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400 Results Found

  • Article
  • Open Access
2 Citations
1,703 Views
19 Pages

Olive Pomace Fly Ash as an Alternative Alkaline Activator for Electric Arc Furnace Slag for Sustainable Cementitious Materials

  • Ana Muñoz-Castillo,
  • Francisca Andrés-Castro,
  • Miguel Ángel Gómez-Casero and
  • Dolores Eliche-Quesada

28 January 2025

This study analyzes the potential of olive pomace fly ash (OPFA) as an alternative alkaline activator for electric arc furnace slag (EAFS) in the manufacture of sustainable cementitious materials. Cements were prepared by replacing 30–50 wt% of...

  • Article
  • Open Access
31 Citations
4,966 Views
14 Pages

Commercial sodium hydroxide (NaOH) and sodium silicate (SS) are commonly used as alkaline activators in geopolymer concrete production despite concerns about their availability and associated CO2 emissions. This study employs an alternative alkaline...

  • Article
  • Open Access
21 Citations
3,978 Views
14 Pages

14 December 2021

This article demonstrates the possibility of producing alkali-activated hybrid cements based on fly ash (FA), and construction and demolition wastes (concrete waste, COW; ceramic waste, CEW; and masonry waste, MAW) using sodium sulfate (Na2SO4) (2&nd...

  • Article
  • Open Access
628 Views
24 Pages

Performance and Environmental Assessment of Alkali-Activated Cements from Agricultural and Industrial Residues

  • Rafaela Pollon,
  • Giovani Jordi Bruschi,
  • Suéllen Tonatto Ferrazzo,
  • Arielle Cristina Fornari,
  • Eduarda Razador Lazzari,
  • Pedro Domingos Marques Prietto and
  • Eduardo Pavan Korf

The growing concern with carbon dioxide emissions from the cement industry has driven the search for alternative binders with lower environmental impact. Among these, alkali-activated cements (AACs) stand out due to their ability to produce cementiti...

  • Abstract
  • Open Access
2 Citations
1,410 Views
2 Pages

Reuse of Rice Husk Ash as an Alkaline Activator in the Manufacture of Alkaline Cements

  • A. Muñoz-Castillo,
  • M. A. Gómez-Casero,
  • J. S. Bueno-Rodríguez,
  • L. Pérez-Villarejo and
  • D. Eliche-Quesada

The cement industry is a highly polluting industry, where natural resources (quarries) are exploited and a large amount of polluting gases are emitted into the atmosphere [...]

  • Article
  • Open Access
24 Citations
3,875 Views
18 Pages

Alkali-Activated Stainless Steel Slag as a Cementitious Material in the Manufacture of Self-Compacting Concrete

  • Julia Rosales,
  • Francisco Agrela,
  • José Luis Díaz-López and
  • Manuel Cabrera

14 July 2021

This work develops the manufacture of self-compacting concrete (SCC) with 50% cement reduction. As an alternative binder to cement, the viability of using an alkali-activated combination of stainless steel slag (SSS) and fly ash (FA) has been demonst...

  • Article
  • Open Access
4 Citations
2,067 Views
16 Pages

The Use of Solid Sodium Silicate as Activator for an Amorphous Wollastonitic Hydraulic Binder

  • Mónica Antunes,
  • Rodrigo Lino Santos,
  • João Pereira,
  • Ricardo Bayão Horta and
  • Rogério Colaço

27 January 2024

To ensure the acceptable mechanical strength of amorphous wollastonitic hydraulic binders (AWHs), activation with a sodium silicate solution is necessary. However, the use of this type of activator increases the final cost and the complexity of the p...

  • Article
  • Open Access
2 Citations
2,409 Views
20 Pages

Mechanical Behavior of a Mine Tailing Stabilized with a Sustainable Binder

  • Hamid Reza Manaviparast,
  • João Pinheiro,
  • Elmira Khaksar Najafi,
  • Cláudia Abreu,
  • Nuno Araújo,
  • Nuno Cristelo and
  • Tiago Miranda

23 March 2023

Mining is a primary sector for the national economy of many countries, but exploiting these natural resources causes negative impacts on the environment. Tailings produced during mining, called mine tailings, have to be disposed of, and for that purp...

  • Article
  • Open Access
4 Citations
2,119 Views
16 Pages

Understanding the Effect of Waiting for the Dissolution of Sodium Hydroxide in Geopolymer Concrete Mixes

  • Samara Altameemi,
  • Blessing O. Adeleke,
  • John M. Kinuthia and
  • Jonathan Oti

15 February 2025

Geopolymer concrete (GPC) can be produced by the chemical activation of industrial by-products and processed natural minerals that contain aluminosilicates with the presence of an alkaline activator. Raw components are one of the critical parameters...

  • Article
  • Open Access
5 Citations
3,246 Views
15 Pages

30 September 2020

This experimental research investigated the applicability of the liquid crystal display (LCD) by-product of the refining process as a sustainable and alternative alkali activator for ground granulated blast-furnace slag (GGBFS) blended cement concret...

  • Article
  • Open Access
22 Citations
2,890 Views
15 Pages

Eco-Efficient Hybrid Cements: Pozzolanic, Mechanical and Abrasion Properties

  • Segundo Shagñay,
  • Leticia Ramón,
  • María Fernández-Álvarez,
  • Asunción Bautista,
  • Francisco Velasco and
  • Manuel Torres-Carrasco

16 December 2020

One of the most polluting industries is the cement industry and, for this reason, alternative lines of research recommend the use of substitute materials for traditional Portland cement. This study proposes the use of industrial (slag and fly ash) an...

  • Article
  • Open Access
1 Citations
864 Views
21 Pages

Hybrid Binders Through Alkaline Activation of Fine Construction and Demolition Waste

  • Manuel Retamal-Rojas,
  • Diego Aponte,
  • William Valencia-Saavedra,
  • Rafael Robayo-Salazar and
  • Marilda Barra-Bizinotto

8 July 2025

The use of construction and demolition waste (CDW) as an alternative binder to ordinary Portland cement presents a promising solution through alkaline activation. This study evaluates the physical, mechanical, and microstructural behaviour of pastes...

  • Article
  • Open Access
14 Citations
2,972 Views
21 Pages

Stabilisation of a Plastic Soil with Alkali Activated Cements Developed from Industrial Wastes

  • Nuno Cristelo,
  • Jhonathan Rivera,
  • Tiago Miranda and
  • Ana Fernández-Jiménez

18 April 2021

The development of alternative materials for the construction industry, based on different types of waste, is gaining significant importance in recent years. This is mostly due to the need to increase sustainability of this heavily polluting activity...

  • Article
  • Open Access
9 Citations
6,788 Views
10 Pages

25 September 2015

The development of inexpensive and active Pt-free catalysts as an alternative to Pt-based catalysts for oxygen reduction reaction (ORR) is an essential prerequisite for fuel cell commercialization. In this paper, we report a strategy for the design o...

  • Article
  • Open Access
28 Citations
6,344 Views
15 Pages

20 July 2021

Because of its high strength, energy reduction, and low environmental impact, researchers have encouraged considering alkali-activated slag concrete (AASC) as a potential alternative to conventional concrete. In this study, the impact of mix design p...

  • Article
  • Open Access
4 Citations
2,419 Views
13 Pages

Electrochemical Performance of Metal-Free Carbon-Based Catalysts from Different Hydrothermal Carbonization Treatments for Oxygen Reduction Reaction

  • Aldo Girimonte,
  • Andrea Stefani,
  • Clara Mucci,
  • Roberto Giovanardi,
  • Andrea Marchetti,
  • Massimo Innocenti and
  • Claudio Fontanesi

12 January 2024

This research investigates the difference between products obtained through two hydrothermal carbonization treatments. Our aim is to synthesize metal-free, carbon-based catalysts for the oxygen reduction reaction (ORR) to serve as efficient and cost-...

  • Article
  • Open Access
9 Citations
2,605 Views
21 Pages

The Effect of Fibrous Reinforcement on the Polycondensation Degree of Slag-Based Alkali Activated Composites

  • Isabella Lancellotti,
  • Federica Piccolo,
  • Hoang Nguyen,
  • Mohammad Mastali,
  • Mohammad Alzeer,
  • Mirja Illikainen and
  • Cristina Leonelli

10 August 2021

Alternative cementitious binders, based on industrial side streams, characterized by a low carbon footprint, are profitably proposed to partially replace Portland cement. Among these alternatives, alkali-activated materials have attracted attention a...

  • Article
  • Open Access
13 Citations
3,674 Views
20 Pages

27 June 2024

Due to the growing demand for human-edible protein sources, microalgae are recognized as an economically viable alternative source of proteins. The investigation into the structural characteristics and functional properties of microalgin is highly si...

  • Article
  • Open Access
8 Citations
3,680 Views
23 Pages

Alkali-Activated Hybrid Cement from Mineral Wool Fiber Waste and OPC

  • Diego A. Gutiérrez-Orrego,
  • Maryory A. Gómez-Botero and
  • Edwin F. García

27 January 2023

Cements to replace ordinary portland cement (OPC) are currently being studied due to the high environmental costs of OPC production. One viable alternative is alkali-activated cements, which can be made from pozzolanic materials such as stone wool fi...

  • Article
  • Open Access
31 Citations
4,118 Views
17 Pages

The Emericellipsins A–E from an Alkalophilic Fungus Emericellopsis alkalina Show Potent Activity against Multidrug-Resistant Pathogenic Fungi

  • Anastasia E. Kuvarina,
  • Irina A. Gavryushina,
  • Alexander B. Kulko,
  • Igor A. Ivanov,
  • Eugene A. Rogozhin,
  • Marina L. Georgieva and
  • Vera S. Sadykova

21 February 2021

Novel antimicrobial peptides with antifungal and cytotoxic activity were derived from the alkalophilic fungus Emericellopsis alkalina VKPM F1428. We previously reported that this strain produced emericellipsin A (EmiA), which has strong antifungal an...

  • Review
  • Open Access
10 Citations
3,822 Views
28 Pages

29 December 2023

Alkaline water electrolysis is promising for low-cost and scalable hydrogen production. Renewable energy-driven alkaline water electrolysis requires highly effective electrocatalysts for the hydrogen evolution reaction (HER) and the oxygen evolution...

  • Article
  • Open Access
32 Citations
4,105 Views
18 Pages

Effect of Non-Calcined Sugarcane Bagasse Ash as an Alternative Precursor on the Properties of Alkali-Activated Pastes

  • Leila Nóbrega Sousa,
  • Pâmella Fernandes Figueiredo,
  • Sâmara França,
  • Marcos Vinicio de Moura Solar Silva,
  • Paulo Henrique Ribeiro Borges and
  • Augusto Cesar da Silva Bezerra

10 February 2022

BFS-MK-based alkali-activated materials are well established as an alternative for sustainable and green construction. This work aims to collaborate and encourage the use of biomass ashes, such as sugarcane bagasse ash (SCBA), as a precursor in alkal...

  • Article
  • Open Access
37 Citations
4,836 Views
15 Pages

6 August 2022

Alternative methods were evaluated for chitin isolation from Acheta domesticus. Chemical demineralization was compared to fermentation with Lactococcus lactis, citric acid treatment, and microwave treatment, leading to a degree of demineralization of...

  • Article
  • Open Access
3 Citations
1,985 Views
13 Pages

With the rapid development of anion exchange membrane technology and the availability of high-performance non-noble metal cathode catalysts in alkaline media, the commercialization of anion exchange membrane fuel cells has become feasible. Currently,...

  • Feature Paper
  • Article
  • Open Access
10 Citations
3,270 Views
21 Pages

Preparation and Characterization of the Functional Properties of Synthetic Aggregates from Silico-Manganese Slag

  • Zhibing Xing,
  • Fenglan Han,
  • Jiuliang Tian,
  • Zhichao Xu,
  • Jiaqi Wang,
  • Tengteng Liu,
  • Bin Zheng and
  • Jiahe Huang

29 November 2021

A large number of natural aggregates are used in the field of construction materials, resulting in the exhaustion of natural aggregates. Therefore, looking for an alternative will slow down the consumption of natural aggregates. The sintering method...

  • Article
  • Open Access
18 Citations
3,624 Views
11 Pages

Preparation of Robust Hydrogen Evolution Reaction Electrocatalyst WC/C by Molten Salt

  • Pengpeng Yan,
  • Yuchen Wu,
  • Xiaofeng Wei,
  • Xuewei Zhu and
  • Wei Su

19 August 2020

Tungsten carbide (WC) is an alternative to the costly and resource-constrained Pt-based catalysts for hydrogen evolution reaction (HER). In this work, a one-step facile and easily scalable approach is reported, to synthesize ultrafine WC by molten sa...

  • Article
  • Open Access
8 Citations
3,009 Views
14 Pages

24 June 2021

Utilisation of industrial waste-based material to develop a novel binding material as an alternative to Ordinary Portland Cement (OPC) has attracted growing attention recently to reduce or eliminate the environmental footprint associated with OPC. Th...

  • Review
  • Open Access
56 Citations
5,957 Views
24 Pages

State of Art of Alkaline Earth Metal Oxides Catalysts Used in the Transesterification of Oils for Biodiesel Production

  • Jesús Andrés Tavizón-Pozos,
  • Gerardo Chavez-Esquivel,
  • Víctor Alejandro Suárez-Toriello,
  • Carlos Eduardo Santolalla-Vargas,
  • Oscar Abel Luévano-Rivas,
  • Omar Uriel Valdés-Martínez,
  • Alfonso Talavera-López and
  • Jose Antonio Rodriguez

16 February 2021

Biodiesel produced through catalytic transesterification of triglycerides from edible and non-edible oils and alcohol is considered an alternative to traditional petro-diesel. The interest in the use of alkaline earth metal oxides as heterogeneous ba...

  • Article
  • Open Access
4 Citations
2,756 Views
17 Pages

Interfacial Electronic Rearrangement and Synergistic Catalysis for Alkaline Water Splitting in Carbon-Encapsulated Ni (111)/Ni3C (113) Heterostructures

  • Xiaoyu Li,
  • Zhenbo Peng,
  • Dongmei Jia,
  • Yikang Wang,
  • Wenbo Wu,
  • Ping Deng,
  • Mengqiu Xu,
  • Xudong Xu,
  • Gan Jia and
  • Peng Gao
  • + 1 author

4 November 2022

The realization of efficient water electrolysis is still blocked by the requirement for a high and stable driving potential above thermodynamic requirements. An Ni-based electrocatalyst, is a promising alternative for noble-metal-free electrocatalyst...

  • Article
  • Open Access
904 Views
15 Pages

Nitrogen-Doped Biocarbon Derived from Alginate-Extraction Residues of Sargassum spp.: Towards Low-Cost Electrocatalysts for Alkaline ORR

  • Aurora Caldera,
  • Beatriz Escobar,
  • Juan Briceño,
  • José M. Baas-López,
  • Romeli Barbosa and
  • Jorge Uribe

3 September 2025

Extraction processes of alginates from Sargassum spp. generate a substantial number of solid residues that are commonly discarded. This study explores the sustainable transformation of these residues into nitrogen-doped biocarbon through chemical act...

  • Article
  • Open Access
4 Citations
2,053 Views
17 Pages

Assessment of the Corrosion of Steel Embedded in an Alkali-Activated Hybrid Concrete Exposed to Chlorides

  • William Valencia-Saavedra,
  • Ana María Aguirre-Guerrero and
  • Ruby Mejía de Gutiérrez

19 August 2022

Hybrid alkali-activated cements (HAACs), also known as cements with high percentages of alkali-activated supplementary materials, are alternative cements that combine the advantages of ordinary Portland cement (OPC) and alkali-activated systems. Thes...

  • Article
  • Open Access
5 Citations
3,030 Views
13 Pages

Modification of the Microstructure and Transport Properties of La2CuO4−δ Electrodes via Halogenation Routes

  • Lucía dos Santos-Gómez,
  • Javier Zamudio-García,
  • José M. Porras-Vázquez,
  • Enrique R. Losilla and
  • David Marrero-López

16 June 2022

Ruddlesden–Popper type electrodes with composition La2CuO4−δ are alternative cathode materials for solid oxide fuel cells (SOFCs); however, the undoped compound exhibits low electrical conductivity for potential applications, which...

  • Article
  • Open Access
7 Citations
3,131 Views
19 Pages

Reuse of Oil Refining Sludge Residue Ash via Alkaline Activation in Matrices of Chamotte or Rice Husk Ash

  • Almudena García-Díaz,
  • Salvador Bueno-Rodríguez,
  • Luis Pérez-Villarejo and
  • Dolores Eliche-Quesada

31 March 2023

The aim of this work is to investigate the possibility of reusing ashes obtained by the calcination of industrial sludge from the oil refining industry (ORSA) as a secondary raw material in the manufacture of alkaline activated cements or geopolymers...

  • Article
  • Open Access
21 Citations
3,878 Views
24 Pages

19 October 2022

Recent trends in reducing the ecological footprint of the construction industry have increased the attention surrounding the use of alternative binding systems. Among the most promising are geopolymer binders, which were found to have the capability...

  • Article
  • Open Access
9 Citations
3,551 Views
22 Pages

9 June 2022

Geopolymers are created by mixing a source of aluminosilicates, which can be natural or by-products of other industries, with an alkaline solution, which dissolves the aluminates and silicates present in this source, where after a polymerization proc...

  • Article
  • Open Access
38 Citations
5,691 Views
15 Pages

17 March 2023

Commercial sodium hydroxide (NaOH) and sodium silicate (SS) have remained two of the leading alkaline activators widely used in producing geopolymer concrete, despite some identified negatives regarding their availability and additional CO2 emissions...

  • Article
  • Open Access
13 Citations
3,470 Views
15 Pages

2 March 2023

The production of Portland cement is energy-intensive and polluting. As a result, the search for ecological and economical alternatives has become a global priority. Geopolymers are among the most promising ecological alternatives to Portland cement....

  • Review
  • Open Access
30 Citations
6,261 Views
32 Pages

Self-Sensing Alkali-Activated Materials: A Review

  • Christos Vlachakis,
  • Marcus Perry and
  • Lorena Biondi

6 October 2020

Alkali-activated materials are an emerging technology that can serve as an alternative solution to ordinary Portland cement. Due to their alkaline nature, these materials are inherently more electrically conductive than ordinary Portland cement, and...

  • Feature Paper
  • Article
  • Open Access
13 Citations
3,000 Views
13 Pages

Reuse of Industrial and Agricultural Waste in the Fabrication of Geopolymeric Binders: Mechanical and Microstructural Behavior

  • Jordi Payá,
  • Lourdes Soriano,
  • Alba Font,
  • Maria Victoria Borrachero Rosado,
  • Javier Alejandro Nande and
  • Jose María Monzo Balbuena

21 April 2021

Resource recovery from waste is one of the most important ways to implement the so-called circular economy, and the use of alkali activated materials can become an alternative for traditional PC-based materials. These types of materials are based on...

  • Article
  • Open Access
60 Citations
5,506 Views
18 Pages

30 July 2021

Malaysia is one of the largest palm oil producers in the world and its palm oil industry is predicted to generate a large amount of waste, which increases the need to modify it for sustainable reuse. The green geopolymers produced from industrial was...

  • Article
  • Open Access
1 Citations
1,372 Views
12 Pages

4 December 2024

Developing low-cost, efficient alternatives to catalysts for bifunctional oxygen electrode catalysis in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is critical for advancing the practical applications of alkaline fuel cell...

  • Article
  • Open Access
1 Citations
1,139 Views
26 Pages

Integrated Mechanical and Eco-Economical Assessments of Fly Ash-Based Geopolymer Concrete

  • Qasim Shaukat Khan,
  • Raja Hilal Ahmad,
  • Asad Ullah Qazi,
  • Syed Minhaj Saleem Kazmi,
  • Muhammad Junaid Munir and
  • Muhammad Hassan Javed

20 July 2025

This research evaluates the mechanical properties, environmental impacts, and cost-effectiveness of Hub Coal fly ash (FA)-based geopolymer concrete (FAGPC) as a sustainable alternative to ordinary Portland cement (OPC) concrete. This local FA has not...

  • Article
  • Open Access
17 Citations
4,657 Views
14 Pages

Impact of Serum Source on Human Mesenchymal Stem Cell Osteogenic Differentiation in Culture

  • Alexander Popov,
  • Colin Scotchford,
  • David Grant and
  • Virginie Sottile

11 October 2019

Human mesenchymal stem cells (MSCs) show promise for musculoskeletal repair applications. Animal-derived serum is extensively used for MSC culture as a source of nutrients, extracellular matrix proteins and growth factors. However, the routine use of...

  • Article
  • Open Access
7 Citations
2,204 Views
19 Pages

Evaluation of Thermochemical Treatments for Rice Husk Ash Valorisation as a Source of Silica in Preparing Geopolymers

  • Noelia Bouzón,
  • Alba Font,
  • María Victoria Borrachero,
  • Lourdes Soriano,
  • José Monzó,
  • Mauro M. Tashima and
  • Jordi Payá

28 June 2023

The use of geopolymers has revolutionized research in the field of construction. Although their carbon footprint is often lower than that of traditional mortars with Portland cement, activators such as sodium silicate have a high environmental impact...

  • Review
  • Open Access
121 Citations
9,065 Views
19 Pages

12 April 2019

Alkali-activated slag (AAS) is a promising alternative to ordinary Portland cement (OPC) as sole binder for reinforced concrete structures. OPC is reportedly responsible for over 5% of the global CO2 emission. In addition, slag is an industrial by-pr...

  • Article
  • Open Access
2 Citations
2,184 Views
18 Pages

22 May 2025

The geopolitical and economic situation impacts raw materials demand. As principal ore deposits reach exhaustion, the study of new sources of raw materials becomes essential. Therefore, mining wastes emerge as alternative sources of raw materials. Th...

  • Article
  • Open Access
10 Citations
2,734 Views
14 Pages

Sustainable Soil-Compacted Blocks Containing Blast Furnace Slag (BFS) Activated with Olive Stone BIOMASS Ash (OBA)

  • Jordi Payá,
  • José Monzó,
  • Josefa Roselló,
  • María Victoria Borrachero,
  • Alba Font and
  • Lourdes Soriano

24 November 2020

Soil stabilization using cementing materials is a well-known procedure for earth-based building blocks preparation. For the selected binding materials, innovation usually focuses on low carbon systems, many of which are based on alkaline activation....

  • Article
  • Open Access
13 Citations
3,758 Views
12 Pages

The Role of an Industrial Alkaline Wastewater in the Alkali Activation of Biomass Fly Ash

  • Catarina C. Novo,
  • Luciano Senff,
  • Maria P. Seabra,
  • Rui M. Novais and
  • João A. Labrincha

2 April 2022

Alkali-activated materials are generally considered a more sustainable alternative to Portland cement binders. This derives not only from the use of solid wastes as precursors, but also from the low temperatures required for their synthesis. However,...

  • Review
  • Open Access
61 Citations
6,979 Views
31 Pages

Volcanic Ash as a Sustainable Binder Material: An Extensive Review

  • Andrés Játiva,
  • Evelyn Ruales and
  • Miren Etxeberria

8 March 2021

The construction industry is affected by the constant growth in the populations of urban areas. The demand for cement production has an increasing environmental impact, and there are urgent demands for alternative sustainable solutions. Volcanic ash...

  • Article
  • Open Access
6 Citations
3,713 Views
23 Pages

Geopolymer concrete is concrete made from industrial materials, such as fly ash, GGBS, silica fume, and metakaolin, used as a cement alternative. In this study, geopolymer concrete will be based on fly ash as a binder material, alkaline activators of...

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