the recession-curve displacement method, the results were more consistent with other studies in the surroundings. The average recharge estimated for the basin represents 24% to 54% of annual pluviometry in the hydrological periods of analysis. The recharge data were accounted for in the reserves calculation, including permanent and renewable reserves. Total permanent reserves were estimated to be 3.16 × 109 m3, including the prior aquifer systems of Cauê, Gandarela, and Cercadinho. The total mean renewable reserves of the basin were calculated to be 4.55 × 107 m3/year in the analyzed period. The high BFImax indexes found in baseflow separation, above 90%, suggest a relevant contribution of the karstic Gandarela aquifer on the watershed surface flow. Although in some years it has been concluded that groundwater exploitation outlines the renewable resources availability, in 2024’s scenario, the granted water volume was lower than the estimated availability and reserves. The best methodologies for coupling surface and groundwater are the Weibull distribution for reference surface flows and the recessive-curve displacement for baseflow separations. This research will be a contribution to water resources management strategies for regions with high population growth and water demand increase. Full article
(This article belongs to the Section Hydrogeology)
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28 pages, 29370 KiB  
Article
Perched Hydrologic Systems of the Monahans and the Kermit Dune Fields, Northern Chihuahuan Desert, West Texas, USA
by Alix Fournier, Steven L. Forman and Connor Mayhack
Water 2024, 16(22), 3188; https://doi.org/10.3390/w16223188 - 7 Nov 2024
Viewed by 1483
Abstract
This study highlights the importance of quantifying groundwater resources for the Monahans and Kermit dune fields in the northern Chihuahua Desert, West Texas, USA, as potential contributors to the regional Pecos Valley Aquifer (PVA). Dunal aquifers in arid environments are often unquantified, may [...] Read more.
This study highlights the importance of quantifying groundwater resources for the Monahans and Kermit dune fields in the northern Chihuahua Desert, West Texas, USA, as potential contributors to the regional Pecos Valley Aquifer (PVA). Dunal aquifers in arid environments are often unquantified, may augment regional groundwater resources, and can be compromised by anthropogenic activity. Sedimentary architecture models of these dune fields show perched aquifers with water tables 1–10 m below the surface and southwestern groundwater flow sub-parallel to a Pleistocene/Pliocene aquitard. The deuterium and oxygen isotopic ratios for groundwater from the Kermit and Monahans dune fields show pronounced evaporative isotopic depletion and less isotopic variability than corresponding rainfall, particularly for deuterium values. The radiocarbon and δ13C analyses of dissolved inorganic carbon (DIC) indicate that recharge occurs through enhanced capture of recent precipitation on mostly bare active dunes where infiltration rates are >250 mm/h. In contrast, more evolved 14C values at the western margin (FM = 0.84) and at 30 m below the surface (FM = 0.76) of the dunes, similar to proximal Fm values from the PVA (0.89–0.82), may indicate dissolution of older (>100 ka) DIC from buried playa-lake sediments and less direct atmospheric influence. Mixing models for DIC source partitioning highlighted possible groundwater contamination with hydrocarbon up to 24% in the PVA and in the dunal aquifers. The perched aquifers of the Monahans and Kermit dune fields each contain water volumes >0.1 km3 and may contribute up to 18% of the total annual recharge to the PVA. Full article
(This article belongs to the Section Hydrology)
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17 pages, 3984 KiB  
Article
Utilizing Hydrophobic Sand to Construct an Air-Permeable Aquiclude to Enhance Rice Yield and Lodging Resistance
by Xiaoyan Ma, Jing Wu, Yuming Su, Shengyi Qin and Francesco Pilla
Agronomy 2024, 14(9), 2085; https://doi.org/10.3390/agronomy14092085 - 12 Sep 2024
Cited by 2 | Viewed by 1265
Abstract
Global climate change and persistent droughts lead to soil desertification, posing significant challenges to food security. Desertified lands, characterized by high permeability, struggle to retain water, thereby hindering ecological restoration. Sand, a natural resource abundant in deserts, inspired our proposal to design hydrophobic [...] Read more.
Global climate change and persistent droughts lead to soil desertification, posing significant challenges to food security. Desertified lands, characterized by high permeability, struggle to retain water, thereby hindering ecological restoration. Sand, a natural resource abundant in deserts, inspired our proposal to design hydrophobic sand and construct Air-permeable Aquicludes (APAC) using this material. This approach aims to address issues related to the ecological restoration of desertified lands, food security, and the utilization of sand resources. Reclamation of desertified land and sandy areas can simultaneously address ecological restoration and ensure food security, with soil reconstruction being a critical step. This study investigated the effects of constructing an Air-permeable Aquiclude (APAC) using hydrophobic sand on rice yield and lodging resistance, using clay aquitard (CAT) and plastic aquiclude (PAC) as control groups. The APAC enhanced soil oxygen content, increased internode strength, and improved vascular bundle density, substantially reducing the lodging index and increasing yield. This research finds that the APAC (a) increased internode outer diameter, wall thickness, fresh weight, and filling degree; (b) enhanced the vascular bundle area by 11.11% to 27.66% and increased density; (c) reduced the lodging index by 37.54% to 36.93% (p < 0.01); and (d) increased yield to 8.09 t·hm−2, a rise of 12.05% to 14.59% (p < 0.05), showing a negative correlation with lodging index. These findings suggest that APAC has very good potential for desertified land reclamation and food security. In conclusion, the incorporation of hydrophobic sand in APAC construction considerably strengthens rice stem lodging resistance and increases yield, demonstrating considerable application potential for the reclamation of desertified and sandy land and ensuring food security. Full article
(This article belongs to the Special Issue Transforming AgriFood Systems under a Changing Climate)
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31 pages, 29333 KiB  
Article
VARS and HDMR Sensitivity Analysis of Groundwater Flow Modeling through an Alluvial Aquifer Subject to Tidal Effects
by Javier Samper, Brais Sobral, Bruno Pisani, Alba Mon, Carlos López-Vázquez and Javier Samper-Pilar
Water 2024, 16(17), 2526; https://doi.org/10.3390/w16172526 - 5 Sep 2024
Viewed by 1431
Abstract
Groundwater flow and transport models are essential tools for assessing and quantifying the migration of organic contaminants at polluted sites. Uncertainties in the hydrodynamic and transport parameters of the aquifer have a significant effect on model predictions. Uncertainties can be quantified with advanced [...] Read more.
Groundwater flow and transport models are essential tools for assessing and quantifying the migration of organic contaminants at polluted sites. Uncertainties in the hydrodynamic and transport parameters of the aquifer have a significant effect on model predictions. Uncertainties can be quantified with advanced sensitivity methods such as Sobol’s High Dimensional Model Reduction (HDMR) and Variogram Analysis of Response Surfaces (VARS). Here we present the application of VARS and HDMR to assess the global sensitivities of the outputs of a transient groundwater flow model of the Gállego alluvial aquifer which is located downstream of the Sardas landfill in Huesca (Spain). The aquifer is subject to the tidal effects caused by the daily oscillations of the water level in the Sabiñánigo reservoir. Global sensitivities are analyzed for hydraulic heads, aquifer/reservoir fluxes, groundwater Darcy velocity, and hydraulic head calibration metrics. Input parameters include aquifer hydraulic conductivities and specific storage, aquitard vertical hydraulic conductivities, and boundary inflows and conductances. VARS, HDMR, and graphical methods agree to identify the most influential parameters, which for most of the outputs are the hydraulic conductivities of the zones closest to the landfill, the vertical hydraulic conductivity of the most permeable zones of the aquitard, and the boundary inflow coming from the landfill. The sensitivity of heads and aquifer/reservoir fluxes with respect to specific storage change with time. The aquifer/reservoir flux when the reservoir level is high shows interactions between specific storage and aquitard conductivity. VARS and HDMR parameter rankings are similar for the most influential parameters. However, there are discrepancies for the less relevant parameters. The efficiency of VARS was demonstrated by achieving stable results with a relatively small number of simulations. Full article
(This article belongs to the Section Hydrogeology)
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18 pages, 7517 KiB  
Article
Springs of the Arabian Desert: Hydrogeology and Hydrochemistry of Abu Jir Springs, Central Iraq
by John A. Webb, Jaafar Jotheri and Rod J. Fensham
Water 2024, 16(17), 2491; https://doi.org/10.3390/w16172491 - 2 Sep 2024
Cited by 3 | Viewed by 2724
Abstract
The Arabian Desert is characterised by very low rainfall and high evaporation, yet over 210 springs are on its northeastern edge in central Iraq along the Abu Jir lineament, which represents the western depositional margin of a foreland basin infilled by the floodplain [...] Read more.
The Arabian Desert is characterised by very low rainfall and high evaporation, yet over 210 springs are on its northeastern edge in central Iraq along the Abu Jir lineament, which represents the western depositional margin of a foreland basin infilled by the floodplain sediments of the Tigris and Euphrates Rivers; there is little evidence of faulting. The springs discharge from gently east-dipping Paleocene–Eocene limestones, either where groundwater flowpaths intersect the ground surface or where groundwater flow is forced to the surface by confining aquitards. Calculated annual recharge to the aquifer system across the Arabian Desert plateau (130–500 million m3) is significant, largely due to rapid infiltration through karst dolines, such that karst porosity is the primary enabler of groundwater recharge. The recharge is enough to maintain flow at the Abu Jir springs, but active management of groundwater extraction for agriculture is required for their long-term sustainability. The hydrochemistry of the springs is determined by evaporation, rainfall composition (high SO4 concentrations are due to the dissolution of wind-blown gypsum in rainfall), and plant uptake of Ca and K (despite the sparse vegetation). Limestone dissolution has relatively little impact; many of the springs are undersaturated with respect to calcite and lack tufa/travertine deposits. The springs at Hit-Kubaysa contain tar and high levels of H2S that probably seeped upwards along subvertical faults from underlying oil reservoirs; this is the only location along the Abu Jir lineament where deep-seated faults penetrate to the surface. The presence of hydrocarbons reduces the Hit-Kubaysa spring water and converts the dissolved SO4 to H2S. Full article
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16 pages, 12834 KiB  
Article
Temperature Variations in Deep Thermal Well LZT-1 in Lądek-Zdrój (Bohemian Massif; SW Poland)—Evidence of Geothermal Anomaly and Paleoclimatic Changes
by Barbara Kiełczawa, Wojciech Ciężkowski, Mirosław Wąsik, Karolina Szostak, Iwona Sieniawska and Marek Rasała
Energies 2024, 17(14), 3362; https://doi.org/10.3390/en17143362 - 9 Jul 2024
Cited by 1 | Viewed by 1037
Abstract
The thermal water deposit in Lądek-Zdrój (SW Poland) occurs in fractured reservoir rocks, and its hydrogeological regime is controlled by the features of the local geology and lithology of the hosting crystalline complexes, mainly impermeable high-grade metamorphosed mica schists and gneisses. The fractured [...] Read more.
The thermal water deposit in Lądek-Zdrój (SW Poland) occurs in fractured reservoir rocks, and its hydrogeological regime is controlled by the features of the local geology and lithology of the hosting crystalline complexes, mainly impermeable high-grade metamorphosed mica schists and gneisses. The fractured thermal water aquifer is confined by a thrust fault-type aquitard that creates artesian pressure and, therefore, the water intakes and natural springs in Lądek Zdrój provide spontaneous outflow. Classical geothermometers yield an estimation of reservoir temperatures that ranges from 50 to 70 °C, with a maximum of 88 °C. The heat flux (HF) value of the Lądek-Zdrój region is 64 mW/m2. The new borehole, LZT-1, is in the border zone of a local thermal anomaly with a geothermal degree of 25–27 m/°C. The estimated temperature at the bottom of the LZT-1 borehole, under thermal equilibrium conditions, ranges between 70 °C and 80 °C. A stream of heated waters from the deep system flows from the recharge areas, shaping the local geothermal anomaly and thus influencing the thermal conditions in the Lądek-Zdrój area. The activation of this water circulation system occurred in the Pleistocene. Full article
(This article belongs to the Section H: Geo-Energy)
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23 pages, 19609 KiB  
Article
Transformation of the Geological Environment under the Influence of Liquid Radioactive Waste (Russian Experience in Studying Historical Nuclear Disposal)
by Victoria Krupskaya, Sergey Zakusin and Mikhail Chernov
Minerals 2024, 14(3), 252; https://doi.org/10.3390/min14030252 - 28 Feb 2024
Viewed by 1516
Abstract
Due to various historical events, in the Russian Federation, in addition to the radioactive waste storage facilities used in world practice, there are various nuclear and radiation hazardous facilities that require special procedures for monitoring and decommissioning. One of these facilities is the [...] Read more.
Due to various historical events, in the Russian Federation, in addition to the radioactive waste storage facilities used in world practice, there are various nuclear and radiation hazardous facilities that require special procedures for monitoring and decommissioning. One of these facilities is the disposal site for LRW on the territory of the JSC Siberian Chemical Plant, where specially prepared waste is injected into sand reservoirs lying at depths of 300–350 m between clayey strata. This study examines in detail the features of the lithological and mineral composition of reservoir sands and aquitards. The processes of environmental transformation in reservoir sands, which lead to changes in the composition and structure of rocks, were characterized. These processes manifest themselves in the form of the development of leaching zones and their “healing” with newly formed smectite, the destruction of terrigenous grains, including the development of cracks, and the growth of newly formed smectite in the pore space of reservoirs. The forms of occurrence and localization of authigenic smectite formed as a result of technogenic impact are described. It has been shown that, despite the obvious impact of highly reactive solutions accompanying liquid radioactive waste, the insulating properties of the geological environment are maintained and even improved to some extent. Full article
(This article belongs to the Special Issue Adsorption Properties and Environmental Applications of Clay Minerals)
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15 pages, 1830 KiB  
Article
A Study on the Coexistence of Anthropogenic and Natural Sources in a Three-Dimensional Aquifer
by Animesh Samanta, Ayan Chatterjee and Mritunjay Kumar Singh
Water 2024, 16(1), 177; https://doi.org/10.3390/w16010177 - 3 Jan 2024
Cited by 1 | Viewed by 1638
Abstract
A study using mathematical modeling has been conducted to analyze how both man-made and natural sources of contaminants affect various layers of an aquifer-aquitard system. The xy-, yz-, and zx-plane have been used to depict the locations where the natural sources of contaminant [...] Read more.
A study using mathematical modeling has been conducted to analyze how both man-made and natural sources of contaminants affect various layers of an aquifer-aquitard system. The xy-, yz-, and zx-plane have been used to depict the locations where the natural sources of contaminant occur on the xz- and yz-plane, and where the man-made sources occur, on the xy-plane. It is assumed that the sources occurring in different planes are constant, while the velocity of groundwater flow has been considered only along the x-axis. A three-dimensional advection dispersion equation (ADE) has been used to accurately model the flow of groundwater and contaminants through a porous medium. Three distinct sources exert their influence on three separate planes throughout the entire duration of this study, thus making it possible to model these sources using initial conditions. This study presents a profile of contaminant concentration in space and time when constant sources are located on different planes. Some physical assumptions have been considered to make the model relatable to real-world phenomena. Often, finding stability conditions for numerical solutions becomes difficult, so an unconditionally stable solution is more appreciable. The homotopy analysis method (HAM), a method known for its unconditional stability, has been used to solve a three-dimensional mathematical model (ADE) along with its initial conditions. Man-made sources show more impact than equal-strength natural sources in the aquifer-aquitard system. Full article
(This article belongs to the Section Soil and Water)
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20 pages, 15122 KiB  
Article
Identification of Breaches in a Regional Confining Unit Using Electrical Resistivity Methods in Southwestern Tennessee, USA
by Md Rizwanul Hasan, Daniel Larsen, Scott Schoefernacker and Brian Waldron
Water 2023, 15(23), 4090; https://doi.org/10.3390/w15234090 - 25 Nov 2023
Viewed by 1998
Abstract
Electrical resistivity and borehole data are applied to delineate lithostratigraphic boundaries and image the geometry of confining-unit breaches in Eocene coastal-plain deposits to evaluate inter-aquifer exchange pathways. Eight dipole–dipole array surveys were carried out, and apparent resistivity was inverted to examine the lateral [...] Read more.
Electrical resistivity and borehole data are applied to delineate lithostratigraphic boundaries and image the geometry of confining-unit breaches in Eocene coastal-plain deposits to evaluate inter-aquifer exchange pathways. Eight dipole–dipole array surveys were carried out, and apparent resistivity was inverted to examine the lateral continuity of lithologic units in different water-saturation and geomorphic settings. In addition, sensitivity analysis of inverted resistivity profiles to electrode spacing was performed. Resistivity profiles from Shelby Farms (SF) highlight the effect of varied electrode spacing (2.5, 5, and 10 m), showing an apparent ~0.63 to 0.75 depth shift in resistivity-layer boundaries when spacing is halved, with the 10 m spacing closely matching borehole stratigraphy. Grays Creek and Presidents Island profiles show clay-rich Eocene Cook Mountain Formation (CMF), with resistivity ranging from 10 to 70 Ω-m, overlying the Eocene Memphis Sand—a prolific water-supply aquifer. Resistivity profiles of SF and Audubon Park reveal sandy Cockfield Formation (CFF) paleochannels inset within and through the CMF, providing hydrogeologic connection between aquifers, and clarifying the sedimentary origin of confining-unit breaches in the region. The results underscore the efficacy of the electrical resistivity method in identifying sand-rich paleochannel discontinuities in a low-resistivity regional confining unit, which may be a common origin of breaches in coastal-plain confining units. Full article
(This article belongs to the Special Issue Application of Geophysical Methods for Hydrogeology)
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17 pages, 7560 KiB  
Article
Spatial Distribution and Factors Influencing the Various Forms of Iron in Alluvial–Lacustrine Clayey Aquitard
by Juan Chen, Rui Liu, Yantao Jian and Teng Ma
Water 2023, 15(22), 3934; https://doi.org/10.3390/w15223934 - 11 Nov 2023
Cited by 4 | Viewed by 1759
Abstract
The compression release of pore water in clayey aquitards has a significant impact on groundwater quality. Iron is an active variable element that mediates biochemical reactions in groundwater systems, but its transformation mechanisms in clayey aquitards remain unclear. The sediment and pore water [...] Read more.
The compression release of pore water in clayey aquitards has a significant impact on groundwater quality. Iron is an active variable element that mediates biochemical reactions in groundwater systems, but its transformation mechanisms in clayey aquitards remain unclear. The sediment and pore water samples from the shallow clayey aquitard (thickness = ~20 m) in the Chen Lake area of China were collected in three boreholes. The spatial distribution and influencing factors of Fe occurrence in the aquitard were revealed using hierarchical extraction, statistical analysis, and simulation calculations. The results indicate that the background value of alluvial–lacustrine sediments primarily affects the Fe concentration of clayey sediments. The dissimilatory reduction in free Fe oxide was the main source of Fe ions in pore water, resulting in a major percentage of Fe2+ in the total Fe concentration (0.07−5.91 mg/L). The abundant organic matter in organic-rich clay promoted a dissimilatory reduction in Fe (III) oxides, while the Fe concentrations of sediment and pore water were lower in the sand-rich stratum because of its weak adsorption capacity. The impact of human reclamation activities on the aquitard was mainly concentrated in the shallow layer (>3 m), resulting in water drainage and O2 and CO2 input, which induced the crystallization of poorly crystalline Fe oxides. The input of reactive organic matter from reclaimed crops promoted the dissimilatory reduction in Fe oxides and the enrichment of Fe in deep pore water. The copious Fe2+ in deep stratum pore water tended to interact with CO32− and S2− to form coprecipitation with Fe (II). The concentrations of As, Cr, Sr, Zn, and Mn in pore water followed a similar variation trend to the Fe ion concentration, and their release could be attributed to the reduction dissolution of sediment Fe (III) oxides. Full article
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