Search Results (61)

The teaching of the phytosociological method comprises several stages and aligns closely with the research-oriented teaching–learning process promoted by active methodologies. In both cases, preliminary inquiry is essential to review existing knowledge on vegetation in all its dimensions: bioclimatic, biogeographical, ecological, floristic composition, distribution, and conservation status. The main objective is to connect active teaching methodologies with phytosociological research. To this end, the natural environment is used to bring students into direct contact with plant communities, and the phytosociological research method is applied, through which students learn sampling techniques. This approach provides a rapid and effective assessment of habitat conservation status (EU Habitats Directive 92/43/EEC, European Council, 21 May 1992). As notable results, we highlight the poor conservation status of the three communities described, which is evident from the decline in characteristic association species. The present study focuses on the wetlands of the Costa Tropical, where communities of Juncus acutus, Typha dominguensis, Phragmites australis, and Arundo donax predominate. In this case, these communities act as open-air laboratories for teaching the phytosociological method. The Juncus acutus communities differ from those of Scirpus holoschoenus and other Juncus acutus stands by the presence of the endemic Linum maritimum. Meanwhile, the reedbeds differ from Thypho-Phragmitetum australis through the presence of Halimione portulacoides. In both cases, the influence of sea spray conditions the presence of subhalophilous species such as Juncus acutus, Linum maritimum, and Halimione portulacoides. This has enabled us to establish two new plant associations: LmJa = Lino maritimi–Juncetum acuti (rush stands) and Hp–Phra = Halimione portulacoidis–Phragmitetum australis (reedbeds). Ecological gradients also make it possible to separate Typha communities belonging to the Ca–Td = Cynancho acuti–Typhetum dominguensis association, and Phragmites into two distinct associations. This distinction arises because Typha communities require soil water during the summer period, whereas in Phragmites stands the upper soil horizon dries out. Full article

Electrostatic technology has emerged as a crucial tool for sustainable agricultural development due to its multifunctional characteristics. However, systematic and specialized investigations into its mechanism of action and application principles across diverse agricultural scenarios remain insufficient. Here, this review innovatively constructs a spatial scale classification framework and categorizes it into macroscale spray engineering and microscale plant biostimulation. At the macroscale, electrostatic spraying leverages charged droplets’ properties (high surface charge density, strong electrostatic interaction, enhanced adsorption) to improve canopy deposition efficiency and reduce agrochemical drift losses. At the microscale, electrostatic fields induce electron/ion directional movement, providing non-contact stimulation to regulate plant physiological processes such as seed germination and nutrient uptake. We systematically summarize the latest research progress in electrostatic spraying and electrostatic biostimulation, and further compare them in terms of their fundamental mechanisms, targets, and stages of technological development. Finally, the current limitations and challenges for each technology are overviewed and the forward perspective for the efficient application of electrostatics in agriculture are outlined. This review provides theoretical references and technical guidelines for the application research of electrostatic spraying and electrostatic biostimulation, holding significant importance for promoting the standardized development of electrostatic technology in sustainable and precision agriculture. Full article

Hydroxyapatite (HA) coatings improve implant bioactivity but suffer from brittleness and limited functionality. Here, we report a hybrid coating strategy combining flame-sprayed HA/TiO₂ with in situ hydrogel growth. TiO₂ incorporated into the HA matrix acted as a photocatalytic initiator for acrylamide polymerization under UV. Unlike conventional hydrogel coatings that require added photoinitiators or separate surface modification steps, TiO₂ incorporated into the HA layer serves as a built-in photocatalytic initiator, enabling direct polymerization of acrylamide monomers on the sprayed surface. The resulting HA/TiO₂–hydrogel coatings exhibited a continuous hydrogel layer with intimate contact to the ceramic surface, as evidenced by SEM cross-sections and elemental mapping. The HA/TiO₂ 1% coating produced a continuous coverage in close contact with the surface, while excessive TiO₂(5%) led to uncontrolled hydrogel growth and partial coating failure. SEM cross-sections revealed a dense, well-adhered coating with homogeneously distributed Ca, P, O, and finely dispersed Ti. Upon immersion in simulated body fluid (SBF), submicron globular deposits progressively developed on the coating surface. EDS showed an increase in Ca/P ratio from ~1.66 (as-sprayed) to ~1.92 (14 days). These findings highlight a straightforward approach for combining flame-sprayed ceramics with photocatalytic hydrogel growth, providing a practical route toward multifunctional implant surface modification. Full article

In slab continuous casting, achieving uniform cooling in the secondary cooling zone is essential for ensuring both surface integrity and internal quality. To optimize the process for ship plate steel, a solidification heat transfer model was developed, incorporating radiation, water film evaporation, spray impingement, and roll contact. The influence of secondary cooling water flow on slab temperature distribution was systematically investigated from multiple perspectives. The results show that a weak cooling strategy is crucial for maintaining higher surface temperatures and aligning the solidification endpoint with the soft reduction zone. Along the casting direction, a “strong-to-weak” cooling pattern effectively prevents abrupt temperature fluctuations, while reducing the inner-to-outer arc water ratio from 1.0 to 0.74 mitigates transverse thermal gradients. In addition, shutting off selected nozzles in the later stage of secondary cooling at medium and low casting speeds increases the slab corner temperature in the straightening zone by approximately 50 °C, thereby avoiding brittle temperature ranges. Overall, the proposed multi-dimensional uniform cooling strategy reduces temperature fluctuations and significantly improves slab quality, demonstrating strong potential for industrial application. Full article

Cellulose and chitin are the most abundant natural polymers, and their exploitation paves the way for sustainable materials and products. This work investigates the preparation of composites based on acetylated cellulose and partially deacetylated chitin, i.e., chitosan, using versatile and robust air-assisted solution spraying (AASS), a potential method for preparing materials both in situ and ex situ. These materials, in the form of films, despite being prepared from high-molecular-weight and rigid biopolymers, show high flexibility (Young’s moduli below 1 GPa), outstanding mechanical properties (tensile strengths above 19 MPa and strain at failure higher than 2%), and bioactivity towards E. coli. The unprecedented flexibility, obtained without the use of any plasticizer or by casting with humidity control, is a direct consequence of the specific film morphology, whereby films are constituted from merging droplets. Depending on the solution properties (viscosity, surface tension), various droplet sizes are obtained, thus influencing the roughness and indirectly the wettability. Wettability analysis towards water and oil revealed higher contact angles towards both fluids as the content of chitosan increases in the composite what directly impacts packaging applications by better protecting the food. Besides this, higher chitosan content in the composite (7.5% w/w) enabled bioactivity against E. coli, where colony development was inhibited on the film surface compared with the neat cellulose acetate. This study shows a very high potential for AASS for obtaining uniform thin flexible films for food packaging applications, allowing faster drying and lower energy consumption than other film-forming techniques. Full article

The continuous discharge voltage waveform and phenomena between the electrode and substrate were explored in this paper to study the ultrasonic electro-spark deposition process. Additionally, the impact of ultrasonics on the ultrasonic electro-spark deposition process and the properties of the deposition layer were examined. The results show that the charge–discharge frequency of the ultrasonic electro-spark deposition process was commensurate with the discharge frequency of the ultrasonic electro-spark deposition power source, and the voltage waveform was stable. When ultrasonics is introduced, the molten droplet spray trajectory is efficiently guided, resulting in the spark spray trajectory displaying notable directional concentration characteristics. During a single charging and discharging phase, the electrode and substrate made roughly 15 mechanical contacts, 1 of which was discharging, and the remaining 14 were mechanically contacted reinforcement. The surface of the ultrasonic electro-spark deposition layer exhibited a sputtering morphology with no surface cracks. Phase structures such as Co₃W₃C, Fe₃W₃C, Fe₆W₆C, WC, and W₂C constituted the majority of the ultrasonic electro-spark deposition layer’s microstructure and showed strong metallurgical bonds with the substrate. The ultrasonic electro-spark deposition layer has a surface roughness of 2.554 μm, a cross-section porosity of 1.3%, and a maximum microhardness of 1038.8 HV_0.025. Comparative analysis demonstrates that the addition of ultrasonics can significantly enhance the deposition layer’s quality and performance. When compared to the electro-spark deposition layer, the surface roughness of the ultrasonic electro-spark deposition layer decreases by roughly 61.4%, the cross-sectional porosity decreases by around 57.5%, and the maximum microhardness increases by about 15.5%. Many cracks and much high surface roughness in the conventional electro-spark deposition layer are resolved by the ultrasonic electro-spark deposition technique, which is crucial for cold drawing mold surface strengthening. Full article

Heavy rolling contact fatigue (RCF) may be caused by wheel surface defects under the influence of rail corrosion, which threatens the operational safety of rail vehicles. To investigate the role of surface defects on wheel RCF damage under the influence of rail corrosion, a salt spray tester was used to corrode the rails, an impact testing machine was employed to create surface defects, and RCF tests were completed. The role of surface defects on wheel RCF damage was studied by monitoring the wheel defect surface and cross-section. The results indicate that the tendencies of the RCF crack extension of surface defects of different sizes are similar, and they all extend in a C-shape along the tangential force direction. However, the larger the defect size, the later the crack is initiated. The leading edge material is continuously squeezed into the defect by the tangential force, and a larger plastic deformation layer is formed, which causes the RCF at the leading edge to crack more severely. Meanwhile, under the effect of combined normal force and shear stress, the leading edge crack intersects with the middle edge crack, and the leading edge material is spalled off first. Wheel RCF damage and wear are aggravated by rail corrosion, the longer the corrosion time, the more serious the RCF damage and wear, and the earlier the material spalling time, the lower the fatigue life. Full article

The research presented in this article seeks to identify the possible causes of reinforcement shadows (RS) on the surface of concrete test specimen produced under laboratory conditions. Different hypotheses about RS were selected based on factory practices and simulated in the study. The test specimens were cast horizontally in contact with steel form-facing surfaces coated with a water-soluble release agent. In addition, two scenarios were analysed during specimen production: reinforcing mesh was fixed using plastic spacers or tie wire. The analysis of the reinforcement shadows was based on visual inspection, taking photos, surface moisture content measurements, and colour variation analysis using the Natural Colour System. It was concluded that RS, which are typically characterized by darker lines, can be defined by the percentage of black colour present in the shadowed area compared to the percentage of black colour in the surrounding area. This percentage can be quickly assessed on a factory scale using digital colour readers that provide timely information. The reduced concrete cover thickness from 35 mm to 10 mm revealed light horizontal dark lines on the exposed surface. It was hypothesised that the gap of less than 10 mm between the reinforcing bars and the steel form-facing plate, along with the sieving effect of the fresh concrete, can retard the cement paste hydration process, resulting in unhydrated ferrite phases that contribute to the dark colour of the unhydrated cement. The release agent sprayed on the steel form-facing surface straight through the reinforcing mesh created a RS effect of the reinforcement on the exposed concrete surface. The absence of a release agent under steel rebars decreased the wettability at the interface between the formwork and fresh concrete, resulting in dark lines during the curing process. It is important to avoid such cases when manufacturing precast reinforced concrete elements. Quantitatively assessing RS and proposing a standardized method for calculation and categorization could be a new research direction in the future. Full article

Polymer composite coatings exhibit excellent mechanical properties, chemical resistance, and self-lubricating characteristics, providing an effective solution to address the failure of transmission components under harsh operating conditions, including high-speed, high-pressure, and oil-deficient environments, which often lead to excessive friction and limited bearing performance. This study fabricated three polyamide-imide (PAI) composite coatings modified with monodisperse surface-modified nano-silica (SiO₂) via direct spraying and compared their physicochemical parameters. The tribological performance of the three coatings was evaluated using ring-block high-speed friction and wear tester under continuous loading conditions. The tests were conducted using diesel engine oil CI4-5W40, supplemented with oil-soluble cerium dioxide (CeO₂) nanoparticles as an energy-efficient and restorative additive, as the lubricating medium. The experimental results demonstrated that the PAI composite coating exhibited a load-bearing capacity exceeding 1000 N (66 MPa). The wear mechanism analysis reveals that CeO₂ nanoparticles embedded in the coating surface form a cobblestone-like protective layer. This unique microstructure compensates for the surface pits generated by PAI matrix transfer and minimizes direct contact between the coating and steel ring. Additionally, the synergistic interaction between short carbon fiber (SCF) and the tribofilm contributes to the exceptional tribological properties of the coating, including coefficients of friction as low as 0.04 and wear rates below 0.41 × 10⁻⁸ mm³/N·m. The experimental findings could provide an experimental and theoretical foundation for the application of coatings under conditions involving finished lubricants. Full article

The interrelationships between the topological features, such as surface roughness deduced from atomic force microscopy (AFM), and wettability properties expressed by the contact angle of a water droplet on the surface of nanostructured wide bandgap oxide films prepared by spray pyrolysis are investigated for a wide range of compositions. A direct relationship between the surface roughness and the value of the contact angle was found for nanocomposite (In₂O₃)_1−x(MgO)_x, (In_1−xGa_x)₂O₃, and Zn_1−xMg_xO films, for which both the surface roughness and the contact angle increase with the increasing x-value. On the other hand, in ITO films doped with Ga, it was found that the surface roughness increases by increasing the Ga doping, while the contact angle decreases. Both the surface roughness and the contact angle proved to increase in Ga₂O₃ films when they were alloyed with Al₂O₃, similar to other nanocomposite films. An inverse relationship was revealed for a nanocomposite formed from Ga₂O₃ and SnO₂. The contact angle for a (Ga₂O₃)_0.75(SnO₂)_0.25 film was larger as compared to that of the Ga₂O₃ film, while the surface roughness was lower, similar to ITO films. The highest value of the contact angle equal to 128° was found for a (In₂O₃)_1−x(MgO)_x film with an x-value of 0.8, and the largest RMS roughness of 20 nm was showed by a Ga_1.75Al_0.25O₃ film. The optical properties of the prepared films were also analyzed from optical absorption spectroscopy, demonstrating their bandgap variation in the range of (4 to 4.85) eV, corresponding to the middle ultraviolet spectral range. Full article

The process of osteointegration depends significantly on the surface roughness, structure, chemical composition, and mechanical characteristics of the coating. In this regard, an important direction in the development of medical materials is the development of new techniques of surface modification and the creation of bioactive ceramic coatings. Calcium-phosphate materials based on hydroxyapatite have been proposed as bioactive ceramic coatings on titanium implants for the effective acceleration of bone tissue healing. To obtain bioactive ceramic coatings, pulse power sources are best suited, namely detonation spraying, in which the energy of the explosion of gas mixtures is used as a source of pulse action. The pulse mode of operation in the detonation spraying method is preferable for the formation of bioactive ceramic coatings. It provides a high velocity of hydroxyapatite particles, which promotes their effective fixation on the titanium substrate, while minimizing the heating of the material. This approach preserves the substrate structure and improves the coating adhesion. Four different types of coatings with varying O₂/C₂H₂ molar ratios, ranging from 2.6 to 3.7, were obtained using detonation spraying. Powders and obtained coatings of hydroxyapatite were studied by Raman spectroscopy and XRD structural analysis. The results of XRD phase analysis showed the partial conversion of the hydroxyapatite phase to the α-tricalcium phosphate (α-TCP) phase during the detonation spraying process. The results obtained by Raman spectroscopy indicate that hydroxyapatite is the main phase in coatings. All hydroxyapatite-based coatings exhibited hydrophobic properties, which was confirmed by contact-angle values above 90° in wettability tests, characteristic of hydrophobic surfaces. The adhesive strength of the coatings was measured by the scratch test method. Tribological tests were conducted using the ball-on-disk method under both dry conditions and in Ringer’s solution. This approach enabled the evaluation of wear resistance and friction coefficient of the coatings in different environments, simulating both lubrication-free conditions and those resembling physiological environments. Full article

Vibration sensors are widely applied in the detection of faults and analysis of operational states in engineering machinery and equipment. However, commercial vibration sensors with a feature of high hardness hinder their usage in some practical applications where the measured objects have irregular surfaces that are difficult to install. Moreover, as the operating environments of machinery become increasingly complex, there is a growing demand for sensors capable of working in wet and humid conditions. Here, we present a flexible, superhydrophobic vibration sensor with parallel microcracks. The sensor is fabricated using a femtosecond laser direct writing ablation strategy to create the parallel cracks on a PDMS film, followed by spray-coating with a conductive ink composed of MWCNTs, CB, and PDMS. The results demonstrate that the developed flexible sensor exhibits a high-frequency response of up to 2000 Hz, a high acceleration response of up to 100 m/s², a water contact angle as high as 159.61°, and a linearity of 0.9812 between the voltage signal and acceleration. The results indicate that the sensor can be employed for underwater vibration, sound recognition, and vibration monitoring in fields such as shield cutters, holding significant potential for mechanical equipment vibration monitoring and speech-based human–machine interaction. Full article

Porous conductive polymer structures, in particular Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) structures, are gaining in importance due to their versatile fields of application as sensors, hydrogels, or supercapacitors, to name just a few. Moreover, (porous) conducting polymers have become of interest for wearable and smart textile applications due to their biocompatibility, which enables applications with direct skin contact. Therefore, there is a huge need to investigate distinct, straightforward, and textile-compatible production methods for the fabrication of porous PEDOT:PSS structures. Here, we present novel and uncomplicated approaches to producing diverse porous PEDOT:PSS structures and characterize them thoroughly in terms of porosity, electrical resistance, and their overall appearance. Production methods comprise the incorporation of micro cellulose, the usage of a blowing agent, creating a sponge-like structure, and spraying onto a porous base substrate. This results in the fabrication of various porous structures, ranging from thin and slightly porous to thick and highly porous. Depending on the application, these structures can be modified and integrated into electronic components or wearables to serve as porous electrodes, sensors, or other functional devices. Full article

Botanical insecticides and soaps are frequently proposed as environmentally safer alternatives to synthetic insecticides. However, the efficacy and selectivity of these products are often only partially supported by empirical evidence. Here, we tested the effectiveness of five botanical insecticides, belonging to different categories, on the green peach aphid Myzus persicae (Sulzer) and their selectivity towards two natural enemies, the ladybird beetle Propylea quatuordecimpunctata (L.) and the parasitoid Aphidius colemani (Dalman). White thyme essential oil (EO), sweet orange EO, crude garlic extract and Marseille soap were tested and compared with a pyrethrin-based commercial product. Both direct spray assays and residual contact assays on treated cabbage leaf disks were carried out. The tested products had low efficacy against aphids when compared to pyrethrins but were in general less detrimental to ladybird beetle larvae, meaning that if applied against other pests, they have a lower chance of harming this agent of aphid biocontrol. Some of the products (soap, orange EO) did, however, show direct exposure toxicity toward ladybird larvae, and thyme EO had extensive phytotoxic effects on cabbage leaves, possibly indirectly leading to higher mortality in ladybird adults. These results underline the necessity for case-by-case evaluations of botanical insecticides. Full article

The accumulation of ice on the aero-engine inlet compromises engine safety. Traditional hot air anti-icing systems, which utilize bleed air, require substantial energy, decreasing engine performance and increasing emissions. Superhydrophobic materials have shown potential in reducing energy consumption when combined with these systems. Research indicates that superhydrophobic surfaces on stationary components significantly reduce anti-icing energy consumption by altering runback water flow behavior. However, for rotating aero-engine components, the effectiveness of superhydrophobic surfaces and the influence of surface wettability on runback water flow remain unclear due to centrifugal and Coriolis forces. This study investigates the runback water flow behavior on aero-engine rotating spinner surfaces with varying wettabilities in a straight-flow spray wind tunnel. The results demonstrated that centrifugal force reduces the amount of runback water on the rotating spinner compared to the stationary surface, forming rivulet flows deflected opposite to the direction of rotation. Furthermore, wettability significantly affects the flow characteristics of runback water on rotating surfaces. As the contact angle increases, the liquid water on the rotating spinner transitions from continuous film flow to rivulet and bead-like flows. Notably, the superhydrophobic surface prevents water adhesion, indicating its potential for anti-icing on rotating components. In addition, the interaction between rotational speed and surface wettability enhances the effects, with both increased rotational speed and larger contact angles contributing to higher liquid water flow velocities, promoting the rapid formation and detachment of rivulet and bead-like flows. Full article