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Keywords = “dry” immersion

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25 pages, 2341 KiB  
Article
Lipid-Enriched Cooking Modulates Starch Digestibility and Satiety Hormone Responses in Traditional Nixtamalized Maize Tacos
by Julian de la Rosa-Millan
Foods 2025, 14(15), 2576; https://doi.org/10.3390/foods14152576 - 23 Jul 2025
Viewed by 525
Abstract
Traditional taco preparation methods, such as oil immersion and steaming, can significantly affect the nutritional and metabolic characteristics of the final product. This study evaluated tacos made with five commercial nixtamalized maize flours and four common fillings (chicharron, beef skirt, potato, and refried [...] Read more.
Traditional taco preparation methods, such as oil immersion and steaming, can significantly affect the nutritional and metabolic characteristics of the final product. This study evaluated tacos made with five commercial nixtamalized maize flours and four common fillings (chicharron, beef skirt, potato, and refried beans), processed using three different methods: Plain, Full-Fat, and Patted-Dry. We assessed their chemical composition, starch digestibility, and thermal properties, and measured satiety-related hormone responses in mice. Fillings had a stronger influence on protein, fat, and moisture content than tortilla type. Full-fat tacos exhibited increased amylose–lipid complex formation and a lower gelatinization enthalpy, whereas plain tacos retained more retrograded starch and a crystalline structure. In vitro digestion revealed that Plain tacos, especially those with plant-based fillings, had the highest resistant starch content and the lowest predicted glycemic index. Hierarchical clustering showed that resistant starch, moisture, and gelatinization onset temperature were closely linked in the Plain samples, whereas lipid-driven variables dominated in the Full-Fat tacos. In mice, tacos with a higher resistant starch content led to greater GLP-1 levels, lower ghrelin levels, and reduced insulin responses, suggesting improved satiety and glycemic control. Patted-Dry tacos showed intermediate hormonal effects, supporting their potential as a balanced, health-conscious alternative. These findings demonstrate how traditional preparation techniques can be leveraged to enhance the nutritional profile of culturally relevant foods, such as tacos. Full article
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16 pages, 1945 KiB  
Article
Debaryomyces hansenii Enhances Growth, Nutrient Uptake, and Yield in Rice Plants (Oryza sativa L.) Cultivated in Calcareous Soil
by Jorge Núñez-Cano, Francisco J. Ruiz-Castilla, José Ramos, Francisco J. Romera and Carlos Lucena
Agronomy 2025, 15(7), 1696; https://doi.org/10.3390/agronomy15071696 - 14 Jul 2025
Viewed by 466
Abstract
Calcareous soils, characterized by high pH and calcium carbonate content, often limit the availability of essential nutrients for crops such as rice (Oryza sativa L.), reducing yield and nutritional quality. In this study, we evaluated the effect of the halotolerant yeast Debaryomyces [...] Read more.
Calcareous soils, characterized by high pH and calcium carbonate content, often limit the availability of essential nutrients for crops such as rice (Oryza sativa L.), reducing yield and nutritional quality. In this study, we evaluated the effect of the halotolerant yeast Debaryomyces hansenii on the growth, nutrient uptake, and phosphorus acquisition mechanisms of rice plants cultivated in calcareous soil under controlled greenhouse conditions. Plants inoculated with D. hansenii, particularly via root immersion, exhibited significantly higher SPAD chlorophyll index, plant height, and grain yield compared to controls. A modest increase (~4%) in dry matter content was also observed under sterilized soil conditions. Foliar concentrations of Fe, Zn, and Mn significantly increased in plants inoculated with D. hansenii via root immersion in non-sterilized calcareous soil, indicating improved micronutrient acquisition under these specific conditions. Although leaf phosphorus levels were not significantly increased, D. hansenii stimulated acid phosphatase activity, as visually observed through BCIP staining, and upregulated genes involved in phosphorus acquisition under both P-sufficient and P-deficient conditions. At the molecular level, D. hansenii upregulated the expression of acid phosphatase genes (OsPAP3, OsPAP9) and a phosphate transporter gene (OsPTH1;6), confirming its influence on P-related physiological responses. These findings demonstrate that D. hansenii functions as a plant growth-promoting yeast (PGPY) and may serve as a promising biofertilizer for improving rice productivity and nutrient efficiency in calcareous soils, contributing to sustainable agricultural practices in calcareous soils and other nutrient-limiting environments. Full article
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19 pages, 26396 KiB  
Article
Development of a Networked Multi-Participant Driving Simulator with Synchronized EEG and Telemetry for Traffic Research
by Poorendra Ramlall, Ethan Jones and Subhradeep Roy
Systems 2025, 13(7), 564; https://doi.org/10.3390/systems13070564 - 10 Jul 2025
Viewed by 422
Abstract
This paper presents a multi-participant driving simulation framework designed to support traffic experiments involving the simultaneous collection of vehicle telemetry and cognitive data. The system integrates motion-enabled driving cockpits, high-fidelity steering and pedal systems, immersive visual displays (monitor or virtual reality), and the [...] Read more.
This paper presents a multi-participant driving simulation framework designed to support traffic experiments involving the simultaneous collection of vehicle telemetry and cognitive data. The system integrates motion-enabled driving cockpits, high-fidelity steering and pedal systems, immersive visual displays (monitor or virtual reality), and the Assetto Corsa simulation engine. To capture cognitive states, dry-electrode EEG headsets are used alongside a custom-built software tool that synchronizes EEG signals with vehicle telemetry across multiple drivers. The primary contribution of this work is the development of a modular, scalable, and customizable experimental platform with robust data synchronization, enabling the coordinated collection of neural and telemetry data in multi-driver scenarios. The synchronization software developed through this study is freely available to the research community. This architecture supports the study of human–human interactions by linking driver actions with corresponding neural activity across a range of driving contexts. It provides researchers with a powerful tool to investigate perception, decision-making, and coordination in dynamic, multi-participant traffic environments. Full article
(This article belongs to the Special Issue Modelling and Simulation of Transportation Systems)
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21 pages, 6724 KiB  
Article
Experimental Study on Damage Characteristics and Microcrack Development of Coal Samples with Different Water Erosion Under Uniaxial Compression
by Maoru Sun, Qiang Xu, Heng He, Jiqiang Shen, Xun Zhang, Yuanfeng Fan, Yukuan Fan and Jinrong Ma
Processes 2025, 13(7), 2196; https://doi.org/10.3390/pr13072196 - 9 Jul 2025
Viewed by 344
Abstract
It is vital to stabilize pillar dams in underground reservoirs in coal mine goafs to protect groundwater resources and quarry safety, practice green mining, and protect the ecological environment. Considering the actual occurrence of coal pillar dams in underground reservoirs, acoustic emission (AE) [...] Read more.
It is vital to stabilize pillar dams in underground reservoirs in coal mine goafs to protect groundwater resources and quarry safety, practice green mining, and protect the ecological environment. Considering the actual occurrence of coal pillar dams in underground reservoirs, acoustic emission (AE) mechanical tests were performed on dry, naturally absorbed, and soaked coal samples. According to the mechanical analysis, Quantitative analysis revealed that dry samples exhibited the highest mechanical parameters (peak strength: 12.3 ± 0.8 MPa; elastic modulus: 1.45 ± 0.12 GPa), followed by natural absorption (peak strength: 9.7 ± 0.6 MPa; elastic modulus: 1.02 ± 0.09 GPa), and soaked absorption showed the lowest values (peak strength: 7.2 ± 0.5 MPa; elastic modulus: 0.78 ± 0.07 GPa). The rate of mechanical deterioration increased by ~25% per 1% increase in moisture content. It was identified that the internal crack development presented a macrofracture surface initiating at the sample center and expanding radially outward, and gradually expanding to the edges by adopting AE seismic source localization and the K-means clustering algorithm. Soaked absorption was easier to produce shear cracks than natural absorption, and a higher water content increased the likelihood. The b-value of the AE damage evaluation index based on crack development was negatively correlated with the rock damage state, and the S-value was positively correlated, and both effectively characterized it. The research results can offer reference and guidance for the support design, monitoring, and warning of coal pillar dams in underground reservoirs. (The samples were tested under two moisture conditions: (1) ‘Soaked absorption’—samples fully saturated by immersion in water for 24 h, and (2) ‘Natural absorption’—samples equilibrated at 50% relative humidity and 25 °C for 7 days). Full article
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21 pages, 1558 KiB  
Article
In Vitro Germination of the Mediterranean Xerophytes Thymelaea hirsuta and Thymelaea tartonraira ssp. tartonraira as Affected by Scarification, Temperature, Photoperiod and Storage
by Aikaterini N. Martini and Maria Papafotiou
Seeds 2025, 4(3), 31; https://doi.org/10.3390/seeds4030031 - 4 Jul 2025
Viewed by 401
Abstract
With the aim of developing an efficient propagation method for the exploitation of Thymelaea hirsuta and T. artonraira ssp. tartonraira in the xeriscaping and pharmaceutical industry, the effects of the following were examined on the in vitro germination of their seeds: (i) pretreatment [...] Read more.
With the aim of developing an efficient propagation method for the exploitation of Thymelaea hirsuta and T. artonraira ssp. tartonraira in the xeriscaping and pharmaceutical industry, the effects of the following were examined on the in vitro germination of their seeds: (i) pretreatment (mechanical and chemical scarification or immersion in hot water; (ii) incubation temperature (5–30 °C); (iii) incubation light conditions (16 h photoperiod or continuous darkness); (iv) storage period at room temperature and darkness (up to 24 months). Seeds collected for two years from the same wild plants in Greece were surface-sterilized with a 15% commercial bleach solution for 15 min after the abovementioned treatments and placed for germination in Petri dishes containing a half-strength MS medium in growth chambers. The rate and final percentage of germination were recorded. For both species, scarification after immersion in concentrated H2SO4, preferably for 20 min, was necessary for seed germination, which indicates coat dormancy. Higher germination percentages were observed at temperatures of 10–20 °C, under continuous darkness for T. hirsuta (79–100%) and regardless of photoperiod for T. tartonraira (73–90%). Long storage reduced germination of only T. tartonraira (54–68% at optimum temperatures, 23 months after harvest), while T. hirsuta seeds stored for 5 months germinated at significantly lower percentages (40% maximum) compared to seeds stored for 9–24 months, revealing a dry after-ripening process. Seeds of both species harvested at different years showed stable behavior in terms of germination. For both species, an effective seed propagation protocol suitable for their exploitation as ornamental and landscape plants was developed. Full article
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15 pages, 5321 KiB  
Article
Acoustic Modal Characteristics of Pump Tower Structures Based on Fluid–Structure Coupling Effects
by Wei Song, Aoyu Xie, Yonggang Lu, Yun Zhao and Zhengwei Wang
Water 2025, 17(13), 1864; https://doi.org/10.3390/w17131864 - 23 Jun 2025
Viewed by 326
Abstract
This study investigated the acoustic modal characteristics of pump tower structures under fluid–structure coupling effects through a finite element analysis. Compared with the dry condition, filling the internal pipelines with liquid causes the first three natural frequencies to decrease by 17.12%, 16.80%, and [...] Read more.
This study investigated the acoustic modal characteristics of pump tower structures under fluid–structure coupling effects through a finite element analysis. Compared with the dry condition, filling the internal pipelines with liquid causes the first three natural frequencies to decrease by 17.12%, 16.80%, and 19.50%, respectively, while full external immersion (wet mode) further reduces them by 15.60%, 15.10%, and 5.30%. As the liquid level in the surrounding storage tank increases from 0% to 100%, the first-mode frequency falls from 6.07 Hz to 5.13 Hz (a 15.5% reduction), the second-mode from 14.71 Hz to 12.48 Hz (15.1%), and the third-mode from 19.69 Hz to 18.63 Hz (5.5%). Mode-shape distributions remain qualitatively similar across liquid levels, although local deformation magnitudes decrease by up to 21.0% for the first mode and 18.3% for the second mode. These quantitative findings provide a theoretical and technical basis for predicting dynamic responses of pump tower structures in complex fluid environments. Full article
(This article belongs to the Special Issue Hydrodynamics Science Experiments and Simulations, 2nd Edition)
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12 pages, 764 KiB  
Article
Histological Analysis of Root Surface Treatment with Tetracycline and Ampicillin in the Repair Process of Rat Teeth Subjected to Delayed Replantation
by Guilherme Assumpção Silva, Celso Koogi Sonoda, Marina Fuzette Amaral, Vitor Hugo Gonçalves Sampaio and Daniela Atili Brandini
J. Clin. Med. 2025, 14(13), 4443; https://doi.org/10.3390/jcm14134443 - 23 Jun 2025
Viewed by 321
Abstract
Background/Objectives: Avulsion is a major cause of tooth loss, and its treatment involves replantation. This study analyzed the repair process of incisive teeth subjected to delayed replantation after topical treatment with ampicillin and tetracycline. Methods: Forty male rats were equally divided into four [...] Read more.
Background/Objectives: Avulsion is a major cause of tooth loss, and its treatment involves replantation. This study analyzed the repair process of incisive teeth subjected to delayed replantation after topical treatment with ampicillin and tetracycline. Methods: Forty male rats were equally divided into four groups: immediate replantation (IM), ampicillin (AM), tetracycline (TR), and dry medium (SE). In the IM group, replantation was performed 5 min after experimental avulsion, whereas in the SE group, the teeth were kept in a dry medium for 60 min. In the AM and TR groups, the teeth were stored in whole bovine milk for 60 min, and then immersed in their respective ampicillin and tetracycline solutions for 5 min. Euthanasia was performed 60 days after the experimental surgery. Histological slides were stained with Hematoxylin and Eosin for quantitative and qualitative analyses. Results: No statistically significant differences were observed among the IM, AM, and TR groups regarding the total resorption area, reattached periodontal ligament fibers, and ankylosis. However, when compared to the SE group, these groups exhibited a smaller total resorption area (IM: p = 0.005; AM: p = 0.0007; TR: p = 0.03), a larger area of periodontal ligament fibers reattachment (IM: p = 0.0002; AM: p = 0.0002; TR: p = 0.02), and a lower presence of ankylosis (IM: p = 0.005; AM: p = 0.0002; TR: p = 0.03). The AM group exhibited the smallest inflammatory resorption. Conclusions: It is concluded that, in an aseptic environment, the use of topical antibiotics such as ampicillin and tetracycline in the treatment of the root surface during replantation of teeth stored in milk is beneficial to the periodontal repair process and root resorption. Notably, ampicillin demonstrated superior efficacy in mitigating inflammatory root resorption and better periodontal ligament reattachment. Full article
(This article belongs to the Section Dentistry, Oral Surgery and Oral Medicine)
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15 pages, 3367 KiB  
Article
Chitosan Nanoparticles: An Alternative for In Vitro Multiplication of Sugarcane (Saccharum spp.) in Semi-Automated Bioreactors
by Eucario Mancilla-Álvarez, María Karen Serrano-Fuentes, María Angélica Fuentes-Torres, Ricardo Sánchez-Páez and Jericó Jabín Bello-Bello
Plants 2025, 14(11), 1697; https://doi.org/10.3390/plants14111697 - 1 Jun 2025
Viewed by 827
Abstract
Chitosan nanoparticles (CsNPs) are biocompatible, biodegradable, and non-toxic natural polymers at low concentrations with diverse applications in in vitro plant tissue culture. This study aims to evaluate the effect of CsNPs during in vitro multiplication of sugarcane (Saccharum spp.) using temporary immersion [...] Read more.
Chitosan nanoparticles (CsNPs) are biocompatible, biodegradable, and non-toxic natural polymers at low concentrations with diverse applications in in vitro plant tissue culture. This study aims to evaluate the effect of CsNPs during in vitro multiplication of sugarcane (Saccharum spp.) using temporary immersion bioreactors. CsNPs were evaluated at concentrations of 0, 25, 50, 100, and 200 mg L−1 in Murashige and Skoog liquid culture medium. After four weeks of culture, response percentage, the number of shoots per explant, shoot length, number of leaves per explant, dry matter, chlorophyll content, β-carotene content, lipid peroxidation, phenolic content, hydrogen peroxide content, and antioxidant capacity were evaluated. The results showed that the highest response percentages were obtained in the treatments with 0, 25, and 50 mg L−1 CsNPs, whereas the lowest response percentages were obtained in the treatments with 100 and 200 mg L−1 CsNPs. Concentrations of 25 and 50 mg L−1 CsNPs promoted cell growth and differentiation, whereas 100 and 200 mg L−1 CsNPs inhibited it. Chlorophyll content increased by 25 and 50 mg L-1 CsNPs, whereas β-carotene content increased by 100 and 200 mg L−1 CsNPs. Lipid peroxidation and antioxidant capacity increased with increasing CsNP concentrations. The phenolic content increased by 100 mg L−1 CsNPs, whereas the hydrogen peroxide content decreased with increasing CsNP concentrations. In conclusion, CsNPs are an alternative for stimulating tissue growth and differentiation during the in vitro multiplication of sugarcane. Full article
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19 pages, 2790 KiB  
Article
Characterization of Water-Resistant Adhesive Prepared by Cross-Linking Reaction of Oxidized Starch with Lignin
by Chengyuan Liu, Huali Lin, Shichao Zhang, Hisham Essawy, Hongyan Wang, Longxu Wu, Xinyi Chen, Xiaojian Zhou, Antonios N. Papadopoulos, Antonio Pizzi and Ming Cao
Polymers 2025, 17(11), 1545; https://doi.org/10.3390/polym17111545 - 1 Jun 2025
Viewed by 776
Abstract
Wood adhesives play a critical role in the wood processing industry; however, traditional formaldehyde-based adhesives pose health risks and are reliant on non-renewable resources. This study aims to develop a bio-based wood adhesive with excellent water resistance, focusing on environmentally friendly solutions. The [...] Read more.
Wood adhesives play a critical role in the wood processing industry; however, traditional formaldehyde-based adhesives pose health risks and are reliant on non-renewable resources. This study aims to develop a bio-based wood adhesive with excellent water resistance, focusing on environmentally friendly solutions. The synthesis of an oxidized starch-lignin (OSTL) composite adhesive was accomplished by modifying starch via oxidation and subsequent cross-linking with lignin. Ammonium persulfate (APS) was employed for oxidation of starch, introducing aldehyde groups that upgrade its reactivity with lignin. Subsequently, the oxidized starch (OST) was cross-linked with the phenolic rings of lignin, resulting in a strong network structure. The oxidation of starch and its cross-linking mechanism with lignin were investigated using the Fourier transform infrared (FT-IR), proton nuclear magnetic resonance (1H-NMR), and X-ray photoelectron spectroscopy (XPS) techniques, proving the formation of aldehyde and carboxyl groups with subsequent reaction possibilities. The effects of oxidant dosage, oxidation time, and the ratio of starch to lignin on the adhesive properties were systematically studied. The results demonstrated that the OSTL adhesive, prepared under optimized conditions, exhibited outstanding adhesion strength (1.23 MPa in dry state) and water resistance (0.94 MPa after 24 h cold water immersion, 1.04 MPa after 3 h in hot water, and 0.69 MPa after 3 h in boiling water), significantly outperforming conventional wood adhesives in terms of cold water, hot water, and boiling water resistance. In addition, the thermal behavior of the OSTL adhesive was further validated using differential scanning calorimetry (DSC) as well as thermogravimetric analysis (TGA). This study presents new insights and technical support for the development of green, environmentally friendly, and highly water-resistant lignin-based bio-adhesives. Full article
(This article belongs to the Special Issue Advances in Wood and Wood Polymer Composites)
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17 pages, 4513 KiB  
Article
Physicochemical Investigations on Samples Composed of a Mixture of Plant Extracts and Biopolymers in the Broad Context of Further Pharmaceutical Development
by Andreea Roxana Ungureanu, Adina Magdalena Musuc, Emma Adriana Ozon, Mihai Anastasescu, Irina Atkinson, Raul-Augustin Mitran, Adriana Rusu, Emanuela-Alice Luță, Carmen Lidia Chițescu and Cerasela Elena Gîrd
Polymers 2025, 17(11), 1499; https://doi.org/10.3390/polym17111499 - 28 May 2025
Viewed by 457
Abstract
Vegetal sources are a continuous research field and different types of extracts have been obtained over time. The most challenging part is compounding them in a pharmaceutical product. This study aimed to integrate a mixture (EX) of four extracts (SE-Sophorae flos, [...] Read more.
Vegetal sources are a continuous research field and different types of extracts have been obtained over time. The most challenging part is compounding them in a pharmaceutical product. This study aimed to integrate a mixture (EX) of four extracts (SE-Sophorae flos, GE-Ginkgo bilobae folium, ME-Meliloti herba, CE-Calendulae flos) in formulations with polymers (polyhydroxybutyrate, polylactic-co-glycolic acid) and their physicochemical profiling. The resulting samples consist of particle suspensions, which were subjected to Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy analysis. When compared to single-extract formulations spectra, they revealed band changes, depending on the complex interactions. Using X-ray Diffractometry, the partially crystalline phase was highlighted for EX-PLGA, while the others were amorphous. Moreover, Atomic Force Microscopy pointed out the nanoscale particles and the topography of the samples, and the outstanding roughness belonging to EX-PHB-PLGA. A 30 min period of immersion was enough for the formulations to spread on the surface of the compression stockings material (CS) and after drying, it became a polymeric film. TGA analysis was performed, which evaluated the impregnated content: 5.9% CS-EX-PHB, 6.4% CS-EX-PLGA, and 7.5% CS-EX-PHB-PLGA. In conclusion, the extract’s phytochemicals and the interactions established with the polymers or with the other extracts from the mixture have a significant impact on the physicochemical properties of the obtained formulations, which are particularly important in pharmaceutical product development. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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22 pages, 6061 KiB  
Article
Back-Silting Characteristics of Foundation Trench Excavation in an Ultra-Wide Inland Immersed Tunnel and Its Impacts on Slope Stability: A Case Study of the Tanzhou Waterway in Shunde
by Qixian Wu, Maojie Tang, Dan Chang, Jiankun Liu and Xingbang Lu
Buildings 2025, 15(11), 1810; https://doi.org/10.3390/buildings15111810 - 25 May 2025
Viewed by 429
Abstract
During the construction of a large immersed tunnel crossing an ultra-wide inland river, the long drying time after the excavation of the foundation trench and changes in river flow velocity result in the river carrying a large amount of sediment into the foundation [...] Read more.
During the construction of a large immersed tunnel crossing an ultra-wide inland river, the long drying time after the excavation of the foundation trench and changes in river flow velocity result in the river carrying a large amount of sediment into the foundation trench and the slope, increasing installation difficulties and threatening construction safety. This study investigates the back-silting characteristics and their impacts on foundation trench slope stability during an ultra-wide immersed tunnel excavation at LunGui Road in Foshan City, China. Numerical simulations reveal the spatiotemporal distribution patterns of deposited sediments at the trench bottom and side slopes, with distinct behaviors identified between the flood season and dry season. Siltation predominantly occurs at the trench bottom, with deposition thickness decreasing almost linearly from the bottom to the slope crest. Hydroperiod variations considerably influence the spatiotemporal distribution of back-silting. Then, the Morgenstern–Price method was employed to analyze slope stability under varying back-silting and dredging conditions, quantifying the relationship between safety factor and sediment thickness. Furthermore, the evolution of critical failure surfaces and the safety factor under different dredging strategies was systematically examined. The critical values of back-silting thickness corresponding to different dredging slope ratios are provided. The research findings provide valuable insights for formulating engineering strategies for trench excavation of extra-wide immersed tube tunnels in inland waterways. Full article
(This article belongs to the Special Issue Design, Construction and Maintenance of Underground Structures)
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22 pages, 11588 KiB  
Article
Seawater-Activated Mineral Synergy in Sulfoaluminate Cement: Corrosion Resistance Optimization via Orthogonal Design
by Chuanlin Wang, Shupeng Zhou, Qingyou Ou, Junkai Liu and Ming Wu
Materials 2025, 18(11), 2428; https://doi.org/10.3390/ma18112428 - 22 May 2025
Cited by 1 | Viewed by 339
Abstract
Mineral admixtures exhibit significant enhancement effects on the seawater corrosion resistance of sulfoaluminate cement (SAC). This study systematically investigates the influence mechanisms of fly ash (FA), silica fume (SF), and slag powder (SP) on the physicochemical properties of SAC-based materials. Experimental results demonstrate [...] Read more.
Mineral admixtures exhibit significant enhancement effects on the seawater corrosion resistance of sulfoaluminate cement (SAC). This study systematically investigates the influence mechanisms of fly ash (FA), silica fume (SF), and slag powder (SP) on the physicochemical properties of SAC-based materials. Experimental results demonstrate that FA effectively enhances the fluidity of fresh SAC paste while mitigating drying shrinkage. Under standard curing conditions, the compressive strength of SAC mortar decreases with increasing FA content, reaching optimal performance at a 5% replacement level. However, in seawater immersion environments, FA undergoes chemical activation induced by seawater ions, leading to a positive correlation between mortar strength and FA content, with the 10% replacement ratio demonstrating maximum efficacy. SF addition reduces workability but significantly suppresses shrinkage deformation. While exhibiting detrimental effects on flexural strength under standard curing (optimal dosage: 7.5%), a 5.0% SF content manifests superior seawater resistance in marine environments. SP incorporation minimally impacts mortar rheology but exacerbates shrinkage behavior, showing limited improvement in both standard-cured compressive strength and seawater corrosion resistance. Orthogonal experimental analysis reveals that SF exerts the most pronounced influence on SAC mortar fluidity. Both standard curing and seawater immersion conditions indicate FA as the dominant factor affecting mechanical strength parameters. The optimal composite formulation, determined through orthogonal combination testing, achieves peak compressive strength with 5% FA, 5% SF, and 5% SP synergistic incorporation. Full article
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19 pages, 3419 KiB  
Article
Effect of Osmotic Dehydration on Physico-Chemical Characteristics, Bioactive Compounds and Volatiles Profile of Diospyros kaki Subjected to Different Drying Methods
by Cecília Morais Santana Matos, Mônica Silva de Jesus, Augusto de Souza da Silva, Nayjara Carvalho Gualberto, Hannah Caroline Santos Araujo, Rafael Donizete Dutra Sandes, Raquel Anne Ribeiro dos Santos, Maria Terezinha Santos Leite Neta and Narendra Narain
Foods 2025, 14(10), 1727; https://doi.org/10.3390/foods14101727 - 13 May 2025
Viewed by 424
Abstract
The seasonality of Diospyros kaki limits its consumption, making it increasingly necessary to develop products that allow it to be available all year round. Therefore, the aim of this study was to optimize the osmotic dehydration process and to evaluate the changes in [...] Read more.
The seasonality of Diospyros kaki limits its consumption, making it increasingly necessary to develop products that allow it to be available all year round. Therefore, the aim of this study was to optimize the osmotic dehydration process and to evaluate the changes in the physico-chemical, bioactive and volatile composition of persimmon subjected to drying. A central composite rotatable design was used with the independent variables as sucrose concentration (%) and immersion time (min). The desirability function for sucrose solution concentration and immersion time was 29.5% for 60 min for hot air oven drying and 38% for 29 min for freeze drying. The dehydrated fruit treated with osmotic pretreatment showed better responses in the quantification of bioactive compounds and retention of volatile compounds. Compounds such as nonanal and 6-methyl-5-hepten-2-one were identified in all the dehydrated products and the OD had a positive influence on their retention, especially for the lyophilized samples. Thus, it is clear that osmotic pretreatment is an ally in protecting the physico-chemical and chemical characteristics of the fruit when it undergoes a drying process, especially with regard to bioactive and volatile compounds. Full article
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17 pages, 2749 KiB  
Article
Low MXene Loading of Epoxy Composite with Enhanced Hydrothermal Resistance
by Mengke Jing, Shujie Zhang, Sichang Zhang, Mingzhou Li, Fan Chen, Yuchen Ma and Bo Sun
Polymers 2025, 17(9), 1229; https://doi.org/10.3390/polym17091229 - 30 Apr 2025
Viewed by 485
Abstract
This work focuses on the hydrothermal aging of two-dimensional layered Ti3C2Tx (MXene)/epoxy (EP) nanocomposites. MXene/EP composites were successfully prepared by homogeneously dispersing multilayer MXene (m-MXene) and few-layer MXene (f-MXene) into the curing agent, methyl nadic anhydride (MNA). Considering [...] Read more.
This work focuses on the hydrothermal aging of two-dimensional layered Ti3C2Tx (MXene)/epoxy (EP) nanocomposites. MXene/EP composites were successfully prepared by homogeneously dispersing multilayer MXene (m-MXene) and few-layer MXene (f-MXene) into the curing agent, methyl nadic anhydride (MNA). Considering the application, the MXene loading was designed to be 0.1 wt.%. Characterization included the characteristics of MXene, the water absorption behavior of the resin and composite samples, the glass transition temperatures (Tg) in various states, and the tensile strength evolution during aging. The curing behavior of the MXene composites was also discussed to facilitate an understanding of the processability. The results showed that MNA can chemically bond with MXene to obtain a stable suspension. The addition of MXene increased the curing characteristic temperature of the system, but the change in the activation energy of the curing reaction was minimal. The addition of MXene decreased the crosslink density of the epoxy resin, leading to a decrease in the Tg value of the initial samples. After hydrothermal aging, the Tg of pure EP decreased by 46.9 °C, and re-drying the samples did not fully restore the Tg. However, the Tg of the MXene/EP system decreased by only 8.9 °C (m-MXene) and 9.5 °C (f-MXene), respectively, and the Tg values of the samples were fully restored to their pre-aging levels via re-drying. Experiments with immersion at 25 °C and 100 °C showed that the difference in water absorption behavior between the MXene/EP and pure EP systems was minimal. Tensile tests showed that the addition of MXene increased the initial strength of the resin system by 14.7% (m-MXene) and 20.9% (f-MXene). After 400 h of hydrothermal aging, the tensile strength retention of the pure EP samples was 69.1%, while the strength retention of the MXene/EP samples was 85.3% (m-MXene) and 83.0% (f-MXene). The combined results demonstrate that the addition of MXene with a low loading of only 0.1% can effectively improve the hydrothermal resistance of epoxy resins. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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29 pages, 8105 KiB  
Article
UV-C and UV-C/H₂O-Induced Abiotic Degradation of Films of Commercial PBAT/TPS Blends
by K. Gutiérrez-Silva, Antonio J. Capezza, O. Gil-Castell and J. D. Badia-Valiente
Polymers 2025, 17(9), 1173; https://doi.org/10.3390/polym17091173 - 25 Apr 2025
Viewed by 511
Abstract
The environmental impact of conventional plastics has spurred interest in biopolymers as sustainable alternatives, yet their performance under abiotic degradation conditions still remain unclear. This study investigated the effects of ultraviolet C (UV-C) irradiation and its combination with water immersion (UV-C/H2O) [...] Read more.
The environmental impact of conventional plastics has spurred interest in biopolymers as sustainable alternatives, yet their performance under abiotic degradation conditions still remain unclear. This study investigated the effects of ultraviolet C (UV-C) irradiation and its combination with water immersion (UV-C/H2O) on films of commercial poly(butylene adipate-co-terephthalate)-thermoplastic starch (PBAT/TPS) blends. Changes in structural, chemical, morphological, and thermal properties, as well as molar mass, were analyzed. The results showed distinct degradation mechanisms during exposure to UV-C irradiation either in dry or during water-immersion conditions. UV-C irradiation disrupted PBAT ester linkages, inducing photodegradation and chain scission, leading to a more pronounced molar mass decrease compared to that under water immersion, where a more restrained impact on the molar mass was ascribed to diffuse attenuation coefficient of irradiation. Nevertheless, under UV-C/H2O conditions, erosion and disintegration were enhanced by dissolving and leaching of mainly the TPS fraction, creating a porous structure that facilitated the degradation of the film. Blends with higher TPS content exhibited greater susceptibility, with pronounced reductions in PBAT molar mass. In conclusion, exposure of films of PBAT/TPS blends to ultraviolet/water-assisted environments effectively initiated abiotic degradation, in which fragmentation was accentuated by the contribution of water immersion. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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