Search Results (319)

The disposal of agro-industrial waste is a pressing environmental issue. At the same time, due to the high silica content in specific agricultural residues, their processed products can be utilised in various industrial sectors as substitutes for commercial materials. This study investigates the key technological, physico-mechanical, and viscoelastic properties of industrial elastomeric compounds based on synthetic styrene–butadiene rubber, intended for the tread of summer passenger car tyres, when replacing the commercially used highly reinforcing silica filler (SF), Extrasil 150VD brand (white carbon black), with a carbon–silica filler (CSF). The CSF is produced by carbonising a finely ground mixture of rice production waste (rice husks and stems) in a pyrolysis furnace at 550–600 °C without oxygen. It was found that replacing 20 wt.pts. of silica filler with CSF in industrial tread formulations improves processing parameters (Mooney viscosity increases by up to 5.3%, optimal vulcanisation time by up to 9.2%), resistance to plastic deformation (by up to 7.7%), and tackiness of the rubber compounds (by 31.3–34.4%). Viscoelastic properties also improved: the loss modulus and mechanical loss tangent decreased by up to 24.0% and 14.3%, respectively; the rebound elasticity increased by up to 6.3% and fatigue resistance by up to 2.7 thousand cycles; and the internal temperature of samples decreased by 7 °C. However, a decrease in tensile strength (by 10.7–27.0%) and an increase in wear rate (up to 43.3% before and up to 22.5% after thermal ageing) were observed. Nevertheless, the overall results of this study indicate that the CSF derived from the carbonisation of rice production waste—containing both silica and carbon components—can effectively be used as a partial replacement for the commercially utilised reinforcing silica filler in the production of tread rubber for summer passenger car tyres. Full article

According to the World Health Organization (WHO), indoor air quality (IAQ) is becoming a serious global concern due to its significant impact on human health. However, not all relevant health parameters are currently regulated. For example, particle number concentration (PNC) and its associated carbonaceous species, such as black carbon (BC), which are classified as carcinogenic by the International Agency for Research on Cancer (IARC), are not currently regulated. Compared with IAQ studies in other types of buildings, studies focusing on IAQ in hospitals or other healthcare facilities are scarce. Therefore, this study aims to evaluate the impact of these outdoor pollutants, among others, on the indoor environment of a hospital under different atmospheric conditions. To identify the seasonal influence, two different periods of two consecutive seasons (summer 2020 and winter 2021) were selected for the measurements. Regulated pollutants (NO, NO₂, O₃, PM₁₀, and PM_2.5) and nonregulated pollutants (PM₁, PNC, and equivalent BC (eBC)) in outdoor air were simultaneously measured indoor and outdoor. This study also investigated the impact of indoor activities on indoor air quality. In the absence of indoor activities, outdoor sources significantly contribute to indoor traffic-related pollutants. Indoor and outdoor (I-O) measurements showed similar behavior, but indoor concentrations were lower, with peak levels delayed by up to two hours. Seasonal variations in indoor/outdoor ($\mathrm{I}/\mathrm{O}$) ratios were lower for particles than for associated gaseous pollutants. Particle infiltration depended on particle size, with it being higher the smaller the particle size. Indoor activities also significantly affected indoor pollutants. PM_x (especially PM₁₀ and PM_2.5) concentrations were mainly modulated by walking-induced particle resuspension. Vertical eBC profiles indicated a relatively well-mixed environment. Ventilation through open windows rapidly altered indoor air quality. Outdoor-dominant pollutants (PNC, eBC, and NO_X) had $\mathrm{I}/\mathrm{O}$ ratios ≥ 1. Staying in the room with an open window had a synergistic effect, increasing the $\mathrm{I}/\mathrm{O}$ ratios for all pollutants. Higher I/O ratios were associated with turbulent outdoor conditions in both unoccupied and occupied conditions. Statistically significant differences were observed between stable (TKE ≤ 1 m² s⁻²) and unstable (TKE > 1 m² s⁻²) conditions, except for NO₂ in summer. This finding was particularly significant when the wind direction was westerly or easterly during unstable conditions. The results of this study highlight the importance of understanding the behavior of indoor particulate matter and related pollutants. These pollutants are highly variable, and knowledge about them is crucial for determining their health effects, particularly in public buildings such as hospitals, where information on IAQ is often limited. More measurement data is particularly important for further research into I-O transport mechanisms, which are essential for developing preventive measures and improving IAQ. Full article

This study presents a simulation-based evaluation of advanced control strategies for residential air conditioning systems, including On–Off, PI, and Model Predictive Control (MPC) approaches. A black-box system model was identified using an ARX(2,2,0) structure, achieving over 90% prediction accuracy (FIT) for indoor temperature and power consumption. Six controllers were implemented and benchmarked in a high-fidelity Simscape environment under a realistic 48-h summer temperature profile. The proposed MPC scheme, particularly when incorporating outdoor temperature gradient logic, reduced energy consumption by up to 30% compared to conventional PI control while maintaining indoor thermal comfort within the acceptable range. This virtual design workflow shortens the development cycle by deferring climatic chamber testing to the final validation phase. Full article

Arbuscular mycorrhizal fungi (AMF) symbiosis has great potential in improving grapevine performance and reducing external input dependency in viticulture. However, the precise, strain-specific impacts of different AMF species on ‘Summer Black’ grapevine cuttings across multiple physiological and morphological dimensions remain underexplored. To address this, we conducted a controlled greenhouse pot experiment, systematically evaluating four different AMF species (Diversispora versiformis, Diversispora spurca, Funneliformis mosseae, and Paraglomus occultum) on ‘Summer Black’ grapevine cuttings. All AMF treatments successfully established root colonization, with F. mosseae achieving the highest infection rate. In detail, F. mosseae notably enhanced total root length, root surface area, and volume, while D. versiformis specifically improved primary adventitious and 2nd-order lateral root numbers. Phosphorus (P) uptake in both leaves and roots was significantly elevated across all AMF treatments, with F. mosseae leading to a 42% increase in leaf P content. Furthermore, AMF inoculation generally enhanced the activities of catalase, superoxide dismutase, and peroxidase, along with soluble protein and soluble sugar contents in leaves and roots. Photosynthetic parameters, including net photosynthetic rate (Pn), stomatal conductance (Gs), and transpiration rate (Tr), were dramatically increased in AMF-colonized cutting seedlings. Whereas, P. occultum exhibited inhibitory effects on several growth metrics, such as shoot length, leaf and root biomass, and adventitious lateral root numbers, and decreased the contents of Nitrogen (N), potassium (K), magnesium (Mg), and iron (Fe) in both leaves and roots. These findings conclusively demonstrate that AMF symbiosis optimizes root morphology, enhances nutrient acquisition, and boosts photosynthetic efficiency and stress resilience, thus providing valuable insights for developing targeted bio-fertilization strategies in sustainable viticulture. Full article

Poplars and aspens (Populus L. spp.) are undervalued options for use in managed landscapes. The genus comprises a multitude of taxa often negatively associated with disease susceptibility and short lifespans; however, it also hosts a diverse range of abiotic stress tolerances. The objective of this study was to generate a relative scale of the predicted drought tolerance of Populus spp. to inform site and taxon selection in managed settings. Utilizing vapor pressure osmometry, this study examined seasonal osmotic adjustment and predicted leaf water potential at the turgor loss point (Ψ_po) among several Populus taxa. All evaluated taxa demonstrated the ability to osmotically adjust (ΔΨ_π100) throughout the growing season. Bigtooth aspen (P. grandidentata Michx.) exhibited the most osmotic adjustment (−1.1 MPa), whereas black cottonwood (P. trichocarpa Torr. & A. Gray ex Hook.) exhibited the least (−0.44 MPa). Across the taxa, the estimated mean Ψ_po values in spring and summer were −1.8 MPa and −2.8 MPa, respectively. Chinese aspen (P. cathayana Rehder) exhibited the lowest Ψ_po (−3.32 MPa), whereas black cottonwood exhibited the highest (−2.47 MPa). The results indicate that drought tolerance varies widely among these ten Populus species and hybrids; bigtooth aspen and Chinese aspen are the best suited to tolerating drought in managed landscapes. Full article

The rapid development of urban subway network is prompting higher requirements for daylighting in subway stations. The skylight daylighting space of shallow buried subway stations not only improves the quality of light environment but also brings challenges for the optimization of light and thermal performance, especially in areas with hot summers and cold winters. In this paper, key parameters such as illumination, air temperature, and the black sphere temperature of skylight and artificial lighting areas at stations A and B in Shanghai were tested with a field test system. The results show that the light environment in the skylight areas was significantly improved, but the need for regulation and control of the thermal environment increased. Combined with response surface analysis, 10 sample models for two types of daylighting space (partitioned and open atrium styles) were studied and constructed, including 254 simulated working conditions. The results reveal that design parameters such as the number, aspect ratio, depth of light openings, and skylight angle have significant effects on combined energy consumption. The decentralized double slope roof daylighting space has the best performance in partitioned and open atrium-style public areas, and combined energy consumption can be reduced to 385.14 kWh/m². The optimization strategies proposed in this study can provide a quantitative basis for the skylight design of shallow buried subway stations and an important reference for the design of low-carbon and energy-saving underground spaces. Full article

This study examines the seasonality of Black Carbon (BC) and Brown Carbon (BrC) spectral absorption characteristics at a continental background site (Kozani) in southern Balkans (NW Greece). It aims to assess the seasonality and impact of different sources on light absorption properties, BC concentrations, and the fraction of BrC absorption. Moderate-to-low BC concentrations were observed, ranging from 0.05 µg m⁻³ to 2.44 µg m⁻³ on an hourly basis (annual mean: 0.44 ± 0.27 µg m⁻³; median: 0.39 µg m⁻³) with higher levels during winter (0.53 ± 0.33), reflecting enhanced emissions from residential wood burning (RWB) for heating purposes. Atmospheric conditions are mostly clean during spring (MAM) (BC: 0.34 µg m⁻³), associated with increased rainfall. BC components associated with fossil fuel combustion (BC_ff) and biomass burning (BC_bb), maximize in summer (0.36 µg m⁻³) and winter (0.28 µg m⁻³), respectively, while the absorption Ångstrôm exponent (AAE_370–880) values ranged from 1.09 to 1.93 on daily basis. The annual mean total absorption coefficient (b_abs,520) inferred by aethalometer (AE33) was 4.09 ± 2.65 Mm⁻¹ (median: 3.51 Mm⁻¹), peaking in winter (5.30 ± 3.35 Mm⁻¹). Furthermore, the contribution of BrC absorption at 370 nm, was also high in winter (36.7%), and lower during the rest of the year (17.3–29.8%). The measuring station is located at a rural background site 4 km outside Kozani City and is not directly affected by traffic and urban heating emissions. Therefore, the regional background atmosphere is composed of a significant fraction of carbonaceous aerosols from RWB in nearby villages, a characteristic feature of the Balkan’s rural environment. Emissions from the lignin-fired power plants, still operating in the region, have decreased during the last years and moderately affect the atmospheric conditions. Full article

This study evaluates remote sensing features to resolve problems associated with feature redundancy, low efficiency, and insufficient input feature analysis in bushfire detection. It calculates spectral features, remote sensing indices, and texture features from Sentinel-2 data for the Blue Mountains region of New South Wales, Australia. Feature separability was evaluated with three measures: J-M distance, discriminant index, and mutual information, leading to an assessment of the best remote sensing features. The results show that for post-fire smoke detection, the best features are the normalized difference vegetation index (NDVI), the B1 band, and the angular second moment (ASM) in the B1 band, with respective scores of 0.900, 0.900, and 0.838. For burned land detection, the best features are NDVI, the B2 band, and correlation (Corr) in the B5 band, with corresponding scores of 1.000, 0.9436, and 0.9173. These results demonstrate the effectiveness of NDVI, the B1 and B2 bands, and specific texture features in the post-fire analysis of remote sensing data. These findings provide valuable insights for the monitoring and analysis of bushfires and offer a solid foundation for future model construction, fire mapping, and feature interpretation tasks. Full article

Background: We recently reported that the transcutaneous bilirubinometer (TCB) tends to underestimate the severity of neonatal jaundice (NJ). We hypothesize that the cumulative ambient light exposure contributes to the discrepancy. Objectives: This study aimed to identify factors that affect the TCB underestimation. Methods: We analyzed prospectively collected data over a twenty-month period at a level III medical facility. Neonates at risk for NJ who couldn’t secure an appointment with the primary practitioner were followed by the nursery team. Neonates who had phototherapy or forehead bruises were excluded. Concurrently collected total serum bilirubin (TSB) was determined by the diazo method. The primary endpoint was the discrepancy between TCB and the corresponding TSB (TCB-TSB). A mixed-effects model was used to assess the correlation between (TCB-TSB) and potential contributors, including visit age (in hours), gestational age (GA), sex, TSB, season, birth weight, and race. Results: There were 795 visits for 559 neonates, including 341 males, 179 white, 235 black, 103 Hispanic, 41 Asian, and one unrecorded race. The TSB ranged between 1.8 and 33.9 mg/dL. The (TCB-TSB) ranged between −20.0 and 6.4 mg/dL. The median GA and birth weight were 38.7 weeks and 3214.5 g. The visits occurred between 48 and 381 h of age. 133, 148, 132, and 146 visits were in Spring, Summer, Autumn, and Winter, respectively. Fifty-four neonates (9.7%) were admitted for management. 500 sternum TCB readings were also collected from 350 neonates together with the corresponding forehead TCBs. We found that the forehead (TCB-TSB) was significantly less in winter than in spring and summer (p = 0.0014 and 0.0003, respectively). There was a negative correlation between forehead (TCB-TSB) and visit age in hours (p = 0.0006). After adjusting for visit age and season, the (TCB-TSB) is significantly correlated with TSB (p < 0.0001). Similar findings were also seen in the sternum (TCB-TSB) except for the season (p = 0.0808). Conclusions: Cumulative ambient light exposure and the severity of NJ may contribute to (TCB-TSB). Full article

The effects of climate change are particularly pronounced in cities, where urban green infrastructure—such as trees, parks, and green spaces—plays a vital role in both climate adaptation and mitigation. This study assesses the carbon sequestration potential of urban forests in Budapest, the capital city of Hungary, which lies at the intersection of the Great Hungarian Plain and the Buda Hills, and is traversed by the Danube River. The city is characterized by a temperate climate with hot summers and cold winters, and a diverse range of soil types, including shallow Leptosols and Cambisols in the limestone and dolomite hills of Buda, well-developed Luvisols and Regosols in the valleys, Fluvisols and Arenosols in the flood-affected areas of Pest, and Technosols found on both sides of the city. The assessment utilizes data from the National Forestry Database and the Copernicus Land Monitoring Service High Resolution Layer Tree Cover Density. The results show that Budapest’s urban forests and trees contribute an estimated annual carbon offset of −41,338 tCO₂, approximately 1% of the city’s total emissions. The urban forests on the Buda and Pest sides of the city exhibit notable differences in carbon sequestration and storage, age class structure, tree species composition, and naturalness. On the Buda side, older semi-natural forests dominated by native species primarily act as in situ carbon reservoirs, with limited additional sequestration capacity due to their older age, slower growth, and longer rotation periods. In contrast, the Pest-side forests, which are primarily extensively managed introduced forests and tree plantations, contain a higher proportion of non-native species such as black locust (Robinia pseudoacacia) and hybrid poplars (Populus × euramericana). Despite harsher climatic conditions, Pest-side forests perform better in carbon sink capacity compared to those on the Buda side, as they are younger, with lower carbon stocks but higher sequestration rates. Our findings provide valuable insights for the development of climate-resilient urban forestry and planning strategies, emphasizing the importance of enhancing the long-term carbon sequestration potential of urban forests. Full article

On the beach of Linosa Island (Italy), 43 loggerhead sea turtle (Caretta caretta) unhatched eggs were recovered from nests, formalin-fixed and necropsied. The tissue samples were stained with hematoxylin-eosin (HE), Grocott, von Kossa, periodic acid-Schiff (PAS), and Movat pentachrome stains. Histologically, vacuolar degeneration (100.0%) and increased numbers of melanomacrophages (18.6%) in the liver, and edema (14.0%) in the lungs were observed. Twenty-five kidneys (58.1%) showed deposition of blue amorphous material with HE staining, which also appeared PAS-positive and black with von Kossa staining, allowing a diagnosis of calcium oxalate, confirmed by transmission electron microscopy (TEM). The hepatic lesions may be indicative of toxicosis, infection, or a defense mechanism. A statistically significant association between the nest position and renal oxalosis (renal calcium oxalate deposition) was observed. Renal oxalosis was probably due to the exceptionally high summer temperatures, which were statistically higher compared to the temperatures recorded in the previous two years. Full article

Mid-day maximum soil temperatures were measured at 10 study plots during different hot summer days in Haleakalā Crater, Maui, with thermocouple thermometers on five adjacent microsite types: bare surface soils, soils under black tephra, soils under reddish tephra, soils shaded by silverswords, and soils under plant litter. The main tephra morphologies and geomorphic environments, as well as their geoecological association with silversword rosettes (Argyroxiphium sandwicense), were also assessed; silversword density was substantially greater on reddish tephra-covered areas than under black tephra fragments. Silversword seeds are extremely sensitive to high temperatures and fail to germinate after a short exposure to soil temperatures ≥35 °C. Thermal data sets were statistically compared with parallel box plots; the ability of various microsites to provide safe sites for silversword growth was also assessed. Bare soils and black tephra reached the highest median temperatures, up to 48.7 °C and 40.3 °C, respectively; reddish tephra remained much cooler, with all median temperatures ≤30.8 °C. Rosette-shaded soils and soils under silversword litter were the coolest, with temperatures below 18.7 °C and 18.5 °C, respectively. Temperatures in all microsites, except those under black tephra, were significantly lower (p < 0.0001) than on contiguous bare ground. It was concluded that reddish tephra provides the ideal conditions for silversword regeneration. Full article

Droughts present a significant global challenge, particularly to forest ecosystems in regions such as eastern New South Wales, Australia, which is known for its dry climate and frequent, intense droughts. Recent studies have indicated a notable increase in tree mortality and canopy browning across this area, especially during the recent extreme drought period culminating in the Black Summer of 2019–2020. Our study investigates the impacts of drought on eucalypt forests by leveraging remote sensing and field observation data to detect and analyse vegetation health and stress indicators. Utilising data from Sentinel-2, alongside historical Landsat observations, we applied multiple spectral vegetation indices, namely the Normalized Difference Vegetation Index (NDVI), Normalized Difference Moisture Index (NDMI), Normalized Burn Ratio (NBR), and Tasseled Cap Transformation, to assess the extent of drought impacts. We found NBR to show the most consistent agreement with ground-based observations of drought-related tree mortality. Additionally, by integrating ground-based data from the “Dead Tree Detective” citizen science project, we were able to validate the remote sensing outcomes with a 90.22% consistency, providing confirmation of the extensive spatial distribution and severity of the inferred impacts. Our findings reveal that 13.16% of eucalypt forests and woodlands across eastern New South Wales experienced severe stress associated with drought during the 2019–2020 Black Summer drought. This study demonstrates the utility of satellite-derived drought indicators in monitoring forest health and highlights the necessity for continuous monitoring and research to understand the factors that trigger tree vitality loss. Full article

At present, there are few studies on seasonal differences in the aroma quality and volatile components of Rucheng Baimao (Camellia pubescens) black tea. In this study, sensory evaluation and volatile component analysis were carried out on one sample of Rucheng Baimao black tea corresponding to spring, summer, and autumn, respectively. The results of sensory evaluation showed that the black teas of all three seasons had floral aromas. However, the aroma quality of spring black tea was the best, followed by that of autumn black tea, and summer black tea was the worst. The analysis of volatile components showed that alcohols, esters, and alkanes were the main substance categories. In addition, the results of the aroma index were consistent with those of the sensory evaluation, indicating that spring black tea had the best aroma quality, followed by autumn black tea and then summer black tea. Eleven key differential volatile components were screened by combining PLS-DA analysis (VIP > 1, p < 0.05) and rOAV > 1. Among them, geraniol, methyl salicylate, nonanal, and (E)-citral accumulated the most in spring black tea, linalool, phenylacetaldehyde, benzaldehyde, phenethyl alcohol, benzyl alcohol, and β-ionone accumulated the most in summer black tea, and trans-nerolidol accumulated the most in autumn black tea. This study aims to provide a theoretical reference for the regulation of the aroma quality of Rucheng Baimao black tea. Full article

Community members seeking alternatives to policing have played a substantive role in promoting safety and responding to harm for decades. The Survival Line was formed as a volunteer-run hotline to respond to community members’ concerns about neighborhood crime or police misconduct. It was established in the summer of 1970 as a mechanism for gathering data while also referring callers to community resources like pro bono attorneys and low-cost social services. It ran as a 24/7 hotline staffed entirely by volunteers from the Action for Survival coalition, a group of community-based organizations, which included the Chicago Urban League. Using historical analytic methods, this study asks the following: what function did this citizen-run hotline serve in 1970s Chicago? This study mobilizes archival research methods to analyze call records, meeting minutes, publicity materials, and internal memos from the Chicago Urban League and its Survival Line archives. This archival analysis found that the Survival Line served multiple functions; it was a non-state response to urban crises, a vehicle for Black solidarity, and a mechanism for gathering data on crime and police misconduct in the city. By functioning as an alternative to policing and state responses to crime, a vehicle for Black neighborhood solidarity, and a data collection mechanism, the Survival Line was at the core of an impactful micropolitical intervention upon urban crises in 1970s Chicago. As a historical example of community-driven violence and crisis response, this hotline has implications for contemporary social work—specifically for direct practice, community organizing, program design and evaluation, and community-based participatory research. Full article