Search Results (162)

This study looks at the effect of surface conditioners hydrofluoric acid (HFA), Ytterbium fibre laser (YFL), and Hydroxyapatite nanoparticles (HANPs) on the surface roughness (Ra) and shear bond strength (SBS) of different viscosity resin cements to lithium disilicate glass ceramic (LDC). A total of 78 IPS Emax discs were prepared and categorized into groups based on conditioning methods. Group 1 HFA–Silane (S), Group 2: YFL-S, and Group 3: HANPs-S. A scanning electron microscope (n = 1) and profilometer (n = 5) were used on each conditioned group for the assessment of surface topography and Ra. A total of 20 LDC discs for each conditioned group were subsequently categorized into two subgroups based on the application of high- and low-viscosity dual-cured resin cement. SBS and failure mode were assessed. ANOVA and post hoc Tukey tests were employed to identify significant differences in Ra and SBS among different groups. LDC conditioned with HFA-S, HANPs-S, and YFL-S demonstrated comparable Ra scores (p > 0.05). Also, irrespective of the type of conditioning regime, the use of low-viscosity cement improves bond values when bonded to the LDC. LDC treated with YFL-S and HANPs-S can serve as an effective substitute for HFA-S in enhancing the Ra and surface characteristics of LDC. The low-viscosity resin cement demonstrated superior performance by achieving greater bond strength. Full article

The nanostructural features of a mechanically alloyed Sb-doped (Ti_0.4Zr_0.6)_0.7Hf_0.3NiSn thermoelectric (TE) Half-Heusler (HH) compound were addressed using Transmission Electron Microscopy (TEM) coupled with Energy Dispersive Spectroscopy measurements and Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. The EXAFS measurements at the Ni-K, Sn-K, Zr-K, and Hf-L₃-edge were implemented in an effort to reveal the influence of Hf and Zr incorporation into the crystal with respect to their previously measured TE properties. The substitution of Ti by Hf and Zr is expected to yield local lattice distortions due to the different atomic sizes of the dopants or/and electronic charge redistribution amongst the cations. However, the material is characterised by a high degree of crystallinity in both the short and long-range order, on average, and the nominal stoichiometry is identified as (Zr_0.42Hf_0.30Ti_0.28)NiSn_0.98Sb_0.02. The synergistic effect of minimization of extended structural defects or lattice distortions and considerable alloying-induced point defect population contributes to the improved TE properties and leads to the previously reported enhancement of the figure of merit of the mixed HHs. Full article

The effects of cation substitution are the main emphasis of this investigation into the structural, mechanical, electronic, and optical properties of double perovskites K₂AgSbBr₆ and K₂NaScBr₆. Outwardly favorable tolerance and octahedral factors and negative formation energy confirmed structural stability and thermodynamic feasibility. Mechanical analysis showed that K₂AgSbBr₆ possesses greater volumetric stability and rigidity, while K₂NaScBr₆ exhibits greater ductility and isotropic characteristics. The electronic properties determined based on density functional theory (DFT) calculations indicate that K₂AgSbBr₆ has an indirect bandgap of 0.857 eV, making it suitable for applications using visible light, and K₂NaScBr₆ has a direct bandgap of 3.107 eV, making it ideal for UV-specific technologies. Optical analyses demonstrate complementary characteristics, particularly in terms of the dielectric function, absorption, reflectivity, energy loss function, refractive index, extinction coefficient, and optical conductivity. K₂AgSbBr₆ exhibits strong visible light absorptivity. Full article

The cubic phase of the high-entropy alloy AgBi_1−xSb_xSe_0.8S_0.6Te_0.6 compound, characterized by the substitution of Sb for Bi in the structure to enhance phonon scattering, has been analyzed for local atomic displacements and electronic structure using a combination of X-ray absorption and X-ray photoelectron spectroscopy techniques. Notably, Ag K-edge and Bi L₃-edge X-ray absorption measurements demonstrate a contraction of bond distances upon substitution due to the smaller size of Sb. Conversely, X-ray photoelectron spectroscopy reveals that, while Ag remains predominantly in the Ag¹⁺ state across all samples, Bi and Sb exhibit a single valence state only for minimal Sb substitution. At higher Sb substitution levels, both Bi and Sb manifest mixed valence states, indicating complex electronic behavior that potentially influences the thermoelectric properties of the system. These findings suggest that optimizing the local structure through Sb substitution can be beneficial in enhancing the material’s thermoelectric performance. Full article

Background/Objectives: Night shift workers (NSWs) are at a high risk of cardiovascular disease (CVD). However, the association between CVD risk factors and lifestyle behavior (sedentary behavior [SB], physical activity [PA], and sleep) is unclear among NSWs. NSWs lead different lifestyles on workdays and leisure days. This study aimed to investigate the association between lifestyle behavior times and CVD risk factors among NSWs during workdays and leisure days using an isotemporal substitution model. Methods: This cross-sectional study included 66 male NSWs. Time spent on lifestyle behaviors was obtained using a tri-axial accelerometer and classified into SB, light-intensity PA, moderate-to-vigorous PA (MVPA), and sleep. Lifestyle behavior times were divided into workdays and leisure days. CVD risk factors were determined based on periodic health checkups. An isotemporal substitution model was used to estimate the effect of replacing one lifestyle behavior with another on CVD risk factors. Results: The lifestyle behavior times differed between workdays and leisure days. On workdays, reallocating 30 min of SB to light-intensity PA was significantly associated with a lower waist circumference. In addition, reallocating sleep to SB or MVPA was significantly associated with higher triglyceride levels. On leisure days, reallocating SB or sleep time to MVPA was significantly associated with lower aspartate aminotransferase levels. Conclusions: Given the difference in the associations between lifestyle behavior times and CVD risk factors among NSWs between workdays and leisure days, NSWs should be mindful of the time spent on SB, PA, and sleep on workdays and leisure days to achieve healthier outcomes. Full article

Low-temperature cracking is a primary failure mode of asphalt pavement. The poker chip test provides a straightforward and efficient approach to simulating the film state of asphalt binders in asphalt structures. By measuring the tensile strength and ultimate tensile strain of the binder film, this test can effectively evaluate the cracking resistance and ductility of asphalt binders. Accordingly, this study employed the poker chip test to analyze the evolutions of low-temperature cracking resistance under various aging levels. To ensure the reliability of tensile strength and ultimate tensile strain, a Pearson correlation analysis was conducted between the two indicators and the traditional low-temperature performance evaluation indicators: stiffness modulus, creep rate, and the Glover-Rowe (G-R) parameter. The results indicate that the tensile strength and ultimate tensile strain of styrene–butadiene–styrene (SBS)-modified asphalt are higher than those of 70# base asphalt at the same aging level. With increasing aging time, the tensile strength of both SBS-modified asphalt and 70# base asphalt increases, while the ultimate tensile strain decreases. Additionally, the tensile strength and ultimate tensile strain are sensitive to changes in asphalt binder types and aging levels. They have a good linear correlation with stiffness modulus and creep rate, with correlation coefficients exceeding 0.9. Due to the distinct characteristics represented, the correlation between the two indicators and the G-R parameter is relatively weaker, with correlation coefficients exceeding 0.7. The findings of this study demonstrate that tensile strength and ultimate tensile strain are effective indicators for assessing the low-temperature performance of asphalt binders. They can serve as substitute indicators of stiffness modulus and creep rate, respectively. Full article

The reactivity of the benzenedithiolate (bdt)-bridged complex [Fe₂(CO)₆(µ-bdt)] with arsine, stibine and phosphine ligands has been studied. The new mono- and disubstituted complexes [Fe₂(CO)₅(EPh₃)(µ-bdt)] (E = As, 1; E = Sb 3) and [Fe₂(CO)₄(EPh₃)₂(µ-bdt)] (E = As, 2; E = Sb, 4) and the previously reported [Fe₂(CO)₄(PPh₂H)₂(µ-bdt)] (5) have been prepared by Me₃NO-initiated carbonyl substitution reactions of [Fe₂(CO)₆(µ-bdt)] with appropriate ligands at 80 °C. Spectroscopic and single-crystal X-ray diffraction studies reveal that in all cases the introduced ligands occupy apical coordination site(s) lying trans to the iron–iron bond. Their electrochemistry has been probed by cyclic voltammetry and selected complexes have been tested as proton reduction catalysts. Monosubstituted complexes 1 and 3 show two irreversible reductions at ca. −1.7 V and −2.0 V, respectively, relative to Fc⁺/Fc, while the disubstituted complexes 2 and 5 show a single irreversible reduction at ca. −2.2 V and −1.84 V, respectively. Complexes 1, 3 and 5 can catalyse electrocatalytic proton reduction in the presence of either p-toluene sulfonic acid (TsOH) or trifluoroacetic acid (CF₃CO₂H). Full article

Objectives: This study assessed associations of total and mental-activity-based sedentary behavior (SB) with the risk of being overweight or obese in adults. The role of sex and SB patterns and the effects of statistically exchanging different mental-activity-based SBs on body mass index (BMI) were explored. Methods: Participants (n = 1154) from the Saudi Post-COVID-19 Sedentary Behavior Survey self-reported demographics, health-related variables, and last-measured body height and weight. BMI was calculated to classify adults as normal weight or overweight/obese. The Sedentary Behavior Questionnaire estimated total and mentally active and passive SB per day, during weekdays, and on weekends. Adjusted logistic regression and isotemporal substitution models assessed the associations of SBs with the risk of being overweight or obese and the effects of displacing mental-activity-based SBs on BMI, respectively. Results: No significant relationships were observed in the overall sample (p > 0.05). Once sex was considered, the risk of being overweight or obese increased between 5.2% and 10.7% for each hour increase in total and mentally active SBs per day and on weekends in men only (p < 0.05 for all). Replacing one hour of mentally active SB with mentally passive SB resulted in non-significant effects on BMI (p > 0.05). Conclusions: These findings reveal the importance of distinguishing between SBs based on mental activity for more optimal obesity outcomes, particularly in men. Importantly, exchanging mental-activity-based SBs does not appear to be an effective behavioral strategy to reduce obesity. Obesity prevention and management plans should target reducing total and mentally active SBs daily and on weekends. Full article

This paper provides a critical analysis of the molecular mechanisms presently used to explain transcriptional strand asymmetries of single base substitution (SBS) signatures observed in cancer genomes curated at the Catalogue of Somatic Mutations in Cancer (COSMIC) database (Wellcome Trust Sanger Institute). The analysis is based on a deaminase-driven reverse transcriptase (DRT) mutagenesis model of cancer oncogenesis involving both the cytosine (AID/APOBEC) and adenosine (ADAR) mutagenic deaminases. In this analysis we apply what is known, or can reasonably be inferred, of the immunoglobulin somatic hypermutation (Ig SHM) mechanism to the analysis of the transcriptional stand asymmetries of the COSMIC SBS signatures that are observed in cancer genomes. The underlying assumption is that somatic mutations arising in cancer genomes are driven by dysregulated off-target Ig SHM-like mutagenic processes at non-Ig loci. It is reasoned that most SBS signatures whether of “unknown etiology” or assigned-molecular causation, can be readily understood in terms of the DRT-paradigm. These include the major age-related “clock-like” SBS5 signature observed in all cancer genomes sequenced and many other common subset signatures including SBS1, SBS3, SBS2/13, SBS6, SBS12, SBS16, SBS17a/17b, SBS19, SBS21, as well as signatures clearly arising from exogenous causation. We conclude that the DRT-model provides a plausible molecular framework that augments our current understanding of immunogenetic mechanisms driving oncogenesis. It accommodates both what is known about AID/APOBEC and ADAR somatic mutation strand asymmetries and provides a fully integrated understanding into the molecular origins of common COSMIC SBS signatures. The DRT-paradigm thus provides scientists and clinicians with additional molecular insights into the causal links between deaminase-associated genomic signatures and oncogenic processes. Full article

Four quaternary Zintl phase thermoelectric (TE) materials belonging to the Ba_1-xEu_xZn₂Sb₂ (x = 0.02(1), 0.04(1), 0.08(1), 0.15(1)) system were successfully synthesized using the molten Pb-flux or the conventional high-temperature reaction methods. Their crystal structures were characterized by both powder and single-crystal X-ray diffraction analyses, and all four isotypic title compounds adopted the orthorhombic BaCu₂S₂-type (Pnma, Z = 4, Pearson code oP20) structure. The radius ratio criterion, based on the cationic and anionic elements (i.e., r₊/r₋), was successfully verified in the title system, as in our previous reports, where r₊/r₋ > 1 for the BaCu₂S₂-type structure. A series of density functional theory calculations were performed using a hypothetical model with the idealized compositions of Ba_0.75Eu_0.25Zn₂Sb₂, and the results were compared with the ternary parental compound BaZn₂Sb₂ to understand the influence of Eu substituents in the Ba_1-xEu_xZn₂Sb₂ system. A similar overall shape of the density of states (DOS) curves and the near-constant DOS values at E_F before and after the cationic substitution suggest only marginal changes in the carrier concentration. Therefore, carrier mobility has a dominant role in rationalizing the observed variations in the electrical transport properties of the title system. Temperature-dependent TE property measurements proved that an increase in the Seebeck coefficient S and a decrease in electrical conductivity σ were observed as the Eu substituents gradually increased in the Ba_1-xEu_xZn₂Sb₂ system, although the overall S and σ values were lower than those in the parental compound BaZn₂Sb₂. The thermal conductivities of these title compounds were successfully lowered by phonon scattering, but due to the overall smaller electrical transport properties, the observed maximum ZT was 0.49 at 773 K for Ba_0.98(1)Eu_0.02Zn₂Sb₂. Full article

The newly discovered Erdaodianzi gold deposit in southern Jilin Province, Northeast China, is located in the eastern segment of the northern margin of the North China Craton (NCC). It is a large-scale gold deposit with reserves of 38.4 tons of gold. Gold mineralization in the ore district primarily occurs in gold-bearing quartz–sulfide veins. The gold ore occurs mainly as vein, veinlet, crumby, and disseminated structures. The hydrothermal process can be divided into three stages: stage I, characterized by quartz, arsenopyrite, and pyrite; stage II, featuring quartz, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, sphalerite, and native gold; and stage III, consisting of quartz, pyrite, sphalerite, galena, electrum (a naturally occurring Au–Ag alloy), and calcite. Electrum and native gold primarily occur within the fissures of the polymetallic sulfides. To determine the enrichment mechanism of the Au element and the genetic types of ore deposits in the Erdaodianzi deposit, sourcing in situ trace element data, element mapping and sulfur isotope analysis were carried out on sphalerites from different stages using LA-ICP-MS. Minor invisible gold, in the form of Au–Ag alloy inclusions, is present within sphalerites, as revealed by time-resolved depth profiles. The LA-ICP-MS trace element data and mapping results indicate that trivalent or quadrivalent cations, such as Sb³⁺ and Te⁴⁺, exhibit a strong correlation with Au. This correlation can be explained by a coupled substitution mechanism, where these cations (Sb³⁺ and Te⁴⁺) replace zinc ions within the mineral structure, resulting in a strong association with Au. Similarly, the element Pb exhibits a close relationship with Au, which can be attributed to the incorporation of tetravalent cations like Te⁴⁺ into the mineral structure. The positive correlation between Hg and Au can be attributed to the formation of vacancies and defects within sphalerite, caused by the aforementioned coupled substitution mechanism. A slight positive relationship between Au and other divalent cations, including Fe²⁺, Mn²⁺, and Cd²⁺, may result from these cations simply replacing Zn within the sphalerite lattice. The crystallization temperatures of the sphalerite, calculated via the Fe/Zn ratio, range from 238 °C to 320 °C. The δ³⁴S values are divided into two intervals: one ranging from −1.99 to −1.12‰ and the other varying from 10.96 to 11.48‰. The sulfur isotopic analysis revealed that the ore-forming materials originated from magmatic rock, with some incorporation of metamorphic rock. Comparative studies of the Erdaodianzi gold deposit and other gold deposits in the Jiapigou–Haigou gold belt have confirmed that they are all mesothermal magmatic–hydrothermal lode gold deposits formed at the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate during the Middle Jurassic. The Jiapigou–Haigou gold belt extends northwest to the Huadian area of Jilin province. This suggests potential for research on gold mineralization in the northwest of the belt and indicates a new direction for further gold prospecting in the region. Full article

Phase-change random access memory (PcRAM) faces significant challenges due to the inherent instability of amorphous Ge₂Sb₂Te₅ (GST). While doping has emerged as an effective method for amorphous stabilization, understanding the precise mechanisms of structural modification and their impact on material stability remains a critical challenge. This study provides a comprehensive investigation of elastic strain and stress in crystalline lattices induced by various dopants (C, N, and Al) through systematic measurements of film thickness changes during crystallization. Through detailed analysis of cross-sectional electron microscopy data and theoretical calculations, we reveal distinct behavior patterns between interstitial and substitutional dopants. Interstitial dopants (C and N) generate substantial elastic strain energy (~9 J/g) due to their smaller atomic radii (0.07–0.08 nm) and ability to occupy spaces between lattice sites. In contrast, substitutional dopants (Al) produce lower strain energy (~5 J/g) due to their similar atomic radius (0.14 nm) to host atoms. We demonstrate that N doping achieves higher elastic strain energy compared to C doping, attributed to its preferential formation of Ge-N bonds and resulting lattice distortions. The correlation between dopant properties, structural features, and induced strain energy provides quantitative insights for optimizing dopant selection. These findings establish a fundamental framework for understanding dopant-induced thermodynamic stabilization in GST materials, offering practical guidelines for enhancing the reliability and performance of next-generation PcRAM devices. Full article

Discovered within the North Himalayan Metallogenic Belt (NHMB), the Zhaxikang Pb–Zn–Ag–Sb deposit stands as the sole super-large scale ore deposit in the region. This deposit holds significant quantities of Pb and Zn (2.066 million tons at 6.38% average grade), Ag (2661 tons at an average of 101.64 g/t), and Sb (0.235 million tons at 1.14% average grade), making it one of China’s foremost Sb–polymetallic deposits. Stibnite represents the main carrier of Sb in this deposit and has been of great attention since its initial discovery. However, the trace element composition of stibnite in the Zhaxikang deposit has not yet been determined. This study carried out an analysis of the distribution patterns and substitution processes of trace elements within stibnite gathered from the Zhaxikang deposit, aiming to provide crucial information on ore-forming processes. Utilizing high-precision laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we discovered that the studied stibnite is notably enriched in arsenic (~100 ppm) and lead (~10 ppm). Furthermore, the notably consistent time-resolved profiles suggest that elements such as Fe, Cu, As, In, Sn, Hg, and Pb predominantly exist as solid solutions within stibnite. Consequently, it is probable that the enrichment of Cu, Pb, and Sn in stibnite is due to isomorphic substitution reactions, including 3Pb²⁺↔2Sb³⁺, Cu⁺ + Pb²⁺↔Sb³⁺, and In³⁺ + Sn³⁺↔2Sb³⁺. Apart from that, Mn, Pb, and Hg with the spiky signals indicate their existence within stibnite as micro-inclusions. Overall, we found that the trace element substitutions in stibnite from the Zhaxikang Pb–Zn–Ag–Sb deposit are complicated. Incorporations of trace elements such as Pb, Cu, and In into stibnite are largely influenced by a variety of factors. The simple lattice structure and constant trace elements in studied stibnite indicate a low-temperature hydrothermal system and a relatively stable process for stibnite formation. Full article

Mg₃Sb₂-based materials, part of the Zintl compound family, are known for their low thermal conductivity but face challenges in thermoelectric applications due to their low energy conversion efficiency. This study addressed these limitations through first-principles calculations using the CASTEP module in Materials Studio 8.0, aiming to enhance the thermoelectric performance of Mg₃Sb₂ via strategic doping. Density functional theory (DFT) calculations were performed to analyze electronic properties, including band structure and density of states (D.O.S.), providing insights into the influence of various dopants. The semiclassical Boltzmann transport theory, implemented in BoltzTrap (version 1.2.5), was used to evaluate key thermoelectric properties such as the Seebeck coefficient, electrical conductivity, electronic thermal conductivity, and electronic figure of merit (eZT). The results indicate that doping significantly improved the thermoelectric properties of Mg₃Sb₂, facilitating a transition from p-type to n-type behavior. Bi doping reduced the band gap from 0.401 eV to 0.144 eV, increasing carrier concentration and mobility, resulting in an electrical conductivity of 1.66 × 10⁶ S/m and an eZT of 0.757. Ge doping increased the Seebeck coefficient to −392.1 μV/K at 300 K and reduced the band gap to 0.09 eV, achieving an electronic ZT of 0.859 with low thermal conductivity (11 W/mK). Si doping enhanced stability and achieved an electrical conductivity of 1.627 × 10⁶ S/m with an electronic thermal conductivity of 11.3 W/mK, improving thermoelectric performance. These findings established the potential of doped Mg₃Sb₂ as a highly efficient thermoelectric material, paving the way for future research and applications in sustainable energy solutions. Full article

This experiment aimed to evaluate the effects of using sugarcane bagasse (SB) as a substitute for soybean hulls and wheat bran in the diet of pregnant sows on their reproductive performance and gut microbiota. A total of seventy-two primiparous sows were randomly divided into four treatment groups, with eighteen replicates of one sow each. The sows were fed a basal diet supplemented with 0% (CON), 5%, 10%, and 15% SB to replace soybean hulls from day 57 of gestation until the day of the end of the gestation period. The results showed that SB contains higher levels of crude fiber (42.1%) and neutral detergent fiber (81.3%) than soybean hulls, and it also exhibited the highest volumetric expansion when soaked in water (50 g expanding to 389.8 mL) compared to the other six materials we tested (vegetable scraps, soybean hulls, wheat bran, rice bran meal, rice bran, and corn DDGS). Compared with the CON, 5% SB significantly increased the litter birth weight of piglets. Meanwhile, 10% and 15% SB significantly increased the rates of constipation and reduced the contents of isobutyric acid and isovaleric acid in feces. Furthermore, 10% and 15% SB significantly disturbed gut microbial diversity with increasing Streptococcus and decreasing Prevotellaceae_NK3B31-group and Christensenellaceae_R-7-group genera in feces. Interestingly, Streptococcus had a significant negative correlation with isobutyric acid, isovaleric acid, and fecal score, while Prevotellaceae_NK3B31-group and Christensenellaceae_R-7-group had a positive correlation with them. In conclusion, our study indicates that 5% SB can be used as an equivalent substitute for soybean hulls to improve the reproductive performance of sows without affecting their gut microbiota. Full article