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Keywords = Beer-Lambert Law

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18 pages, 3665 KiB  
Article
Analytical Device and Prediction Method for Urine Component Concentrations
by Zhe Wang, Jianbang Huang, Qimeng Chen, Yuanhua Yu, Xuan Yu, Yue Zhao, Yan Wang, Chunxiang Shi, Zizhao Zhao and Dachun Tang
Micromachines 2025, 16(7), 789; https://doi.org/10.3390/mi16070789 - 2 Jul 2025
Viewed by 349
Abstract
To tackle the low-accuracy problem with analyzing urine component concentrations in real time, a fully automated dipstick analysis device of urine dry chemistry was designed, and a prediction method combining an image acquisition system with a whale optimization algorithm (WOA) for BP neural [...] Read more.
To tackle the low-accuracy problem with analyzing urine component concentrations in real time, a fully automated dipstick analysis device of urine dry chemistry was designed, and a prediction method combining an image acquisition system with a whale optimization algorithm (WOA) for BP neural network optimization was proposed. The image acquisition system, which comprised an ESP32S3 chip and a GC2145 camera, was used to collect the urine test strip images, and then color data were calibrated by image processing and color correction on the upper computer. The correlations between reflected light and concentrations were established following the Kubelka–Munk theory and the Beer–Lambert law. A mathematical model of urine colorimetric value and concentration was constructed based on the least squares method. The WOA algorithm was applied to optimize the weight and threshold of the BP neural network, and substantial data were utilized to train the neural network and perform comparative analysis. The experimental results show that the MAE, RMSE and R2 of predicted versus actual urine protein values were, respectively, 3.1415, 4.328 and approximately 1. The WOA-BP neural network model exhibited high precision and accuracy in predicting the urine component concentrations. Full article
(This article belongs to the Section B:Biology and Biomedicine)
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19 pages, 15038 KiB  
Article
Enhancing Underwater LiDAR Accuracy Through a Multi-Scattering Model for Pulsed Laser Echoes
by Ruichun Dong, Xin Fang, Xiangqian Meng, Chengyun Yang and Tao Li
Remote Sens. 2025, 17(13), 2251; https://doi.org/10.3390/rs17132251 - 30 Jun 2025
Viewed by 374
Abstract
In airborne LiDAR measurements of shallow water bathymetry, conventional data processing often overlooks the radiative losses associated with multiple scattering events, affecting detection accuracy. This study presents a Monte Carlo-based approach to construct a mathematical model that accurately characterizes the multiple returns in [...] Read more.
In airborne LiDAR measurements of shallow water bathymetry, conventional data processing often overlooks the radiative losses associated with multiple scattering events, affecting detection accuracy. This study presents a Monte Carlo-based approach to construct a mathematical model that accurately characterizes the multiple returns in airborne laser bathymetric systems. The model enables rapid simulation of laser propagation through water, accounting for multiple scattering events. Based on the Beer–Lambert law and incorporating the parameters of typical Jerlov 1 clear coastal water, the proposed model achieves a seamless integration of the H-G phase function with a Monte Carlo random process, enabling accurate simulation and validation of pulse temporal broadening in waters with varying optical transparency. Unlike most existing studies, which primarily focus on modeling the laser emission process, this work introduces a novel perspective by analyzing the probability of light reception in LiDAR return signals, offering a more comprehensive understanding of signal attenuation and detection performance in underwater environments. The results demonstrate that, for detecting underwater targets at depths of 10 m, considering three or more scattering events improves the accuracy by ~7%. For detecting underwater targets at depths of 50 m, considering three or more scattering events improves the accuracy by 15~33%. These findings can help enhance the detection accuracy and efficiency of experimental systems. Full article
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14 pages, 4598 KiB  
Article
Solar Spectral Beam Splitting Simulation of Aluminum-Based Nanofluid Compatible with Photovoltaic Cells
by Gang Wang, Peng Chou, Yongxiang Li, Longyu Xia, Ye Liu and Gaosheng Wei
Energies 2025, 18(10), 2460; https://doi.org/10.3390/en18102460 - 11 May 2025
Viewed by 388
Abstract
Solar photovoltaic/thermal (PV/T) systems can simultaneously solve PV overheating and obtain high-quality thermal energy through nanofluid spectral splitting technology. However, the existing nanofluid splitting devices have insufficient short-wavelength extinction and stability defects. To achieve the precise matching of the nanofluid splitting performance with [...] Read more.
Solar photovoltaic/thermal (PV/T) systems can simultaneously solve PV overheating and obtain high-quality thermal energy through nanofluid spectral splitting technology. However, the existing nanofluid splitting devices have insufficient short-wavelength extinction and stability defects. To achieve the precise matching of the nanofluid splitting performance with the optimal spectral window of the PV/T system, this paper carries out a relevant study on the optical properties of Al nanoparticles and proposes an Al@Ag nanoparticle. The optical behaviors of nanoparticles and nanofluids are numerically analyzed using the finite-difference time-domain (FDTD) method and the Beer–Lambert law. The results demonstrate that adjusting particle size enables modulation of nanoparticle extinction performance, including extinction intensity and resonance peak range. The Al@Ag core–shell structure effectively mitigates the oxidation susceptibility of pure Al nanoparticles. Furthermore, coating Al nanoparticles with an Ag shell significantly enhances their extinction efficiency in the short-wavelength range (350–640 nm). After dispersing Al nanoparticles into water to form a nanofluid, the transmittance in the short-wavelength range is significantly reduced compared to pure water. Compared to 50 nm pure Al particles, the Al@Ag nanofluid further reduces the transmittance by up to 13% in the wavelength range of 350–650 nm, while having almost no impact on the transmittance in the photovoltaic window (640–1080 nm). Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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20 pages, 2107 KiB  
Article
Exact Solutions to Cancer Laser Ablation Modeling
by Luisa Consiglieri
Photonics 2025, 12(4), 400; https://doi.org/10.3390/photonics12040400 - 21 Apr 2025
Viewed by 602
Abstract
The present paper deals with the study of the fluence rate over both healthy and tumor tissues in the presence of focal laser ablation (FLA). We propose new analytical solutions for a coupled partial differential equation (PDE) system, which includes the transport equation [...] Read more.
The present paper deals with the study of the fluence rate over both healthy and tumor tissues in the presence of focal laser ablation (FLA). We propose new analytical solutions for a coupled partial differential equation (PDE) system, which includes the transport equation modeling of light penetration into biological tissue, the bioheat equation modeling the heat transfer, and its respective damage. The present work could be the first step toward knowledge of the mathematical framework for biothermophysical problems, as well as the main key to simplify the numerical calculations due to its zero cost. We derive exact solutions and simulate results from them. We discuss the potential physical contributions and present respective conclusions about the following: (1) the validity of the diffusion approximation of the radiative transfer equation; (2) the local behavior of the source of scattered photons; (3) the unsteady state of the fluence rate; and (4) the boundedness of the critical time of the thermal damage to the cancerous tissue. We also discuss some controversial and diverging hypotheses. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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13 pages, 2731 KiB  
Article
Machine Learning-Based VO2 Estimation Using a Wearable Multiwavelength Photoplethysmography Device
by Chin-To Hsiao, Carl Tong and Gerard L. Coté
Biosensors 2025, 15(4), 208; https://doi.org/10.3390/bios15040208 - 24 Mar 2025
Cited by 1 | Viewed by 1151
Abstract
The rate of oxygen consumption, which is measured as the volume of oxygen consumed per mass per minute (VO2) mL/kg/min, is a critical metric for evaluating cardiovascular health, metabolic status, and respiratory function. Specifically, VO2 is a powerful prognostic predictor [...] Read more.
The rate of oxygen consumption, which is measured as the volume of oxygen consumed per mass per minute (VO2) mL/kg/min, is a critical metric for evaluating cardiovascular health, metabolic status, and respiratory function. Specifically, VO2 is a powerful prognostic predictor of survival in patients with heart failure (HF) because it provides an indirect assessment of a patient’s ability to increase cardiac output (CO). In addition, VO2 measurements, particularly VO2 max, are significant because they provide a reliable indicator of your cardiovascular fitness and aerobic endurance. However, traditional VO2 assessment requires bulky, breath-by-breath gas analysis systems, limiting frequent and continuous monitoring to specialized settings. This study presents a novel wrist-worn multiwavelength photoplethysmography (PPG) device and machine learning algorithm designed to estimate VO2 continuously. Unlike conventional wearables that rely on static formulas for VO2 max estimation, our algorithm leverages the data from the PPG wearable and uses the Beer–Lambert Law with inputs from five wavelengths (670 nm, 770 nm, 810 nm, 850 nm, and 950 nm), incorporating the isosbestic point at 810 nm to differentiate oxy- and deoxy-hemoglobin. A validation study was conducted with eight subjects using a modified Bruce protocol, comparing the PPG-based estimates to the gold-standard Parvo Medics gas analysis system. The results demonstrated a mean absolute error of 1.66 mL/kg/min and an R2 of 0.94. By providing precise, individualized VO2 estimates using direct tissue oxygenation data, this wearable solution offers significant clinical and practical advantages over traditional methods, making continuous and accurate cardiovascular assessment readily available beyond clinical environments. Full article
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17 pages, 5360 KiB  
Article
A Portable Smartphone-Based 3D-Printed Biosensing Platform for Kidney Function Biomarker Quantification
by Sangeeta Palekar, Sharayu Kalambe, Jayu Kalambe, Madhusudan B. Kulkarni and Manish Bhaiyya
Biosensors 2025, 15(3), 192; https://doi.org/10.3390/bios15030192 - 18 Mar 2025
Cited by 2 | Viewed by 835
Abstract
Detecting kidney function biomarkers is critical for the early diagnosis of kidney diseases and monitoring treatment efficacy. In this work, a portable, 3D-printed colorimetric sensor platform was developed to detect key kidney biomarkers: uric acid, creatinine, and albumin. The platform features a 3D-printed [...] Read more.
Detecting kidney function biomarkers is critical for the early diagnosis of kidney diseases and monitoring treatment efficacy. In this work, a portable, 3D-printed colorimetric sensor platform was developed to detect key kidney biomarkers: uric acid, creatinine, and albumin. The platform features a 3D-printed enclosure with integrated diffused LED lighting to ensure a controlled environment for image acquisition. A disposable 3D-printed flow cell holds samples, ensuring precision and minimizing contamination. The sensor relies on colorimetric analysis, where a reagent reacts with blood serum to produce a color shift proportional to the biomarker concentration. Using a smartphone, the color change is captured, and RGB values are normalized to calculate concentrations based on the Beer-Lambert Law. The system adapts to variations in smartphones, reagent brands, and lighting conditions through an adaptive calibration algorithm, ensuring flexibility and accuracy. The sensor demonstrated good linear detection ranges for uric acid (1–30 mg/dL), creatinine (0.1–20 mg/dL), and albumin (0.1–8 g/dL), with detection limits of 1.15 mg/dL, 0.15 mg/dL, and 0.11 g/dL, respectively. These results correlated well with commercial biochemistry analyzers. Additionally, an Android application was developed to handle image processing and database management, providing a user-friendly interface for real-time blood analysis. This portable, cost-effective platform shows significant potential for point-of-care diagnostics and remote health monitoring. Full article
(This article belongs to the Special Issue Innovative Biosensing Technologies for Sustainable Healthcare)
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21 pages, 16165 KiB  
Article
A Small-Scale Investigation into the Viability of Detecting Canopy Damage Caused by Acantholyda posticalis Disturbance Using High-Resolution Satellite Imagery in a Managed Pinus sylvestris Stand in Central Poland
by Jackson Seymour, Michał Brach and Marek Sławski
Forests 2025, 16(3), 472; https://doi.org/10.3390/f16030472 - 7 Mar 2025
Viewed by 446
Abstract
As the effects of climate change progressively worsen, many scientists are concerned over the expanding geographic range and impact of forest-defoliating insects. Many are currently pointing to this form of disturbance becoming a key focus of remote sensing research in the coming decades; [...] Read more.
As the effects of climate change progressively worsen, many scientists are concerned over the expanding geographic range and impact of forest-defoliating insects. Many are currently pointing to this form of disturbance becoming a key focus of remote sensing research in the coming decades; however, the available body of research remains lacking. This study investigated the viability of detecting and quantifying damage caused to a managed Scots pine forest in central Poland by insect defoliation disturbance using high-resolution multispectral satellite imagery. Observed leaf area index (LAI) values were compared to frass observations (insect detritus) to assess the relationship between LAI and defoliating insect activity across a single life cycle of A. posticalis Mats. Across four managed plots, four vegetative indices (NDVI, GNDVI, EVI, and MSAVI2) were calculated using multispectral satellite imagery from a PlanetScope (PSB.SD instrument) satellite system. Then, 1137 point-sampled digital number (DN) values were extracted from each index, and a correlation analysis compared each to 40 ground-observed LAI data points. LAI was modeled on the basis of NDVI values. Three models were assessed for their performance in predicting LAI. They were fit using a variety of regression techniques and assessed using several goodness-of-fit measures. A relationship between observed LAI and frass observations was found to be statistically significant (p-value = 0.000303). NDVI was found to be the correlated LAI values (rho = 0.612). Model 3, which was based on concepts of the Beer–Lambert law, resulted in the most robust predictions of LAI. All parameters were found to be significant post fitting of the model using a nonlinear least squares method. Despite the success of the Beer’s law model in predicting LAI, detection of A. posticalis damage was not achieved. This was predominately due to issues of resolution and plot condition, among others. The results of this analysis address many interesting facets of remote sensing analysis and challenge the commonly held view of the impeachability of these methods. Full article
(This article belongs to the Section Forest Inventory, Modeling and Remote Sensing)
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14 pages, 7661 KiB  
Article
Single Scattering Dynamics of Vector Bessel–Gaussian Beams in Winter Haze Conditions
by Yixiang Yang, Yuancong Cao, Wenjie Jiang, Lixin Guo and Mingjian Cheng
Photonics 2025, 12(3), 182; https://doi.org/10.3390/photonics12030182 - 22 Feb 2025
Viewed by 821
Abstract
This study investigates the scattering dynamics of vector Bessel–Gaussian (BG) beams in winter haze environments, with a particular emphasis on the influence of ice-coated haze particles on light propagation. Employing the Generalized Lorenz–Mie Theory (GLMT), we analyze the scattering coefficients of particles transitioning [...] Read more.
This study investigates the scattering dynamics of vector Bessel–Gaussian (BG) beams in winter haze environments, with a particular emphasis on the influence of ice-coated haze particles on light propagation. Employing the Generalized Lorenz–Mie Theory (GLMT), we analyze the scattering coefficients of particles transitioning from water to ice coatings under varying atmospheric conditions. Our results demonstrate that the presence of ice coatings significantly alters the scattering and extinction efficiencies of BG beams, revealing distinct differences compared to particles coated with water. Furthermore, the study examines the role of Orbital Angular Momentum (OAM) modes in shaping scattering behavior. We show that higher OAM modes, characterized by broader energy distributions and larger beam spot sizes, induce weaker localized interactions with individual particles, leading to diminished scattering and attenuation. In contrast, lower OAM modes, with energy concentrated in smaller regions, exhibit stronger interactions with particles, thereby enhancing scattering and attenuation. These findings align with the Beer–Lambert law in the single scattering regime, where beam intensity attenuation is influenced by the spatial distribution of radiation, while overall power attenuation follows the standard exponential decay with respect to propagation distance. The transmission attenuation of BG beams through haze-laden atmospheres is further explored, emphasizing the critical roles of particle concentration and humidity. This study provides valuable insights into the interactions between vector BG beams and atmospheric haze, advancing the understanding of optical communication and environmental monitoring in hazy conditions. Full article
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22 pages, 25548 KiB  
Article
Improvement of FAPAR Estimation Under the Presence of Non-Green Vegetation Considering Fractional Vegetation Coverage
by Rui Li, Baolin Li, Yecheng Yuan, Wei Liu, Jie Zhu, Jiali Qi, Haijiang Liu, Guangwen Ma, Yuhao Jiang, Ying Li and Qiuyuan Tan
Remote Sens. 2025, 17(4), 603; https://doi.org/10.3390/rs17040603 - 10 Feb 2025
Viewed by 670
Abstract
The homogeneous turbid medium assumption inherent to the Beer-Lambert’s law can lead to a reduction in the shading effect between leaves when non-green vegetation canopies are present, resulting in an overestimation of the fraction of absorbed photosynthetically active radiation (FAPAR). This paper proposed [...] Read more.
The homogeneous turbid medium assumption inherent to the Beer-Lambert’s law can lead to a reduction in the shading effect between leaves when non-green vegetation canopies are present, resulting in an overestimation of the fraction of absorbed photosynthetically active radiation (FAPAR). This paper proposed a method to improve the FAPAR estimation (FAPARFVC) based on Beer-Lambert’s law by incorporating fractional vegetation coverage (FVC). Initially, the canopy-scale leaf area index (LAI) of the green canopy distribution area within the pixel (sample site) was determined based on the FVC. Subsequently, the canopy-scale FAPAR was calculated within the green canopy distribution area, adhering to the assumption of a homogeneous turbid medium in the Beer-Lambert’s law. Finally, the average FAPAR across the pixel (sample site) was calculated based on the FVC. This paper conducted a case study using measured data from the BigFoot Project and grass savanna in Senegal, West Africa, as well as Moderate Resolution Imaging Spectroradiometer (MODIS) LAI/FPAR products. The results indicated that the FAPARFVC approach demonstrated superior accuracy compared to the FAPAR determined by MODIS LAI, according to the Beer-Lambert’s law (FAPARLAI) and MODIS FPAR products (FAPARMOD). The mean absolute percentage error of FAPARFVC was 48.2%, which is 25.6% and 52.1% lower than that of FAPARLAI and FAPARMOD, respectively. The mean percentage error of FAPARFVC was 16.8%, which was 71.6% and 73.4% lower than that of FAPARLAI and FAPARMOD, respectively. The improvements in accuracy and the decrease in overestimation for FAPARFVC became more pronounced with increasing FVC compared to FAPARLAI. The findings suggested that the FAPARFVC method enhanced the accuracy of FAPAR estimation under the presence of non-green vegetation canopies. The method can be extended to regional scale FAPAR and gross primary production (GPP) estimations, thereby providing more accurate inputs for understanding its tempo-spatial patterns and drivers. Full article
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21 pages, 7142 KiB  
Article
Implicit Measurement of Sweetness Intensity and Affective Value Based on fNIRS
by Jiayu Mai, Siying Li, Zhenbo Wei and Yi Sun
Chemosensors 2025, 13(2), 36; https://doi.org/10.3390/chemosensors13020036 - 26 Jan 2025
Viewed by 1116
Abstract
This study explores the effectiveness of functional near-infrared spectroscopy (fNIRS) as an implicit measurement tool for evaluating sweetness intensity and affective value. Thirty-two participants tasted sucrose solutions at concentrations of 0.15 M, 0.3 M, and 0.6 M, while both their neural responses were [...] Read more.
This study explores the effectiveness of functional near-infrared spectroscopy (fNIRS) as an implicit measurement tool for evaluating sweetness intensity and affective value. Thirty-two participants tasted sucrose solutions at concentrations of 0.15 M, 0.3 M, and 0.6 M, while both their neural responses were recorded with a 24-channel fNIRS system and their self-reported assessments of sweetness intensity and affective value were collected. The neural fNIRS data were converted into oxygenated hemoglobin (HbO) and deoxygenated hemoglobin (HbR) concentrations using the modified Beer–Lambert Law, and analyzed through univariate activation analysis and multivariable decoding analysis to identify neural activation patterns associated with sweetness perception. The results showed significant activation in the dorsolateral prefrontal cortex (dlPFC) and orbitofrontal cortex (OFC) in response to varying levels of sweetness intensity and affective value, with channels 8, 10, 12, 13, 14, 15, and 17 consistently activated across all sucrose concentrations. As sweetness concentration increased from 0.15 M to 0.6 M, the number of significantly activated channels rose from seven to eleven, indicating stronger and more widespread neural responses corresponding to higher sweetness intensity. The multivariable decoding analysis further demonstrated the capability of fNIRS in accurately distinguishing positive affective responses, with up to 72.1% accuracy. The moderate positive correlation between explicit self-reports and implicit fNIRS data regarding sweetness intensity further supports the validity of fNIRS as a reliable tool for assessing taste perception. This study highlights the potential of fNIRS in sensory neuroscience, demonstrating its effectiveness in capturing the neural mechanisms underlying sweet taste perception. Full article
(This article belongs to the Special Issue Advancements of Chemosensors and Biosensors in China—2nd Edition)
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13 pages, 2687 KiB  
Article
Quantitative Modeling of High-Energy Electron Scattering in Thick Samples Using Monte Carlo Techniques
by Bradyn Quintard, Xi Yang and Liguo Wang
Appl. Sci. 2025, 15(2), 565; https://doi.org/10.3390/app15020565 - 9 Jan 2025
Cited by 1 | Viewed by 1094
Abstract
Cryo-electron microscopy (cryo-EM) is a powerful tool for imaging biological samples but is typically limited by sample thickness, which is restricted to a few hundred nanometers depending on the electron energy. However, there is a growing need for imaging techniques capable of studying [...] Read more.
Cryo-electron microscopy (cryo-EM) is a powerful tool for imaging biological samples but is typically limited by sample thickness, which is restricted to a few hundred nanometers depending on the electron energy. However, there is a growing need for imaging techniques capable of studying biological samples up to 10 µm in thickness while maintaining nanoscale resolution. This need motivates the use of mega-electron-volt scanning transmission electron microscopy (MeV-STEM), which leverages the high penetration power of MeV electrons to generate high-resolution images of thicker samples. In this study, we employ Monte Carlo simulations to model electron–sample interactions and explore the signal decay of imaging electrons through thick specimens. By incorporating material properties, interaction cross-sections for energy loss, and experimental parameters, we investigate the relationship between the incident and transmitted beam intensities. Key factors such as detector collection angle, convergence semi-angle, and the material properties of samples were analyzed. Our results demonstrate that the relationship between incident and transmitted beam intensities follows the Beer–Lambert law over thicknesses ranging from a few microns to several tens of microns, depending on material composition, electron energy, and collection angles. The linear depth of silicon dioxide reaches 3.9 µm at 3 MeV, about 6 times higher than that at 300 keV. Meanwhile, the linear depth of amorphous ice reaches 17.9 µm at 3 MeV, approximately 11.5 times higher than that at 300 keV. These findings are crucial for advancing the study of thick biological and semiconductor samples using MeV-STEM. Full article
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12 pages, 5960 KiB  
Article
CRDS Technology-Based Integrated Breath Gas Detection System for Breath Acetone Real-Time Accurate Detection Application
by Jing Sun, Dongxin Shi, Le Wang, Xiaolin Yu, Binghong Song, Wangxin Li, Jiankun Zhu, Yong Yang, Bingqiang Cao and Chenyu Jiang
Chemosensors 2024, 12(12), 261; https://doi.org/10.3390/chemosensors12120261 - 13 Dec 2024
Cited by 1 | Viewed by 1260
Abstract
The monitoring of acetone in exhaled breath is expected to provide a noninvasive and painless method for dynamic monitoring of summarized physiological metabolic status during obesity treatment. Although the commonly used Mass Spectrometry (MS) technology has high accuracy, the long detection time and [...] Read more.
The monitoring of acetone in exhaled breath is expected to provide a noninvasive and painless method for dynamic monitoring of summarized physiological metabolic status during obesity treatment. Although the commonly used Mass Spectrometry (MS) technology has high accuracy, the long detection time and large equipment size limit the application of daily bedside detection. As for the real-time and accurate detection of acetone, the gas sensor has become the best choice of gas detection technology, but it is easy to be disturbed by water vapor in breath gas. An integrated breath gas detection system based on cavity ring-down spectroscopy (CRDS) is reported in this paper, which is a laser absorption spectroscopy technique with high-sensitivity detection and absolute quantitative analysis. The system uses a 266 nm single-wavelength ultraviolet laser combined with a breath gas pretreatment unit to effectively remove the influence of water vapor. The ring-down time of this system was 1.068 μs, the detection sensitivity was 1 ppb, and the stability of the system was 0.13%. The detection principle of the integrated breath gas detection system follows Lambert–Beer’s law, which is an absolute measurement with very high detection accuracy, and was further validated by Gas Chromatography–Mass Spectrometer (GC-MS) testing. Significant differences in the response of the integrated breath gas detection system to simulated gases containing different concentrations of acetone indicate the potential of the system for the detection of trace amounts of acetone. Meanwhile, the monitoring of acetone during obesity treatment also signifies the feasibility of this system in the dynamic monitoring of physiological indicators, which is not only important for the optimization of the obesity treatment process but also promises to shed further light on the interaction between obesity treatment and physiological metabolism in medicine. Full article
(This article belongs to the Special Issue Advanced Chemical Sensors for Gas Detection)
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13 pages, 3192 KiB  
Article
Suspended Slot Membrane Waveguide Based on Germanium-on-Silicon-on-Insulator at λ = 4.23 µm for CO2 Monitoring
by Muhammad A. Butt and Ryszard Piramidowicz
Micromachines 2024, 15(12), 1434; https://doi.org/10.3390/mi15121434 - 28 Nov 2024
Cited by 5 | Viewed by 1171
Abstract
In this work, we propose a novel suspended slot membrane waveguide (SSMW) utilizing a germanium-on-silicon-on-insulator (Ge-on-SOI) platform for carbon dioxide (CO2) gas-sensing applications. The design and analysis focus on the absorption line of CO2 in the mid-infrared region, specifically at [...] Read more.
In this work, we propose a novel suspended slot membrane waveguide (SSMW) utilizing a germanium-on-silicon-on-insulator (Ge-on-SOI) platform for carbon dioxide (CO2) gas-sensing applications. The design and analysis focus on the absorption line of CO2 in the mid-infrared region, specifically at a wavelength of 4.23 µm. The waveguide geometry has been precisely optimized to achieve a high evanescent field ratio (EFR) and minimize waveguide propagation losses. These optimizations significantly enhance the sensitivity of the waveguide, making it highly effective for evanescent field absorption-based gas sensing. Our optimized waveguide geometry demonstrates a notable EFR of 0.86, with a low propagation loss of just 1.07 dB/cm, and achieves a sensitivity as high as ~1.12 × 10−4 ppm−1 for SSMW lengths as short as 0.9 cm. Full article
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23 pages, 5158 KiB  
Article
Development of Analytical Model to Describe Reflectance Spectra in Leaves with Palisade and Spongy Mesophyll
by Ekaterina Sukhova, Yuriy Zolin, Kseniya Grebneva, Ekaterina Berezina, Oleg Bondarev, Anastasiia Kior, Alyona Popova, Daria Ratnitsyna, Lyubov Yudina and Vladimir Sukhov
Plants 2024, 13(22), 3258; https://doi.org/10.3390/plants13223258 - 20 Nov 2024
Cited by 2 | Viewed by 1422
Abstract
Remote sensing plays an important role in plant cultivation and ecological monitoring. This sensing is often based on measuring spectra of leaf reflectance, which are dependent on morphological, biochemical, and physiological characteristics of plants. However, interpretation of the reflectance spectra requires the development [...] Read more.
Remote sensing plays an important role in plant cultivation and ecological monitoring. This sensing is often based on measuring spectra of leaf reflectance, which are dependent on morphological, biochemical, and physiological characteristics of plants. However, interpretation of the reflectance spectra requires the development of new tools to analyze relations between plant characteristics and leaf reflectance. The current study was devoted to the development, parameterization, and verification of the analytical model to describe reflectance spectra of the dicot plant leaf with palisade and spongy mesophyll layers (on the example of pea leaves). Four variables (intensities of forward and backward collimated light and intensities of forward and backward scattered light) were considered. Light reflectance and transmittance on borders of lamina (Snell’s and Fresnel’s laws), light transmittance in the palisade mesophyll (Beer–Bouguer–Lambert law), and light transmittance and scattering in the spongy mesophyll (Kubelka–Munk theory) were described. The developed model was parameterized based on experimental results (reflectance spectra, contents of chlorophylls and carotenoid, and thicknesses of palisade and spongy mesophyll in pea leaves) and the literature data (final R2 was 0.989 for experimental and model-based reflectance spectra). Further model-based and experimental investigations showed that decreasing palisade and spongy mesophyll thicknesses in pea leaves (from 35.5 to 25.2 µm and from 58.6 to 47.8 µm, respectively) increased reflectance of green light and decreased reflectance of near-infrared light. Similarity between model-based and experimental results verified the developed model. Thus, the model can be used to analyze leaf reflectance spectra and, thereby, to increase efficiency of the plant remote and proximal sensing. Full article
(This article belongs to the Special Issue Integration of Spectroscopic and Photosynthetic Analyses in Plants)
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19 pages, 15782 KiB  
Article
Recycled Carbon Black/High-Density Polyethylene Composite from Waste Tires: Manufacturing, Testing, and Aging Characterization
by Catherine Billotte, Laurence Romana, Anny Flory, Serge Kaliaguine and Edu Ruiz
Recycling 2024, 9(6), 107; https://doi.org/10.3390/recycling9060107 - 5 Nov 2024
Cited by 2 | Viewed by 2530
Abstract
This study addresses the global issue of recycling used vehicle tires, typically burned out or trimmed to be reused in playground floors or road banks. In this study, we explore a novel environmentally responsive approach to decomposing and recovering the carbon black particles [...] Read more.
This study addresses the global issue of recycling used vehicle tires, typically burned out or trimmed to be reused in playground floors or road banks. In this study, we explore a novel environmentally responsive approach to decomposing and recovering the carbon black particles contained in tires (25–30 wt.%) by vacuum pyrolysis. Given that carbon black is well known for its UV protection in plastics, the objective of this research is to provide an ecological alternative to commercial carbon black of fossil origin by recycling the carbon black (rCB) from used tires. In our research, we create a composite material using rCB and high-density polyethylene (HDPE). In this article, we present the environmental aging studies carried out on this composite material. The topographic evolution of the samples with aging and the oxidation kinetics of the surface and through the thickness were studied. The Beer–Lambert law is used to relate the oxidative index to the characteristic depth of the samples. The UV photons are observed to penetrate up to 54% less with the addition of 6 wt.% of rCB compared to virgin HDPE. In this work, the addition of rCB as filler for HDPE used for outdoor applications has demonstrated to be an antioxidant for UV protection and a good substitute for commercial carbon black for industrial goods. Full article
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