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11 pages, 243 KB  
Article
Association Between Shift Work and Auditory–Cognitive Processing in Middle-Aged Healthcare Workers
by Margarida Roque, Tatiana Marques and Margarida Serrano
Audiol. Res. 2025, 15(6), 145; https://doi.org/10.3390/audiolres15060145 - 25 Oct 2025
Viewed by 768
Abstract
Background/Objectives: Shift work in healthcare professionals affects performance in high cognitive processing, especially in complex environments. However, the beneficial effects that working in complex environments may have on auditory–cognitive processing remain unknown. These professionals face increased challenges in decision-making due to factors such [...] Read more.
Background/Objectives: Shift work in healthcare professionals affects performance in high cognitive processing, especially in complex environments. However, the beneficial effects that working in complex environments may have on auditory–cognitive processing remain unknown. These professionals face increased challenges in decision-making due to factors such as noise exposure and sleep disturbances, which may lead to the development of enhanced auditory–cognitive resources. This study aims to investigate the associations between shift work and auditory–cognitive processing in middle-aged healthcare workers. Methods: Thirty middle-aged healthcare workers were equally allocated to a shift worker (SW) or a fixed-schedule worker (FSW) group. Performance on a cognitive test, and in pure-tone audiometry, speech in quiet and noise, and listening effort were used to explore whether correlations were specific to shift work. Results: Exploratory analyses indicated that shift workers tended to perform better in visuospatial/executive function, memory recall, memory index, orientation, and total MoCA score domains compared to fixed-schedule workers. In the SW group, hearing thresholds correlated with memory recall and memory index. In the FSW group, hearing thresholds correlated with orientation, memory index, and total MoCA score, while listening effort correlated with naming, and speech intelligibility in quiet correlated with total MoCA scores. Conclusions: These exploratory findings suggest that shift work may be linked to distinct auditory–cognitive patterns, with potential compensatory mechanisms in visuospatial/executive functions and memory among middle-aged healthcare workers. Larger, longitudinal studies are warranted to confirm whether these patterns reflect true adaptive mechanisms. Full article
(This article belongs to the Special Issue The Aging Ear)
24 pages, 4399 KB  
Article
Research on the Infrastructure Resilience System and Sustainable Development of Coastal Cities in the Bohai Sea, China: A Multi-Model and Spatiotemporal Heterogeneity Analysis Based on CAS
by Dan Zhu, Xinhang Li and Hongchang Li
Sustainability 2025, 17(18), 8232; https://doi.org/10.3390/su17188232 - 12 Sep 2025
Viewed by 1263
Abstract
In recent years, urban risk incidents have become more common. Enhancing infrastructure resilience is not only crucial for adapting to climate change and addressing natural disasters but also serves as a key cornerstone for sustaining urban sustainable development. The research objects for this [...] Read more.
In recent years, urban risk incidents have become more common. Enhancing infrastructure resilience is not only crucial for adapting to climate change and addressing natural disasters but also serves as a key cornerstone for sustaining urban sustainable development. The research objects for this study are 17 coastal cities in the Bohai Rim region of China. Based on the Complex Adaptive System (CAS) theory, from the multi-dimensional perspective of urban sustainable development, a resilience evaluation index system covering five subsystems, namely transportation, water supply and drainage, energy, environment, and communication, is constructed. Employing panel data from 2013 to 2022, this study develops the entropy weight–TOPSIS model to quantify resilience levels, and applies the obstacle degree model, geographical detector, and Geographically and Temporally Weighted Regression (GTWR) model to analyze influencing factors. The main research results are as follows: (1) The regional infrastructure resilience shows a slow upward trend, but the insufficient synergy among subsystems restricts urban sustainable development; (2) The primary barrier is the drainage and water supply system, and the environmental and communication systems’ notable spatial heterogeneity will result in uneven regional sustainable development; (3) The influence of driving factors such as economic level gradually weakens over time. Based on the above research results, the following paths for resilience improvement and urban sustainable development are proposed: Improve the regional coordination and long-term governance mechanism; Focus on key shortcomings and implement a resilience enhancement plan for water supply and drainage systems; Implement dynamic and precise policy adjustments to stimulate multiple drivers; Enhance smart empowerment and build a digital twin-based collaborative management platform. Full article
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15 pages, 486 KB  
Article
Association Between Healthy Lifestyle and Cognitive Function in Middle-Aged and Older Adults
by Rouba Khalil Naaman, Shoug Alashmali, Manar Abduljalil Bakhsh, Shomookh Ahmed Alneami, Elaf Saeed Algamdi, Ghaday Abdulwahab Al-Ghamdi and Shouq Mohammed Alqarni
Healthcare 2025, 13(10), 1140; https://doi.org/10.3390/healthcare13101140 - 14 May 2025
Viewed by 3372
Abstract
Background/Objectives: The adherence to a healthy lifestyle is important for supporting healthy cognitive function as aging progresses. This study aimed to assess the association between a healthy lifestyle, specifically diet quality, physical activity, and smoking, and cognitive function in middle-aged and older [...] Read more.
Background/Objectives: The adherence to a healthy lifestyle is important for supporting healthy cognitive function as aging progresses. This study aimed to assess the association between a healthy lifestyle, specifically diet quality, physical activity, and smoking, and cognitive function in middle-aged and older adults. Methods: A cross-sectional study was conducted among participants aged 45 and older with normal cognition. Participants’ cognitive performance was assessed by the Montreal Cognitive Assessment (MoCA). Dietary intake was assessed using a 24 h dietary recall, and diet quality was assessed using the Diet Quality Index-International (DQI-I). Physical activity was assessed using the International Physical Activity Questionnaire (IPAQ). Participants were categorized as unhealthy (score ≤ 1), average (score 2), and healthy (score 3). Results: In this study, a total of 176 participants were recruited, 46% of them were classified as unhealthy, 40% was average, and 14% as healthy. Participants in the unhealthy group had lower performance in the naming cognitive domain compared to the other groups (p = 0.01). Participants in the average group scored significantly lower than the other groups in the orientation domain (p = 0.02). Performing moderate and high physical activity levels were significantly associated with higher scores of MoCA (p = 0.04) and in the naming domain (p = 0.02). Conclusions: Adopting a healthy lifestyle is associated with maintaining cognitive health among middle-aged and older adults, supporting the relevance of multidomain lifestyle interventions. Further longitudinal research is warranted to evaluate the long-term feasibility and effectiveness of lifestyle interventions in this population. Full article
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38 pages, 14828 KB  
Article
Novel Recycling, Defibrillation, and Delignification Methods for Isolating α-Cellulose from Different Lignocellulosic Precursors for the Eco-Friendly Fiber Industry
by Sherif S. Hindi
Polymers 2024, 16(17), 2430; https://doi.org/10.3390/polym16172430 - 27 Aug 2024
Cited by 6 | Viewed by 2439
Abstract
Alpha-cellulose, a unique, natural, and essential polymer for the fiber industry, was isolated in an ecofriendly manner using eleven novel systems comprising recycling, defibrillation, and delignification of prosenchyma cells (vessels and fibers) of ten lignocellulosic resources. Seven hardwood species were selected, namely Conocorpus [...] Read more.
Alpha-cellulose, a unique, natural, and essential polymer for the fiber industry, was isolated in an ecofriendly manner using eleven novel systems comprising recycling, defibrillation, and delignification of prosenchyma cells (vessels and fibers) of ten lignocellulosic resources. Seven hardwood species were selected, namely Conocorpus erectus, Leucaena leucocephala, Simmondsia chinensis, Azadirachta indica, Moringa perigrina, Calotropis procera, and Ceiba pentandra. Moreover, three recycled cellulosic wastes were chosen due to their high levels of accumulation annually in the fibrous wastes of Saudi Arabia, namely recycled writing papers (RWPs), recycled newspapers (RNPs), and recycled cardboard (RC). Each of the parent samples and the resultant alpha-cellulose was characterized physically, chemically, and anatomically. The properties examined differed significantly among the ten resources studied, and their mean values lies within the cited ranges. Among the seven tree species, L. leucocephala was the best cellulosic precursor due to its higher fiber yield (55.46%) and holocellulose content (70.82%) with the lowest content of Klasson lignin (18.86%). Moreover, RWP was the best α-cellulose precursor, exhibiting the highest holocellulose (87%) and the lowest lignin (2%) content. Despite the high content of ash and other additives accompanied with the three lignocellulosic wastes that were added upon fabrication to enhance their quality (10%, 11%, and 14.52% for RWP, RNP, and RC, respectively), they can be considered as an inexhaustible treasure source for cellulose production due to the ease and efficiency of discarding their ash minerals using the novel CaCO3-elimination process along with the other innovative techniques. Besides its main role for adjusting the pH of the delignification process, citric acid serves as an effective and environmentally friendly additive enhancing lignin breakdown while preserving cellulose integrity. Comparing the thermal behavior of the ten cellulosic resources, C. procera and C. pentandra exhibited the highest moisture content and void volume as well as having the lowest specific gravity, crystallinity index, and holocellulose content and were found to yield the highest mass loss during their thermal degradation based on thermogravimetric and differential thermal analysis in an inert atmosphere. However, the other resources used were found to yield lower mass losses. The obtained results indicate that using the innovative procedures of recycling, defibrillation, and delignification did not alter or distort either the yield or structure of the isolated α-cellulose. This is a clear indicator of their high efficiency for isolating cellulose from lignocellulosic precursors. Full article
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22 pages, 11157 KB  
Article
Multi-Dimensional Landscape Connectivity Index for Prioritizing Forest Cover Change Scenarios: A Case Study of Southeast China
by Zhu He, Zhihui Lin, Qianle Xu, Shanshan Ding, Xiaochun Bao, Xuefei Li, Xisheng Hu and Jian Li
Forests 2024, 15(9), 1490; https://doi.org/10.3390/f15091490 - 25 Aug 2024
Cited by 2 | Viewed by 1790
Abstract
Predicting forest cover change (FCC) and screening development scenarios are crucial for ecological resilience. However, quantitative evaluations of prioritizing forest change scenarios are limited. Here, we took five shared socio-economic pathways (SSPs) representing potential global changes, namely SSP1: sustainability, SSP2: middle of the [...] Read more.
Predicting forest cover change (FCC) and screening development scenarios are crucial for ecological resilience. However, quantitative evaluations of prioritizing forest change scenarios are limited. Here, we took five shared socio-economic pathways (SSPs) representing potential global changes, namely SSP1: sustainability, SSP2: middle of the road, SSP3: regional rivalry, SSP4: inequality, and SSP5: fossil-fueled development, which were constructed by integrated assessment and climate models. We modeled them with the patch-generating land use simulation (PLUS) and constructed a multi-dimensional landscape connectivity index (MLCI) employing forest landscape connectivity (FLC) indices to assess forest development in Fujian Province, Southeast China. The MLCI visualized by radar charts was based on five metrics, including forest patch size (class area (CA), number (patch density (PD), isolation (landscape division index (DIVISION), aggregation (mean nearest-neighbor index (ENN_MN), and connectance index, (CONNECT). The results indicate that FC will remain above 61.4% until 2030, with growth observed in SSP1 and SSP4. Particularly, FC in SSP4 substantially increased, converted from cropland (1140.809 km2) and grassland (645.741 km2). SSP4 has the largest MLCI values and demonstrates significant enhancements in forest landscape integrity, with CA, ENN_MN and CONNECT increasing greatly. Our study offers valuable approaches to and insights into forest protection and restoration. Full article
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17 pages, 7349 KB  
Article
Temporal Patterns of Vegetation Greenness for the Main Forest-Forming Tree Species in the European Temperate Zone
by Kinga Kulesza and Agata Hościło
Remote Sens. 2024, 16(15), 2844; https://doi.org/10.3390/rs16152844 - 2 Aug 2024
Cited by 4 | Viewed by 1681
Abstract
In light of recently accelerating global warming, the changes in vegetation trends are vital for the monitoring of the dynamics of both whole ecosystems and individual species. Detecting changes within the time series of specific forest ecosystems or species is very important in [...] Read more.
In light of recently accelerating global warming, the changes in vegetation trends are vital for the monitoring of the dynamics of both whole ecosystems and individual species. Detecting changes within the time series of specific forest ecosystems or species is very important in the context of assessing their vulnerability to climate change and other negative phenomena. Hence, the aim of this paper was to identify the trend change points and periods of greening and browning in multi-annual time series of the normalised difference vegetation index (NDVI) and enhanced vegetation index (EVI) of four main forest-forming tree species in the temperate zone: pine, spruce, oak and beech. The research was conducted over the last two decades (2002–2022), and was based on vegetation indices data derived from the Moderate Resolution Imaging Spectroradiometer (MODIS). To this end, several research approaches, including calculating the linear trends in the moving periods and BEAST algorithm, were adapted. A pattern of browning then greening then constant was detected for coniferous species, mostly pine. In turn, for broadleaved species, namely oak and beech, a pattern of greening then constant was identified, without the initial phase of browning. The main trend change points seem to be ca. 2006 and ca. 2015 for coniferous species and solely around 2015 for deciduous ones. Full article
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13 pages, 2880 KB  
Article
Effect of Soil pH on the Uptake of Essential Elements by Tea Plant and Subsequent Impact on Growth and Leaf Quality
by Miao Jia, Yuhua Wang, Qingxu Zhang, Shaoxiong Lin, Qi Zhang, Yiling Chen, Lei Hong, Xiaoli Jia, Jianghua Ye and Haibin Wang
Agronomy 2024, 14(6), 1338; https://doi.org/10.3390/agronomy14061338 - 20 Jun 2024
Cited by 17 | Viewed by 5918
Abstract
Tea plant is an acidophilic plant, and soil pH has an important effect on the absorption and enrichment of elements, tea plant growth and quality. In this study, rhizosphere soils and leaves of tea plants from 30 tea plantations were collected to determine [...] Read more.
Tea plant is an acidophilic plant, and soil pH has an important effect on the absorption and enrichment of elements, tea plant growth and quality. In this study, rhizosphere soils and leaves of tea plants from 30 tea plantations were collected to determine soil pH and multi-element content of soil and leaves of tea plants, to obtain and validate key elements that are enriched by pH affecting tea plants, and to analyze the effects of pH on the growth and quality of tea plants. The results showed that soil pH significantly affected the enrichment of 15 elements by tea plants, and the enrichment coefficients of 11 elements (C, Mg, Si, N, P, Mn, Sr, Cd, S, Ca and Sb) tended to increase significantly with the increase of soil pH, while the opposite was true for the other four elements (Cu, Rb, Ba and Al). TOPSIS analysis showed that soil pH had the greatest effect on tea plant enrichment of seven elements, namely N (100%), Mn (43.32%), C (39.22%), P (27.66%), Sr (15.30%), Mg (13.41%) and Ba (10.47%). Pot experiments with tea seedlings also verified that soil pH significantly affected the enrichment of tea leaves for seven key elements. Moreover, with the increase of soil pH, the growth indexes, photosynthesis indexes and quality indexes of tea seedlings showed a significant upward trend. Interaction analysis showed that the enhanced enrichment of N, Mn, C, P, Sr and Mg by tea plants was beneficial to increase the photosynthetic capacity of tea plants, promote the growth of tea plants and improve the quality of tea leaves. This study provides an important theoretical basis for the cultivation and management of tea plants. Full article
(This article belongs to the Special Issue Advances in Soil Fertility, Plant Nutrition and Nutrient Management)
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21 pages, 5232 KB  
Article
Assessment of Water Quality of Key Dams in Jordan for Irrigation Purposes with Insights on Parameter Thresholds
by Mamoun A. Gharaibeh, Ammar A. Albalasmeh and Mohammad M. Obeidat
Water 2024, 16(12), 1726; https://doi.org/10.3390/w16121726 - 18 Jun 2024
Cited by 3 | Viewed by 2716
Abstract
Dams play a vital role as a primary water supply for irrigation in Jordan, necessitating an assessment of their water quality. This study aimed to evaluate the suitability of irrigation water in a key number of Jordanian dams, namely Al Kafrain, Al Waala, [...] Read more.
Dams play a vital role as a primary water supply for irrigation in Jordan, necessitating an assessment of their water quality. This study aimed to evaluate the suitability of irrigation water in a key number of Jordanian dams, namely Al Kafrain, Al Waala, King Talal (KTD), Mujib, Shuaib, and Sharhabil. Monthly readings of major water parameters (EC, Cl, SO42−, HCO3, Na+, Ca2+, and Mg2+) were recorded for seven years (2015–2021) for each dam. The assessment criteria included the sodium adsorption ratio (SAR), soluble sodium percentage (SSP), residual sodium carbonate (RSC), magnesium adsorption ratio (MAR), kelley ratio (KR), total hardness (TH), and water quality index (WQI) using both average (APL) and maximum permissible limits (MPL). Additionally, USSL, Wilcox, Doneen, Piper, and Gibbs diagrams were applied. The findings indicate that all the dams demonstrated suitability for irrigation based on the SAR, SSP, RSC, MAR, and KR values. The USSL diagrams showed most samples falling under C2S1 and C3S1, except KTD, which fell under C3S2. According to the Wilcox diagram, the water was either Excellent to Good or Good to Permissible, while the KTD water was classified as Permissible to Doubtful. Furthermore, the water chemistry was found to be mainly influenced by rock weathering, as revealed in the Gibbs diagram, and has no restriction on permeability, according to the Doneen diagram. The WQI showed that all the dams fall in the Good and Excellent category for irrigation using APL, while applying MPL, all the dams were in the Excellent category, which demonstrates the necessity of considering extreme events and regulatory thresholds. Full article
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12 pages, 9820 KB  
Article
The Identification and Gene Mapping of Spotted Leaf Mutant spl43 in Rice
by Chen Wang, Wen-Jun Liu, Xin-Wei Liao, Xia Xu, Shihua Yang, Xiao-Bo Zhang, Hai Zhou, Chuxiong Zhuang, Junyi Gong and Jian-Li Wu
Int. J. Mol. Sci. 2024, 25(12), 6637; https://doi.org/10.3390/ijms25126637 - 17 Jun 2024
Cited by 2 | Viewed by 1684
Abstract
Our study investigates the genetic mechanisms underlying the spotted leaf phenotype in rice, focusing on the spl43 mutant. This mutant is characterized by persistent reddish-brown leaf spots from the seedling stage to maturity, leading to extensive leaf necrosis. Using map-based cloning, we localized [...] Read more.
Our study investigates the genetic mechanisms underlying the spotted leaf phenotype in rice, focusing on the spl43 mutant. This mutant is characterized by persistent reddish-brown leaf spots from the seedling stage to maturity, leading to extensive leaf necrosis. Using map-based cloning, we localized the responsible locus to a 330 Kb region on chromosome 2. We identified LOC_Os02g56000, named OsRPT5A, as the causative gene. A point mutation in OsRPT5A, substituting valine for glutamic acid, was identified as the critical factor for the phenotype. Functional complementation and the generation of CRISPR/Cas9-mediated knockout lines in the IR64 background confirmed the central role of OsRPT5A in controlling this trait. The qPCR results from different parts of the rice plant revealed that OsRPT5A is constitutively expressed across various tissues, with its subcellular localization unaffected by the mutation. Notably, we observed an abnormal accumulation of reactive oxygen species (ROS) in spl43 mutants by examining the physiological indexes of leaves, suggesting a disruption in the ROS system. Complementation studies indicated OsRPT5A’s involvement in ROS homeostasis and catalase activity regulation. Moreover, the spl43 mutant exhibited enhanced resistance to Xanthomonas oryzae pv. oryzae (Xoo), highlighting OsRPT5A’s role in rice pathogen resistance mechanisms. Overall, our results suggest that OsRPT5A plays a critical role in regulating ROS homeostasis and enhancing pathogen resistance in rice. Full article
(This article belongs to the Section Molecular Plant Sciences)
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26 pages, 10820 KB  
Article
Landslide Susceptibility Assessment and Future Prediction with Land Use Change and Urbanization towards Sustainable Development: The Case of the Li River Valley in Yongding, China
by Chi Yang, Jinghan Wang, Shuyi Li, Ruihan Xiong, Xiaobo Li, Lin Gao, Xu Guo, Chuanming Ma, Hanxiang Xiong and Yang Qiu
Sustainability 2024, 16(11), 4416; https://doi.org/10.3390/su16114416 - 23 May 2024
Cited by 10 | Viewed by 2718
Abstract
The land use change (LUC) and urbanization caused by human activities have markedly increased the occurrence of landslides, presenting significant challenges in accurately predicting landslide susceptibility despite decades of model advancements. This study, focusing on the Li River Valley (LRV) within the Yongding [...] Read more.
The land use change (LUC) and urbanization caused by human activities have markedly increased the occurrence of landslides, presenting significant challenges in accurately predicting landslide susceptibility despite decades of model advancements. This study, focusing on the Li River Valley (LRV) within the Yongding District, China, employs two common models, namely an analytic hierarchy process–comprehensive index (AHP-CI) model and a logistic regression (LR) model to assess landslide susceptibility (LS). The AHP-CI model is empirically based, with the advantage of being constructible and applicable at various scales without a dataset, though it remains highly subjective. The LR model is a statistical model that requires a training set. The two models represent heuristic and statistical approaches, respectively, to assessing LS. Meanwhile, the basic geological and environmental conditions are considered in the AHP-CI model, while the LR model accounts for the conditions of LUC and urbanization. The results of the multicollinearity diagnostics reflect the rationality of the predisposing factor selection (1.131 < VIF < 4.441). The findings reveal that the AHP-CI model underperforms in LUC and urbanization conditions (AUROC = 0.645, 0.628, and 0.667 for different validation datasets). However, when all the time-varying human activity predisposing factors are considered, the LR model (AUROC = 0.852) performs significantly better under the conditions of solely considering 2010 (AUROC = 0.744) and 2020 (AUROC = 0.810). The CA–Markov model was employed to project the future land use for the short-term (2025), mid-term (2030), and long-term (2040) planning periods. Based on these projections, maps of future LS were created. Importantly, this paper discussed the relationships between landslide management and regional sustainable development under the framework of the UN SDGs, which are relevant to Goal 1, Goal 11, Goal 13, and Goal 15. Finally, this study highlights the importance of integrating strategic land planning, reforestation efforts, and a thorough assessment of human impact predisposing factors with SDG-aligned LS predictions, advocating for a comprehensive, multi-stakeholder strategy to promote sustainable landslide mitigation. Full article
(This article belongs to the Section Hazards and Sustainability)
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6 pages, 911 KB  
Proceeding Paper
Irrigation Water Management and Quality in Two Rocha Pear Orchards
by Cláudia Campos Pessoa, Ana Coelho Marques, Ana Rita F. Coelho, Diana Daccak, Inês Carmo Luís, Manuela Simões, Paulo Legoinha, Maria Manuela Silva, Fernando H. Reboredo, Paula Scotti-Campos, Isabel P. Pais, José N. Semedo, José C. Ramalho and Fernando C. Lidon
Biol. Life Sci. Forum 2024, 30(1), 21; https://doi.org/10.3390/IOCAG2023-17341 - 18 Apr 2024
Viewed by 999
Abstract
Tackling human malnutrition resulting from mineral deficits in foods is currently an agro-industrial problem. To address this problem, an agronomic workflow to enrich Rocha pears with calcium (Ca) was considered in two orchards in Portugal. This study aims to assess quality differences in [...] Read more.
Tackling human malnutrition resulting from mineral deficits in foods is currently an agro-industrial problem. To address this problem, an agronomic workflow to enrich Rocha pears with calcium (Ca) was considered in two orchards in Portugal. This study aims to assess quality differences in the irrigation water of two orchards (of Rocha pear) where an agronomic Ca enrichment workflow would be performed and identify possible conditioning to Ca increases in fruits. Thus, electrical conductivity (EC), pH, pHs, cations (Na+, K+, Ca2+, and Mg2+), and anions (HCO3, Cl, and SO42−) were attained to calculate the Sodium Adsorption Ratio (SAR) index and the Langelier Saturation Index (LSI) and assess the agricultural use. The values of EC, pH, pHs, SAR index and LSI of both orchards varied between 1198 and 1211 µS/cm, 7.4 and 7.5, 7.7 and 8.1, 3.5 and 7.4, and −0.69 and −0.21, respectively. Regarding Piper classification, irrigation waters were classified as sodium bicarbonate (orchard 1) and sodium chloride bicarbonate (orchard 2). Both orchards presented different classifications regarding agricultural use, namely C3S1 (orchard 2) and C3S2 (orchard 1). The water of both orchards presented the same salinity hazard (C3), but the use of these irrigation waters is enabled since these trees can be considered salt-tolerant. However, regarding the alkalinization hazard to soils, the irrigation water from orchard 2 offers less danger (S1) in comparison to orchard 1 (S2). Meanwhile, a slightly inferior LSI (orchard 1) can favor a higher tendency to dissolve calcium carbonate. In conclusion, although slightly different, analysis indicated that the waters of both orchards did not induce toxicity in Rocha pear trees. Full article
(This article belongs to the Proceedings of The 2nd International Online Conference on Agriculture)
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38 pages, 5235 KB  
Article
Mineral Indicators of Geologically Recent Past Habitability on Mars
by Roger Hart and Dawn Cardace
Life 2023, 13(12), 2349; https://doi.org/10.3390/life13122349 - 15 Dec 2023
Cited by 2 | Viewed by 4350
Abstract
We provide new support for habitable microenvironments in the near-subsurface of Mars, hosted in Fe- and Mg-rich rock units, and present a list of minerals that can serve as indicators of specific water–rock reactions in recent geologic paleohabitats for follow-on study. We modeled, [...] Read more.
We provide new support for habitable microenvironments in the near-subsurface of Mars, hosted in Fe- and Mg-rich rock units, and present a list of minerals that can serve as indicators of specific water–rock reactions in recent geologic paleohabitats for follow-on study. We modeled, using a thermodynamic basis without selective phase suppression, the reactions of published Martian meteorites and Jezero Crater igneous rock compositions and reasonable planetary waters (saline, alkaline waters) using Geochemist’s Workbench Ver. 12.0. Solid-phase inputs were meteorite compositions for ALH 77005, Nakhla, and Chassigny, and two rock units from the Mars 2020 Perseverance rover sites, Máaz and Séítah. Six plausible Martian groundwater types [NaClO4, Mg(ClO4)2, Ca(ClO4)2, Mg-Na2(ClO4)2, Ca-Na2(ClO4)2, Mg-Ca(ClO4)2] and a unique Mars soil-water analog solution (dilute saline solution) named “Rosy Red”, related to the Phoenix Lander mission, were the aqueous-phase inputs. Geophysical conditions were tuned to near-subsurface Mars (100 °C or 373.15 K, associated with residual heat from a magmatic system, impact event, or a concentration of radionuclides, and 101.3 kPa, similar to <10 m depth). Mineral products were dominated by phyllosilicates such as serpentine-group minerals in most reaction paths, but differed in some important indicator minerals. Modeled products varied in physicochemical properties (pH, Eh, conductivity), major ion activities, and related gas fugacities, with different ecological implications. The microbial habitability of pore spaces in subsurface groundwater percolation systems was interrogated at equilibrium in a thermodynamic framework, based on Gibbs Free Energy Minimization. Models run with the Chassigny meteorite produced the overall highest H2 fugacity. Models reliant on the Rosy Red soil-water analog produced the highest sustained CH4 fugacity (maximum values observed for reactant ALH 77005). In general, Chassigny meteorite protoliths produced the best yield regarding Gibbs Free Energy, from an astrobiological perspective. Occurrences of serpentine and saponite across models are key: these minerals have been observed using CRISM spectral data, and their formation via serpentinization would be consistent with geologically recent-past H2 and CH4 production and sustained energy sources for microbial life. We list index minerals to be used as diagnostic for paleo water–rock models that could have supported geologically recent-past microbial activity, and suggest their application as criteria for future astrobiology study-site selections. Full article
(This article belongs to the Special Issue What Is Life?)
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14 pages, 2095 KB  
Article
Acclimation of the Grapevine Vitis vinifera L. cv. Assyrtiko to Water Deficit: Coordination of Structural and Functional Leaf Traits and the Dynamic of Calcium Oxalate Crystals
by Foteini Kolyva, Dimosthenis Nikolopoulos, Panagiota Bresta, Georgios Liakopoulos, George Karabourniotis and Sophia Rhizopoulou
Plants 2023, 12(23), 3992; https://doi.org/10.3390/plants12233992 - 27 Nov 2023
Cited by 3 | Viewed by 2309
Abstract
Grapevine leaves contain abundant CaOx crystals located either within the mesophyll in the form of raphides, or in the bundle sheaths as druses. CaOx crystals function as internal carbon pools providing CO2 for a baseline level of photosynthesis, named “alarm [...] Read more.
Grapevine leaves contain abundant CaOx crystals located either within the mesophyll in the form of raphides, or in the bundle sheaths as druses. CaOx crystals function as internal carbon pools providing CO2 for a baseline level of photosynthesis, named “alarm photosynthesis”, despite closed stomata; thus, preventing the photoinhibition and the oxidative risk due to carbon starvation under adverse conditions. Structural and functional leaf traits of acclimated grapevine plants (Vitis vinifera L. cv. Assyrtiko) were investigated in response to water availability, in order to evaluate the dynamic functionality of CaOx. Leaf water potential, leaf area, leaf mass per area, stomatal properties, gas exchange parameters and performance index (PI) were decreased in leaves of vines acclimated to water deficit in comparison to the leaves of well-irrigated vines, although the chlorophyll fluorescence parameters showed that the operational efficiency of the photosystem II (PSII) photochemistry (Fv/Fm) did not change, indicating that the photosynthetic apparatus was not subjected to water stress. During the afternoon, more than half of the morning’s existing druses disappeared in the drought-acclimated leaves. Also, the raphides’ area of the drought-acclimated leaves was reduced more than that of the well-watered leaves. The substantial decomposition of druses under water deficit conditions compared to that of the raphides may have important implications for the maintenance of their different though overlapping roles. According to the results, it seems likely that, under water deficit conditions, a mechanism of “alarm photosynthesis” provides an additional tolerance trait in the leaves of Vitis vinifera cv. Assyrtiko; hence, leaf structure relates to function. Full article
(This article belongs to the Special Issue Mediterranean Plants II)
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22 pages, 3005 KB  
Article
Assessing Groundwater Quality for Sustainable Drinking and Irrigation: A GIS-Based Hydro-Chemical and Health Risk Study in Kovilpatti Taluk, Tamil Nadu
by Vivek Sivakumar, Venkada Lakshmi Ramamoorthy, Uma Maguesvari Muthaiyan, Shumugapriya Kaliyappan, Gokulan Ravindiran, Sethuraman Shanmugam, Priya Velusamy, Logesh Natarajan, Hussein Almohamad, Motrih Al-Mutiry and Hazem Ghassan Abdo
Water 2023, 15(22), 3916; https://doi.org/10.3390/w15223916 - 9 Nov 2023
Cited by 27 | Viewed by 5260
Abstract
The continuous investigation of water resources is essential to assess pollution risks. This study investigated a groundwater assessment in the coastal belt of Tamil Nadu’s Kovilpatti Taluk, Thoothukudi district. Twenty-one groundwater samples were collected during the pre-monsoon and post-monsoon seasons, analyzing water quality [...] Read more.
The continuous investigation of water resources is essential to assess pollution risks. This study investigated a groundwater assessment in the coastal belt of Tamil Nadu’s Kovilpatti Taluk, Thoothukudi district. Twenty-one groundwater samples were collected during the pre-monsoon and post-monsoon seasons, analyzing water quality parameters, namely pH, EC, Cl, SO42−, Ca2+, Mg2+, HCO3, TH, Na2+, and K+. The Water Quality Index (WQI) was computed and it is observed that 5% of pre-monsoon and 9% of post-monsoon samples were unsuitable for drinking. SAR, MHR, RSC, %Na and Kelley’s index were used to determine irrigation suitability. Pre-monsoon shows 29% (MHR) and 71% (RSC) unsuitable, and post-monsoon shows 59% (MHR) and 9% (RSC) unsuitable. Coastal activity, urbanization, and industrialization in Kovilpatti resulted in the degradation of groundwater quality. Solving this coastal issue requires sustainable wastewater treatment and strict industrial discharge guidelines. Spatial distribution plots, Box plots, Gibbs plots, Piper plots, Wilcox plots and Correlation Matrices had similar results to the computed WQI and its physical–chemical parameters. According to the human health risk assessment, the Mooppanpatti, Illuppaiurani, and Vijayapuri regions show high health risks due to the nitrate and fluoride concentration in the groundwater. Kadambu, Melparaipatti, Therkuilandhaikulam, and Vadakku Vandanam have low levels, posing a minimal health risk. Full article
(This article belongs to the Special Issue Sustainable Developments Goals: Water and Wastewater Management)
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Proceeding Paper
Can the Normalized Difference Vegetation Index Be Used for Yield Prediction in Solanum tuberosum L. Plants Biofortified with Calcium?
by Ana Rita F. Coelho, Diana Daccak, Inês Carmo Luís, Ana Coelho Marques, Cláudia Campos Pessoa, Maria Brito, José Kullberg, Manuela Simões, Maria Manuela Silva, Maria F. Pessoa, Fernando H. Reboredo, Paulo Legoinha, José C. Ramalho, Paula S. Campos, Isabel P. Pais, José N. Semedo and Fernando C. Lidon
Biol. Life Sci. Forum 2023, 27(1), 13; https://doi.org/10.3390/IECAG2023-15757 - 1 Nov 2023
Cited by 1 | Viewed by 1138
Abstract
Remote sensing technology (namely UAVs) has been used to monitor potato crops. As such, this study aims to analyze the relationship between the NDVI model and yield productivity in Solanum tuberosum L. plants from the Agria variety, submitted to a Ca biofortification process [...] Read more.
Remote sensing technology (namely UAVs) has been used to monitor potato crops. As such, this study aims to analyze the relationship between the NDVI model and yield productivity in Solanum tuberosum L. plants from the Agria variety, submitted to a Ca biofortification process with two different concentrations (12 and 24 kg/ha) of CaCl2 or Ca-EDTA. The NDVI values were collected six days after the six foliar applications and analyzed alongside the Ca content in the potato tubers (at harvest) and the total yield. The results highlight the fact that 24 kg/ha of CaCl2 presented the lowest NDVI value, yet these plants did not show the lowest yield. Moreover, that same treatment presented the highest Ca biofortification index in tubers. Also, it seems that the NDVI can be used in decision making to improve crop management strategies, considering that it is an indicator for detecting plant growth or vigor; however, in this research, it is not sufficient for yield prediction. Full article
(This article belongs to the Proceedings of The 3rd International Electronic Conference on Agronomy)
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