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26 pages, 9198 KiB  
Article
The Exotic Igneous Clasts Attributed to the Cuman Cordillera: Insights into the Makeup of a Cadomian/Pan-African Basement Covered by the Moldavides of the Eastern Carpathians, Romania
by Sarolta Lőrincz, Marian Munteanu, Ştefan Marincea, Relu Dumitru Roban, Valentina Maria Cetean, George Dincă and Mihaela Melinte-Dobrinescu
Geosciences 2025, 15(7), 256; https://doi.org/10.3390/geosciences15070256 - 3 Jul 2025
Viewed by 304
Abstract
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock [...] Read more.
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock fragments preserved in the sedimentary successions of the Carpathian fold and thrust belt, specifically in the Outer Dacides and the Moldavides. Fragments of felsic rocks occurring within the sedimentary units of the Upper Cretaceous successions of the Moldavides have long been attributed to the Cuman Cordillera—an intrabasinal ridge in the Eastern Outer Carpathians. This work is the first complex geochemical and geochronological study on the exotic igneous clasts of the Cuman Cordillera. Igneous clasts from the southern part of the Moldavides (Variegated clay nappe/formation) are investigated here. They include mainly granites and rhyolites. Phaneritic rocks are composed of cumulus plagioclase, albite, amphibole and biotite, and intercumulus quartz and potassium feldspar, with apatite, magnetite, sphene, and zircon as main accessories, while the porphyritic rocks have a mineral assemblage similar to that mentioned above, displayed in a porphyritic texture with a usually crystallized groundmass. SHRIMP U-Pb zircon dating indicated the 583–597 Ma age interval for magma crystallization. Based on calcareous nannofossils, the depositional age of the investigated igneous clasts is Cenomanian to Maastrichtian, implying that the Cuman Cordillera was an emerged piece of land, herein an active source of sediments in the flysch basin for at least 40 Ma, from the Early Cretaceous (Aptian) to the Late Cretaceous (Maastrichtian). The intrusive and subvolcanic rocks show similar trends for trace and major elements, evincing their comagmatic nature. The enrichment in LILE and LREE relative to HFSE and HREE, as well as the element anomalies (e.g., negative Nb, Ta, and Eu and positive Rb, Ba, K, and Pb) suggest a convergent continental plate margin tectonic setting. Mineral chemistry suggests magma crystallization in relatively oxic conditions (magnetite series), during ascent within a depth of 15 km to 5 km. The igneous rocks attributed to the Cuman ridge display compositional and geochronological features similar to Brno and Thaya batholiths in the Brunovistulian terrane, which could be a piece of the Carpathian foreland not covered by the Tertiary thrusts. Our data confirm the non-Carpathian origin of the igneous clasts, revealing a Neoproterozoic history of the Carpathian foreland units, which include a Cadomian/Pan-African continental arc, exposed mainly during the Late Cretaceous as an intrabasinal island of the Alpine Tethys, traditionally known as the Cuman Cordillera. Full article
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29 pages, 12574 KiB  
Article
Weathering Records from an Early Cretaceous Syn-Rift Lake
by Yaohua Li, Qianyou Wang and Richard H. Worden
Hydrology 2025, 12(7), 179; https://doi.org/10.3390/hydrology12070179 - 3 Jul 2025
Viewed by 325
Abstract
The Aptian–Albian interval represents a significant cooling phase within the Cretaceous “hothouse” climate, marked by dynamic climatic fluctuations. High-resolution continental records are essential for reconstructing terrestrial climate and ecosystem evolution during this period. This study examines a lacustrine-dominated succession of the Shahezi Formation [...] Read more.
The Aptian–Albian interval represents a significant cooling phase within the Cretaceous “hothouse” climate, marked by dynamic climatic fluctuations. High-resolution continental records are essential for reconstructing terrestrial climate and ecosystem evolution during this period. This study examines a lacustrine-dominated succession of the Shahezi Formation (Lishu Rift Depression, Songliao Basin, NE Asia) to access paleo-weathering intensity and paleoclimate variability between the Middle Aptian and Early Albian (c. 118.2–112.3 Ma). Multiple geochemical proxies, including the Chemical Index of Alteration (CIA), were applied within a sequence stratigraphic framework covering four stages of lake evolution. Our results indicate that a hot and humid subtropical climate predominated in the Lishu paleo-lake, punctuated by transient cooling and drying events. Periods of lake expansion corresponded to episodes of intense chemical weathering, while two distinct intervals of aridity and cooling coincided with phases of a reduced lake level and fan delta progradation. To address the impact of potassium enrichment on CIA values, we introduced a rectangular coordinate system on A(Al2O3)-CN(CaO* + Na2O)-K(K2O) ternary diagrams, enabling more accurate weathering trends and CIA corrections (CIAcorr). Uncertainties in CIA correction were evaluated by integrating geochemical and petrographic evidence from deposits affected by hydrothermal fluids and external potassium addition. Importantly, our results show that metasomatic potassium addition cannot be reliably inferred solely from deviations in A-CN-K diagrams or the presence of authigenic illite and altered plagioclase. Calculations of “excess K2O” and CIAcorr values should only be made when supported by robust geochemical and petrographic evidence for external potassium enrichment. This work advances lacustrine paleoclimate reconstruction methodology and highlights the need for careful interpretation of weathering proxies in complex sedimentary systems. Full article
(This article belongs to the Special Issue Lakes as Sensitive Indicators of Hydrology, Environment, and Climate)
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21 pages, 5802 KiB  
Article
Response of Cretaceous Palynological Records to Regional Tectonic Events and Global Climate Change in Liupanshan Basin, Northwest China
by Bohua Liu, Fang Wu, Lijie Wei, Zhenhong Li and Xiaopeng Dong
Appl. Sci. 2025, 15(11), 5900; https://doi.org/10.3390/app15115900 - 23 May 2025
Viewed by 357
Abstract
The transition of the East Asian tectonic system during the Jurassic-Cretaceous period has had a profound influence on the paleoclimatic evolution in Northwest China. However, there are few studies on the climatic response to the tectonic events of this period. This study is [...] Read more.
The transition of the East Asian tectonic system during the Jurassic-Cretaceous period has had a profound influence on the paleoclimatic evolution in Northwest China. However, there are few studies on the climatic response to the tectonic events of this period. This study is based on the palynological analysis of the Lower Cretaceous Madongshan Formation in the southern Liupanshan Basin, Northwest China, and the summary of published data. It establishes a stratigraphic framework for the Early Cretaceous of the Liupanshan Basin and adjacent areas. It integrates the global Lower Cretaceous paleoclimatic background with the Middle Jurassic-late Lower Cretaceous sedimentary facies and the paleogeographic pattern of the Liupanshan Basin and the adjacent Ordos Basin. This integration aims to explore the climatic background differences between the Liupanshan and the Ordos Basin and to deduce the paleoclimatic response to tectonism and global paleoclimatic events. We determine an Aptian-Albian age for the Madongshan Formation in the Liupanshan Basin. This formation can be divided into three palynological assemblage zones from bottom to top (Zones I–III). In general, the climate changed from dry to wet, and the climate in Zone I was arid. In contrast, the adjacent Ordos Basin remained in a cool and humid environment during the sedimentation corresponding to Zone I. This points to a significant influence of the Jurassic-Cretaceous tectonic uplift on the regional climate evolution. Furthermore, the climate of Zone III became relatively humid in response to a global climatic cooling event at the Aptian-Albian transition. The study showed that the global climate change and regional tectonic events jointly influenced the regional climate evolution. Moreover, global climate change affected the paleoclimatic evolution of Northwest China later than the regional tectonic activities. Full article
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19 pages, 3019 KiB  
Article
Composition of Pre-Salt Siliciclastic Units of the Lower Congo Basin and Paleogeographic Implications for the Early Stages of Opening of the South Atlantic
by João Constantino, Pedro A. Dinis, Ricardo Sousa Gomes and Mário Miguel Mendes
Geosciences 2025, 15(5), 189; https://doi.org/10.3390/geosciences15050189 - 21 May 2025
Viewed by 591
Abstract
The Lower Congo Basin (LCB) is a rift-type basin with petroleum systems that developed at the western African margin in association with the opening of the South Atlantic. Two pre-salt siliciclastic units of the LCB, Lucula (uppermost Jurassic to Lower Cretaceous) and Chela [...] Read more.
The Lower Congo Basin (LCB) is a rift-type basin with petroleum systems that developed at the western African margin in association with the opening of the South Atlantic. Two pre-salt siliciclastic units of the LCB, Lucula (uppermost Jurassic to Lower Cretaceous) and Chela (Aptian) formations, were sampled in deep wells and outcrops. Heavy mineral assemblages, XRD mineralogy and geochemistry indicate prevailing source in high rank metamorphic rocks from western regions of the Lower Congo Belt. However, sediment composition reveals some provenance heterogeneity. For the Chela Formation, occasionally abundant amphibole in the heavy mineral fraction, coupled with relatively high Fe and Ti proportions, suggest that it formed when deeper crustal units were exhumed. The Lucula Formation collected in outcrops have composition substantially different from Lucula and Chela samples collected in deep wells, indicating distinct provenance and the incorporation of recycled material. A significant diagenetic overprint compromises the interpretation of compositional features in terms of paleoclimate. The presence of a chemical component with dolomite, halite and diverse sulphates and the stratigraphic position of the Chela Formation at the transition to a thick evaporitic succession are compelling evidence of deposition under warm and dry conditions, which are probably more extreme than those associated with the original stages of rifting recorded by the Lucula Formation. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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30 pages, 200218 KiB  
Article
Tectonic Evolution and Structural Control of Dike-Hosted Orogenic Gold Deposits in the Yana–Kolyma Collision Orogen (Eastern Siberia): Insights from the Eastern Margin of the Siberian Craton
by Valery Yurievich Fridovsky and Maxim Vasilievich Kudrin
Geosciences 2025, 15(5), 168; https://doi.org/10.3390/geosciences15050168 - 7 May 2025
Viewed by 586
Abstract
The Yana–Kolyma collision orogen, Eastern Siberia, is one of world-class gold economic belts, where large gold deposits are localized, mainly in the Upper Paleozoic and Lower Mesozoic clastic rocks. Dike-hosted orogenic gold deposits are found and to a lesser extent studied, but they [...] Read more.
The Yana–Kolyma collision orogen, Eastern Siberia, is one of world-class gold economic belts, where large gold deposits are localized, mainly in the Upper Paleozoic and Lower Mesozoic clastic rocks. Dike-hosted orogenic gold deposits are found and to a lesser extent studied, but they are important for understanding the structural control of mineralization within the framework of the orogen. Orogenic gold deposits of the Vyun ore field are hosted in Kimmeridgian–Titonian mafic, intermediate and felsic dikes, but they have no genetic connection with dikes. The late formation of deposits led to the fact that previously reactivated polydeformed structures were subsequently mineralized. The study of the structural control of mineralization is also complicated by superimposed late tectonic events. Based on the analysis of collected field materials, this paper presents the results of the study of deformation structures of the Vyun ore field within the framework of the Mesozoic evolution history throughout the geological time of the eastern convergent margin of the Siberian Craton. Four stages of deformations are identified. The pre-mineralization deformations and metamorphic and magmatic events share a common NE-SW shortening (D1 phase), which is related to the subduction of the Oymyakon oceanic slab and collision of the Kolyma–Omolon superterrane from the eastern margin of the Siberian Craton. This first stage is characterized by the superposition of several tectonic events under conditions of compression and progressive deformations (D1/1 and D1/2). Ore mineralization was formed at the end of compression in the same stress field (D1/2). Its structural control is determined by reactivation of older dikes and faults. Dikes are areas of heterogeneous stress and heterogeneous strain, being favorable for the concentration of ore fluids. The metallogenic time of formation of the gold mineralization is synchronous with the tectonic event, which likely reflects the final stages of the Kolyma–Omolon microcontinent–Siberian Craton collision of the Valanginian during crustal thickening. The main impulse of the Au mineralization D1/2 phase coincided with a slowdown in convergence. The post-mineralization tectonic regime was related to the Aptian–Late Cretaceous tectonic transition from compression to transpression. Transpressional tectonics were determined accordingly by W-E (D2 phase) and N-S (D3 phase) stress fields caused by several accretion events in the Cretaceous on the northern and eastern margins of Siberia. D4 phase extensional structures were caused by the opening of the Eurasian Oceanic basin in the Arctic in the Paleocene. The obtained results have a first-order impact on the understanding of the structural control of orogenic gold deposits and their relationship to the evolution of the host orogen. The new findings improve the tectonic knowledge of an area of interest for ore deposit exploration targeting orogenic gold deposits in Phanerozoic terranes of craton margins. Full article
(This article belongs to the Section Structural Geology and Tectonics)
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17 pages, 7526 KiB  
Article
Facies-Controlled Sedimentary Distribution and Hydrocarbon Control of Lower Cretaceous Source Rocks in the Northern Persian Gulf
by Yaning Wang, Wei Huang, Tao Cheng, Xuan Chen, Qinqin Cong and Jianhao Liang
J. Mar. Sci. Eng. 2025, 13(3), 576; https://doi.org/10.3390/jmse13030576 - 15 Mar 2025
Viewed by 643
Abstract
The two-phase source rocks deposited during the Lower Cretaceous in the Persian Gulf Basin play a pivotal role in the regional hydrocarbon system. However, previous studies have lacked a macroscopic perspective constrained by the Tethyan Ocean context, which has limited a deeper understanding [...] Read more.
The two-phase source rocks deposited during the Lower Cretaceous in the Persian Gulf Basin play a pivotal role in the regional hydrocarbon system. However, previous studies have lacked a macroscopic perspective constrained by the Tethyan Ocean context, which has limited a deeper understanding of their developmental patterns and hydrocarbon control mechanisms. To address this issue, this study aims to clarify the spatiotemporal evolution of the two-phase source rocks and their hydrocarbon control effects, with a particular emphasis on the critical impact of terrestrial input on the quality improvement of source rocks. Unlike previous studies that relied on a single research method, this study employed a comprehensive approach, including time series analysis, sequence stratigraphy, lithofacies, well logging, well correlation, seismic data, and geochemical analysis, to systematically compare and analyze the depositional periods, distribution, and characteristics of the two-phase source rocks under different sedimentary facies in the region. The goal was to reveal the intrinsic relationship between the Neo-Tethyan Ocean context and regional sedimentary responses. The results indicate the following: (1) the late Tithonian–Berriasian and Aptian–Albian source rocks in the Northern Persian Gulf were deposited during periods of extensive marine transgression, closely aligning with the global Weissert and OAE1d anoxic events, reflecting the profound impact of global environmental changes on regional sedimentary processes; (2) in the early stages of the Neo-Tethyan Ocean, controlled by residual topography, the Late Tithonian–Berriasian source rocks exhibited a shelf–intrashelf basin facies association, with the intrashelf basin showing higher TOC, lower HI, and higher Ro values compared to the deep shelf facies, indicating more favorable conditions for organic matter enrichment; (3) with the opening and deepening of the Neo-Tethyan Ocean, the Aptian–Albian source rocks at the end of the Lower Cretaceous transitioned to a shelf–basin facies association, with the basin facies showing superior organic matter characteristics compared to the shelf facies; (4) the organic matter content, type, and thermal maturity of the two-phase source rocks are primarily controlled by sedimentary facies and terrestrial input, with the Aptian–Albian source rocks in areas with terrestrial input showing significantly better quality than those without, confirming the decisive role of terrestrial input in improving source rock quality. In summary, this study not only reveals the differences in the depositional environments and hydrocarbon control mechanisms of the two-phase source rocks, but also highlights the core role of terrestrial input in enhancing source rock quality. The findings provide a basis for facies selection in deep natural gas exploration in the Zagros Belt and shale oil exploration in the western Rub’ al-Khali Basin, offering systematic theoretical guidance and practical insights for hydrocarbon exploration in the Persian Gulf and broader tectonic domains. Full article
(This article belongs to the Special Issue Advances in Offshore Oil and Gas Exploration and Development)
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26 pages, 8635 KiB  
Review
The Mundeck Salt Unit: A Review of Aptian Depositional Context and Hydrocarbon Potential in the Kribi-Campo Sub-Basin (South Cameroon Atlantic Basin)
by Mike-Franck Mienlam Essi, Eun Young Lee, Mbida Yem, Jean Marcel Abate Essi and Joseph Quentin Yene Atangana
Geosciences 2024, 14(10), 267; https://doi.org/10.3390/geosciences14100267 - 11 Oct 2024
Viewed by 1320
Abstract
The Kribi-Campo sub-basin, located in the Gulf of Guinea, constitutes the southeastern segment of the Cameroon Atlantic Margin. Drilling in the Aptian salt unit revealed a sparse hydrocarbon presence, contrasting with modest finds in its counterparts like the Ezanga Salt in Gabon and [...] Read more.
The Kribi-Campo sub-basin, located in the Gulf of Guinea, constitutes the southeastern segment of the Cameroon Atlantic Margin. Drilling in the Aptian salt unit revealed a sparse hydrocarbon presence, contrasting with modest finds in its counterparts like the Ezanga Salt in Gabon and the Rio Muni Salt in Equatorial Guinea. This discrepancy prompted a reassessment of the depositional context and hydrocarbon potential of the Mundeck salt unit. By integrating 2D seismic reflection and borehole data analysis, this study established the structural and stratigraphic framework of the area, emphasizing the salt unit’s significance. Borehole data indicate a localized salt unit offshore Kribi, with seismic reflection data revealing distinct forms of diapir and pillow. This salt unit displays a substantial lateral extent with thicknesses ranging from 4000 m to 6000 m. The depositional context is linked to the following two major geological events: a significant sea-level drop due to margin uplift during the Aptian and thermodynamic processes driven by transfer faults related to mid-oceanic ridge formation. These events were crucial in forming and evolving the Mundeck Salt. Regarding hydrocarbon prospects, this study identifies the unit as being associated with potential petroleum plays, supported by direct hydrocarbon indicators and fault-related structures. The findings suggest that untapped hydrocarbon resources may still exist, underscoring the need for further exploration and analysis. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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18 pages, 19382 KiB  
Article
Geosites of Northern Mountainous Adygeya (Southwestern Russia): A Novel Vision
by Anna V. Mikhailenko and Dmitry A. Ruban
Geosciences 2024, 14(10), 249; https://doi.org/10.3390/geosciences14100249 - 24 Sep 2024
Cited by 2 | Viewed by 1183
Abstract
Territorial inventories of geosites remain on the international agenda, and they can help in acquiring information for solving pure geological research tasks. New field investigations in the northern part of Mountainous Adygeya (geoheritage-rich territory in the western Greater Caucasus) permitted us to extend [...] Read more.
Territorial inventories of geosites remain on the international agenda, and they can help in acquiring information for solving pure geological research tasks. New field investigations in the northern part of Mountainous Adygeya (geoheritage-rich territory in the western Greater Caucasus) permitted us to extend our knowledge of its geosites. Five geosites were described qualitatively and assessed semi-quantitatively, namely the Polkovnitskaya River Valley (ammonite-bearing concretions of Aptian glauconitic sandstones), the Little Khadzhokh River Valley (Aptian glauconitic sandstones with fossils and trace fossils), the Shakhan and Middle Khadzhokh River Valley (Upper Jurassic variegated siliciclastics, Hauterivian fluvial and deltaic sandstones, mixed ancient and modern clastic material), the Big Khadzhoh Waterfall (splendid waterfall and exposures of locally folded Oxfordian–Kimmeridgian limestones), and the Verblyud Mountain (small, camel-shaped cuesta’s remnant). They were ranked nationally (one geosite), regionally (three geosites), and locally (one geosite). Close examination of the considered geosites permitted to register pure geological peculiarities (changes in the dip direction between sedimentary packages), which indicate the tectonic activity across the Jurassic–Cretaceous transition. Additionally, complex accessibility patterns were established in some geosites, and these patterns should be addressed in further refinements of the semi-quantitative approaches to geosite assessment. Full article
(This article belongs to the Section Geoheritage, Geoparks and Geotourism)
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22 pages, 10641 KiB  
Article
Systematic of a Massively Constructed Specimen of Iguanodon galvensis (Ornithopoda, Iguanodontidae) from the Early Barremian (Early Cretaceous) of Eastern Spain
by Josué García-Cobeña, Francisco J. Verdú and Alberto Cobos
Diversity 2024, 16(9), 586; https://doi.org/10.3390/d16090586 - 17 Sep 2024
Cited by 2 | Viewed by 4886
Abstract
Styracosternan ornithopods are plenty abundant in the Lower Cretaceous fossil record of Europe. In particular, Iguanodon, the second genus of dinosaurs described worldwide, has been found in UK, Belgium, France, Germany, and Spain, evidencing a wide geographical distribution. Currently, the genus Iguanodon [...] Read more.
Styracosternan ornithopods are plenty abundant in the Lower Cretaceous fossil record of Europe. In particular, Iguanodon, the second genus of dinosaurs described worldwide, has been found in UK, Belgium, France, Germany, and Spain, evidencing a wide geographical distribution. Currently, the genus Iguanodon comprises two species, the type species I. bernissartensis from the late Barremian–Aptian of Europe and I. galvensis from the early Barremian of Teruel, Spain. The latter species is well known mainly from perinate and juvenile specimens. Here, axial and appendicular fossils of an adult, large and massively constructed ornithopod from the lower Barremian (Lower Cretaceous) Camarillas Formation of Galve (province of Teruel, Spain) are described. Fossil dimensions and some osteological evidence reveal that the specimen was a large (roughly 10 m long) ornithopod. An autapomorphic feature in the ischium and other characters allow us to ascribe this specimen to I. galvensis. In addition, postcranial co-ossification and fusion of the neurocentral suture indicate that the specimen was skeletally mature. Part of the material studied here was unknown in adults of I. galvensis, providing a better knowledge of the axial and appendicular region of this species. Full article
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9 pages, 2815 KiB  
Communication
Flower Buds Confirmed in the Early Cretaceous of China
by Weijia Huang and Xin Wang
Biology 2024, 13(6), 413; https://doi.org/10.3390/biology13060413 - 4 Jun 2024
Viewed by 2696
Abstract
The Yixian Formation (Lower Cretaceous) in China is famous worldwide for its fossils of early angiosperms, but there has been only one record of flower buds (Archaebuda lingyuanensis) hitherto, in which only the surface of the flower bud was documented while [...] Read more.
The Yixian Formation (Lower Cretaceous) in China is famous worldwide for its fossils of early angiosperms, but there has been only one record of flower buds (Archaebuda lingyuanensis) hitherto, in which only the surface of the flower bud was documented while no internal details were known. Such a partial knowledge of flower buds hinders our understanding of the evolution of flowers, and this knowledge lacuna needs to be filled. Our new specimen was collected from an outcrop of the Yixian Formation (Barremian–Aptian, Lower Cretaceous) near Dawangzhangzi, Lingyuan, Liaoning, China. Our observations reveal a new fossil flower bud, Archaebuda cretaceae sp. nov., from the Lower Cretaceous of China. This new record of Archaebuda in the Yixian Formation not only confirms the truthful existence of the expected gynoecium (plus possible androecium) in a flower bud but also underscores the occurrence of typical flowers in the Early Cretaceous. This new information adds first-hand data to flower sexuality, pollination, and evolution. Full article
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20 pages, 3764 KiB  
Article
Carbonate Stable Isotope Data Suggest Freshwater Environment for the McMurray Formation (Aptian), Alberta, Canada
by Franek Hasiuk, Abdullah Wahbi, Luis González, Mike Blum and Greg Ludvigson
Geosciences 2024, 14(5), 120; https://doi.org/10.3390/geosciences14050120 - 28 Apr 2024
Viewed by 2017
Abstract
Stable isotope, trace element, and cathodoluminescence analyses were performed on gastropods and matrix from rock cores of the Middle to Upper McMurray Formation (Lower Cretaceous/Aptian, Northwestern Alberta, Canada) to characterize the extent to which pristine material remained from which depositional environmental conditions could [...] Read more.
Stable isotope, trace element, and cathodoluminescence analyses were performed on gastropods and matrix from rock cores of the Middle to Upper McMurray Formation (Lower Cretaceous/Aptian, Northwestern Alberta, Canada) to characterize the extent to which pristine material remained from which depositional environmental conditions could be estimated. Aragonitic gastropod shells retain their original depositional chemistry, and along with other closely associated authigenic carbonate components, indicate that the Middle to Upper McMurray Formation was deposited in a freshwater environment that was part of a continent-scale river system. Full article
(This article belongs to the Section Climate and Environment)
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26 pages, 45411 KiB  
Article
Metallogenic Difference between the Late Aptian Nansu and Aishan Pluton in Jiaodong: Constraints from In Situ Apatite Elemental and Nd Isotopic Composition
by Kexin Li, Liqiang Yang, Lei Ju and Dong Xie
Minerals 2024, 14(4), 372; https://doi.org/10.3390/min14040372 - 31 Mar 2024
Viewed by 1804
Abstract
A series of Mo-polymetallic deposits have been developed in the Jiaodong Peninsula. Notably, these Mo-dominant deposits formed essentially during the same period as the well-known world-class Au deposits in this area, hinting at a potentially unique geological correlation between them. Therefore, conducting thorough [...] Read more.
A series of Mo-polymetallic deposits have been developed in the Jiaodong Peninsula. Notably, these Mo-dominant deposits formed essentially during the same period as the well-known world-class Au deposits in this area, hinting at a potentially unique geological correlation between them. Therefore, conducting thorough research on Mo deposits in Jiaodong holds significant importance in exploring the area’s controlling factors of Mesozoic metal endowments. To reveal the petrogenesis and metallogenic potentials of Mo-fertile and ore-barren granitoid, apatite grains from the Late Aptian Nansu granodiorite and Aishan monzogranite are investigated in this study. Detailed petrographical observations, combined with in situ analysis of electron probe micro-analyzer (EPMA) and Laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), have been conducted on apatite grains from the Nansu and Aishan plutons. This comprehensive analysis, encompassing both major and trace elements as well as isotopic characteristics of apatite, aims to elucidate the metallogenic differences within the late Early Cretaceous granitoids of Jiaodong. The results reveal that the apatite grains across all samples belong to fluorapatites, suggesting their magmatic origin. Additionally, chondrite-normalized rare earth element (REE) patterns of apatites in ore-fertile and ore-barren granitoids exhibit a “right-leaning” trend, characterized by relative enrichments in light REEs and depletions in heavy REEs. Both the Nansu and Aishan plutons exhibit moderately negative Eu anomalies (with averages δEu values of 0.44 and 0.51, respectively), along with slightly positive Ce anomalies (averaging δCe values of 1.08 and 1.11, respectively). A negative correlation is observed between their δEu and δCe values, indicating that the parental magmas of ore-fertile and ore-barren granitoids were formed in a relatively oxidizing environment. The calculated apatite OH contents for the Nansu pluton range from 0.26 to 1.38, while those for the Aishan pluton vary between 0.24 and 1.51, indicating comparable melt H2O abundances. Consequently, the results suggest that neither the oxygen fugacities nor the water contents of the parental magma can account for the metallogenic differences between Nansu and Aishan plutons. The apatite in the Nansu pluton exhibits a higher Ce/Pb ratio and a relatively lower Th/U ratio, indicating the involvement of a greater volume of fluids in the magmatic evolution process of this ore-bearing granitoid. Apatite grains sourced from the Nansu and Aishan plutons exhibit εNd(t) values ranging from −16.63 to −17.61 (t = 115.7 Ma) and −17.86 to −20.86 (t = 116.8 Ma), respectively. These results suggest that their parental magmas primarily originated from the partial melting of Precambrian metamorphic basement rocks within the North China Craton, with a minor contribution from mantle-derived materials. Additionally, the presence of mafic microgranular enclaves in both the Nansu and Aishan plutons indicates that both have undergone magma mixing processes. The binary diagrams plotting the ratios of Ba/Th, Sr/Th, and U/Th against La/Sm demonstrate that apatite grains of ore-fertile granitoid exhibit a distinct trend towards sediment melting. This suggests the potential incorporation of sedimentary materials, particularly those rich in molybdenum, into the magmatic source of the Nansu pluton, ultimately leading to the occurrence of molybdenum mineralization. Full article
(This article belongs to the Special Issue The Formation and Evolution of Gold Deposits in China)
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35 pages, 37975 KiB  
Article
Interactions between Clays and Carbonates in the Aptian Pre-Salt Reservoirs of Santos Basin, Eastern Brazilian Margin
by Argos Belmonte Silveira Schrank, Thisiane Dos Santos, Sabrina Danni Altenhofen, William Freitas, Elias Cembrani, Thiago Haubert, Felipe Dalla Vecchia, Rosalia Barili, Amanda Goulart Rodrigues, Anderson Maraschin and Luiz Fernando De Ros
Minerals 2024, 14(2), 191; https://doi.org/10.3390/min14020191 - 11 Feb 2024
Cited by 7 | Viewed by 3314
Abstract
The giant Pre-salt reservoirs represent most of the oil production in Brazil. The main Aptian sag reservoirs were deposited in a unique and highly complex hyper-alkaline lacustrine setting. These deposits are essentially constituted by fascicular and spherulitic calcite precipitated in a magnesian clay [...] Read more.
The giant Pre-salt reservoirs represent most of the oil production in Brazil. The main Aptian sag reservoirs were deposited in a unique and highly complex hyper-alkaline lacustrine setting. These deposits are essentially constituted by fascicular and spherulitic calcite precipitated in a magnesian clay matrix (stevensite, kerolite, and saponite/hectorite). Although vital for understanding the origin and main reservoir quality control, the genesis and interactions of clays and carbonates are still poorly constrained. The detailed petrographic description was focused on 812 thin sections from five wells drilled in the Santos Basin Aptian Barra Velha Formation, combined with cathodoluminescence, UV epifluorescence, and X-ray diffraction analyses. The main syngenetic processes were the deposition of finely laminated peloidal and ooidal Mg-clays, the formation of fascicular calcite crusts on the sediment–water interface, and the redeposition of these materials as intraclasts. Abundant clay peloids engulfed in syngenetic shrubs indicate that calcite and clay precipitation was concomitant, though with highly variable rates. Eodiagenetic phases include matrix-replacive and -displacive spherulites and fascicular shrubs; matrix-replacive blocky calcite and dolomite; lamellar carbonates filling matrix shrinkage pores; and microcrystalline calcite, dolomite, and silica replacing the Mg-clay matrix. The preferential dolomitization and calcitization of peloidal layers were most likely due to their higher permeability and larger specific surface. Matrix-replacive saddle dolomite, macrocrystalline calcite, and dawsonite are interpreted as mesodiagenetic or hydrothermal phases after significant matrix dissolution. Unraveling the processes of the formation and alteration of the carbonates and clays and their interactions in the Pre-salt deposits is essential for constraining the depositional and diagenetic conditions in their unique environments and their diagenetic overprinting and for decreasing the exploration risks and increasing the production of those extraordinary reservoirs. Full article
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31 pages, 7614 KiB  
Article
Aptian Li-F Granites of the Northern Verkhoyansk–Kolyma Orogenic Belt, Eastern Russia: Composition, Genesis, and Ore Potential
by Vera A. Trunilina and Andrei V. Prokopiev
Minerals 2024, 14(2), 173; https://doi.org/10.3390/min14020173 - 5 Feb 2024
Viewed by 1419
Abstract
This paper reports the results from an investigation on the geochemistry and petrogenesis of the Aptian Li-F granites from the Omchikandya, Burgali, and Arga Ynnakh Khaya ore fields in the northern Verkhoyansk–Kolyma orogenic belt in eastern Russia. Li-F microcline–albite granites intrude the Late [...] Read more.
This paper reports the results from an investigation on the geochemistry and petrogenesis of the Aptian Li-F granites from the Omchikandya, Burgali, and Arga Ynnakh Khaya ore fields in the northern Verkhoyansk–Kolyma orogenic belt in eastern Russia. Li-F microcline–albite granites intrude the Late Jurassic to Early Cretaceous syn-collisional granitoids. According to their geochemical composition, they are close to A-type granites and can be subdivided into low-P and high-P varieties, differing in their geochemistry and genesis. The low-P microcline–albite granites (Omchikandya massif) intrude syn-collisional biotite granites. It is assumed that the formation of their parent melt occurred at deep levels in the same magma chamber that produced biotite granites. The high-P granites (Verkhne–Burgali ethmolith and Kester harpolith) are supposed to have been derived from melts originated from a high-grade metamorphosed lower crustal protolith under the influence of deep-seated fluid flows related to diapirs of alkaline-ultrabasic or alkaline-basic composition. It is supposed that their formation was related to post-collisional extension during the early stages of the evolution of the Aptian–Late Cretaceous Indigirka belt of crust extension. All studied Li-F granites are enriched with rare metals and have associated Li deposits with accompanying Sn, W, Ta, and Nb mineralization. In the low-P Li-F Omchikandya massif, mineralization tends to occur within greisenized granites and greisens in their apical parts. In the high-P granite massifs, mineralization is found throughout their volume, and, therefore, the Verkhne–Burgali ethmolith and Kester harpolith can be considered as large ore bodies. There is a direct dependence of the content and reserves of Li2O on the content of P2O5. Minimum Li2O reserves are established in low-P Li-F microcline–albite granites of the Polyarnoe deposit of the Omchikandya ore field, whereas in the high-P granites of the Verkhne–Burgali and Kester deposits, the Li2O reserves are significantly higher. Full article
(This article belongs to the Section Mineral Deposits)
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18 pages, 4616 KiB  
Article
A New Sinamiin Fish (Actinopterygii) from the Early Cretaceous of Thailand: Implications on the Evolutionary History of the Amiid Lineage
by Uthumporn Deesri, Wilailuck Naksri, Pratueng Jintasakul, Yoshikazu Noda, Hirokazu Yukawa, Tamara El Hossny and Lionel Cavin
Diversity 2023, 15(4), 491; https://doi.org/10.3390/d15040491 - 27 Mar 2023
Cited by 3 | Viewed by 3776
Abstract
The Sinamiidae are a family of halecomorph fishes (Holostei) stratigraphically limited to the Lower Cretaceous and confined to East Asia. The first species of sinamiids were discovered in China, and then new occurrences were recorded in Thailand and Japan. The three recognized genera, [...] Read more.
The Sinamiidae are a family of halecomorph fishes (Holostei) stratigraphically limited to the Lower Cretaceous and confined to East Asia. The first species of sinamiids were discovered in China, and then new occurrences were recorded in Thailand and Japan. The three recognized genera, Sinamia, Siamamia and Ikechaoamia, are notably characterized by an unpaired parietal. Here, we describe a new genus and species of sinamiid based on material from the Aptian Khok Kruat Formation of Ban Krok Duean Ha, Nakhon Ratchasima, Thailand. The new taxon known from preserved specimens in 3D is characterized by four pairs of extrascapular and tall cylindrical teeth with a conical enamel stalk topped by an arrowhead-shaped acrodine cap, among other characters. A phylogenetic analysis of the halecomorph fishes shows that the new taxon is the sister of the other Thai species, Siamamia naga, and that the two are grouped with two Chinese genera in a strongly supported clade, the Sinamiinae. This subfamily is here grouped with the Amiinae that contained the extant Amia. This new discovery is a clue that Southeast Asia may have been a center of diversification for this fish clade, and the phylogenetic analysis reveals that amiines may have originated somewhere in Asia during the Cretaceous before they spread throughout the northern hemisphere. Full article
(This article belongs to the Special Issue Women’s Special Issue Series: Diversity)
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