Search Results (68)

Adsorption chillers are distinguished by their low electricity consumption, lack of moving parts and exceptional reliability. However, their considerable weight, due to the low sorption capacity of conventional adsorbents, remains a key limitation. This study investigates the effect of introducing thermally conductive additives—aluminium powder, copper powder and graphite flakes—at 5, 15 and 25 wt.% to silica-gel-based adsorbent beds on the enhancement of heat transfer. In contrast to other works, this study also includes a novel analysis of the thermal properties of dry sorbents, since the moisture content affects the thermal conductivity. Additives improve the thermal conductivity, as measured by the laser flash method (LFA), of the bed by up to 20.7% while maintaining a reasonable sorption capacity, as measured by the dynamic vapor sorption (DVS). Additions of copper at 5–15 wt.% and graphite flakes at 15–25 wt.% provide an optimal compromise between thermal conductivity and sorption capacity. Aluminium powder, on the other hand, offers flexibility over a wider range (5–25 wt.%). The increased thermal conductivity of these modified materials is expected to lead to more efficient heat transport, which suggests the hypothesis that it could reduce the cycle time and increase the efficiency of adsorption chillers. Full article

Reductions of carbon dioxide emissions from the building sector are mandatory for climate protection. This calls for both a reduction of the construction material and energy as well as a reduction of the operational energy. Against this background, a novel facade-integrated adsorption system for solar cooling of lightweight buildings is proposed and theoretically investigated in this work. For this purpose, a detailed simulation model is developed to analyze both the processes in the single components as well as the overall system behavior. The proposed system consists of the three components adsorber, condenser and evaporator, which are connected vacuum-tight and are coupled by vapor transfer. The simulation results of a defined reference case yield cooling rates of $54 \mathrm{W}$ per installed square meter of adsorber facade. The cooling power can be maintained for 12 h, confirming the applicability of the proposed system. Furthermore, a comprehensive parametric study is carried out in order to identify an optimum set of parameter values for maximum cooling rate under the assumed conditions. The results reveal that controlled constant cooling rates of $105 \mathrm{W}$ per square meter of adsorber facade can be reached and a maximum peak power of $145 \mathrm{W}$ per square meter of adsorber facade is possible. Full article

Broadly defined climate protection is a powerful incentive in the search for environmentally friendly refrigeration technologies. Adsorption chillers are considered to be one such technology; however, their main disadvantages include a low cooling capacity, a low energy efficiency ratio (EER), and cyclic operation. Thus, a great deal of effort is being put into improving adsorption-chiller performance. In this paper, the influence of the spray angle, the number of nozzles, and the water flow rate through the nozzles on adsorption-chiller performance was investigated. Adsorption-chiller performance was investigated mainly in terms of the cooling capacity (CC), the energy efficiency ratio (EER), and the specific cooling power (SCP). The results indicated that the chiller’s cooling capacity increased from about 210 W to 316 W and that the EER increased from 0.110 to 0.167 when the spray angle of the nozzles was increased from 90° to 120°. It was also reported that increasing the flow rate of water through the nozzles did not improve the average cooling capacity or the other performance parameters but resulted in more stable operation of the chiller. Additionally, using six nozzles instead of three improved the average cooling capacity and EER tenfold. Full article

Sustainable development policy focuses on reducing the carbon footprint generated by the global industry and energy sector. Replacing conventional energy sources with environmentally friendly ones requires advanced research to increase energy efficiency and reduce the instability and intermittence of renewable sources. Moreover, adsorption chillers are an opportunity to introduce net-zero emission technologies to the refrigeration, air-conditioning, and desalination industries. Adsorption devices could be popularized if a method of effective heat transfer in the volume of the adsorption bed is developed. The innovative concept of introducing fluidized beds into the adsorption system can achieve the most promising results in improving energy efficiency. To confirm the adopted assumption, heat transfer coefficient calculations for the packed and fluidized bed were carried out in this paper based on experimental tests and literature data. The empirical research aims to extend the fundamental knowledge in the implementation of fluidization under low-pressure conditions, characteristic of the adsorption systems’ working cycle. Experiments were conducted on a unique test stand equipped with the Intensified Heat Transfer Adsorption Bed (IHTAB) reactor prototype. Five adsorption bed samples were analyzed. The reference sample consisted only of silica gel, and the subsequent ones contained aluminum or carbon nanotubes with 5 and 10% additions. In the case of samples with admixtures, the fluidized state increased the heat transfer coefficient on average from approx. 36.9 W/m² K to approx. 245.4 W/m² K. Full article

Adsorption refrigerators are a compelling ecological alternative to compressor refrigerators; global warming forces us to constantly look for alternative sources of energy and cold. Cold production in adsorption chillers is based on the use of heat generated by other processes running in the company. Waste heat from production processes, which has, until now, been irretrievably lost, is a potential source of energy for generating cold via an adsorption unit producing chilled water. Cooling optimizes the use of the heating network in summer and can lead to increased electricity production while reducing heat supply losses. Thus far, attempts to implement adsorption refrigerators for widespread use have not been successful as a result of the low efficiency of these devices; this is directly related to the poor heat and mass transfer conditions in the beds and heat exchangers of adsorption refrigerators. The solutions used so far, such as new working pairs, glued beds or modifications to the structure or cycle length, are still not strong enough for these devices. Therefore, it is necessary to look for new solutions. Using micro- and nanobubbles as media to increase mass and heat transfer in refrigerators is an innovative and pioneering solution. Thus, this document describes the most important features of micro- and nanobubble technology applications in adsorption refrigerators. This article is an introduction and a basis for the implementation of further research, consolidating the existing literature as a review. Full article

Thermal-driven refrigeration technologies, e.g., absorption- or adsorption-type, are gathering momentum since they can utilize low-grade heat from industrial, solar or geothermal energy. However, heat sources and end users are usually mismatched, which could lead to potential heat pollution and increased carbon emissions. Long-distance thermal energy transportation is good for district heating and cooling, which is of great significance if it can achieve a high energy-transportation density and low heat loss. In this paper, a compression-assisted chemisorption chiller driven by a low-temperature heat source for cold transportation is initially proposed, which aims to transport liquid ammonia with chemical potential and generate a cooling effect for end users. A feasibility analysis of the compression-assisted chemisorption chiller is preliminarily performed for 2 km cold transportation. The results show that the highest theoretical coefficient of performance and the energy efficiency of the compression-assisted adsorption chiller using a sodium bromide–ammonia working pair can reach 0.46 and 0.25, respectively, when the evaporation temperature is 20 °C. Among the three selected low-temperature salts, ammonium chloride–ammonia shows the best performance, which is up to about 40% higher than those of sodium bromide–ammonia and barium chloride–ammonia. It is demonstrated that compared with common absorption chillers, a compression-assisted adsorption system has a reasonable working efficiency to transport cold energy when the low- or ultralow-temperature heat source, e.g., lower than 60 °C, is required to be utilized. Full article

In this study, transient modelling for a solar-powered adsorption-based multi-generation system working under the climatic conditions of the Gulf Cooperation Council (GCC) countries is conducted. Three cities are selected for this study: Sharjah in the United Arab Emirates, Riyadh in Saudi Arabia, and Kuwait City in Kuwait. The system comprises (i) evacuated tube solar collectors (ETCs), (ii) photovoltaic-thermal (PVT) solar collectors, and (iii) a single-stage double-bed silica gel/water-based adsorption chiller for cooling purposes. A MATLAB code is developed and implemented to theoretically investigate the performance of the proposed system. The main findings of this study indicate that among the selected cities, based on the proposed systems and the operating conditions, Riyadh has the highest cooling capacity of 10.4 kW, followed by Kuwait City, then Sharjah. As for the coefficient of performance (COP), Kuwait City demonstrates the highest value of 0.47. The electricity generated by the proposed system in Riyadh, Kuwait City, and Sharjah is 31.65, 31.3, and 30.24 kWh/day, respectively. Furthermore, the theoretical results show that at 18:00, the overall efficiency of the proposed system reaches about 0.64 because of the inclusion of a storage tank and its feeding for the adsorption chiller. This study analyzes the feasibility of using a combination of ETCs and PVT collectors to drive the adsorption chiller system and produce electricity in challenging weather conditions. Full article

Adsorption technology utilizes low-temperature renewable and waste heat sources for cost-effective and environmentally friendly cooling and water desalination systems. However, the problem with existing adsorption refrigerators is the low COP. This is caused by poor heat and mass transfer in existing packed bed designs. The solution to this problem lies in the use of fluidized bed technology, which enhances heat and mass transfer mechanisms. Various approaches to the construction and operation of adsorption systems with a fluidized bed of adsorbent can be found in the literature; hence, the aim of the work is to analyze the existing applications of a fluidized bed in adsorption refrigerators and other systems utilizing sorption beds. There are many methods for improving the energy efficiency of adsorption refrigerators. However, the literature suggests that fluidized bed systems have the potential to significantly improve the energy efficiency of adsorption cooling and desalination systems. Based on the review, it was concluded that using fluidization technology in adsorption cooling and desalination systems can be beneficial and represents significant potential for future research. Full article

Adsorption heat transformation and storage (AHTS) is an environmentally benign and energy-saving alternative to common compression chillers and heat pumps. The low specific power (SP) of adsorption systems is a key drawback that hinders their broader dissemination. The optimization of adsorption dynamics is a prerequisite for SP enhancement. In this work, we studied the dynamics of water vapor adsorption on MOF-801—a promising adsorbent for AHTS. For the first time, two configurations of compact MOF-801 bed, namely, grains glued to the surface of a metal support and thin adsorbent coatings, are prepared, and their porous structure is characterized. The water adsorption dynamics is compared with a common loose grains configuration. The main findings are: (a) the binder can both accelerate and decelerate the water adsorption, and its chemical nature is subject to careful selection; (b) at the initial time, heat transfer between the support and adsorbent bed controls the adsorption rate, and, at a longer time, mass transfer starts to affect it; (c) polyvinylpyrrolidone, bentonite, thermal grease, and hydroxyethylcellulose increase the heat transfer coefficients and accelerate adsorption; polyvinyl alcohol and polyaniline slow it down; and (d) for the coatings prepared with polyvinylpyrrolidone, an SP of 1.6–5.1 kW/kg can be achieved, which is about twice that for the loose grains. The new configurations can be recommended for effective but expensive adsorbents such as MOFs, and their implementation will contribute to the further spread of AHTS technology. Full article

Adsorption systems are alternatives to compressor cooling systems. Apart from many advantages, these systems are characterized by low COP and SCP parameters. One of the most promising options to improve the performance of adsorption chillers is the replacement of the stationary bed with a fluidized one. A fluidized bed significantly increases the heat and mass transfer within the bed, enables better contact between gas and solid phases, and results in the proper mixing of adsorbent particles. This paper presents the possibility of using fluidized beds in adsorption chillers. This paper shows the results of CFD numerical modelling of the operation of a fluidized bed for an adsorption chiller and simulations of the bed temperature profiles during the adsorption and desorption processes of sorbent in a fluidized bed. This article presents an analysis of CFD simulation results for the optimal angle of heat exchangers. Full article

Adsorption cooling technology is a promising alternative to replace conventional solutions. However, adsorption chillers still need to be improved in terms of performance parameters. One of the most important factors affecting their efficiency is the characteristics of the adsorbent, which should have the highest adsorption capacity and enable efficient heat transport in the bed. The objective of this paper is to present current developments in the field of composite sorbents with silica gel matrix as modern and very promising materials and then perform a detailed analysis of them. The paper summarises the methods of synthesis of composite sorbents and the current knowledge concerning these materials. The analysis focuses on a comparison of the available data, particular taking into account the types of matrixes, so that the analysis provides a clear and qualitative basis for further research. As a result of exploring the state of the art, this subject is found to be insufficiently described; therefore, these materials are comprehensively analysed in terms of their properties and the impact of their use on the COP (coefficient of performance) and SCP (specific cooling power) of adsorption chillers. Based on the analysis of the literature, the most promising directions for further research are also indicated. Full article

Demand for space cooling systems is growing worldwide. The main reasons are socioeconomic developments such as the growing world population and the rise of economic wealth, especially in developing countries. These developments run simultaneously with global warming effects, increasing the need for cooling. This study introduces the development of the Cooling Demand Market Index (CDMI), which indicates the demand for cooling appliances worldwide at a spatial resolution of 1 km. It is based on population density, Gross Domestic Product (GDP)/capita and Cooling Degree Days (CDD) per climate zone. The CDMI is calculated for 2020 and 2050 in four different future scenarios in accordance with the Spatial Socioeconomic Pathways (SSP) and Representative Concentration Pathways (RCP). Further, the Solar Thermal Cooling Index (STCI) was developed to spatially estimate the worldwide potential to use solar thermal cooling systems based on solar availability and limitations due to maximum heat rejection temperature. Results of the CDMI show that the economic demand for cooling solutions is increasing, especially in developing countries, and that India will be by far the largest market by 2050. Countries such as Burundi and the Democratic Republic of the Congo show the strongest national increases in CDMI. The STCI indicates that ammonia absorption chillers and zeolite adsorption chillers can serve the vast majority of the market thanks to their capability to run at high condenser temperatures. Full article

A tri-generation system combining cooling, heating, and power generation can contribute to increased system efficiency and thereby reduce greenhouse gas emissions. This study proposed a novel concept using 100-kW polymer electrolyte membrane fuel cells (PEMFCs) as the basis for a tri-generation system with an integrated heat pump and adsorption chiller for greenhouse use. Three configurations of heat pump loop were designed to recover the waste heat from PEMFCs and used either for direct heating or cooling power generation in adsorption cooling. Analyses were carried out in terms of primary energy rate (PER) and exergy efficiencies. Of those investigated, the layout with a heat pump and internal heat exchanger demonstrated the best performance, with PERs of the cooling and heating modes at 0.94 and 0.78, respectively. Additionally, the exergy analysis revealed that the exergies are mostly destroyed at the expansion valve and evaporator due to differences in pressure and temperature. These differences are minimized when the system layout contains a cascade heat pump loop or an internal heat exchanger, thus resolving the problem of exergy destruction. As a result, the total exergy destruction in the system was decreased from 61.11% to 49.18% and 46.60%, respectively. Furthermore, the proposed configurations showed 36.1% and 31.4% lower values in terms of energy consumption compared with relevant works in the heating mode and cooling mode, respectively. Full article

In this paper, an economic investigation is performed to identify the economic feasibility of a solar-powered adsorption cooling system. In the first step, the system is mathematically formulated, and the solar fraction of the system is calculated. After that, the system is economically optimized for a cooling load related to a single-family house using particle swarm optimization. In order to identify the most efficient application of the system, the cost per 1 kW of cooling capacity is calculated over different cooling loads. The results demonstrated that the system under study is more suitable for small-scale applications. In addition, sensitivity to electricity price analysis demonstrates that the main bottleneck of cost-efficient system design is the initial price of the solar collector. Therefore, in the next step, the former sensitivity analysis to electricity price is jointly performed over different initial prices of the solar collector at two different cooling loads. Finally, by considering the cost of CO₂ capture and the amount of avoided CO₂ by utilizing solar energy, the environmental benefit of the system under investigation is calculated. The results show that the optimum solution is 13% more cost-efficient compared to the base design. In addition, taking the CO₂ capture parameters into account, the environmentally friendly case has 21% more annual cost compared to the optimal solution one. However, this extra cost can be justified through CO₂ capture cost. Full article

Adsorption chillers produce cold energy, using heat instead of electricity, thus reducing electrical energy consumption. A major industrial waste, fly ash, can be converted to zeolite and used in adsorption chillers as an adsorbent. In this research, three different types of zeolites were synthesised from fly ash via a hydrothermal reaction in an alkaline solution (NaOH). The obtained samples (Na-A zeolites) were modified with K₂CO₃ to increase the water adsorption capacity of these samples. Phase and morphology analyses shows that desired zeolites formed properly but other crystalline phases also exist along with nonporous amorphous phases. The determined specific surface areas for Na-A zeolite (12 h) and Na-A zeolite (24 h) are 45 m²/g and 185 m²/g respectively, while the specific surface area for synthesized 13X zeolite is almost negligible. Water-isotherm for each of these samples was measured. Considering the application of adsorption chillers, average adsorption capacity was very low, 1.73% and 1.27%, respectively, for the two most probable operating conditions for synthesized 13X zeolite, whereas no water was available for the evaporation from Na-A zeolite (12 h) and Na-A zeolite (24 h). This analysis implies that among the synthesized materials only 13X zeolite has a potential as an adsorber in sorption chillers. Full article