Search Results (1,975)

To overcome the limitations imposed by the intermittent nature of sunlight in photocatalytic applications, this research constructs a round-the-clock purification system. We integrated an optimized S-scheme CoFe₂O₄/BiVO₄ (CFO/BV) heterojunction (synthesized via ultrasonic self-assembly at a 0.5:0.5 ratio) with a thermal energy storage (TES) unit consisting of SiO₂-encapsulated Na₂SO₄·10H₂O phase change materials (PCMs). Comprehensive characterization techniques, including XRD, HRTEM, UV-Vis DRS, EPR, and DSC, confirmed the successful formation of the interface, a broadened visible-light response (λ > 650 nm), efficient radical production, and a high latent heat storage capacity (>200 J/g). Under simulated solar irradiation, the composite exhibited superior performance, degrading 98% of the Rhodamine B within 6 h (k = 0.00994 min⁻¹), significantly surpassing single-component counterparts. More importantly, during the subsequent 12 h dark period, the heat released from the PCM maintained the reaction temperature above 35 °C, driving a 64% degradation efficiency via a thermocatalytic pathway. The system demonstrated robust stability (>90% efficiency after five cycles), excellent magnetic recoverability (98%), and high tolerance to saline textile wastewater (<10% activity loss). Furthermore, Life Cycle Assessment (LCA) indicated a 40% reduction in energy consumption compared to conventional UV/TiO₂ processes, highlighting a sustainable strategy for continuous wastewater remediation through synergistic photocatalysis and thermocatalysis. Full article

The growing use of integrated circuits has made it essential to assess and minimize the environmental impacts of these systems. As most integrated circuits are manufactured on electronic-grade silicon (EG Si) wafers, the first step is to obtain reliable, consistent and complete life cycle inventory (LCI) data on their production. This work proposes an update to the LCI of EG Si wafers with recent data available for solar-grade silicon (SoG Si) wafers. In addition, as thickness, shape and purity differ greatly between SoG and EG Si wafers, an adaptation to the manufacturing process’s LCI has been made. Full article

This paper presents the design and analysis of solar systems for agricultural applications and the sustainable energy supply of villages, based on a case study of a rural settlement comprising 30 households. The village energy demand is quantified through a detailed assessment of hourly load profiles for daytime and nighttime operation, identifying peak loads and total daily energy consumption. Energy usage patterns are established for residential buildings, agricultural water pumping, public lighting, healthcare facilities, and commercial services. To meet these energy requirements sustainably, a 60 kW photovoltaic (PV) system is proposed in combination with a solar thermal water heating system designed to supply domestic and agricultural hot water. This study details the design methodology and simulation of the solar thermal system, including heat transfer modeling and system dimensioning. MATLAB (V.22b) simulations are conducted to evaluate system performance, covering PV energy generation, battery charge–discharge cycles, and thermal behavior over a 24 h period. Comparative analyses of standalone PV, hybrid PV/T, and combined PV and solar thermal configurations demonstrate that separate PV and thermal systems provide superior cost-effectiveness, operational reliability, and reduced maintenance requirements. The results confirm the technical feasibility, economic viability, and environmental benefits of solar-based solutions for rural electrification and agricultural applications. The results indicate that the analyzed rural settlement has an estimated daily electricity demand of approximately 590 kWh. Based on this demand, a 60 kW photovoltaic system was selected to ensure sufficient daytime electricity production while also allowing battery charging for nighttime consumption. In addition, the solar thermal system can increase the water temperature from approximately 10 °C to 55–80 °C, depending on solar irradiance conditions. The combined PV and solar thermal configuration demonstrates the potential to provide a reliable and sustainable energy solution for rural off-grid communities. Full article

Perovskite solar cells (PSCs) are approaching large-scale deployment, yet short lifetimes and end-of-life risks make circular strategies essential. Here we propose a time-resolved Sustainability Benefit Ratio (SBR), a dimensionless indicator that aggregates (i) physically accounted greenhouse-gas emissions/avoidance and (ii) monetized life-cycle costs converted to CO₂-equivalent via an economic carbon-intensity coefficient (CC), enabling a unified assessment of environmental performance and economic burdens over time. This work highlights design for remanufacturing as a key enabler of circular PSC deployment. Using an industrially relevant carbon-based PSC architecture designed for remanufacturing, we simulate multi-cycle operation under periodic remanufacturing and repeated new manufacturing, and derive an analytic steady-state limit, SBR_ss. Remanufacturing markedly increases long-run circular value relative to renewal replacement under realistic lifetimes, while conventional payback economic indicators diverge in timing, motivating an explicit bridge between environmental payback and economic feasibility. We therefore introduce a circular value weighting factor β applied only to CC-converted terms, where β = 0 recovers a purely physical CO₂-based benefit-to-burden ratio, and β-sweeps transparently represent stakeholder-dependent emphasis on valuation-weighted burdens/credits. Finally, feasibility-constrained design maps and Bayesian optimization demonstrate that SBR_ss can serve as a practical objective function to efficiently explore economically viable remanufacturing specifications and identify dominant design levers governing circular value. Full article

Artificial intelligence (AI) is increasingly applied to the design and optimization of solar thermal collectors, particularly in the development of selective absorber coatings. This systematic review analyzes recent advances (2020–2026) in AI-driven modeling, optimization, and sustainability strategies for solar thermal technologies following the PRISMA 2020 methodology. The results indicate that current research is largely dominated by Artificial Neural Networks and metaheuristic algorithms, mainly focused on short-term performance prediction and system-level optimization. However, durability, degradation mechanisms, and life-cycle sustainability metrics remain significantly underrepresented in AI-assisted design frameworks. From a materials perspective, recent studies highlight the emergence of multifunctional absorber surfaces, including thermochromic, self-cleaning, and multilayer coatings, often combined with AI-enabled monitoring and digital twin approaches. In addition, sustainable processing routes such as green sol–gel synthesis and low-temperature deposition show strong potential for reducing environmental impact when integrated with AI-based optimization. Nevertheless, the holistic integration of AI with sustainability metrics at the early design stage remains limited. Future research should therefore focus on hybrid and physics-informed AI frameworks capable of simultaneously addressing performance, durability, economic viability, and environmental impact in solar thermal collector design. Full article

Perovskite solar cells (PSCs) have rapidly evolved into one of the most promising photovoltaic technologies, achieving power conversion efficiencies comparable to established silicon devices while offering unique advantages such as low weight, mechanical flexibility, and low-temperature, solution-based manufacturing. These attributes, combined with recently demonstrated tolerance to high-energy particle irradiation, position PSCs as compelling candidates for next-generation space power systems. This perspective work summarizes recent advances in PSC development for space environments, focusing on their behaviour under key stressors such as radiation (e.g., electrons, protons, gamma rays, and neutrons), ultraviolet exposure, extreme thermal cycling, and ultra-high vacuum. Progress in material design, device architecture, self-healing mechanisms, and encapsulation strategies is discussed, along with early in-orbit and suborbital demonstrations. Remaining challenges, including long-term stability, encapsulation reliability, large-area scalability, and the need for standardized space-qualification protocols, are also outlined. Indeed, PSCs represent a compelling opportunity for next-generation space photovoltaics, provided that targeted materials and engineering solutions address critical issues of encapsulation and durability under combined stressors to ensure reliable operation in harsh extraterrestrial conditions. Full article

The integration of thermoelectric modules (TEMs) into renewable energy systems represents a critical technological frontier for global energy efficiency. This review systematically analyzes the scientific output in the field, which has experienced accelerated growth over the last decade, reaching a historical peak in publications between 2023 and 2024. Geographically, research is led by China, Iran, Turkey, and India. Regarding sectoral distribution, the analysis reveals that solar energy dominates applications, divided into solar thermal (25.53%) and photovoltaics (23.40%), followed by biomass (21.28%) and geothermal energy (17.02%), while ocean energy (12.77%) remains the least developed area. Despite the surge in scientific interest, the results confirm a significant methodological gap: 72.34% of the literature relies exclusively on pure simulations and numerical modeling, whereas only 27.66% incorporates experimental validation. This theoretical dependence translates into a lack of data regarding long-term operational reliability; consequently, mechanical analysis indicates that performance degradation becomes critical after the first 4000 cycles of operation, resulting in an 18% power loss. It is concluded that closing the gap toward commercial scale requires a transition from idealized modeling toward polygeneration schemes and thermal coupling designs that mitigate cyclic mechanical stress. This work provides a synthesis that serves as a roadmap for future engineering implementations at the energy-thermal management nexus. Full article

Agrivoltaic systems integrate solar electricity generation with agricultural production on the same land and have emerged as a promising strategy to address land-use conflicts between food and energy systems. This PRISMA-based systematic review synthesizes evidence from 249 peer-reviewed studies published between 2010 and 2025, applying an integrated three-dimensional framework that simultaneously examines technical efficiency, environmental sustainability, and institutional governance. The results show that agrivoltaic systems consistently achieve superior land-use performance, with Land Equivalent Ratio values typically ranging between 1.2 and 1.8, indicating 20–80% greater territorial efficiency than separate agricultural and photovoltaic systems. In water-stressed regions, reported improvements in water-use efficiency commonly reach 15–30%, while life-cycle assessments indicate substantial reductions in greenhouse gas emissions and other environmental impacts. The integrated analysis also reveals important design-dependent trade-offs related to panel density, crop selection, and local agroclimatic conditions. Despite their demonstrated technical and environmental maturity, the large-scale deployment of agrivoltaic systems remains constrained by institutional barriers, including the lack of dedicated regulatory frameworks, fragmented agricultural and energy policies, and the strong geographical concentration of research in the Global North, with limited evidence from Latin America and other regions of the Global South. Overall, the findings indicate that agrivoltaic systems represent a credible component of integrated land-use and energy transition strategies, but their responsible scaling will depend primarily on advances in governance, policy alignment, and context-specific system design. Full article

SrTiO₃ has attracted considerable attention owing to its favorable electronic structure and chemical stability among various semiconductor photocatalysts. However, its practical application is hindered by a wide bandgap and rapid recombination of photogenerated charge carriers. Herein, we report the fabrication of a SrTiO₃/carbon quantum dot (CQD) heterojunction via a two-step hydrothermal method for efficient CO₂-to-CH₄ photocatalysis, a strategy that circumvents the need for high-temperature treatment and noble metals. TEM images revealed well-defined lattice fringes and intimate interfacial contact between SrTiO₃ and CQDs, suggesting efficient charge transfer pathways. Optical measurements confirmed that CQD modification extends the visible-light absorption range of SrTiO₃ to 420 nm while significantly enhancing charge separation efficiency. The SrTiO₃/CQDs composite with 10 wt% CQD loading exhibited optimal activity, achieving a CH₄ evolution rate of 1.16 μmol·g⁻¹·h⁻¹—16.3 times higher than that of pristine SrTiO₃. Mechanistic investigations demonstrate that CQDs serve as efficient electron reservoirs, facilitating interfacial charge transfer and suppressing the recombination of photogenerated charge carriers. The catalyst maintained stable performance over four consecutive cycles, confirming its structural robustness and reusability. This work demonstrates that CQD modification effectively enhances the visible-light response and charge separation efficiency of SrTiO₃, offering a viable strategy for designing high-performance photocatalysts toward solar fuel production. Full article

This study develops and optimizes a hybrid plant that couples a recompression sCO₂ Brayton cycle to a central-tower particle receiver with a bottoming Organic Rankine Cycle (ORC), including environmental and exergy balances. The two scenarios revealed Pareto points that raised the exergy efficiency to 0.65 in winter and reduced the fuel flow to 15 kg/s. Scenario number two achieves an overall thermal efficiency of 0.50 with total daily emissions of 2520 t CO₂ and 2850 kg NO_x, enabling nearly constant net power. Exergy destruction is concentrated in the high-temperature recuperator (HTR) and ORC turbines (27% each) and the ORC condenser (25%). Compared to a non-optimized baseline, the best solutions increased the ORC and Brayton efficiencies by 6.8–12.66% and 33.4–33.5%, respectively; cut gas-turbine power by 34% and ORC power to 10%; and lowered daily CO₂ and NO_x emissions by 52%. The gains stem from the coordinated adjustments of key levers: lower gas-turbine inlet temperature (about 10%), reduced Brayton mass flow (23%), and tuned ORC turbine inlet pressure. Full article

Polymer–ceramic hybrid composites are emerging as attractive candidates for lightweight, corrosion-resistant absorber components in solar thermal collectors; however, their adoption is constrained by the intrinsically low thermal conductivity of polymers, processing-induced anisotropic heat transport, interfacial thermal resistance at tube/laminate joints, and durability challenges under outdoor exposure. This review provides a collector-centered synthesis of polymer–ceramic hybrid materials, emphasizing the translation of composite properties into collector-level outcomes rather than conductivity enhancement alone. A structure–property–performance mapping approach is presented to connect directional thermal conductivity ((k_in-plane), (k_perp)), thermal diffusivity, heat capacity, coefficient of thermal expansion, and service temperature with collector performance parameters such as heat removal effectiveness, overall heat losses, and stagnation behavior. Ceramic fillers (e.g., boron nitride, aluminum nitride, silicon carbide, alumina) are examined for stable conduction-network formation, coating compatibility, and long-term reliability, while carbon fillers (graphite, graphene nanoplatelets, carbon nanotubes) are evaluated for combined heat spreading and solar absorption benefits, with attention to emissivity penalties. Hybrid ceramic–carbon architectures and multilayer absorber designs are identified as the most promising routes to balance thermal transport, optical selectivity (high solar absorptance and low thermal emittance), manufacturability, and durability under UV, humidity, and thermal cycling. Full article

This study explores a solar-driven hybrid desalination approach developed for Saudi Arabian climatic conditions, combining adsorption desalination (AD) based on a silica gel/CaCl₂ composite with an ejector (EJ) and a HDH system. The proposed integration aims to enhance vapor utilization and reuse condenser heat to generate additional distillate. Two operating modes are examined, including a productivity-focused strategy that activates evaporator/condenser heat recovery (HR) when cooling is not required. Compared to raw silica gel (SG), the composite adsorbent improves adsorption cycle performance, raising the COP from about 0.38–0.43 to 0.55–0.63, and increasing SCP from roughly 130–240 W/kg to 320–675 W/kg. Without HR, the full AD–EJ–HDH system achieves SDWP of 52–100 m³/ton·day with GOR of 2.40–2.75 over the year. In HR-enabled operation, SDWP increases to 81–140 m³/ton·day and GOR rises to 2.7–2.95, reflecting stronger internal heat reuse and improved vapor management. Techno-economic results show that the solar-driven unit cost for AD–EJ–HDH decreases from winter values (2.7–2.9 $/m³) to a minimum around June (1.53 $/m³), while waste heat operation reduces the cost further to 0.49 $/m³ in June (rising to ~0.76–0.80 $/m³ in winter). With HR, the full AD–HR–EJ–HDH reaches around 1.44 $/m³ (solar, June) and 0.38–0.40 $/m³ (waste heat, summer), confirming the advantage of desalination-focused HR operation when cooling is not required. Finally, compared with SWRO, the AD–HR–EJ–HDH configuration delivers an approximately 90% lower carbon footprint on the same environmental assessment basis. The study highlights the environmental benefit of the intensified SG/CaCl₂ hybrid configuration. Full article

Two-dimensional (2D) materials are competitive in a diverse range of areas, spanning from electronic and optoelectronic devices to wearable devices, due to their unique physical and chemical characteristics, as well as remarkable flexibility. As a typical 2D material, lead iodide (PbI₂), featuring a high atomic number and tunable band gap, has been extensively studied in many applications of electroluminescent (EL) devices, photodetectors, and perovskite solar cells. However, high-performance PbI₂-based photodetectors remain a challenge. Herein, we present a high-performance flexible photodetector based on 2D layered PbI₂ nanoplates, which were synthesized via a straightforward air sublimation method. The PbI₂-based photodetector exhibits an excellent photoresponse and the highest responsivity peaks at 34 A/W at 405 nm, together with an ultrahigh transient switching on/off current ratio of 10⁷. Due to a low dark current (10⁻¹⁴ A), the device exhibits an extremely low noise level (<10⁻²⁶ A²Hz⁻¹) and acceptable detectivity (2 × 10¹⁰ Jones). Furthermore, remarkable mechanical flexibility was observed in the device on a PET substrate, preserving both its electrical conductance and photoresponse stability after 560 bending cycles. Finally, high-resolution imaging applications were implemented under a 100 Hz modulated light signal. This work highlights the superior optoelectrical properties of 2D PbI₂ growth by the in-air sublimation method and proves its promising future in flexible and wearable optoelectronic devices. Full article

Decarbonizing ocean-going shipping requires decision-grade environmental evidence for propulsion transitions, yet conventional LCA relies on static inventories that inadequately represent dynamic operations and route-dependent renewable generation. This study evaluates well-to-wake (WtW) Global Warming Potential (GWP) for two large container ships operated by a Korean company under four scenarios: conventional diesel main engine, diesel–electric with onboard generator, full battery-electric supplied by shore electricity from the Republic of Korea grid, and battery-electric with a route-resolved solar PV system. A Live-LCA (LLCA) framework couples LCI data with MATLAB/Simulink power and propulsion modeling driven by actual operating profiles and route environmental conditions to generate operational inventories for impact calculation. Diesel–electric operation increases annual WtW GWP by over 26% for both ships versus the baseline of a conventional diesel main engine, whereas shore-electric battery operation is able to reduce WtW GWP by around 40% versus diesel–electric. With limited PV installation, additional reductions are marginal. Depending on electricity profile, it can increase battery-electric GHG emissions by approximately 27%, highlighting sensitivity to electricity evolution. Overall, electric propulsion delivers climate benefits only when paired with low-carbon electricity, and LLCA enables operationally and route-grounded LCA for large container ships. Full article

With Zr-doped ceria (Ce_0.6Zr_0.4O₂, CZ40) discovered as a promising redox material, metal oxide (MO)-based thermochemical cycles offer a feasible technique for CO₂ splitting (CDS) at lower temperatures. There are currently few thorough thermodynamic efficiency evaluations available, despite experimental validation of its redox efficacy. The two-step CZ40-driven CDS cycle is modeled in this study, and experimental data are used to perform the efficiency analysis. Solar-to-fuel efficiency increases from 0.74% to 1.00% as a result of reducing solar heat demand from 434.05 kW to 322.17 kW by boosting gas-to-gas heat recuperation from 0.0 to 0.3. Full article