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24 pages, 6356 KiB  
Article
The Significance of Metasomatism in the Formation of the Tanbreez REE Deposit in South Greenland
by Hans Kristian Schønwandt, Thomas Ulrich, Greg Barnes and Ole Christiansen
Minerals 2025, 15(8), 797; https://doi.org/10.3390/min15080797 - 29 Jul 2025
Viewed by 122
Abstract
The layering of the lower layered kakortokite in the per-alkaline Ilímaussaq complex has been interpreted as an orthocumulus rock. Petrographic observation and mineral chemical data from the topmost and the lowest part of the layered kakortokite show signs that indicate massive metasomatic overprint. [...] Read more.
The layering of the lower layered kakortokite in the per-alkaline Ilímaussaq complex has been interpreted as an orthocumulus rock. Petrographic observation and mineral chemical data from the topmost and the lowest part of the layered kakortokite show signs that indicate massive metasomatic overprint. The occurrence of globular structures in the top part of kakortokite and fine-grained inclusions in the lower layered kakortokite are interpreted as the precursor of kakortokite and the result of a subsolidus reaction between a fluid phase and the underlying rock, respectively. Two different processes led to the formation of kakortokite, a precursor where a clear repetitive layering occurs and a chemical reaction between a fluid phase and the underlying rock where different kakortokite types are randomly interstratified. Both metasomatic events led to a higher rare earth element (REE) grade of the original REE mineralization. Full article
(This article belongs to the Special Issue Ore Deposits Related to Metamorphism)
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27 pages, 12402 KiB  
Article
Global and Regional Snow Cover Decline: 2000–2022
by Stephen S. Young
Climate 2023, 11(8), 162; https://doi.org/10.3390/cli11080162 - 29 Jul 2023
Cited by 6 | Viewed by 11784
Abstract
Snow cover affects the global surface energy balance and, with its high albedo, exerts a cooling effect on the Earth’s climate. Decreases in snow cover alter the flow of solar energy from being reflected away from Earth to being absorbed, increasing the Earth’s [...] Read more.
Snow cover affects the global surface energy balance and, with its high albedo, exerts a cooling effect on the Earth’s climate. Decreases in snow cover alter the flow of solar energy from being reflected away from Earth to being absorbed, increasing the Earth’s surface temperature. To gain a global understanding of snow cover change, in situ measurements are too few and far between, so remotely sensed data are needed. This research used the medium-resolution sensor MODIS on the Terra satellite, which has been observing global snow cover almost daily since the year 2000. Here, the MOD10C2 eight-day maximum value composite time series data from February 2000 to March 2023 were analyzed to detect global and regional trends in snow cover extent for the first 23 years of the 21st century. Trends in snow cover change during different time periods (seasons and snow-year) were examined using the Mann—Kendall test and the univariate differencing analysis. Both methods produced similar results. Globally, snow cover declined two to ten times as much as it increased, depending on the season of analysis, and annually, global snow cover decreased 5.12% (not including Antarctica or Greenland) based on the Mann—Kendall test at the 95th percentile (p < 0.05). Regionally, Asia had the greatest net area decline in snow cover, followed by Europe. Although North America has the second-largest extent of snow cover, it had the least amount of net decreasing snow cover relative to its size. South America had the greatest local decline in snow cover, decreasing 20.60% of its annual (snow-year) snow cover area. The Australia–New Zealand region, with just 0.34% of the global snow cover, was the only region to have a net increase in snow cover, increasing 3.61% of its annual snow cover area. Full article
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16 pages, 2772 KiB  
Article
Late Holocene Environmental History and Norse Settlement in Outer Fjords from South Greenland: A Case Study at Lake Qallimiut
by Emilie Gauthier, Andrés Currás, Charly Massa, Typhaine Guillemot, Hervé Richard and Vincent Bichet
Geosciences 2023, 13(4), 123; https://doi.org/10.3390/geosciences13040123 - 20 Apr 2023
Cited by 1 | Viewed by 2581
Abstract
To complement discussions about vegetation history and climate variations in south Greenland, especially during the Norse settlement, we developed a sedimentological multiproxy approach to study a 4300-year-old lacustrine core comprising pollen analysis, NPPs analysis, physical measurements (magnetic susceptibility, density, and grain size), and [...] Read more.
To complement discussions about vegetation history and climate variations in south Greenland, especially during the Norse settlement, we developed a sedimentological multiproxy approach to study a 4300-year-old lacustrine core comprising pollen analysis, NPPs analysis, physical measurements (magnetic susceptibility, density, and grain size), and geochemical analyses (X-ray fluorescence, X-ray diffraction, and elemental analyses). Sediment archives were retrieved from a river-fed lake, Lake Qallimiut, located in the outer fjords of the Vatnahverfi area. The pollen analysis indicated a transition from juniper and willow cover to a dwarf birch forest. Non-pollen palynomorphs (NPPs) suggested grazing pressure and the presence of wild herbivores between 2300 and 1800 cal. BC. From ca. 1000 cal. AD, the presence of Norse farmers was evidenced in this area by archaeological surveys, and pollen analyses confirm the presence of human activities from the 11th century to the end of the 13th century. However, human impact progressively vanished between the 12th and 13th centuries, much earlier than at the other Vatnahverfi sites. Full article
(This article belongs to the Special Issue Arctic Geoarchaeology and Environmental Archaeology)
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15 pages, 4938 KiB  
Article
The Application of RGB, Multispectral, and Thermal Imagery to Document and Monitor Archaeological Sites in the Arctic: A Case Study from South Greenland
by Jørgen Hollesen, Malte Skov Jepsen and Hans Harmsen
Drones 2023, 7(2), 115; https://doi.org/10.3390/drones7020115 - 8 Feb 2023
Cited by 6 | Viewed by 4934
Abstract
Over the past decades, climate change has accelerated the deterioration of heritage sites and archaeological resources in Arctic and subarctic landscapes. At the same time, increased tourism and growing numbers of site visitors contribute to the degradation and manipulation of archaeological sites. This [...] Read more.
Over the past decades, climate change has accelerated the deterioration of heritage sites and archaeological resources in Arctic and subarctic landscapes. At the same time, increased tourism and growing numbers of site visitors contribute to the degradation and manipulation of archaeological sites. This situation has created an urgent need for new, quick, and non-invasive tools and methodologies that can help cultural heritage managers detect, monitor, and mitigate vulnerable sites. In this context, remote sensing and the applications of UAVs could play an important role. Here, we used a drone equipped with an RGB camera and a single multispectral/thermal camera to test different possible archeological applications at two well-known archaeological sites in the UNESCO World Heritage area of Kujataa in south Greenland. The data collected were used to test the potential of using the cameras for mapping (1) ruins and structures, (2) the impact of human activity, and (3) soil moisture variability. Our results showed that a combination of RGB and digital surface models offers very useful information to identify and map ruins and structures at the study sites. Furthermore, a combination of RGB and NDVI maps seems to be the best method to monitor wear and tear on the vegetation caused by visitors. Finally, we tried to estimate the surface soil moisture content based on temperature rise and the Temperature Vegetation Dryness Index (TVDI), but did not achieve any meaningful connection between TVDI and on-site soil moisture measurements. Ultimately, our results pointed to a limited archaeological applicability of the TVDI method in Arctic contexts. Full article
(This article belongs to the Special Issue (Re)Defining the Archaeological Use of UAVs)
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16 pages, 13210 KiB  
Article
On Tide Aliasing in GRACE Time-Variable Gravity Observations
by Zhen Li, Zizhan Zhang and Hansheng Wang
Remote Sens. 2022, 14(21), 5403; https://doi.org/10.3390/rs14215403 - 28 Oct 2022
Cited by 4 | Viewed by 1987
Abstract
Aliasing error induced by tide-related high frequency mass variations is one of the most significant errors in the Gravity Recovery and Climate Experiment (GRACE). In the present work, we evaluated the 161.0-day S2, 171.2-day P1, and 322.1-day S1 [...] Read more.
Aliasing error induced by tide-related high frequency mass variations is one of the most significant errors in the Gravity Recovery and Climate Experiment (GRACE). In the present work, we evaluated the 161.0-day S2, 171.2-day P1, and 322.1-day S1 ocean tide aliasing in GRACE latest RL06 data based on nearly 15 years of observation from 2002 to 2017. Tide aliasing was still obvious for current GRACE observations, especially for S2 and P1 aliasing. S2 aliasing was mostly evident over West Antarctica, and was a clearly eastward propagation that travelled around Antarctica in about 2 years, while P1 showed strongest aliasing over South Greenland. More seriously, we found that GRACE mascon data showed an extremely large aliasing error. The mascon data may have unintentionally amplified the aliasing error on land due to the regularization (or constraint) applied for reducing signal leakage. Enough attention must be paid to tide aliasing when using GRACE for assessing mass variations at high latitudes (e.g., glaciers in polar regions) which can cause potential obstacles to estimation of actual seasonality. Full article
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15 pages, 3535 KiB  
Article
Moisture Transport and Contribution to the Continental Precipitation
by Yazhu Yang, Chunlei Liu, Niansen Ou, Xiaoqing Liao, Ning Cao, Ni Chen, Liang Jin, Rong Zheng, Ke Yang and Qianye Su
Atmosphere 2022, 13(10), 1694; https://doi.org/10.3390/atmos13101694 - 16 Oct 2022
Cited by 5 | Viewed by 2531
Abstract
Understanding the water cycle change under a warming climate is essential, particularly the ocean to land moisture transport, which affects the precipitation over land areas and influences society and the ecosystem. Using ERA5 data from 1988 to 2020, the time series of moisture [...] Read more.
Understanding the water cycle change under a warming climate is essential, particularly the ocean to land moisture transport, which affects the precipitation over land areas and influences society and the ecosystem. Using ERA5 data from 1988 to 2020, the time series of moisture transport and the trend across the boundary of each continent, including Eurasia, Africa, North America, South America, Antarctic, Australia, and Greenland, have been investigated. The inflow and outflow sections of the moisture have been identified for each continent. The trends of moisture convergence over Eurasia, Africa, North America, and Antarctic are all positive, with the values of 2.59 ± 3.12, 2.60 ± 3.17, 12.98 ± 2.28, and 0.32 ± 0.47 (in 106 kg/s/decade), respectively, but only the trend over North America is statistically significant at a 0.1 significance level. The moisture convergence trend of −0.59 ± 3.63 (in 106 kg/s/decade) over South America is negative but insignificant. The positive trend of 0.10 ± 0.35 (in 106 kg/s/decade) over Greenland is very weak. The precipitation, evaporation, and moisture convergence are well balanced at middle and low latitudes, but the combination of moisture convergence and evaporation is systematically lower than the precipitation over Antarctic and Greenland. Contributions of evaporation and moisture convergence (or transport) to the continental precipitation vary with the continent, but the moisture convergence dominates the precipitation variability over all continents, and the significant correlation coefficients between the anomaly time series of continental mean moisture convergence and precipitation are higher than 0.8 in all continents. Full article
(This article belongs to the Section Climatology)
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16 pages, 3773 KiB  
Article
Establishing a Provenance Framework for Sandstones in the Greenland–Norway Rift from the Composition of Moraine/Outwash Sediments
by Adam G. Szulc, Andrew C. Morton, Andrew G. Whitham, Sidney R. Hemming and Stuart N. Thomson
Geosciences 2022, 12(2), 73; https://doi.org/10.3390/geosciences12020073 - 4 Feb 2022
Cited by 2 | Viewed by 2984
Abstract
The crystalline basement and Caledonian orogenic belt of East Greenland between 70 and 78° N are divided into five source regions on the basis of heavy mineral assemblages, mineral geochemistry, and isotopic age data from 42 modern moraine/outwash samples. The sand types generated [...] Read more.
The crystalline basement and Caledonian orogenic belt of East Greenland between 70 and 78° N are divided into five source regions on the basis of heavy mineral assemblages, mineral geochemistry, and isotopic age data from 42 modern moraine/outwash samples. The sand types generated by the five source regions can be recognized in the Mesozoic sedimentary rocks of Mid-Norway, and are named, from south to north, MN7 (Gåseland), MN4i (Milne Land–Renland), MN2ii (Hinks Land–Suess Land), MN2iii (Payer Land–Dronning Louise Land), and MN6 (Germania Land). These provide a framework for interpreting the provenance of Greenland–Norway rift sedimentary deposits. The provenance characteristics of Liverpool Land have also been defined, but whether this relatively small region merits a separate provenance status is unclear. Provenance links can be made by comparing the source region sand types with the composition of onshore and offshore sediments from previous studies. Triassic sandstones of the Nordland Ridge and the far south of the Møre Basin, along with Jurassic sandstones of the Heidrun Field in the Haltenbanken area, were derived from the MN4i source region. The provenance of Cretaceous sandstones in East Greenland can be linked to the MN2ii source region. The source of Turonian sandstones on Traill Ø can be pinpointed by zircon U–Pb ages to the Neoproterozoic Lyell Land Group of the Franz Josef Allochthon. Cretaceous sandstones in the Vøring and Møre basins were derived from the MN2iii and MN4i source regions. In addition, some of the Cenomanian–Campanian sedimentary rocks of East Greenland and Mid-Norway contain Permian–Cretaceous-aged zircon grains that are absent from the moraine/outwash samples. The most likely source of these zircon grains is the circum-Arctic region, implying the existence of a long-lived axial drainage system that entered the Greenland–Norway rift from the north. Full article
(This article belongs to the Collection Detrital Minerals: Their Application in Palaeo-Reconstruction)
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15 pages, 3092 KiB  
Article
Spatial and Temporal Variations in Crustal Structure in the Eurasian Basin
by Lihong Zhao, Tao Zhang, Zilong Ling, Mujie Li, Pengyao Zhi, Renwei Ding and Chaoyang Li
J. Mar. Sci. Eng. 2022, 10(2), 157; https://doi.org/10.3390/jmse10020157 - 26 Jan 2022
Cited by 3 | Viewed by 2962
Abstract
To understand the tectonic–magmatic history, crustal structure and crustal accretion mode of the Eurasian Basin in the Arctic, we calculated the crustal thickness, residual bathymetry (RB) and non-isostatic topography of the Eurasian Basin by using the latest bathymetry, free-air gravity anomaly, crustal age [...] Read more.
To understand the tectonic–magmatic history, crustal structure and crustal accretion mode of the Eurasian Basin in the Arctic, we calculated the crustal thickness, residual bathymetry (RB) and non-isostatic topography of the Eurasian Basin by using the latest bathymetry, free-air gravity anomaly, crustal age and sediment thickness data. The tectonic–magmatic process of the Eurasian Basin can be divided into two stages. During magnetic isochrons 24-13 (C24-C13), the crustal structure of the basin was characterized by regional variations, while the crustal structure of the basin was characterized by local variations during magnetic isochrons 13-0 (C13-0). On the whole, the western part of the basin had a thicker crustal thickness and higher RB than the eastern part of the basin during C24-C13, which should result from the northward movement of Greenland. During magnetic isochrons 24-20 (C24-C20), the crustal structure of the eastern part of the basin had abnormally strong asymmetry. We speculate that there may be mantle upwelling beneath the Kara Sea Shelf in the south of the Eastern Eurasian Basin, which provides a large amount of melt for the crustal accretion of the southern part of the Eastern Eurasian Basin. The melt focusing supply could generate abnormally thick crust (>7 km) during magma enhancement period. The Western Eurasian Basin had stronger spatial variability and more frequency asymmetric polarity reversal than the Eastern Eurasian Basin during magnetic isochrons 6-0 (C6-0). We attribute this to the inflow of the North Atlantic mantle. Full article
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9 pages, 3160 KiB  
Proceeding Paper
Moisture Sources for the Explosive Cyclogenesis of Extratropical Cyclone Miguel (2019) through a Lagrangian Approach
by Patricia Coll-Hidalgo, Albenis Pérez-Alarcón, José Carlos Fernández-Alvarez, Raquel Nieto and Luis Gimeno
Environ. Sci. Proc. 2021, 8(1), 19; https://doi.org/10.3390/ecas2021-10331 - 22 Jun 2021
Viewed by 1503
Abstract
In this study, the moisture sources for the explosive cyclogenesis Miguel that occurred during 4–9 June 2019 in the North Atlantic were investigated. To determine the moisture sources, the Lagrangian FLEXPART particle dispersion model was used. The moisture uptake pattern revealed the western [...] Read more.
In this study, the moisture sources for the explosive cyclogenesis Miguel that occurred during 4–9 June 2019 in the North Atlantic were investigated. To determine the moisture sources, the Lagrangian FLEXPART particle dispersion model was used. The moisture uptake pattern revealed the western North Atlantic Ocean extending to north-western North America, the south-eastern coast of Greenland, and the central North Atlantic Ocean around 45° N and 50°–20° W as the main moisture sources for Miguel explosive cyclogenesis. Furthermore, the moisture uptake from these regions was higher than the climatology. During the intensification of Miguel, the moisture contribution from oceanic sources was higher than terrestrial sources. Although the total amount of atmospheric moisture achieved during the explosive intensification was similar to that absorbed the 24 h prior, they changed in intensity geographically, being more intense the local support over central and northern North Atlantic basin. Full article
(This article belongs to the Proceedings of The 4th International Electronic Conference on Atmospheric Sciences)
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20 pages, 40264 KiB  
Article
Evaluation of the MODIS (C6) Daily Albedo Products for Livingston Island, Antarctic
by Alejandro Corbea-Pérez, Javier F. Calleja, Carmen Recondo and Susana Fernández
Remote Sens. 2021, 13(12), 2357; https://doi.org/10.3390/rs13122357 - 16 Jun 2021
Cited by 13 | Viewed by 3646
Abstract
Although extensive research of Moderate Resolution Imaging Spectroradiometer (MODIS) albedo data is available on the Greenland Ice Sheet, there is a lack of studies evaluating MODIS albedo products over Antarctica. In this paper, MOD10A1, MYD10A1, and MCD43 (C6) daily albedo products were compared [...] Read more.
Although extensive research of Moderate Resolution Imaging Spectroradiometer (MODIS) albedo data is available on the Greenland Ice Sheet, there is a lack of studies evaluating MODIS albedo products over Antarctica. In this paper, MOD10A1, MYD10A1, and MCD43 (C6) daily albedo products were compared with the in situ albedo data on Livingston Island, South Shetland Islands (SSI), Antarctica, from 2006 to 2015, for both all-sky and clear-sky conditions, and for the entire study period and only the southern summer months. This is the first evaluation in which MYD10A1 and MCD43 are also included, which can be used to improve the accuracy of the snow BRDF/albedo modeling. The best correlation was obtained with MOD10A1 in clear-sky conditions (r = 0.7 and RMSE = 0.042). With MCD43, only data from the backup algorithm could be used, so the correlations obtained were lower (r = 0.6). However, it was found that there was no significant difference between the values obtained for all-sky and for clear-sky data. In addition, the MODIS products were found to describe the in situ data trend, with increasing albedo values in the range between 0.04 decade−1 and 0.16 decade−1. We conclude that MODIS daily albedo products can be applied to study the albedo in the study area. Full article
(This article belongs to the Special Issue Estimating Meteorological Variables by Remote Sensing Data)
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9 pages, 4864 KiB  
Article
Bromine Isotope Variations in Magmatic and Hydrothermal Sodalite and Tugtupite and the Estimation of Br Isotope Fractionation between Melt and Sodalite
by Hans G. M. Eggenkamp, Michael A. W. Marks, Pascale Louvat and Gregor Markl
Minerals 2021, 11(4), 370; https://doi.org/10.3390/min11040370 - 31 Mar 2021
Cited by 3 | Viewed by 2326
Abstract
We determined the bromine isotope compositions of magmatic and hydrothermal sodalite (Na8Al6Si6O24Cl2) and tugtupite (Na8Al2Be2Si8O24Cl2) from the Ilímaussaq intrusion in South [...] Read more.
We determined the bromine isotope compositions of magmatic and hydrothermal sodalite (Na8Al6Si6O24Cl2) and tugtupite (Na8Al2Be2Si8O24Cl2) from the Ilímaussaq intrusion in South Greenland, in order to constrain the Br isotope composition of the melt and hydrothermal fluids from which these minerals were formed. Early formed magmatic sodalite has high Br contents (138 ± 10 µg/g, n = 5) and low δ81Br values (+0.23 ± 0.07‰). Late stage hydrothermal sodalite has lower Br contents (53±10 µg/g, n = 5) and higher δ81Br values (+0.36 ± 0.08‰). Tugtupite that forms at even later stages shows the lowest Br contents (26 ± 2 µg/g, n = 2) and the highest δ81Br values (+0.71 ± 0.17‰). One hydrothermal sodalite has a Br concentration of 48 ± 9 µg/g and an exceptionally high δ81Br of 0.82 ± 0.12‰, very similar to the δ81Br of tugtupites. We suggest that this may be a very late stage sodalite that possibly formed under Be deficient conditions. The data set suggests that sodalite crystallises with a negative Br isotope fractionation factor, which means that the sodalite has a more negative δ81Br than the melt, of −0.3 to −0.4‰ from the melt. This leads to a value of +0.5 to +0.6‰ relative to SMOB for the melt from which sodalite crystallises. This value is similar to a recently published δ81Br value of +0.7‰ for very deep geothermal fluids with very high R/Ra He isotope ratios, presumably derived from the mantle. During crystallisation of later stage hydrothermal sodalite and the Be mineral tugtupite, δ81Br of the residual fluids (both melt and hydrothermal fluid) increases as light 79Br crystallises in the sodalite and tugtupite. This results in increasing δ81Br values of later stage minerals that crystallise with comparable fractionation factors from a fluid with increasingly higher δ81Br values. Full article
(This article belongs to the Special Issue Halogen Stable Isotope Studies in Geological Processes)
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13 pages, 1949 KiB  
Article
Latitudinal Cline in Chromosome Numbers of Ice Cod A. glacialis (Gadidae) from Northeast Greenland
by Laura Ghigliotti, Jørgen S. Christiansen, Erica Carlig, Davide Di Blasi and Eva Pisano
Genes 2020, 11(12), 1515; https://doi.org/10.3390/genes11121515 - 18 Dec 2020
Cited by 6 | Viewed by 2786
Abstract
The ice cod Arctogadus glacialis (Peters, 1872) is one of the few fish species endemic to the Arctic. With a circumpolar distribution, the species is confined to the fjords and shelves of the Arctic seas. Biological information on A. glacialis is scarce, with [...] Read more.
The ice cod Arctogadus glacialis (Peters, 1872) is one of the few fish species endemic to the Arctic. With a circumpolar distribution, the species is confined to the fjords and shelves of the Arctic seas. Biological information on A. glacialis is scarce, with genomic information restricted to microsatellites. Within the frame of the TUNU-Programme: Arctic Ocean Fishes—Diversity, Adaptation and Conservation, we studied A. glacialis at the chromosomal level to explore fish diversity and evolutionary aspects. The analysis of over 50 individuals from the Northeast Greenland fjords between latitudes 71°09′ N and 76°42′ N revealed a remarkable intraspecific diversity epitomized by chromosome numbers spanning from 28 to 33, the occurrence of putative B chromosomes, and diversified patterns of distribution of heterochromatin and rDNAs. The number of B chromosomes followed a latitudinal gradient from 0–2 in the north to 2–5 in the south. Considering the benthic and rather stationary life history of this species, the observed chromosomal differences might have arisen independently, possibly driven and/or fostered by the dynamics of repetitive sequences, and are being fixed in relatively isolated fjord populations. The resulting latitudinal cline we observe today might have repercussions on the fate of local populations facing the ongoing climate-driven environmental changes. Full article
(This article belongs to the Special Issue Fish Cytogenetics: Present and Future)
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20 pages, 5699 KiB  
Article
Evaluation of the Impact of Climate Change on Runoff Generation in an Andean Glacier Watershed
by Rossana Escanilla-Minchel, Hernán Alcayaga, Marco Soto-Alvarez, Christophe Kinnard and Roberto Urrutia
Water 2020, 12(12), 3547; https://doi.org/10.3390/w12123547 - 17 Dec 2020
Cited by 22 | Viewed by 4944
Abstract
Excluding Antarctica and Greenland, 3.8% of the world’s glacier area is concentrated in Chile. The country has been strongly affected by the mega drought, which affects the south-central area and has produced an increase in dependence on water resources from snow and glacier [...] Read more.
Excluding Antarctica and Greenland, 3.8% of the world’s glacier area is concentrated in Chile. The country has been strongly affected by the mega drought, which affects the south-central area and has produced an increase in dependence on water resources from snow and glacier melting in dry periods. Recent climate change has led to an elevation of the zero-degree isotherm, a decrease in solid-state precipitation amounts and an accelerated loss of glacier and snow storage in the Chilean Andes. This situation calls for a better understanding of future water discharge in Andean headwater catchments in order to improve water resources management in glacier-fed populated areas. The present study uses hydrological modeling to characterize the hydrological processes occurring in a glacio-nival watershed of the central Andes and to examine the impact of different climate change scenarios on discharge. The study site is the upper sub-watershed of the Tinguiririca River (area: 141 km2), of which nearly 20% is covered by Universidad Glacier. The semi-distributed Snowmelt Runoff Model + Glacier (SRM+G) was forced with local meteorological data to simulate catchment runoff. The model was calibrated on even years and validated on odd years during the 2008–2014 period and found to correctly reproduce daily runoff. The model was then forced with downscaled ensemble projected precipitation and temperature series under the RCP 4.5 and RCP 8.5 scenarios, and the glacier adjusted using a volume-area scaling relationship. The results obtained for 2050 indicate a decrease in mean annual discharge (MAD) of 18.1% for the lowest emission scenario and 43.3% for the most pessimistic emission scenario, while for 2100 the MAD decreases by 31.4 and 54.2%, respectively, for each emission scenario. Results show that decreasing precipitation lead to reduced rainfall and snowmelt contributions to discharge. Glacier melt thus partly buffers the drying climate trend, but our results show that the peak water occurs near 2040, after which glacier depletion leads to reducing discharge, threatening the long-term water resource availability in this region. Full article
(This article belongs to the Special Issue Whither Cold Regions Hydrology under Changing Climate Conditions)
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18 pages, 4051 KiB  
Review
Review on the Compositional Variation of Eudialyte-Group Minerals in the Ilímaussaq Complex (South Greenland)
by Michael A.W. Marks, Hans G.M. Eggenkamp, Petya Atanasova, Felicitas Mundel, Sascha Kümmel, Matthias Hagen, Thomas Wenzel and Gregor Markl
Minerals 2020, 10(11), 1011; https://doi.org/10.3390/min10111011 - 13 Nov 2020
Cited by 10 | Viewed by 3059
Abstract
We review the compositional variation of eudialyte-group minerals (EGM) from the Ilímaussaq complex in South Greenland. Investigated samples cover all major rock units and associated pegmatites and aplites. The whole data set (>3000 analyses from >250 samples) exhibits variable XMn (0.1–0.5), REE (0.2–1.7 [...] Read more.
We review the compositional variation of eudialyte-group minerals (EGM) from the Ilímaussaq complex in South Greenland. Investigated samples cover all major rock units and associated pegmatites and aplites. The whole data set (>3000 analyses from >250 samples) exhibits variable XMn (0.1–0.5), REE (0.2–1.7 apfu), Nb (0.1–0.4), and Cl contents (0.4–1.6 apfu). Most EGM compositions are Na-rich (13–15 apfu), while deviations to Na-rich but also to Na-poor compositions occur because of a combination of primary features (peralkalinity, water activity) and secondary alteration. During magma evolution, REE contents in EGM cores generally increase and reach their highest contents in the most evolved rock units of the complex. This points to the moderate compatibility of REE in EGM and a bulk D (cEGM/cmelt) value of <1 during magma differentiation. Chlorine contents in EGM cores continuously decrease, and are lowest at the rims of individual crystals, suggesting a continuous decrease of Cl activity in the magmas by large-scale EGM and sodalite extraction during the orthomagmatic stage and water enrichment during the late-magmatic stage. The overall variations of XMn across stratigraphy are only minor and likely influenced by the co-crystallization of sodic pyroxene and amphibole (c.f. aegirine, arfvedsonite) and local phase proportions. Similarly, Nb and Ti contents are influenced by co-crystallizing aenigmatite, rinkite, and others. Their presence buffers Ti and Nb contents to rather constant and low values, while their absence may cause variable enrichment on a local scale. Very low Sr contents (<0.1 apfu) in magmatic EGM from Ilímaussaq are related to the basaltic nature of the parental magmas of the complex, as large-scale plagioclase fractionation occurred prior to the formation of the Ilímaussaq magmas, effectively removing Sr from the system. This is in line with very strong negative Eu anomalies in EGM from Ilímaussaq. Consistently, Sr contents in EGM from alkaline complexes, for which foiditic parental magmas are assumed, are much higher and, in such cases, negative Eu anomalies are generally absent. Full article
(This article belongs to the Special Issue Study of the Eudialyte Group Minerals)
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23 pages, 3524 KiB  
Article
Changes in Halogen (F, Cl, Br, and I) and S Ratios in Rock-Forming Minerals as Monitors for Magmatic Differentiation, Volatile-Loss, and Hydrothermal Overprint: The Case for Peralkaline Systems
by Hans G.M. Eggenkamp, Michael A.W. Marks, Petya Atanasova, Thomas Wenzel and Gregor Markl
Minerals 2020, 10(11), 995; https://doi.org/10.3390/min10110995 - 10 Nov 2020
Cited by 10 | Viewed by 3582
Abstract
We determined the halogen (F, Cl, Br, and I) and sulfur (S) concentrations in Cl-rich rock-forming minerals from five peralkaline complexes. We investigated sodalite (N = 42), eudialyte-group minerals (N = 84), and tugtupite (N = 8) from representative rock samples derived from [...] Read more.
We determined the halogen (F, Cl, Br, and I) and sulfur (S) concentrations in Cl-rich rock-forming minerals from five peralkaline complexes. We investigated sodalite (N = 42), eudialyte-group minerals (N = 84), and tugtupite (N = 8) from representative rock samples derived from Ilímaussaq (South Greenland), Norra Kärr (Sweden), Tamazeght (Morocco), Lovozero, and Khibina (Russian Federation). Taken together, sodalite and eudialyte-group minerals dominate the Cl and Br budget of the investigated rocks. For F, however, several other phases (e.g., amphibole, fluorite, villiaumite, and minerals of the rinkite group and the apatite supergroup) are additional sinks, and parts of the S may be scavenged in generally rare sulfides. The investigated minerals contain Cl at the wt.% level, F and S concentrations are in the hundreds to thousands of µg/g-range, Br is less common (0.2–200 µg/g) and I is rare (mostly well below 1 µg/g). Normalized to Cl, sodalite prefers Br relative to eudialyte-group minerals, while F is always enriched in the latter. Our data show that both F and S may represent important components in eudialyte-group minerals, sometimes at similar levels as Cl, which normally dominates. Sulfur reveals redox-dependent behavior: Under reduced crystallization conditions, S is more compatible in eudialyte-group minerals (EGM) than in sodalite, which flips to the opposite under water-rich and presumably more oxidized conditions. We investigate the applicability of F/Cl, Br/Cl, and S/Cl ratios in these minerals in peralkaline systems to better understand the interplay of magmatic differentiation, fluid loss and hydrothermal overprint. Similar to apatite in metaluminous systems, fractionation of sodalite, and eudialyte-group minerals in peralkaline magmas leads to decreasing Br/Cl ratios. The data presented in this study bear implications for the mineral chemistry and compositional variation of sodalite and especially EGM in general. Volatile components in EGM that are not normally considered, such as F and S, can reach concentrations of thousands of µg/g. Especially in the case of F, with its low atomic weight, the results obtained in this study indicate that it is very significant for formulae calculations, neutral charge-balance, and similar aspects at such concentration levels. This study demonstrates that halogen contents and ratios are sensitive monitors for a variety of processes in magmatic-hydrothermal systems, including magmatic fractionation, volatile loss, and fluid–rock interaction. Full article
(This article belongs to the Special Issue Study of the Eudialyte Group Minerals)
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