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26 pages, 3558 KB  
Article
Avocado: An Interpretable Fine-Grained Intrusion Detection Model for Advanced Industrial Control Network Attacks
by Xin Liu, Tao Liu and Ning Hu
Electronics 2025, 14(21), 4233; https://doi.org/10.3390/electronics14214233 - 29 Oct 2025
Viewed by 429
Abstract
Industrial control systems (ICS), as critical infrastructure supporting national operations, are increasingly threatened by sophisticated stealthy network attacks. These attacks often break malicious behaviors into multiple highly camouflaged packets, which are embedded into large-scale background traffic with low frequency, making them semantically and [...] Read more.
Industrial control systems (ICS), as critical infrastructure supporting national operations, are increasingly threatened by sophisticated stealthy network attacks. These attacks often break malicious behaviors into multiple highly camouflaged packets, which are embedded into large-scale background traffic with low frequency, making them semantically and temporally indistinguishable from normal traffic and thus evading traditional detection. Existing methods largely rely on flow-level statistics or long-sequence modeling, resulting in coarse detection granularity, high latency, and poor byte-level interpretability, falling short of industrial demands for real-time and actionable detection. To address these challenges, we propose Avocado, a fine-grained, multi-level intrusion detection model. Avocado’s core innovation lies in contextual flow-feature fusion: it models each packet jointly with its surrounding packet sequence, enabling independent abnormality detection and precise localization. Moreover, a shared-query multi-head self-attention mechanism is designed to quantify byte-level importance within packets. Experimental results show that Avocado significantly outperforms state-of-the-art flow-level methods on NGAS and CLIA-M221 datasets, improving packet-level detection ACC by 1.55% on average, and reducing FPR and FNR to 3.2%, 3.6% (NGAS), and 3.7%, 4.3% (CLIA-M221), respectively, demonstrating its superior performance in both detection and interpretability. Full article
(This article belongs to the Special Issue Novel Approaches for Deep Learning in Cybersecurity)
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23 pages, 4794 KB  
Article
IHGR-RAG: An Enhanced Retrieval-Augmented Generation Framework for Accurate and Interpretable Power Equipment Condition Assessment
by Zhenhao Ye, Donglian Qi, Hanlin Liu and Siqi Zhang
Electronics 2025, 14(16), 3284; https://doi.org/10.3390/electronics14163284 - 19 Aug 2025
Viewed by 1652
Abstract
Condition assessment of power equipment is crucial for optimizing maintenance strategies. However, knowledge-driven approaches rely heavily on manual alignment between equipment failure characteristics and guideline information, while data-driven methods predominantly depend on on-site experiments to detect abnormal conditions. Both face challenges in terms [...] Read more.
Condition assessment of power equipment is crucial for optimizing maintenance strategies. However, knowledge-driven approaches rely heavily on manual alignment between equipment failure characteristics and guideline information, while data-driven methods predominantly depend on on-site experiments to detect abnormal conditions. Both face challenges in terms of inefficiency and timeliness limitations. With the growing integration of information systems, a significant portion of condition assessment-related information is represented in textual formats, such as system alerts and experimental records. Although Large Language Models (LLMs) and Retrieval-Augmented Generation (RAG) show promise in processing such text-based information, their practical application is constrained by LLMs’ hallucinations and RAG’s coarse-grained retrieval mechanisms, which struggle with semantically similar but contextually distinct guideline items. To address these issues, this paper proposes an enhanced RAG framework that integrates hierarchical and global retrieval mechanisms (IHGR-RAG). The framework comprehensively incorporates three optimization strategies: a query rewriting mechanism based on few-shot learning prompt engineering, an integrated approach combining hierarchical and global retrieval mechanisms, and a zero-shot chain-of-thought generation optimization pipeline. Additionally, a Task-Specific Quantitative Evaluation Benchmark is developed to rigorously evaluate model performance. Experimental results indicate that IHGR-RAG achieves accuracy improvements of 4.14% and 5.12% in the task of matching the solely correct guideline item, compared to conventional RAG and standalone hierarchical methods, respectively. Ablation studies confirm the effectiveness of each module. This work advances dynamic health monitoring for power equipment by balancing interpretability, accuracy, and domain adaptability, providing a cost-effective optimization pathway for scenarios with limited annotated data. Full article
(This article belongs to the Special Issue Advances in Condition Monitoring and Fault Diagnosis)
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19 pages, 3627 KB  
Article
Numerical Analysis of Pulse Decay Characteristics in Solid Rocket Motors for Different Finocyl Grain Configurations
by Fengnan Guo, Fengrui Li, Hongfeng Ji, Lin Fu and Xuyang Gao
Aerospace 2025, 12(6), 537; https://doi.org/10.3390/aerospace12060537 - 13 Jun 2025
Viewed by 1229
Abstract
Combustion instability is an abnormal working state that often occurs in advanced solid rocket motors (SRMs), which can arouse pressure oscillations, increase the risk of mission failure, and even cause structural damage. In this paper, a numerical simulation method is adapted to analyze [...] Read more.
Combustion instability is an abnormal working state that often occurs in advanced solid rocket motors (SRMs), which can arouse pressure oscillations, increase the risk of mission failure, and even cause structural damage. In this paper, a numerical simulation method is adapted to analyze the combustion instability problem of a typical finocyl grain SRM, and the working process and pressure oscillation of different-structure SRMs are compared and analyzed. Firstly, the acoustic finite element analysis (FEA) method and the large eddy simulation (LES) method for SRM combustion instability analysis are given. Then, the numerical simulation method presented in this paper is verified by comparing the present results with the experimental data of Ariane-5 P230 motor, and finally, the pressure oscillation characteristics of SRMs with different structures by external pulse excitation are studied. The simulation results show that the pressure decay rate of the front finocyl grain structure is faster than that of the rear finocyl grain structure under the same external excitation. The excitation position has a relatively minor influence on the decay characteristics of pressure oscillations. The results can provide a certain reference for the combustion stability design of SRMs. Full article
(This article belongs to the Special Issue Combustion of Solid Propellants)
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21 pages, 9038 KB  
Article
Deep Learning-Based Detection and Digital Twin Implementation of Beak Deformities in Caged Layer Chickens
by Hengtai Li, Hongfei Chen, Jinlin Liu, Qiuhong Zhang, Tao Liu, Xinyu Zhang, Yuhua Li, Yan Qian and Xiuguo Zou
Agriculture 2025, 15(11), 1170; https://doi.org/10.3390/agriculture15111170 - 29 May 2025
Cited by 1 | Viewed by 1710
Abstract
With the increasing urgency for digital transformation in large-scale caged layer farms, traditional methods for monitoring the environment and chicken health, which often rely on human experience, face challenges related to low efficiency and poor real-time performance. In this study, we focused on [...] Read more.
With the increasing urgency for digital transformation in large-scale caged layer farms, traditional methods for monitoring the environment and chicken health, which often rely on human experience, face challenges related to low efficiency and poor real-time performance. In this study, we focused on caged layer chickens and proposed an improved abnormal beak detection model based on the You Only Look Once v8 (YOLOv8) framework. Data collection was conducted using an inspection robot, enhancing automation and consistency. To address the interference caused by chicken cages, an Efficient Multi-Scale Attention (EMA) mechanism was integrated into the Spatial Pyramid Pooling-Fast (SPPF) module within the backbone network, significantly improving the model’s ability to capture fine-grained beak features. Additionally, the standard convolutional blocks in the neck of the original model were replaced with Grouped Shuffle Convolution (GSConv) modules, effectively reducing information loss during feature extraction. The model was deployed on edge computing devices for the real-time detection of abnormal beak features in layer chickens. Beyond local detection, a digital twin remote monitoring system was developed, combining three-dimensional (3D) modeling, the Internet of Things (IoT), and cloud-edge collaboration to create a dynamic, real-time mapping of physical layer farms to their virtual counterparts. This innovative approach not only improves the extraction of subtle features but also addresses occlusion challenges commonly encountered in small target detection. Experimental results demonstrate that the improved model achieved a detection accuracy of 92.7%. In terms of the comprehensive evaluation metric (mAP), it surpassed the baseline model and YOLOv5 by 2.4% and 3.2%, respectively. The digital twin system also proved stable in real-world scenarios, effectively mapping physical conditions to virtual environments. Overall, this study integrates deep learning and digital twin technology into a smart farming system, presenting a novel solution for the digital transformation of poultry farming. Full article
(This article belongs to the Section Artificial Intelligence and Digital Agriculture)
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16 pages, 25952 KB  
Article
Microstructure Characteristics and Mechanical Properties of High-Strength Invar Alloy by Wire Arc Additive Manufacturing
by Cuixin Chen, Chenyu Zhao, Zhonghua Sun, Jun He, Weibing Guo, Haitao Xue, Baoxi Liu, Caidong Zhang and Hongxin Zhang
Appl. Sci. 2025, 15(6), 3351; https://doi.org/10.3390/app15063351 - 19 Mar 2025
Cited by 2 | Viewed by 1712
Abstract
Wire arc additive manufacturing (WAAM) is a viable technology for manufacturing complex and medium-to-large-sized invar alloy components. However, the cyclic thermal input during the WAAM process may cause the austenite grains in the component to grow abnormally, adversely impacting the material’s mechanical properties. [...] Read more.
Wire arc additive manufacturing (WAAM) is a viable technology for manufacturing complex and medium-to-large-sized invar alloy components. However, the cyclic thermal input during the WAAM process may cause the austenite grains in the component to grow abnormally, adversely impacting the material’s mechanical properties. The addition of alloying elements such as Cr, Mo, and V can refine the microstructure of invar alloy to solve these problems. This study examines the influence of Cr, Mo, V, and N on the microstructure and mechanical properties of invar alloy produced through wire arc additive manufacturing. The elements Cr, Mo, and V can form various carbides and nitrides in invar alloys. These precipitation phases are distributed in various forms at grain boundaries and inside the grain, which can refine both the grain and the cellular substructure inside the grain. Moreover, these precipitation phases are distributed in different forms, impeding dislocation movement, thereby enhancing the strength of the invar alloy. The mean tensile strength of WAAM-fabricated high-strength invar alloy in this study attained 793 MPa, approximately 99% higher than that of ordinary invar alloy. The mechanical anisotropy of WAAM-fabricated invar alloy can be ascribed to the thermal interactions between adjacent deposition units. Full article
(This article belongs to the Section Additive Manufacturing Technologies)
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28 pages, 10098 KB  
Review
A Short Review of Advancements in Additive Manufacturing of Cemented Carbides
by Zhe Zhao, Xiaonan Ni, Zijian Hu, Wenxin Yang, Xin Deng, Shanghua Wu, Yanhui Li, Guanglin Nie, Haidong Wu, Jinyang Liu and Yong Huang
Crystals 2025, 15(2), 146; https://doi.org/10.3390/cryst15020146 - 30 Jan 2025
Cited by 7 | Viewed by 2268
Abstract
Cemented carbides, renowned for their exceptional strength, hardness, elastic modulus, wear resistance, corrosion resistance, low coefficient of thermal expansion, and chemical stability, have long been indispensable tooling materials in metal cutting, oil drilling, and engineering excavation. The advent of additive manufacturing (AM), commonly [...] Read more.
Cemented carbides, renowned for their exceptional strength, hardness, elastic modulus, wear resistance, corrosion resistance, low coefficient of thermal expansion, and chemical stability, have long been indispensable tooling materials in metal cutting, oil drilling, and engineering excavation. The advent of additive manufacturing (AM), commonly known as “3D printing”, has sparked considerable interest in the processing of cemented carbides. Among the various AM techniques, Selective Laser Melting (SLM), Selective Laser Sintering (SLS), Selective Electron Beam Melting (SEBM), and Binder Jetting Additive Manufacturing (BJAM) have garnered frequent attention. Despite the great application potential of AM, no single AM technique has been universally adopted for the large-scale production of cemented carbides yet. The SLM and SEBM processes confront substantial challenges, such as a non-uniform sintering temperature field, which often result in uneven sintering and frequent post-solidification cracking. SLS notably struggles with achieving a high relative density of carbides. While BJAM yields WC-Co samples with a lower incidence of cracking, it is not without flaws, including abnormal WC grain growth, coarse WC clustering, Co-rich pool formation, and porosity. Three-dimensional gel-printing, though possessing certain advantages from its sintering performance, falls short in dimensional and geometric precision control, as well as fabrication efficiency. Cemented carbides produced via AM processes have yet to match the quality of their traditionally prepared counterparts. To date, the specific densification and microstructure evolution mechanisms during the AM process, and their interrelationship with the feedstock carbide material design, printing/sintering process, and resulting mechanical behavior, have not been thoroughly investigated. This gap in our knowledge impedes the rapid advancement of AM for carbide processing. This article offers a succinct overview of additive manufacturing of cemented carbides, complemented by an analysis of the current research landscape. It highlights the benefits and inherent challenges of these techniques, aiming to provide clarity on the present state of the AM processing of cemented carbides and to offer insights into potential future research directions and technological advancements. Full article
(This article belongs to the Special Issue High-Performance Metallic Materials)
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18 pages, 15689 KB  
Article
Using a Combined FE-CA Approach to Investigate Abnormally Large Grains Formed by the Limited Recrystallization Mechanism in a Powder Metallurgy Nickel-Based Superalloy
by Yanhui Yang, Boyan Zhang, Xiuquan Chen, Xiaoxuan Wang, Yankai Feng, Lidong Su, Zhengfei Liang and Yifan Liu
Crystals 2025, 15(1), 91; https://doi.org/10.3390/cryst15010091 - 19 Jan 2025
Cited by 1 | Viewed by 1065
Abstract
Powder nickel-based superalloy is the key material for hot-end components such as turbine disks and gas engine disks in aeroengines, and its microstructure uniformity has an important influence on the disks’ service performance. However, thermomechanical treatments make it easy to produce abnormally large [...] Read more.
Powder nickel-based superalloy is the key material for hot-end components such as turbine disks and gas engine disks in aeroengines, and its microstructure uniformity has an important influence on the disks’ service performance. However, thermomechanical treatments make it easy to produce abnormally large grains (ALGs) in powder superalloy disks. In order to investigate the relationship between the hot deformation conditions and ALGs of powder superalloys, isothermal compression experiments under various deformation conditions were carried out and a FE-CA method was constructed to investigate the ALGs formed by the limited recrystallization mechanism. The results indicate a close relationship between the ALGs formed after the supersolvus treatment of this alloy and the equivalent stress after thermal deformation, and the local dissolution of the γ′ phase in supersolvus heat treatment does not produce ALGs. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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8 pages, 206 KB  
Commentary
Problems with Congestive Heart Failure and Lameness That Have Increased in Grain-Fed Steers and Heifers
by Temple Grandin
Animals 2024, 14(19), 2824; https://doi.org/10.3390/ani14192824 - 30 Sep 2024
Viewed by 3005
Abstract
Grain-fed steers and heifers have increasing problems with both lameness and congestive heart failure. Congestive heart failure used to be limited to cattle raised at high altitudes. It is now occurring at much lower elevations. An inspection of hearts at the slaughter plant [...] Read more.
Grain-fed steers and heifers have increasing problems with both lameness and congestive heart failure. Congestive heart failure used to be limited to cattle raised at high altitudes. It is now occurring at much lower elevations. An inspection of hearts at the slaughter plant indicated that some groups of grain-fed steers and heifers had abnormally swollen hearts in 34% of the animals. Congestive heart failure may also increase death losses in the late stages of the feeding program. Lameness has also increased to 8% of grain-fed steers and heifers arriving at U.S. slaughter plants. Twenty years ago, observations by the author indicated that lameness in fed cattle arriving at the slaughter plant was almost zero. There has also been an increasing occurrence of abnormal hoof structure and poor leg conformation. Genetic selection for rapid growth and a large ribeye may be associated with the increase in both of these problems. Lameness and heart problems severely compromise animal welfare. Full article
(This article belongs to the Section Cattle)
20 pages, 6719 KB  
Article
Source and U-Pb Chronology of Diagenetic Fluids in the Permian Maokou Formation Dolomite Reservoir, Eastern Sichuan Basin, China
by Shuangjian Li, Jian Gao, Tianbo Yang, Tianyi Li, Tianjia Liu, Yunqing Hao, Zhiliang He and Entao Liu
Minerals 2024, 14(8), 803; https://doi.org/10.3390/min14080803 - 7 Aug 2024
Cited by 1 | Viewed by 1970
Abstract
The hydrothermal dolomitization, facilitated by basement fault activities, had an important impact on the Permian Maokou Formation dolomite in the Sichuan Basin, which experienced complex diagenesis and presented strong reservoir heterogeneity. The source and age of diagenetic fluids in this succession remain controversial. [...] Read more.
The hydrothermal dolomitization, facilitated by basement fault activities, had an important impact on the Permian Maokou Formation dolomite in the Sichuan Basin, which experienced complex diagenesis and presented strong reservoir heterogeneity. The source and age of diagenetic fluids in this succession remain controversial. In this study, various analyses were implemented on samples collected from outcrops and wells near the No. 15 fault in the eastern Sichuan Basin to reconstruct the multi-stage fluid activity and analyze the impact on reservoir development, including petrology, micro-domain isotopes, rare earth elements, homogenization temperature of fluid inclusions, and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) U-Pb dating. The homogenization temperature of primary brine inclusions in fine-grained matrix dolomite and saddle dolomite is concentrated between 100 and 150 °C, which indicates that the impacts of abnormally high temperatures of other geological bodies. The δ13C and δ18O value and low 87Sr/86Sr value indicate that the diagenetic fluid of fine-grained matrix dolomite is mainly Permian seawater. The U-Pb ages of fine-grained matrix dolomite are ~260 Ma, which coincides with the age of the main magmatism of Emeishan Large Igneous Province (ELIP), and hydrothermal fluid provided a favorable high-temperature environment in the penecontemporaneous stage. While highly radiogenic 87Sr/86Sr compositions suggests those of saddle dolomite, the high-temperature Sr-rich formation fluid. The U-Pb ages of saddle dolomite are 245–250 Ma, which coincides with the age of the 255~251 Ma magmatism of ELIP. This indicates that those should be the diagenetic products of the ELIP hydrothermal fluid in the shallow burial stage. The U-Pb age of coarse-grained calcite is 190–220 Ma, and it should be the diagenetic product of the deep burial stage. Brine inclusions associated with primary methane inclusions were developed in coarse-grained calcite, with a homogenization temperature range of 140.8–199.8 °C, which indicates that the formation fluid activities were related to hydrocarbon charging. The Permian Maokou Formation dolomite was firstly formed in the penecontemporaneous shallow burial stage, and then it was subjected to further hydrothermal dolomitization due to the basement faulting and the abnormally high heat flow during the active period of ELIP. Hydrothermal dolomitization contributed to the formation and maintenance of intercrystalline and dissolution pores, whereas it also formed saddle dolomite to fill the pores, and reduce the pore space. The influence of deep fluid activities on reservoir evolution is further distinguished. Full article
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14 pages, 12015 KB  
Communication
Microstructure Evolution of Alloy 800H during Cold Rolling and Subsequent Annealing
by Qingshan Dong, Qiang Wang and Fei Long
Metals 2024, 14(7), 766; https://doi.org/10.3390/met14070766 - 28 Jun 2024
Viewed by 1693
Abstract
The microstructure evolution during the cold rolling and subsequent annealing of Alloy 800H was investigated. Two distinct rolling methods, unidirectional rolling and cross-rolling, were introduced. Cracks were observed in the cross-rolled plates, while such cracks did not appear in the unidirectionally rolled plates, [...] Read more.
The microstructure evolution during the cold rolling and subsequent annealing of Alloy 800H was investigated. Two distinct rolling methods, unidirectional rolling and cross-rolling, were introduced. Cracks were observed in the cross-rolled plates, while such cracks did not appear in the unidirectionally rolled plates, which indicated better ductility during the unidirectional rolling process. The difference between the two different rolling methods was explained by the evolution of Schmit factors during the deformation. A higher volume fraction of large, deformed grains was observed in the cross-rolled plates than in the unidirectionally rolled plates. Abnormal grain growth was observed in the cross-rolled specimens after annealing while no abnormal grain growth was seen in the unidirectionally rolled ones. In addition, the recrystallization occurred faster in plates from unidirectional rolling than from cross-rolling. Full article
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12 pages, 3977 KB  
Article
Reducing Water Absorption and Improving Flexural Strength of Aluminosilicate Ceramics by MnO2 Doping
by Bingxin Yang, Shaojun Lu, Caihong Li, Chen Fang, Yan Wan and Yangming Lin
Materials 2024, 17(11), 2557; https://doi.org/10.3390/ma17112557 - 25 May 2024
Cited by 3 | Viewed by 1895
Abstract
As key performance indicators, the water absorption and mechanical strength of ceramics are highly associated with sintering temperature. Lower sintering temperatures, although favorable for energy saving in ceramics production, normally render the densification degree and water absorption of as-prepared ceramics to largely decline [...] Read more.
As key performance indicators, the water absorption and mechanical strength of ceramics are highly associated with sintering temperature. Lower sintering temperatures, although favorable for energy saving in ceramics production, normally render the densification degree and water absorption of as-prepared ceramics to largely decline and increase, respectively. In the present work, 0.5 wt.% MnO2, serving as an additive, was mixed with aluminosilicate ceramics using mechanical stirring at room temperature, achieving a flexural strength of 58.36 MPa and water absorption of 0.05% and lowering the sintering temperature by 50 °C concurrently. On the basis of the results of TG-DSC, XRD, MIP, and XPS, etc., we speculate that the MnO2 additive promoted the elimination of water vapor in the ceramic bodies, effectively suppressing the generation of pores in the sintering process and facilitating the densification of ceramics at a lower temperature. This is probably because the MnO2 transformed into a liquid phase in the sintering process flows into the gap between grains, which removed the gas inside pores and filled the pores, suppressing the generation of pores and the abnormal growth of grains. This study demonstrated a facile and economical method to reduce the porosity and enhance the densification degree in the practical production of aluminosilicate ceramics. Full article
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15 pages, 9861 KB  
Article
Improvement in Grain Size Distribution Uniformity for Nuclear-Grade Austenitic Stainless Steel through Thermomechanical Treatment
by Yong Wang, Weiwei Xue, Zongxu Pang, Zichen Zhao, Zhuohua Liu, Chenyuan Liu, Fei Gao and Weijuan Li
Materials 2024, 17(10), 2313; https://doi.org/10.3390/ma17102313 - 14 May 2024
Cited by 2 | Viewed by 1441
Abstract
In this work, thermomechanical treatment (single-pass rolling at 800 °C and solution treatment) was applied to nuclear-grade hot-rolled austenitic stainless steel to eliminate the mixed grain induced by the uneven hot-rolled microstructure. By employing high-temperature laser scanning confocal microscopy, microstructure evolution during solution [...] Read more.
In this work, thermomechanical treatment (single-pass rolling at 800 °C and solution treatment) was applied to nuclear-grade hot-rolled austenitic stainless steel to eliminate the mixed grain induced by the uneven hot-rolled microstructure. By employing high-temperature laser scanning confocal microscopy, microstructure evolution during solution treatment was observed in situ, and the effect of single-pass rolling reduction on it was investigated. In uneven hot-rolled microstructure, the millimeter-grade elongated grains (MEGs) possessed an extremely large size and a high Schmid factor for slip compared to the fine grains, which led to greater plastic deformation and increased dislocation density and deformation energy storage during single-pass rolling. During subsequent solution treatment, there were fewer nucleation sites for the new grain, and the grain boundary (GB) was the main nucleation site in MEGs at a lower rolling reduction. In contrast, at a higher reduction, increased uniformly distributed rolling deformation and more nucleation sites were developed in MEGs. As the reduction increased, the number of in-grain nucleation sites gradually exceeded that of GB nucleation sites, and in-grain nucleation preferentially occurred. This was beneficial for promoting the refinement of new recrystallized grains and a reduction in the size difference of new grains during recrystallization. The single-pass rolling reduction of 15–20% can effectively increase the nucleation sites and improve the uniformity of rolling deformation distribution in the MEGs, promote in-grain nucleation, and finally refine the abnormally coarse elongated grain, and eliminate the mixed-grain structure after solution treatment. Full article
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15 pages, 3877 KB  
Article
The Role of the Ascorbic Acid–Glutathione Cycle in Young Wheat Ears’ Response to Spring Freezing Stress
by Yuting Zhang, Chunyang Ni, Yongwen Dong, Xue Jiang, Chang Liu, Weiling Wang, Can Zhao, Guohui Li, Ke Xu and Zhongyang Huo
Plants 2023, 12(24), 4170; https://doi.org/10.3390/plants12244170 - 15 Dec 2023
Cited by 5 | Viewed by 2017
Abstract
Freezing stress in spring often causes the death and abnormal development of young ears of wheat, leading to a significant reduction in grain production. However, the mechanisms of young wheat ears responding to freezing are largely unclear. In this study, the role of [...] Read more.
Freezing stress in spring often causes the death and abnormal development of young ears of wheat, leading to a significant reduction in grain production. However, the mechanisms of young wheat ears responding to freezing are largely unclear. In this study, the role of the ascorbic acid–glutathione cycle (AsA–GSH cycle) in alleviating freezing-caused oxidative damage in young wheat ears at the anther connective tissue formation phase (ACFP) was investigated. The results showed that the release rate of reactive oxygen species (ROS) and the relative electrolyte conductivity in young ears of Jimai22 (JM22, freezing-tolerant) were significantly lower than those in young ears of Xumai33 (XM33, freezing-sensitive) under freezing. The level of the GSH pool (231.8~392.3 μg/g FW) was strikingly higher than that of the AsA pool (98.86~123.4 μg/g FW) in young wheat ears at the ACFP. Freezing significantly increased the level of the AsA pool and the activities of ascorbate peroxidase (APX) and monodehydroascorbate reductase (MDHAR) in the young ears of both varieties. The level of the GSH pool increased in the young ears of XM33 under freezing but decreased in the young ears of JM22. The young ears of JM22 showed higher activities of glutathione reductase (GR), glutathione-S-transferase (GST) and glutathione peroxidase (GPX) than the young ears of XM33 under freezing. Collectively, these results suggest that the AsA–GSH cycle plays a positive role in alleviating freezing-induced oxidative damage in young wheat ears. Furthermore, the ability of utilizing GSH as a substrate to scavenge ROS is an important factor affecting the freezing tolerance of young wheat ears. In addition, abscisic acid (ABA), salicylic acid (SA), 3-indolebutyric acid (IBA) and cis-zeatin (cZ) may be involved in regulating the AsA–GSH cycle metabolism in young wheat ears under freezing. Full article
(This article belongs to the Special Issue Strategies and Mechanisms for Enhancing Stress Tolerance in Wheat)
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18 pages, 10461 KB  
Article
Nonuniform Distribution of Crystalline Phases and Grain Sizes in the Surface Layers of WC Ceramics Produced by Spark Plasma Sintering
by Ksenia E. Smetanina, Pavel V. Andreev, Evgeny A. Lantsev, Aleksey V. Nokhrin, Artem A. Murashov, Natalia V. Isaeva, Yury V. Blagoveshchensky, Maksim S. Boldin and Vladimir N. Chuvil’deev
Coatings 2023, 13(6), 1051; https://doi.org/10.3390/coatings13061051 - 6 Jun 2023
Cited by 2 | Viewed by 2231
Abstract
The research results conducted on binderless tungsten carbide (WC) ceramics obtained by spark plasma sintering (SPS) of WC powders with different average particle sizes (95, 800, 3000 nm) are presented. Nonuniform distribution of crystalline phases and microstructure of the WC ceramics was studied [...] Read more.
The research results conducted on binderless tungsten carbide (WC) ceramics obtained by spark plasma sintering (SPS) of WC powders with different average particle sizes (95, 800, 3000 nm) are presented. Nonuniform distribution of crystalline phases and microstructure of the WC ceramics was studied using layer-by-layer X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). Surface layers of the WC-based ceramics are characterized by nonuniform distribution of W2C crystalline phase and grain sizes, including the appearance of abnormally large grains. Thickness of the nonuniform layer was at least 50 μm. The effect under study is associated with an intense carbon diffusion from graphite foil. On the one hand, this contributed to a decrease in the intensity of W2C phase particle formation, which is transformed into α-WC phase due to the carbon. On the other hand, it caused abnormal grain growth in the layer where the carbon diffused. The obtained value of the carbon diffusion depth (50 μm) exceeds the values known from the literature (up to 1 μm in the case of volume diffusion even at temperature of 2370 °C and exposure time of ~60 h). The use of boron nitride (BN) as a protective coating on graphite mold parts did not prevent the formation of nonuniform layer on the ceramic surface. Full article
(This article belongs to the Special Issue Trends in Spark Plasma Sintering of Advanced Materials)
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18 pages, 5154 KB  
Article
A Modified Constitutive Model and Microstructure Characterization for 2195 Al-Li Alloy Hot Extrusion
by Hui Li, Jian Wang, Yuanchun Huang and Rong Fu
Materials 2023, 16(10), 3826; https://doi.org/10.3390/ma16103826 - 18 May 2023
Cited by 3 | Viewed by 2129
Abstract
The quality of extruded profiles depends largely on accurate constitutive models and thermal processing maps. In this study, a modified Arrhenius constitutive model for homogenized 2195 Al-Li alloy with multi-parameter co-compensation was developed and further enhanced the prediction accuracy of flow stresses. Through [...] Read more.
The quality of extruded profiles depends largely on accurate constitutive models and thermal processing maps. In this study, a modified Arrhenius constitutive model for homogenized 2195 Al-Li alloy with multi-parameter co-compensation was developed and further enhanced the prediction accuracy of flow stresses. Through the processing map and microstructure characterization, the 2195 Al-Li alloy could be deformed optimally at the temperature range of 710~783 K and strain rate of 0.001~0.12 s−1, preventing the occurrence of local plastic flow and abnormal growth of recrystallized grains. The accuracy of the constitutive model was verified through numerical simulation of 2195 Al-Li alloy extruded profiles with large shaped cross-sections. Dynamic recrystallization occurred at different regions during the practical extrusion process, resulting in slight variations in the microstructure. The differences in microstructure were due to the varying degrees of temperature and stress experienced by the material in different regions. Full article
(This article belongs to the Special Issue Heat Treatments and Performance of Alloy and Metal)
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