Search Results (329)

This study aims to systematically evaluate the balancing mechanism between road performance, carbon emissions, and economic cost when selecting asphalt materials for severe cold regions, filling the gap in multi-criteria decision-making for composite chemical modifications. To address alternating temperatures, heavy traffic, and modified asphalt transport difficulties, this study presents a novel evaluation framework focusing on the performance–environmental–cost nexus of a desulfurized rubber powder composite SBS-modified asphalt mixture, which provides a clear technological breakthrough for high-ratio scrap tire recycling in seasonal frost zones. Two reference mixtures serve as comparisons: a conventional rubber powder composite SBS (styrene–butadiene–styrene triblock)-modified asphalt mixture (CR-SBS) and an SBS-modified asphalt mixture (SBS). A comparative experiment was conducted between the two materials and the SBS-modified asphalt mixture (ACR-SBS) compounded with desulfurized rubber powder. High-temperature stability was tested by the rutting test, low-temperature crack resistance by the beam bending test, and water stability by the immersion Marshall and freeze–thaw splitting tests. Life cycle carbon emissions and economic costs were quantified from raw material acquisition to construction. The results show that desulfurized rubber powder composite with ACR-SBS delivers the most superior overall road performance. However, it also generates the highest life cycle carbon footprint. Its total carbon emission reaches 162,800 kgCO₂eq, which is 13.7% (19,600 kgCO₂eq) higher than SBS (143,200 kgCO₂eq) and 7.7% (11,600 kgCO₂eq) higher than CR-SBS (151,200 kgCO₂eq). The total cost of ACR-SBS is 391,000 CNY, which is 1.5% (6000 CNY) higher than SBS (385,000 CNY) and 1.3% (5000 CNY) lower than CR-SBS (396,000 CNY). These findings provide a basis for the selection of high-performance, low-carbon, and economical composite-modified asphalt in severe cold regions. Full article

Asphalt concrete pavements in many regions suffer from premature deterioration caused by low-temperature cracking and rutting resistance under heavy traffic loads and high summer temperatures. While polymer-modified bitumen is widely used to improve pavement performance, the high cost of commercial polymers restricts its extensive application. This study evaluates the potential of polymer waste as an alternative modifier for asphalt binders to enhance mechanical performance while reducing economic and environmental costs. Experimental results demonstrate that an optimal plastic waste content of 1.0–1.5% significantly improves rutting resistance and increases binder rigidity. The incorporation of 1.5% low-density polyethylene (LDPE) and high-density polyethylene (HDPE) enhances deformation resistance, elastic modulus, and temperature stability. LDPE exhibits better compatibility with bitumen and dissolves more readily, contributing to improved binder homogeneity, whereas HDPE provides higher stiffness and thermal stability. The combined use of polymer waste with styrene–butadiene–styrene (SBS) produces a pronounced synergistic effect, leading to improvements in physical and mechanical properties exceeding 25% compared to Kazakhstan regulatory standards. Increasing polymer waste content further enhances the rigidity of both the binder and asphalt concrete, thereby improving rutting resistance and plastic deformation at elevated temperatures. The proposed approach offers a cost-effective and sustainable solution for road construction, promoting plastic waste recycling, reducing reliance on virgin polymers, and improving pavement durability, particularly under the climatic and traffic conditions of Kazakhstan. Full article

Styrene-butadiene-styrene (SBS) modifier can enhance the resistance of asphalt mixtures to load-induced deformation and fatigue cracking by constructing a three-dimensional physical gel network. However, a rigorous mechanical characterization of this mechanism remains lacking. This study elucidates the nonlinear fatigue damage evolution of SBS-modified asphalt mixtures with physical gel structures based on residual strain response analysis. Indirect tensile fatigue tests were conducted to characterize the residual strain response of SBS-modified asphalt mixtures. A damage-informed residual strain model was established, and a relative residual strain change rate was defined to analyze the correlation between fatigue cracking and residual strain response. Furthermore, the nonlinear fatigue damage evolution of SBS-modified asphalt mixtures was investigated based on the fatigue damage theory. The results demonstrate a strong correlation between fatigue cracking and a viscoplastic strain in the SBS-modified asphalt mixtures. The proposed residual strain model accurately describes the nonlinear fatigue damage evolution and residual strain response. The relative residual strain change rate serves as a rational indicator of the material’s resistance to fatigue cracking and residual strain accumulation. The SBS modifier enhances resistance to residual strain and fatigue cracking by forming a complex polymer network that establishes a three-dimensional physical gel structure. Full article

The emergence of a novel crumb rubber (CR)/SBS-polymerized pellet has simplified the complex preparation process of composite-modified asphalt. However, the effectiveness of CR/SBS-polymerized pellets in improving asphalt performance has not been confirmed. This study mainly investigated the performance and reinforcement mechanism of polymerized pellet-modified asphalt. First, polymerized pellet-modified asphalt samples with different contents (10%, 20%, 30% and 40% of the asphalt mass) were prepared. Then, the physical properties, rheological behavior, thermal stability, and aging resistance of the pellet-modified asphalt samples were systematically evaluated, using both base asphalt and a commercially available styrene–butadiene–styrene triblock copolymer (SBS)-modified asphalt as control groups for comparison. Finally, the modification mechanism was explored through Fourier transform infrared spectroscopy (FTIR) and fluorescence microscopy (FM). The findings demonstrated that the incorporation of polymerized pellets could effectively decrease the penetration, elevate the softening point, and enhance the viscosity of asphalt. In addition, the high- and low-temperature performance, as well as the aging resistance of the modified asphalt, were significantly improved. These enhancing effects became more pronounced with increasing modifier content. The performance of SBS-modified asphalt is between 20% pellets MA and 30% pellets MA. The pyrolysis temperature range of all asphalt samples is 220 °C~500 °C, and infrared spectroscopy indicated that CR/SBS pellet-modified asphalt is mainly a physical mixing process. This work provides a scientific basis for further engineering applications of CR/SBS pellets. Full article

Considering the production efficiency and performance limitations inherent in conventional wet process asphalt mixtures, this study investigates the synergistic potential of fast-melting styrene–butadiene–styrene (F-SBS) and crumb rubber (CR) in enhancing the performance of asphalt mixtures when applied through the dry process modification method. Firstly, high- and low-temperature rheological tests were conducted on modified asphalt containing different dosages of F-SBS (1–3%) and CR (1–10%) to determine the optimal dosage of the modifier for the asphalt mixture. Furthermore, a comprehensive comparative analysis was conducted to evaluate the performance of asphalt mixtures modified with conventional SBS/CR against the F-SBS/CR system across both wet and dry modification processes. Finally, microscopic tests were conducted on the modified asphalt and asphalt mixtures to further investigate the synergistic mechanisms and effects of F-SBS and CR. The results indicated that F-SBS (2.5%)/CR (8%)-modified asphalt exhibited superior rheological properties, enhanced compatibility, and improved storage stability. Additionally, the dry process F-SBS/CR asphalt mixture demonstrated a 12.9% improvement in high-temperature stability, a 19.1% improvement in split strength after freeze–thaw cycles, and a 14.4% improvement in fatigue resistance compared to wet process conventional SBS/CR asphalt mixtures. The microscopic test results indicate that F-SBS and CR modify the asphalt primarily through physical blending. Observations further confirm that the dry process enhances interfacial bonding among the modifiers, asphalt binder, and aggregates, promoting closer and more stable interactions and thus improving mixing efficiency and overall performance. This study confirms the advantages of applying F-SBS and CR in dry process asphalt mixtures, thereby providing guidance for establishing a connection between laboratory investigations and field construction practices in the future. Full article

The performance and durability of asphalt pavements are strongly influenced by the rheological properties of asphalt binders, particularly under severe climatic and traffic conditions. This study investigates the synergistic effects of incorporating multi-walled carbon nanotubes (CNTs) at dosages ranging from 0.25% to 1% into AC 40-50 asphalt binders modified with 4% Styrene–Butadiene–Styrene (SBS). A comprehensive experimental program involving physical, rheological, and chemical characterization tests was conducted, including penetration, softening point, viscosity, storage stability, a Dynamic Shear Rheometer (DSR), Multiple Stress Creep Recovery (MSCR), Linear Amplitude Sweep (LAS), Fourier Transform Infrared Spectroscopy (FTIR), and Glover-Rowe (G-R) analysis. Statistical inference using one-way ANOVA was also conducted to evaluate the significance of differences among the binder formulations investigated. The results showed a continuous increase in binder stiffness with increasing CNT content, as indicated by decreasing penetration values, higher softening points, and increased viscosity. Incorporating 1% CNT reduced the softening-point difference from 3.1 °C to 1.6 °C in SBS-modified binders, indicating improved storage stability. Rheological evaluations showed that 0.75% CNT increased the high-temperature performance grade from 82 °C to 88 °C and provided the best rutting resistance, as indicated by MSCR results. In contrast, the 0.5% CNT formulation exhibited superior fatigue resistance and the lowest Glover-Rowe index, indicating improved cracking resistance and durability. Overall, the findings demonstrate that CNTs can effectively enhance the performance of SBS-modified asphalt binders, with 0.75% CNT being optimal for hot-climate applications, while 0.5% CNT exhibited improved fatigue and cracking resistance under moderate-temperature conditions. Full article

The degradation of styrene-butadiene-styrene (SBS) modified asphalt under thermal-oxidative aging can reduce pavement service life. Lignin is a renewable material with active phenolic hydroxyl groups. Incorporating lignin into SBS modified asphalt may provide a potential bio-based auxiliary modification route. To investigate the antioxidative effect and rheological properties of SBS modified asphalt after adding lignin, a molecular dynamics test and experimental tests were employed. The molecular simulation results suggested that lignin preferentially associated with asphaltene and resin molecules and changed the molecular mobility of asphalt components in a component-dependent manner. The SBS/lignin composite modified asphalt was evaluated by temperature sweep (TS), Multiple Stress Creep and Recovery (MSCR), Linear Amplitude Sweep (LAS) and Fourier transform infrared spectroscopy (FTIR). Rheological tests showed that lignin increased the complex shear modulus and rutting factor. LAS results showed that lignin reduced the fatigue life of SBS-modified asphalt in the unaged state due to increased stiffness and embrittlement. However, after long-term aging, the lignin-containing binders retained higher fatigue resistance than the SBS-only control, which may be related to the slower evolution of oxidation-related functional groups and SBS-related spectral indices. FTIR analysis provided semi-quantitative evidence that lignin addition reduced the growth of sulfoxide-related bands and helped maintain the polybutadiene-related index during aging. Overall, lignin may serve as a potential auxiliary antioxidant modifier for SBS modified asphalt, while its exact source-specific molecular mechanism requires further verification. Full article

Low-temperature conditioning is a key procedure in the flexibility evaluation of waterproofing membranes and directly affects the reliability of subsequent performance assessments. However, the internal unsteady-state heat transfer kinetics and the thermal gradient evolution mechanisms in multi-layer composite membranes under transient cold shocks require further investigation. Focusing on commonly utilized 3 mm and 4 mm thick SBS (Styrene–Butadiene–Styrene)-modified bitumen waterproofing membranes as subjects, this study investigated the internal dynamic temperature fields and microstructural response of bituminous waterproofing membranes under standard low-temperature flexibility testing conditions. By accurately pre-embedding micro-temperature sensors in situ at the interface between the surface layer and the reinforcement matrix, the transient thermal response profiles of specimens with varying specifications in a −25 °C liquid environment were quantified. Simultaneously, a three-dimensional transient heat conduction finite element model was established to elucidate the dynamic evolution of internal spatial temperature gradients. The congruence between experimental and numerical results demonstrates that upon exposure to extreme cold, composite membranes of different thicknesses exhibit a pronounced “surface-to-core” heat transfer lag effect. The cooling rate maximized within the initial 10 min of exposure. Conversely, the internal interface layer—acting as a high-thermal-resistance zone and the most unfavorable point for heat conduction—necessitated 10~20 min of nonlinear thermal dissipation to stabilize at the target ambient temperature. This study clarifies the transient thermal response and temperature-field evolution laws of bituminous waterproofing membranes, providing a robust theoretical framework for elucidating low-temperature embrittlement mechanisms and informing the material design and application of waterproofing projects in cold regions. Full article

To reveal the long-term anti-aging mechanisms of rubber–plastic elastomer-modified asphalt in complex service environments and overcome the inherent defects of single polymer modifiers—namely their susceptibility to degradation or phase separation—this study prepared styrene-butadiene-styrene (SBS), low Mooney rubber (LMMR), and low-density polyethylene (LDPE)-modified asphalts. Simultaneously, an LMMR-LDPE rubber–plastic thermoplastic elastomer (TPE) was fabricated utilizing twin-screw extrusion technology and subsequently used to prepare a composite-modified asphalt. Three aging protocols were simulated: short-term thermo-oxidative aging (RTFOT), long-term pressure aging (PAV), and ultraviolet light aging (UV). A multi-scale quantitative characterization was conducted using a dynamic shear rheometer, Fourier transform infrared spectroscopy, and atomic force microscopy to evaluate the rutting factor, carbonyl index, and surface microroughness of each system before and after aging. The experimental results indicate that the coupled effect of long-term stress and thermal oxidation causes the most severe damage to the colloidal structure of modified asphalt. Conventional SBS-modified asphalt, due to its abundance of unsaturated double bonds, exhibits a sharp increase in the carbonyl index and aging index of the rutting factor after aging, making it highly susceptible to oxidative chain scission. Although LDPE-modified asphalt possesses chemical inertness, it is prone to crystalline phase separation under aging conditions, resulting in a microroughness distortion rate of up to 86.36%. In contrast, the LMMR-LDPE composite system, leveraging the high chemical stability of the saturated aliphatic carbon chain and the flexibility-enhancing and crystallization-inhibiting effects of LMMR, effectively reduces active oxidation sites and improves interfacial compatibility. This composite system exhibits the lowest carbonyl increment and rheological attenuation under all aging conditions, while effectively inhibiting the free migration and agglomeration of macromolecular components. The LMMR-LDPE composite modification technology effectively overcomes the inherent drawbacks of single polymers, such as susceptibility to degradation or segregation, demonstrating excellent long-term macroscopic rheological stability and microscopic phase morphology anti-aging capability. The present findings provide laboratory-scale mechanistic support for the design of durable rubber–plastic-modified asphalt systems, while further pilot-scale, economic, and field validation is still required before practical engineering application can be fully assessed. Full article

To evaluate the susceptibility of styrene–butadiene–styrene (SBS)-modified asphalt to modifier segregation during high-temperature storage, this study examined its segregation behavior and microstructural evolution under storage conditions ranging from 70 to 163 °C over durations of 48–144 h, with varying warm-mix agent dosages (0%, 3%, 4%, and 5%). The investigation was conducted using softening point measurements, dynamic shear rheometry, infrared spectroscopy, and optical microscopy. The results indicated that the incorporation of the warm-mix agent significantly reduced the difference in softening point, diminished the discrepancies in complex modulus and phase angle between the upper and lower layers, and inhibited SBS aggregation and phase separation. When the warm-mix agent content reached 5%, the softening point difference in the modified asphalt at 163 °C and 48 h decreased from 14.4 °C to 1.6 °C, essentially eliminating segregation. Infrared spectroscopy confirmed that the warm-mix agent did not induce chemical bond changes but improved the compatibility between the SBS modifier and the base asphalt. Microscopic observation further verified that the warm-mix agent facilitated a uniform dispersion of SBS modifier particles, forming a stable microphase structure. The research findings provide valuable insights for improving the storage stability and engineering performance of SBS-modified asphalt. Full article

To achieve synergistic, efficient degradation of volatile, harmful gases in asphalt and to scientifically quantify inhibitor dosage, this study proposes a dosage optimization method that integrates nonlinear regression with a multi-response satisfaction function. Focusing on a proprietary composite volatile gas suppressant, we systematically measured the concentration trends of ammonia, nitrogen oxides, sulfur dioxide, and hydrogen sulfide emitted from three asphalt systems: base asphalt, SBS modified asphalt (Styrene-Butadiene-Styrene modified asphalt), and rubber modified asphalt under different suppressant dosages (0%, 0.02%, 0.04%, 0.06%, 0.08%, and 0.10%). First, high-precision prediction models (R² > 0.95) were established using nonlinear regression to relate different inhibitor dosages to corresponding gas concentrations. Based on a satisfaction function, the multi-objective degradation effects were normalized into a comprehensive satisfaction index, and the optimal dosage was then determined. The results indicate: (1) the constructed models can accurately predict the concentrations of volatile harmful gases at various dosages; (2) the predicted optimal blending ratios vary by asphalt type, specifically 0.082% for base asphalt, 0.079% for SBS modified asphalt, and 0.080% for rubber modified asphalt; and (3) at the optimal blending ratios, all four gases achieve high and balanced degradation levels, resulting in the best overall degradation performance. At the same time, road performance tests confirmed that this blending ratio has no significant negative impact on the high-temperature and low-temperature stability or water stability of the asphalt mixture. Compared with traditional single-factor empirical methods, this approach represents a methodological upgrade from qualitative description to quantitative prediction, and from single-objective comparison to multi-objective synergistic optimization, providing data and theoretical support for the precise, efficient, and engineering-applicable use of asphalt volatile gas inhibitors. Full article

Warm-mix asphalt (WMA) technology and basalt fiber modification have been increasingly applied in road engineering. However, conventional basalt fibers often disperse unevenly and tend to agglomerate. In this study, basalt fiber powder (BFP) was incorporated into a Sasobit-based WMA system and systematically compared with matrix asphalt, Sasobit-modified WMA, conventional basalt fiber-modified WMA, and styrene butadiene styrene (SBS)-modified asphalt. Multiscale characterization—including dynamic shear rheometry (DSR), bending beam rheometry (BBR), scanning electron microscopy (SEM), and nanoindentation—was conducted to elucidate rheological behavior and interfacial micromechanical responses. The corresponding Asphalt Concrete-13 (AC-13) mixtures were further evaluated through rutting tests, low-temperature bending tests, and moisture susceptibility tests. Results demonstrate that micronized BFP achieves more homogeneous dispersion within the asphalt matrix and may promote a more effective reinforcing morphology, significantly enhancing high-temperature deformation resistance while partially mitigating the low-temperature stiffness increase induced by Sasobit. Compared with conventional basalt fiber systems, BFP shows better stress relaxation capacity and interfacial mechanical response under the tested conditions. At the mixture level, the BFP–Sasobit system showed the best overall performance, with the dynamic stability increasing by 242.2% relative to the base asphalt mixture and the residual Marshall stability reaching 92.3%, while the low-temperature flexural strain increased by 33.3%. Overall, the findings suggest that morphology-controlled micronization provides a morphology-guided enhancement strategy for Sasobit-based warm-mix asphalt by promoting coordinated improvements across the rheological, micromechanical, and mixture scales. Full article

This study investigates the synergistic effects of combining polyphosphoric acid (PPA) and styrene–butadiene–styrene (SBS) as modifiers in asphalt binders to enhance their performance. The research focuses on optimizing the concentrations of PPA and SBS to improve the resistance to permanent deformation, cracking at intermediate and low temperatures, and resistance to aging. A series of empirical and rheological tests, including penetration, softening point, elastic recovery, dynamic shear rheometer (DSR), multiple stress creep recovery (MSCR), and bending beam rheometer (BBR), were conducted to evaluate the rheological and engineering properties of the modified binders. The results indicate that PPA can partially replace SBS, offering comparable improvements in high-temperature performance and creep resistance. The MSCR test revealed a statistically significant synergistic effect between PPA and SBS, resulting in improved recovery and reduced non-recoverable compliance. However, PPA alone shows limited effectiveness at low temperatures and in properties that are governed by elastic response. This study highlights the potential for optimizing asphalt modifiers by leveraging the complementary properties of PPA and SBS in hybrid systems, particularly regarding high-temperature properties and dynamic loading. Full article

The synergistic utilization of waste plastics and tires in asphalt modification is a highly promising sustainable strategy. However, the differential impacts of distinct plastic molecular architectures on the performance and network evolution of rubber-modified asphalt remain fundamentally unclear. This study systematically investigated the physical, rheological, and microstructural properties of composite asphalts modified with desulfurized rubber powder (DRP) and four representative plastics: polyethylene (PE), styrene–isoprene–styrene (SIS), styrene–ethylene–butylene–styrene (SEBS), and styrene–butadiene–styrene (SBS). Furthermore, the pavement performance of the asphalt mixtures prepared via dry and wet methods was comparatively evaluated. Microstructural and spectroscopic analyses revealed that the composite modification was primarily governed by physical blending and swelling. The non-polar, semi-crystalline PE resulted in severe phase separation and extreme low-temperature brittleness. Conversely, the saturated hydrogenated mid-blocks of SEBS endowed the asphalt with the highest high-temperature rutting resistance but severely compromised its low-temperature stress relaxation. Remarkably, SBS interacted synergistically with DRP to form a highly homogeneous and densely interwoven three-dimensional network, thereby achieving an optimal viscoelastic balance, outstanding storage stability, and superior low-temperature ductility. Pavement performance tests further demonstrated that the wet method significantly outperformed the dry method for block copolymers by facilitating sufficient pre-swelling. Overall, the SBS-DRP composite-modified asphalt prepared via the wet method exhibited the most exceptional and balanced comprehensive pavement performance, providing a robust theoretical foundation for the sustainable and high-value recycling of multi-source solid wastes in paving engineering. Full article

Polymer-modified bituminous binders are widely used in road construction due to their enhanced mechanical performance; however, the effectiveness of these materials critically depends on the actual concentration of polymer modifiers, particularly styrene-butadiene-styrene (SBS). This study aims to develop and validate a rapid, reproducible Fourier Transform Infrared Spectroscopy—Attenuated Total Reflectance (FTIR-ATR) spectroscopy method for the quantitative determination of SBS content in polymer-modified bitumen (PMB). Since, to date, there is no clearly defined method for controlling the quantitative content of polymers in PMB, this creates difficulties in accepting the roadway into operation. Calibration PMB samples containing 1–4% SBS were prepared, tested for physical and mechanical properties, and analyzed spectroscopically to identify characteristic absorption bands at 966 cm⁻¹ and 699–760 cm⁻¹. A first-order calibration model was constructed to relate peak intensity to polymer concentration. The results demonstrate a clear linear correlation between SBS content and IR absorption features, confirming the suitability of FTIR as an instrumental method for routine laboratory control. Application of the model allowed determination of actual polymer mass fraction with high accuracy and reproducibility. The findings also showed that increased SBS levels improve softening point, elasticity, and low-temperature resistance, with 3–4% representing a performance-optimal range. Overall, the proposed FTIR-based approach provides an objective and efficient tool for quality control of polymer-modified binders and supports broader standardization efforts in the field. Full article