Search Results (18)

Additive manufacturing of NiTi shape memory alloys is challenging due to their sensitivity to composition and thermal history. The gap between high-resolution powder-based AM and high-productivity wire-based processes for NiTi remains a challenge. This study investigates the technical feasibility of depositing Ni-rich NiTi (56 wt.% Ni) using a micro gas metal arc-based directed energy deposition (µ-GMA-DED) process with a 300 µm wire. The investigation was conducted on a single-bead, single-layer geometry deposited onto a titanium substrate. The deposited layer exhibited a heterogeneous microstructure with dendritic and eutectic-like regions, where phase analysis revealed a mixture of NiTi and Ni₃Ti intermetallics. Differential scanning calorimetry showed suppression of the martensitic transformation in the as-deposited condition, likely due to the high fraction of non-transformable Ni₃Ti, compositional redistribution during rapid solidification, and potential substrate dilution. The nanoindentation results reflected this heterogeneity, with Young’s modulus ranging from 64 to 151 GPa. While post-deposition heat treatment partially restored the martensitic transformation, these results demonstrate the preliminary feasibility of the µ-GMA-DED process, noting that strict control over chemistry and dilution is required before the route can be applied to functional components. Full article

Volumetric additive manufacturing (VAM) enables layerless and fast printing within seconds. However, print quality remains highly sensitive to the delivered energy. In this study, the effects of visible (460 nm) and ultraviolet (385 nm) projector power were evaluated in a dual-color VAM setup with a CQ/EDAB initiated TEGDMA/BisGMA resin with an o-Cl-HABI inhibitor. Cubes ($6\times 6\times 6.7 {\mathrm{mm}}^3$) were printed under controlled visible and ultraviolet power and exposure times, then evaluated using in situ shadowgraphy, three-dimensional metrology, and confocal microscopy. Higher visible power reduced the polymerization initiation time, but increasing the visible dose rapidly led to over-polymerization, resulting in dimensional growth, corner rounding, and increased surface roughness ($R_a$). The lowest lateral variation was observed at the shortest exposure times, with a maximum error of 1.8%. Ultraviolet illumination did not significantly change initiation time or reduce over-polymerization within the tested intensities and inhibitor concentration ranges. Surface evaluations revealed a periodic line texture with a pattern pitch of approximately 25 μm. By shifting the focal plane and using a low-resolution projector, the pattern pitch increased to about 150 μm. These values were aligned with the ${\mathrm{MTF}}_{50}$ spatial frequencies of each projector at different defocus positions. This study provides useful guidelines for adjusting intensity to achieve high-fidelity VAM printed parts. Full article

The conducted study was focused on the development of a new type of polymer blends intended for additive manufacturing applications, in particular, the material extrusion method (MEX). The developed materials were prepared from recycled poly(ethylene terephthalate) and amorphous copolymers poly(ethylene terephthalate-glycol) (PETG), and poly(cyclohexylenedimethyl terephthalate-glycol) (PCTG). The basic blend systems were additionally modified with POE-g-GMA impact modifier (IM) during the reactive extrusion process. The main aim of the work was to assess the effectiveness of using composite additives and their influence on the mechanical and thermomechanical parameters of the tested systems. To prepare the composites, selected polymer blends were modified with 10% of talc (T) and carbon fibers (CF). The properties evaluation includes the mechanical/thermomechanical testing, thermal analysis and structural observations. The accuracy of printing was measured using optical scanning methods. The test results indicate that even the relatively small amount of the CF filler could lead to a significant increase in tensile modulus from reference 1.6 GPa to 2.9 GPa; the same improvement applies to strength values, where the CF-modified materials reached 45 MPa, compared to the reference 31 MPa. The heat deflection tests (0.455 MPa) after annealing revealed the maximum HDT of around 170 °C for both types of CF-modified materials. The Vicat test results were also favorable for annealed materials. Considering that the Vicat/HDT results after the 3D-printing process usually reach around 70 °C, the performed heat treatment strongly enhanced the heat resistance for most of the prepared blends. The performed studies revealed that for most of the prepared materials, the brittleness was a common drawback for both MEX-printed and injection-molded materials. Full article

Compared with planar layering, the morphology of spatial GMA deposition beads formed by curved layering is influenced by gravity, resulting in asymmetric and complex cross-sections. To quantitatively describe the bead orientation and cross-sectional shape, this study introduces the path inclination angle and path direction angle, along with five characteristic parameters—height, width, eccentricity, upper plumpness, and lower plumpness—using piecewise polynomial fitting for profile modeling. A full-factorial experiment was conducted to establish the relationship between deposition speed, bead spatial orientation, and cross-sectional features. The obtained fitting equation had a mean relative error of less than 2.5%, and an overlapping strategy was proposed to achieve flat, curved GMA layers. The proposed bead characterization method, parameter planning model, and overlap strategy were validated through deposition experiments on cylindrical surfaces without a positioner, providing a foundation for high-precision curved GMA additive manufacturing. Full article

Wire Arc Additive Manufacturing (WAAM) is a process for fabricating metal parts known for its high productivity and material flexibility. However, defects such as overheating, residual stresses, distortions, porosity, and a non-homogeneous microstructure limit its commercial applications. Therefore, the present study aims to analyze the correlation between electrical sensing anomalies in the Gas Metal Arc (GMA) during WAAM and the occurrence of microscopic defects caused by external contamination. To achieve this, experiments were conducted to fabricate walls using WAAM with controlled contaminant introduction. Simultaneously, electrical arc data, specifically voltage and current, were segmented and acquired during the wall deposition process. Metallographic analysis confirmed the presence of microscopic defects or changes in the solidification patterns in regions with contaminant inclusion, distinguishing them from other areas of the analyzed samples. Similarly, the contaminations were proven to cause anomalies in attributes associated with the electrical arc. Therefore, this approach confirms the criticality of electrical arc monitoring in WAAM, as it demonstrates that anomalies in the electrical arc could lead to microstructural consequences. Full article

The main objective of this work was to propose and evaluate a methodology for shielding-gas selection in additive manufacturing assisted by wire arc additive manufacturing (WAAM) with an austenitic stainless steel as feedstock. To validate the proposed methodology, the impact of multi-component gases was valued using three different Ar-based blends recommended as shielding gas for GMA (gas metal arc) of the target material, using CMT (cold metal transfer) as the process version. This assessment considered features that potentially affect the building of the case study of thin walls, such as metal transfer regularity, deposition time, and geometrical and metallurgical characteristics. Different settings of wire-feed speeds were conceived to maintain a similar mean current (first constraint for comparison’s sake) among the three gas blends. This approach implied different mean wire-feed speeds and simultaneously forced a change in the deposition speed to maintain the same amount of material deposited per unit of length (second comparison constraint). The composition of the gases affects the operational performance of the shielding gases. It was concluded that by following this methodology, shielding-gas selection decision-making is possible based on the perceived characteristics of the different commercial blends. Full article

Cold wire gas metal arc (CWGMA) additive manufacturing (AM) is more productive and beneficial than the common electric arc processes currently used in wire arc additive manufacturing (WAAM). Adding a non-energised wire to the gas metal arc (GMA) system makes it possible to overcome a process limitation and decouple the energy input from the material feed rate. Two novel process control methods were proposed, namely, arc power and travel speed control, which can keep the required geometry accuracy in WAAM through a broad range of thermal conditions. The reinforcement area of the bead is kept constant with accurate control over the height and width while still reducing the energy input to the substrate; decreasing penetration depth, remelting, and the heat-affected zone (HAZ); and reaching a dilution lower than 10%. This work also presents improved productivity compared to all the other single-arc energy-based processes with a demonstrator part built using 9.57 kg h⁻¹ with CWGMA AM. Full article

Gas metal arc welding-based additive manufacturing (GMA–AM) is a promising, low-cost approach to fabricate large-scale and complex geometry components using layer-by-layer deposition of metals. However, the low forming accuracy of GMA–AM still limits its one-off industrial application due to the strong and nonlinear interactions between arc–droplet transfer and molten pool. To fully understand the influential mechanism of this inherent interaction in the GMA–AM process to precisely control the part accuracy, the arc–droplet transfer behavior in the GMA–AM process with different current waveforms was firstly studied experimentally. The phenomena of the arc swing and the differing droplet transfer with the increase in deposited height were interpreted. The thermal force status of the molten pool and its balance boundary conditions were also theoretically analyzed. Finally, the microstructure and the hardness of the AM parts with different cooling times were tested and analyzed. The experimental results demonstrate that using the spray droplet transfer mode can generate a stable AM process under direct current application conditions, but it easily ends the AM process at the third or fourth layer deposition owing to excessive heat input. A more highly accurate deposition morphology can be obtained in one droplet per pulse mode under pulsed current application conditions, which also indicates that the AM process with a constant current welding supply is stabler and easily produces better deposition than the process with a constant voltage welding supply. With the increase in cooling time, the microstructure evolved from fine ferrite to equiaxed ferrite and to columnar ferrite combined with acicular ferrite with a lower proportion of pearlite in the vertical direction of the part, and the average hardness changed to ~168 HV (bottom), ~175 HV (middle), and ~250 HV (top). The analysis indicates that the heat accumulation of the molten pool is a critical factor that affects the deposition accuracy. To this end, a novel strategy that uses the heat accumulation to compensate for the energy formed in the molten pool is proposed to further reduce the arc heat input and weaken the heat accumulation, and its feasibility is discussed. Full article

The BeiDou Global Navigation Satellite System (BDS), including the second generation (BDS-2) and the third generation (BDS-3), has been widely used in areas of positioning, navigation, and timing (PNT). One of the essential prerequisites for accurate PNT service is the precise satellite orbits of multi-frequency and multi-constellation BDS-2 and BDS-3 satellites. As usual, the precise orbit products can be obtained from analysis centers (ACs) of the international GNSS Service (IGS). The precise orbits can also be downloaded from the international GNSS Monitoring and Assessment System (iGMAS). Compared with the IGS ACs, the iGMAS can provide featured services such as satellite orbits based on the new B1C/B2a BDS signals. Considering the indispensability of the new signals, the performance of all BDS precise orbits from iGMAS needs to be known. However, there is no comprehensive assessment of BDS-2 and BDS-3 precise orbits based on B1I/B3II and B1C/B2a frequencies from iGMAS, especially for the period after the BDS entered the stable operation stage. In this paper, BDS-2/BDS-3 final (ISC), rapid (ISR), and ultra-rapid (ISU) products based on B1I/B3I and B1C/B2a frequencies from iGMAS are all assessed comprehensively. Specifically, at first, the precise orbits from iGMAS are compared with the ones from the IGS ACs. Based on this, the satellite laser ranging inspects the precise orbits from iGMAS. Finally, the orbit errors are discussed systematically by considering the beta and elongation angles. Using one year of data, the orbit accuracy of geostationary orbit, inclined geosynchronous orbit, and medium earth orbit (MEO) satellites can almost reach meter to decimeter level, decimeter to sub-decimeter level, and centimeter level, respectively, where the ISC products are the best. The ISC, ISR, and ISU products based on B1I/B3I frequencies are generally better than the ones based on B1C/B2a frequencies. Additionally, according to the SLR data, the results show that the accuracy of precise orbits of BDS-3 is better than that of BDS-2. The mean values of orbit biases of BDS-3 MEO satellites are approximately 2.88 cm. In addition, the orbit errors are related to the beta angle and elongation angle to some extent, and the manufacturers may also have an influence on the orbit errors. Full article

Resource-efficient manufacturing with a high degree of freedom in terms of component shape can be realised through additive manufacturing. The focus can lie not only on the manufacturing process in terms of geometrical correctness, stability, etc., but also on the targeted development of specific material properties. This study shows the development of hybrid material systems made of aluminium and the ferromagnetic particles iron, cobalt, and nickel. The aim is to use the ferromagnetic properties as sensor properties to enable the easy sensing of material properties such as the microstructure, fatigue, or occurring stresses. To easily adopt different compositions, hot isostatic pressing was selected for the characterisation of the material composites Al-Fe, Al-Ni, and Al-Co with regard to their magnetic properties. Subsequently, transfer to the additive manufacturing process of wire and arc additive manufacturing gas metal arc welding was carried out by mixing the powder separately into the weld pool. The study shows that it is possible to prevent a complete transformation of Ni and Co into intermetallic phases with Al by adjusting the influencing variables in the HIP process. Magnetic properties could be detected in the composites of Al-Co and Al-Fe. This work serves as a preliminary work to realise additive components made of hybrid material systems of Al-Fe, Al-Co, and Al-Ni with the GMA welding process. Full article

Wire arc additive manufacturing (WAAM) is the process by which large, metallic structures are built, layer-by-layer, using a welding arc to melt wire feedstock. In this process, the proper selection of the shielding gas plays a vital role in the achievement of structurally acceptable part geometries and quality surface finishes. In this study, the authors used either a ternary mix (He, Ar and CO₂) or a binary mix (Ar and CO₂) of shielding gases to deposit wall geometries using an open loop-controlled WAAM system developed at Oak Ridge National Laboratory’s Manufacturing Demonstration Facility. The binary blend produced a wider and shorter geometry, while the ternary blend resulted in a narrower build that was more equivalent to the CAD geometry. The data indicated that the binary blend provided a higher oxygen concentration in the weld as compared to that of the ternary blend. The results imply that the arc characteristics and heat input had a significantly higher impact on the weld penetration than the surface tension effect of surface active elements. This was further verified by developing and applying a high-fidelity computational fluid dynamics (CFD) model of the thermophysical properties of gas mixtures. The results from the model showed that, while the influence of increased oxygen concentration on the surface tension for the binary blend led to a deeper penetration, the ternary blend gave rise to heat flux to the workpiece. Full article

Poly(ethylene-octene) grafted with glycidyl methacrylate (POE-g-GMA) and ethylene elastomeric grafted with glycidyl methacrylate (EE-g-GMA) were used as impact modifiers, aiming for tailoring poly(lactic acid) (PLA) properties. POE-g-GMA and EE-g-GMA was used in a proportion of 5; 7.5 and 10%, considering a good balance of properties for PLA. The PLA/POE-g-GMA and PLA/EE-g-GMA blends were processed in a twin-screw extruder and injection molded. The FTIR spectra indicated interactions between the PLA and the modifiers. The 10% addition of EE-g-GMA and POE-g-GMA promoted significant increases in impact strength, with gains of 108% and 140%, respectively. These acted as heterogeneous nucleating agents in the PLA matrix, generating a higher crystallinity degree for the blends. This impacted to keep the thermal deflection temperature (HDT) and Shore D hardness at the same level as PLA. By thermogravimetry (TG), the blends showed increased thermal stability, suggesting a stabilizing effect of the modifiers POE-g-GMA and EE-g-GMA on the PLA matrix. Scanning electron microscopy (SEM) showed dispersed POE-g-GMA and EE-g-GMA particles, as well as the presence of ligand reinforcing the systems interaction. The PLA properties can be tailored and improved by adding small concentrations of POE-g-GMA and EE-g-GMA. In light of this, new environmentally friendly and semi-biodegradable materials can be manufactured for application in the packaging industry. Full article

Motivated by environment preservation, the increased use of eco-friendly materials such as biodegradable polymers and biopolymers has raised the interest of researchers and the polymer industry. In this approach, this work aimed to produce bioblends using poly (lactic acid) (PLA) and high-density biopolyethylene (BioPE); due to the low compatibility between these polymers, this work evaluated the additional influence of the compatibilizing agents: poly (ethylene octene) and ethylene elastomer grafted with glycidyl methacrylate (POE-g-GMA and EE-g-GMA, respectively), polyethylene grafted with maleic anhydride (PE-g-MA), polyethylene grafted with acrylic acid (PE-g-AA) and the block copolymer styrene (ethylene-butylene)-styrene grafted with maleic anhydride (SEBS-g-MA) to the thermal, mechanical, thermomechanical, wettability and morphological properties of PLA/BioPE. Upon the compatibilizing agents’ addition, there was an increase in the degree of crystallinity observed by DSC (2.3–7.6% related to PLA), in the thermal stability as verified by TG (6–15 °C for T_D10%, 6–11 °C T_D50% and 112–121 °C for T_D99.9% compared to PLA) and in the mechanical properties such as elongation at break (with more expressive values for the addition of POE-g-GMA and SEBS-g-MA, 9 and 10%, respectively), tensile strength (6–19% increase compared to PLA/BioPE bioblend) and a significant increase in impact strength, with evidence of plastic deformation as observed through SEM, promoted by the PLA/ BioPE phases improvement. Based on the gathered data, the added compatibilizers provided higher performing PLA/BioPE. The POE-g-GMA compatibilizer was considered to provide the best properties in relation to the PLA/BioPE bioblend, as well as the PLA matrix, mainly in relation to impact strength, with an increase of approximately 133 and 100% in relation to PLA and PLA/BioPE bioblend, respectively. Therefore, new ecological materials can be manufactured, aiming at benefits for the environment and society, contributing to sustainable development and stimulating the consumption of eco-products. Full article

The present paper aimed at assessing the effect of two thermal management approaches on geometry and productivity of thin-walled structures built by Wire + Arc Additive Manufacturing (WAAM). Thin-walls of ER 5356 (Al5Mg) with different lengths and the same number of layers were deposited via the gas metal arc (GMA) process with the aid of an active cooling technique (near-immersion active cooling—NIAC) under a fixed set of deposition parameters. Then, the same experiment was performed with natural cooling (NC) in air. To characterize the thermal management approaches, the interpass temperature (i.e., the temperature at which subsequent layers are deposited) were monitored by a trailing/leading infrared pyrometer during the deposition time. Finally, thin walls with a fixed length were deposited using the NC and NIAC approaches with equivalent interpass temperatures. As expected, the shorter the wall length the more intense the deposition concentration, heat accumulation, and, thus, geometric deviation. This behavior was more evident and premature for the NC strategy due to its lower heat sinking effectiveness. The main finding was that, regardless of the thermal management technique applied, if the same interpass temperature is selected and maintained, the geometry of the part being built tends to be stable and very similar. However, the total deposition time is somewhat shorter with the NIAC technique due its greater heat sinking advantage. Thus, the NIAC technique facilitates the non-stop manufacturing of small parts and details via WAAM. Full article

The drying unit of a continuous from-powder-to-tablet manufacturing line based on twin-screw granulation (TSG) is a crucial intermediate process step to achieve the desired tablet quality. Understanding the size reduction of pharmaceutical granules before, during, and after the fluid bed drying process is, however, still lacking. A first major goal was to investigate the breakage and attrition phenomena during transport of wet and dry granules, the filling phase, and drying phase on a ConsiGma-25 system (C25). Pneumatic transport of the wet granules after TSG towards the dryer induced extensive breakage, whereas the turbulent filling and drying phase of the drying cells caused rather moderate breakage and attrition. Subsequently, the dry transfer line was responsible for additional extensive breakage and attrition. The second major goal was to compare the influence of drying air temperature and drying time on granule size and moisture content for granules processed with a commercial-scale ConsiGma-25 system and with the R&D-scale ConsiGma-1 (C1) system. Generally, the granule quality obtained after drying with C1 was not predictive for the C25, making it challenging during process development with the C1 to obtain representative granules for the C25. Full article