Search Results (983)

Famatinite (Cu₃SbS₄) is an earth-abundant, nontoxic material with potential for thermoelectric energy generation applications. Herein, rapid, energy-efficient, and facile one-pot modified polyol synthesis was utilized to produce gram-scale quantities of phase-pure famatinite (Cu_2.7M_0.3SbS₄, M = Cu, Zn, Mn) nanoparticles (diameter 20–30 nm) with controllable and stoichiometric incorporation of transition metal dopants on the Cu-site. To produce pellets for thermoelectric characterization, the densification process by spark plasma sintering was optimized for individual samples based on thermal stability determined using differential scanning calorimetry and thermogravimetric analysis. Electronic transport properties of undoped and doped famatinite nanoparticles were studied from 225–575 K, and the thermoelectric power factor was calculated. This is the first time electronic transport properties of famatinite doped with Zn or Mn have been studied. All famatinite samples had similar resistivities (>0.8 mΩ·m) in the measured temperature range. However, the Mn-doped famatinite nanomaterials exhibited a thermoelectric power factor of 10.3 mW·m⁻¹·K⁻¹ at 575 K, which represented a significant increase relative to the undoped nanomaterials and Zn-doped nanomaterials engendered by an elevated Seebeck coefficient of ~220 µV·K⁻¹ at 575 K. Future investigations into optimizing the thermoelectric properties of Mn-doped famatinite nanomaterials are promising avenues of research for producing low-cost, environmentally friendly, high-performing thermoelectric materials. Full article

HgCdSe has recently been proposed as a potential alternative material to HgCdTe for fabricating high-performance infrared detectors. This work presents a study on the growth of high-crystalline-quality HgCdSe materials on GaSb (211)B substrates via molecular beam epitaxy and demonstration of the first prototype HgCdSe-based mid-wave infrared detectors. By optimizing the MBE growth parameters, and especially the thermal cleaning process of the GaSb substrate surface prior to epitaxial growth, high-quality HgCdSe material was achieved with a record XRD full width at half maximum of ~65 arcsec. At a temperature of 77 K, the mid-wave infrared HgCdSe n-type material demonstrated a minority carrier lifetime of ~1.19 µs, background electron concentration of ~2.2 × 10¹⁷ cm⁻³, and electron mobility of ~1.6 × 10⁴ cm²/Vs. The fabricated mid-wave infrared HgCdSe photoconductor presented a cut-off wavelength of 4.2 µm, a peak responsivity of ~40 V/W, and a peak detectivity of ~1.2 × 10⁹ cmHz^1/2/W at 77 K. Due to the relatively high background electron concentration, the detector performance is lower than that of state-of-the-art low-doped HgCdTe counterparts. However, these preliminary results indicate the great potential of HgCdSe materials for achieving next-generation IR detectors on large-area substrates with features of lower cost and larger array format size. Full article

In this study, we present a comprehensive theoretical analysis of modifications in the physical and chemical properties of MoSe₂ upon the introduction of substitutional transition metal impurities, specifically, Ti, V, Cr, Fe, Co, Ni, Cu, W, Pd, and Pt. Wet systematically calculated the adsorption enthalpies for various representative analytes, including O₂, H₂, CO, CO₂, H₂O, NO₂, formaldehyde, and ethanol, and further evaluated their free energies across a range of temperatures. By employing the formula for probabilities, we accounted for the competition among molecules for active adsorption sites during simultaneous adsorption events. Our findings underscore the importance of integrating temperature effects and competitive adsorption dynamics to predict the performance of highly selective sensors accurately. Additionally, we investigated the influence of temperature and analyte concentration on sensor performance by analyzing the saturation of active sites for specific scenarios using Langmuir sorption theory. Building on our calculated adsorption energies, we screened the catalytic potential of doped MoSe₂ for CO₂-to-methanol conversion reactions. This paper also examines the correlations between the electronic structure of active sites and their associated sensing and catalytic capabilities, offering insights that can inform the design of advanced materials for sensors and catalytic applications. Full article

The commercialization of proton-conducting fuel cells (PCFCs) is hindered by the limited electroactivity and durability of cathodes at intermediate temperatures ranging from 400 to 700 °C, a challenge exacerbated by an insufficient understanding of high-entropy perovskite (HEP) materials for oxygen reduction reaction (ORR) optimization. This study introduces an yttrium-doped HEP to address these limitations. A comparative analysis of Ce_0.2−xY_xBa_0.2Sr_0.2La_0.2Ca_0.2CoO_3−δ (x = 0, 0.2; designated as CBSLCC and YBSLCC) revealed that yttrium doping enhanced the ORR activity, reduced the thermal expansion coefficient (19.9 × 10⁻⁶ K⁻¹, 30–900 °C), and improved the thermomechanical compatibility with the BaZr_0.1Ce_0.7Y_0.1Yb_0.1O_3−δ electrolytes. Electrochemical testing demonstrated a peak power density equal to 586 mW cm⁻² at 700 °C, with a polarization resistance equaling 0.3 Ω cm². Yttrium-induced lattice distortion promotes proton adsorption while suppressing detrimental Co spin-state transitions. These findings advance the development of durable, high-efficiency PCFC cathodes, offering immediate applications in clean energy systems, particularly for distributed power generation. Full article

Volatile organic compounds (VOCs) are presently posing a rather considerable threat to both human health and environmental sustainability. Among these, n-butanol is commonly identified as bringing potential hazards to environmental integrity and individual health. This study presents the creation of a highly sensitive n-butanol gas sensor utilizing cobalt-doped zinc oxide (ZnO) derived from a metal–organic framework (MOF). A series of x-Co/MOF-ZnO (x = 1, 3, 5, 7 wt%) nanomaterials with varying Co ratios were generated using the homogeneous co-precipitation method and assessed for their gas-sensing performances under a low operating temperature (191 °C) and UV excitation (220 mW/cm²). These findings demonstrated that the 5-Co/MOF-ZnO sensor presented the highest oxygen vacancy (O_v) concentration and the largest specific surface area (SSA), representing the optimal reactivity, selectivity, and durability for n-butanol detection. Regarding the sensor’s response to 100 ppm n-butanol under UV excitation, it achieved a value of 1259.06, 9.80 times greater than that of pure MOF-ZnO (128.56) and 2.07 times higher than that in darkness (608.38). Additionally, under UV illumination, the sensor achieved a rapid response time (11 s) and recovery rate (23 s). As a strategy to transform the functionality of ZnO-based sensors for n-butanol gas detection, this study also investigated potential possible redox reactions occurring during the detection process. Full article

In this study, a UVC photodetector (PD) was fabricated by incorporating CsI into a conventional double-cation perovskite (FAMAPbI₃) to enhance its stability. The device utilized a methylammonium iodide post-treatment solution to fabricate CsFAMAPbI₃ perovskite thin films, which functioned as the primary light-absorbing layer in an NIP structure composed of n-type SnO₂ and p-type spiro-OMeTAD. Perovskite films were fabricated and analyzed as a function of the Cs concentration to optimize the Cs content. The results demonstrated that Cs doping improved the crystallinity and phase stability of the films, leading to their enhanced electron mobility and photodetection performance. The UVC PD with an optimum Cs concentration exhibited a responsivity of 58.2 mA/W and a detectivity of 3.52 × 10¹⁴ Jones, representing an approximately 7% improvement over conventional structures. Full article

To enable the highly sensitive detection of acetylene (C₂H₂) dissolved in transformer oil, a high-power quartz-enhanced photoacoustic spectroscopy (QEPAS) sensing system is proposed. A standard 32.7 kHz quartz tuning fork (QTF) was employed as an acoustic transducer, coupled with an optimized acoustic resonator to enhance the acoustic signal. The laser power was boosted to 150 mW using a C-band erbium-doped fiber amplifier (EDFA), achieving a detection limit of 469 ppb for C₂H₂ with an integration time of 1 s. The headspace degassing method was utilized to extract dissolved gases from the transformer oil, and the equilibrium process for the release of dissolved C₂H₂ was successfully monitored using the developed high-power QEPAS system. This approach provides reliable technical support for the real-time monitoring of the operational safety of power transformers. Full article

The development of cost-effective and scalable air/oxygen electrode materials is crucial for the advancement of Zn–air batteries (ZABs). Porous carbon materials doped with heteroatoms have attracted considerable attention in energy and environmental fields because of their tunable nanoporosity and high electrical conductivity. In this work, we report the synthesis of a three-dimensional (3D) N and P co-doped porous carbon (PA@pDC-1000), derived from a conjugated polyaniline–phytic acid polymer. The cross-linked, rigid conjugated polymeric framework plays a crucial role in maintaining the integrity of micro- and mesoporous structures and promoting graphitization during carbonization. As a result, the material exhibits a hierarchical pore structure, a high specific surface area (1045 m² g⁻¹), and a large pore volume (1.02 cm³ g⁻¹). The 3D N, P co-doped PA@pDC-1000 catalyst delivers a half-wave potential of 0.80 V (vs. RHE) and demonstrates a higher current density compared to commercial Pt/C. A primary ZAB utilizing this material achieves an open-circuit voltage of 1.51 V and a peak power density of 217 mW cm⁻². This metal-free, self-templating presents a scalable route for the generating and producing of high-performance oxygen reduction reaction catalysts for ZABs. Full article

Silica fume-based geopolymer composite coatings, an approach to using metallurgical solid waste, exert flame retardancy with ecological, halogen-free, and environmentally friendly advantages, but their fire resistance needs to be improved further. Herein, a silica fume-based geopolymer composite flame-retardant coating was designed by doping boric acid (BA), zinc phytate (ZnPA), and melamine (MEL). The results of a cone calorimeter demonstrated that appropriate ZnPA and BA significantly enhanced its flame retardancy, evidenced by the peak heat release rate (p-HRR) decreasing from 268.78 to 118.72 kW·m⁻², the fire performance index (FPI) increasing from 0.59 to 2.83 s·m²·kW⁻¹, and the flame retardancy index increasing from 1.00 to 8.48, respectively. Meanwhile, the in situ-formed boron phosphate (BPO₄) facilitated the residual resilience of the fire-barrier layer. Furthermore, the pyrolysis kinetics indicated that the three-level chemical reactions governed the pyrolysis of the coatings. BPO₄ made the pyrolysis E_α climb from 94.28 (P5) to 127.08 (B3) kJ·mol⁻¹ with temperatures of 731–940 °C, corresponding to improved thermal stability. Consequently, this study explored the synergistic flame-retardant mechanism of silica fume-based geopolymer coatings doped with ZnPA, BA, and MEL, providing an efficient strategy for the high-value-added recycling utilization of silica fume. Full article

Tungsten-doped vanadium dioxide (W-VO₂) shows semiconductor-to-metal phase transition properties at room temperature, which is an ideal thermo-chromic smart window material. However, low visual transmittance and solar modulation limit its application in building energy saving. In this paper, a W-VO_2−x@AA core-shell nanoparticle is proposed to improve the thermo-chromic performance of W-VO₂. Oxygen vacancies were used to promote the connection of W-VO_2−x nanoparticles with L-ascorbic acid (AA) molecules. Oxygen vacancies were tuned in W-VO₂ nanoparticles by thermal annealing temperatures in vacuum, and W-VO_2−x@AA nanoparticles were synthesized by the hydrothermal method. A smart window was formed by dispersing W-VO_2−x@AA core-shell nanoparticles into PVP evenly and spin-coating them on the surface of glass. The visual transmittance of this smart window reaches up to 67%, and the solar modulation reaches up to 12.1%. This enhanced thermo-chromic performance is related to the electron density enhanced by the AA surface molecular coordination effect through W dopant and oxygen vacancies. This work provides a new strategy to enhance the thermo-chromic performance of W-VO₂ and its application in the building energy-saving field. Full article

The paper shows the effect of using a lubricant in the form of an ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF₆), on the tribological properties of a hydrogenated diamond-like coating (DLC) doped with tungsten a-C:H:W. The coatings were deposited on 100Cr6 steel by plasma-enhanced chemical vapor deposition PECVD. Tribological tests were carried out on a TRB³ tribometer in a rotary motion in a ball–disc combination. 100Cr6 steel balls were used as a counter-sample. Friction and wear tests were carried out for discs made of 100Cr6 steel and 100Cr6 steel discs with a DLC coating. They were performed under friction conditions with and without lubrication under 10 N and 15 N loads. The ionic liquid BMIM-PF₆ was used as a lubricant. Coating thickness was observed on a scanning microscope, and the linear analysis of chemical composition on the cross-section was analyzed using the EDS analyzer. The confocal microscope with an interferometric mode was used for analysis of the geometric structure of the surface before and after the tribological tests. The contact angle of the samples for distilled water, diiodomethane and ionic liquid was tested on an optical tensiometer. The test results showed good cooperation of the DLC coating with the lubricant. It lowered the coefficient of friction in comparison to steel about 20%. This indicates the synergistic nature of the interaction: DLC coating–BMIM-PF₆ lubricant–100Cr6 steel. Full article

Na₀.₈₉Co_0.90Me_0.10O₂ (Me = Cr, Ni, Mo, W, Pb, and Bi) ceramic samples were prepared using a solid-state reaction method, and their crystal structure, microstructure, and electrical, thermal, and thermoelectric properties were investigated. The effect of the nature of the doping metal (Me = Cr, Ni, Mo, W, and Bi) on the structure and properties of layered sodium cobaltite Na_0.89CoO₂ was analyzed. The largest Seebeck coefficient (616 μV/K at 1073 K) and figure-of-merit (1.74 at 1073 K) values among the samples studied were demonstrated by the Na_0.89Co_0.9Bi_0.1O₂ solid solution, which was also characterized by the lowest value of the dimensionless relative self-compatibility factor of about 8% within the 673–873 K temperature range. The obtained results demonstrate that doping of layered sodium cobaltite by transition and heavy metal oxides improves its microstructure and thermoelectric properties, which shows the prospectiveness of the used doping strategy for the development of new thermoelectric oxides with enhanced thermoelectric characteristics. It was also shown that samples with a higher sodium content (Na:Co = 0.89:1) possessed higher chemical and thermal stability than those with a lower sodium content (Na:Co = 0.55:1), which makes them more suitable for practical applications. Full article

Background and Objectives: Conventional methods for removing cemented fixed prosthetic restorations (FPRs) are unreliable and lead to unsatisfactory outcomes. At their best, they allow the tooth to be saved at the expense of a laborious process that also wears down rotating tools and handpieces and occasionally results in abutment fractures. Restorations are nearly never reusable in any of these situations. Erbium-doped yttrium-aluminum-garnet (Er:YAG) and erbium-chromium yttrium-scandium-gallium-garnet (Er,Cr:YSGG) lasers casafely and effectively remove FPRs, according to scientific studiesre. This study sets out to examine the impact of Er:YAG laser radiation on the debonding of different ceramic restorations, comparing the behavior of various ceramic prosthetic restoration types under laser radiation action and evaluating the integrity of prosthetic restorations and dental surfaces exposed to laser radiation. Materials and Methods: The study included a total of 16 removed teeth, each prepared on opposite surfaces as abutments.y. Based on the previously defined groups, four types of ceramic restorations were included in the study: feldspathic (F), lithium disilicates (LD), layered zirconia (LZ), and monolithic zirconia (MZ). The thickness of the prosthetic restorations was measured at three points, and two different materials were used for cementation. The Er:YAG Fotona StarWalker MaQX laser was used to debond the ceramic FPR at a distance of 10 mm using an R14 sapphire tip with 275 mJ, 20 Hz, 5.5 W, with air cooling (setting 1 of 9) and water. After debonding, the debonded surface was visualized under electron microscopy. Results: A total of 23 ceramic FPRs were debonded, of which 12 were intact and the others fractured into two or three pieces. The electron microscopy images showed that debonding took place without causing any harm to the tooth structure. The various restoration types had the following success rates: 100% for the LZ and F groups, 87% for the LD group, and 0% for the MZ group. In terms of cement type, debonding ceramic FPRs cemented with RELYX was successful 75% of the time, compared to Variolink DC’s 69% success rate. Conclusions: In summary, the majority of ceramic prosthetic restorations can be successfully and conservatively debonded with Er:YAG radiation. Full article

Tantalum oxide is a wide bandgap material commonly used as an insulating dielectric layer for devices. In this work, hexagonal Ta₂O₅ (δ-Ta₂O₅) films doped with tungsten (W) were deposited on α-Al₂O₃ (0001) by metal–organic chemical vapor deposition (MOCVD). The effects of W doping on the structural, morphology, and photoelectrical properties of the obtained films were studied. The results showed that all W-doped films were n-type semiconductors. The XRD measurement result exhibited that the increase in the W doping concentration leads to the changes in the preferred growth crystal plane of the films from δ-Ta₂O₅ ($10\overline{1}1$) to (0001). The 1.5% W-doped film possessed the best crystal quality and conductivity. The Hall measurement showed that the minimum resistivity of the film was 2.68 × 10⁴ Ω∙cm, and the maximum carrier concentration was 7.39 × 10¹⁴ cm³. With the increase in the W concentration, the surface roughness of the film increases, while the optical bandgap decreases. The optical band gap of the 1.5% W-doped film was 3.92 eV. The W doping mechanisms were discussed. Full article

Fine-grained Yb:Y₂O₃ laser ceramics with excellent transmittance and thermal conductivity were fabricated from commercial powders. The process involved aqueous colloidal forming, additive-free air pre-sintering at 1400 °C, and hot isostatic pressing at 1550 °C. Suspensions were prepared with a deionization process to alleviate the hydrolysis issue, which optimizes the microstructure uniformity and enhances the green compacts’ density after consolidation. The microstructure, in-line transmittance, microhardness, and fracture toughness of the Yb³⁺-doped Y₂O₃ ceramics with different concentrations were measured. The 5.0 at% Yb³⁺-doped Y₂O₃ ceramic yielded a superior transmittance of 80.1% at 1100 nm and 83.0% in the mid-infrared region. The average grain size was 752 nm. The sample exhibited a thermal conductivity of 9.94 W·m⁻¹·K⁻¹ while achieving a 1076 nm laser output with a 42 mW peak power and 4.3% slope efficiency. Full article