Search Results (17)

Battery electrical vehicle (BEV) ownership has increased in recent years. There is a general concern over the life cycle of the batteries used in such vehicles. This study provides a comprehensive overview of electric vehicles, encompassing their technical evolution, autonomy, and ownership. The analysis delved into the various types of batteries utilized in these vehicles, examining the composition of their constituent materials and the mechanisms underlying their operation. Additionally, it assessed their performance in terms of energy density storage, recharge capabilities, autonomy, and prospects. A critical evaluation of electric vehicles and their internal combustion engine vehicle (ICEV) counterparts, considering the Life Cycle Assessment (LCA) criterion, was conducted. The LCA criterion encompasses emissions during the entire lifecycle, from the “cradle” to the “tank” (WTT) and the “tank” until the end of its cycle (TTW). The findings of this study indicate that BEVs consistently outperformed ICEVs in terms of greenhouse gas (GHG) emissions in all the sizes of vehicles studied. Full article

The aim of this paper is the study of the storage of hydrogen in the liquid state, LH₂, with a focus on the thermal gains for cylindrical and spherical tank geometries. A given tank volume was assumed; three geometries for such a tank were taken, similar to the most common tanks for LH₂ storage: cylindrical (vertical and horizontal) and spherical. An integrated refrigeration system was considered for LH₂ stored at a temperature around 22 K and at a pressure around 3 bar. Then, the energy expenditure by the refrigeration system to maintain LH₂ in the liquid state was determined and compared with the value of the energy contained in the LH₂, in order to compare such a storage method to other hydrogen storage methods, namely compressed hydrogen, in the gaseous state. The most important conclusion was that spherical tanks had lower thermal gains than tanks with other geometries. Full article

The present work addresses the production of nitrogen oxides in ICEs burning hydrogen mixed with methane. A mathematical model that allows the calculation of nitrogen oxide emissions from such combustion was built; this model uses the extended chemical kinetic mechanism of Zeldovich. Numerical simulations were carried out on the production of NO, varying the following variables: proportion of H₂ to CH₄, the equivalence ratio of the reactant mixture, the compression ratio, and the engine speed. The essential purpose was to assess how NO production is affected by the mentioned variables. The main assumptions were (i) Otto cycle; (ii) instantaneous combustion; (iii) chemical equilibrium reached just at the end of combustion; (iv) the formation of NO only during the expansion stroke of pistons. Results were obtained for various proportions of hydrogen and methane, various equivalence ratios, speeds of rotation, and compression ratios of an engine. In short, the results obtained in the current work show that the lowering of the equivalence ratio leads to a lower concentration of NO; that increasing the compression ratio also lowers the concentration of NO; that NO production occurs until shortly after the beginning of the expansion stroke; and finally, that the NO concentration in the engine exhaust is not very sensitive to the H₂/CH₄ ratio in the fuel mixture. Full article

Hydrogen storage in high-pressure tanks can be performed with different filling strategies. Many studies have been carried out on supplies with increasing pressure rates. The present work aims to carry out CFD numerical simulations, using Ansys Fluent^®, in a type 3 tank of 70 MPa normal working pressure (NWP) using a constant flow rate, to analyze the influence of inlet key parameters such as initial temperature, mass flow rate, and material properties on the evolution of temperature, pressure, and velocity. From the analysis of the results, it was possible to discover linear relationships between the increase in the total equilibrium temperature and the final hydrogen temperature, as well as a linear increasing relationship between inlet and final temperatures when the equilibrium temperature was fixed. Considering fully adiabatic walls resulted in a significant increase in temperature with no predictable pattern. The difference between total and static temperatures found in the inlet tube decreased with the decrease in mass flow rate and subsequently the Mach number. The choice of a polymer for the tank lining led to higher temperatures when compared to an aluminum lining. Full article

Microscale abrasion has been intensively used to study the wear behavior o several hard coatings, enabling the observation of different wear mechanisms. Recently, a study arguing whether the surface texture of the ball could influence the dynamics of abrasive particles throughout the contact was presented. In this work, the influence of the abrasive particles concentration able to change the texture of the ball was studied to understand its influence on the wear modes—rolling or grooving. Thus, tests were carried out using samples with a thin coating of TiN, deposited using the Physical Vapor Deposition (PVD) technique, and AISI 52100 steel balls etched over 60 s to induce a change in their texture and roughness were used. Three abrasive slurries were prepared with black silicon carbide (SiC) particles (average particle size of 4 μm) with different concentrations, 0.25, 0.35, and 0.45 g/cm³. The rotation speed used in the tests was 80 rpm and the normal loads applied in the study were 0.2 N and 0.5 N, and 1 N. After the wear tests, the coated samples and tracks on the surface of the balls were observed by SEM and 3D microscopy to understand the abrasive particle dynamics, evaluating the wear mode transition as well as the function of both applied load and slurry concentration. The tracks in the balls showed particles embedded on their surface. A lower concentration of abrasion was conducted to higher specific wear rate. Moreover, a predominant two-body wear mechanism was induced when the abrasive concentration was increased. There was an increase in the roughness of the scar and the surface of the balls with an increase in the abrasive particles’ concentration. Full article

Abrasive wear is a wear mechanism that results in a loss of material from the interaction of a surface with hard particles. This type of wear is frequently found in the surface of machining tools. Microscale abrasion equipment is often used to characterize the resistance to abrasive wear of a surface. The different parameters able to control micro-abrasion wear tests, such as ball rotation, sliding distance between ball and surface sample, abrasive slurry concentration, normal load acting on the sample, and abrasive flow rate over the sample, have been widely studied. The combination of different variables, including sliding distance, concentration of abrasive particles, their hardness, and size of abrasive particles, promotes the transition between two-body, three-body, or mixed abrasive wear modes. However, the influence of the ball surface on the dragging of abrasive particles, which is reflected in the wear modes, is still poorly studied. One of the variables possible to control and less studied is the influence of the ball surface texture on the dragging of abrasive particles in micro-abrasion wear tests. This work intends to correlate the effect of different testing times (500, 1000, and 1500 cycles) and different concentrations of 3 μm Al₂O₃ abrasive slurry (25, 35, and 45 g/100 mL) on the micro abrasion resistance of a TiN thin coating film, using balls of AISI 52100 steel whose texture and roughness were prepared by 60 s chemical etching. The rotation speed of each test was 80 rpm, applying a normal load of 2 N. Subsequently, the craters were carefully analyzed using SEM to evaluate the transition of the wear mode as a function of the applied load, the abrasive particle concentration, and the sliding distance. The textured ball tracks were observed via SEM to assess the particle dynamics. The results showed that, contrarily to what is reported in the literature regarding wear modes where rolling is promoted with increasing abrasive concentration, in this work grooving took place instead. This is a result of the rough balls use in the experiments which, due to the embedment of abrasive particles in the ball grooves, promotes the abrasion mechanism. The higher the abrasive concentration, the higher the grooving mechanism, since more particles are available to scratch the surface. Full article

Due to their high mechanical property values and corrosion resistance, duplex stainless steels (DSSs) are used for a wide variety of industrial applications. DSSs are also selected for applications that require, especially, high corrosion resistance and overall good mechanical properties, such as in the naval and oil-gas exploration industries. The obtention of components made from these materials is quite problematic, as DSSs are considered difficult-to-machine alloys. In this work, the developed wear during milling of the UNS S32101 DSS alloy is presented, employing four types of milling tools with different geometries and coatings. The influence of feed rate and cutting length variations on the tools’ wear and their performance was evaluated. The used tools had two and four flutes with different coatings: TiAlN, TiAlSiN and AlCrN. The cutting behavior of these tools was analyzed by collecting data regarding the cutting forces developed during machining and evaluating the machined surface quality for each tool. After testing, the tools were submitted to SEM analysis, enabling the identification of the wear mechanisms and quantification of flank wear, as well as identifying the early stages of the development of these mechanisms. A comparison of all the tested tools was made, determining that the TiAlSiN-coated tools produced highly satisfactory results, especially in terms of sustained flank wear. Full article

With the global warming of the planet, new forms of energy are being sought as an alternative to fossil fuels. Currently, hydrogen (H₂) is seen as a strong alternative for fueling vehicles. However, the major challenge in the use of H₂ arises from its physical properties. An earlier study was conducted on the storage of H₂, used as fuel in road vehicles powered by spark ignition engines or stacks of fuel cells stored under high pressure inside small spheres randomly packed in an envelope tank. Additionally, the study evaluated the performance of this new storage system and compared it with other storage systems already applied by automakers in their vehicles. The current study aims to evaluate the H₂ leaks from the same storage system, when inserted in any road vehicle parked in conventional garages, and to show the compliance of these leaks with European Standards, provided that an appropriate choice of materials is made. The system’s compliance with safety standards was proved. Regarding the materials of each component of the storage system, the best option from the pool of materials chosen consists of aluminum for the liner of the spheres and the envelope tank, CFEP for the structural layer of the spheres, and Si for the microchip. Full article

Duplex stainless steels are being used on applications that require high corrosion resistance and excellent mechanical properties, such as the naval and oil-gas exploration industry. The components employed in these industries are usually obtained by machining; however, these alloys have low machinability when compared to conventional stainless steels, usually requiring the employment of tool coatings. In the present work, a comparative study of TiAlSiN coating performance obtained by these two techniques in the milling of duplex stainless-steel alloy LDX 2101 was carried out. These coatings were obtained by the conventional direct current magnetron sputtering (dc MS) and the novel high power impulse magnetron sputtering (HiPIMS). The coatings were analyzed and characterized, determining mechanical properties for both coatings, registering slightly higher mechanical properties for the HiPIMS-obtained coating. Machining tests were performed with varying cutting length and feed-rate, while maintaining constant values for axial and radial depth of cut and cutting speed. The surface roughness of the material after machining was assessed, as well as the wear sustained by each of the tool types, identifying the wear mechanisms and behavior of these tools, as well as registering the flank wear values presented for each of the tested tools. The HiPIMS-obtained coating exhibited a very similar behavior when compared to the other, producing similar surface roughness quality. However, the HiPIMS coating exhibited less wear for higher cutting lengths, proving to be a better choice in this case, especially regarding tool life. Full article

Copper-Beryllium alloys have excellent wear resistance and high mechanical properties, they also possess good electrical and thermal conductivity, making these alloys very popular in a wide variety of industries, such as aerospace, in the fabrication of tools for hazardous environments and to produce injection molds and mold inserts. However, there are some problems in the processing of these alloys, particularly when these are subject to machining processes, causing tools to deteriorate quite rapidly, due to material adhesion to the tool’s surface, caused by the material’s ductile nature. An assessment of tool-wear after machining Cu-Be alloy AMPCOLOY 83 using coated and uncoated tools was performed, offering a comparison of the machining performance and wear behavior of solid-carbide uncoated and DLC/CrN multilayered coated end-mills with the same geometry. Multiple machining tests were conducted, varying the values for feed and cutting length. In the initial tests, cutting force values were registered. The material’s surface roughness was also evaluated and the cutting tools’ edges were subsequently analyzed, identifying the main wear mechanisms and how these developed during machining. The coated tools exhibited a better performance for shorter cutting lengths, producing a lower degree of roughness on the surface on the machined material. The wear registered for these tools was less intense than that of uncoated tools, which suffered more adhesive and abrasive damage. However, it was observed that, for greater cutting lengths, the uncoated tool performed better in terms of surface roughness and sustained wear. Full article

The automotive industry is a pioneer in solutions that meet market expectations. However, in the automotive industry, some less environmentally friendly technologies are still used, such as electroplating. Due to legislative restrictions in several countries, thin coatings made in a vacuum have been replacing coatings traditionally made by electroplating, mainly in decorative terms. This work is more focused on the use of these coatings made in vacuum for optical applications, namely on headlights and exterior backlit components. Although these components are protected during the period of use, there may be situations of contact during the assembly of the components or their repair, necessary to safeguard and to ensure that these coatings have the scratch and wear resistance needed to withstand any treatment deficiency during the operations referred to above. Therefore, this work is essentially focused on the study of the wear resistance of Cr coatings made by PVD (Physical Vapour Deposition) on polymeric substrates. To this end, the coatings previously studied have now been subjected to micro-abrasion tests, with a view to assessing their wear resistance. For this purpose, alumina abrasive has been used, and the wear mechanisms observed in the coatings were studied. The abrasion and scratch tests showed that the most stable film has the one provided with 10-layers, showing greater wear resistance as well, greater adhesion to the substrate and less cohesive failures in the performed tests. Given the nature of the substrate and the coating, the results obtained are very promising, showing that these 10-layer Cr thin coatings can overcome any careless operation during manufacturing, assembly and repair processes, when applied in lightning or backlit components in motor vehicles. Full article

The machining process is still a very relevant process in today’s industry, being used to produce high quality parts for multiple industry sectors. The machining processes are heavily researched, with the focus on the improvement of these processes. One of these process improvements was the creation and implementation of tool coatings in various machining operations. These coatings improved overall process productivity and tool-life, with new coatings being developed for various machining applications. TiAlN coatings are still very present in today’s industry, being used due to its incredible wear behavior at high machining speeds, high mechanical properties, having a high-thermal stability and high corrosion resistance even at high machining temperatures. Novel TiAlN-based coatings doped with Ru, Mo and Ta are currently under investigation, as they show tremendous potential in terms of mechanical properties and wear behavior improvement. With the improvement of deposition technology, recent research seems to focus primarily on the study of nanolayered and nanocomposite TiAlN-based coatings, as the thinner layers improve drastically these coating’s beneficial properties for machining applications. In this review, the recent developments of TiAlN-based coatings are going to be presented, analyzed and their mechanical properties and cutting behavior for the turning and milling processes are compared. Full article

Micro-abrasion remains a test configuration hugely used, mainly for thin coatings. Several studies have been carried out investigating the parameters around this configuration. Recently, a new study was launched studying the behavior of different ball materials in abrasive particles’ dynamics in the contact area. This study intends to extend that study, investigating new ball materials never used so far in this test configuration. Thus, commercial balls of American Iron and Steel Institute (AISI) 52100 steel, Stainless Steel (SS) (AISI) 304 steel and Polytetrafluoroethylene (PTFE) were used under different test conditions and abrasive particles, using always the same coating for reference. Craters generated on the coated samples’ surface and tracks on the balls’ surface were carefully observed by Scanning Electron Microscopy (SEM) and 3D microscopy in order to understand the abrasive particles’ dynamics. As a softer material, more abrasive particles were entrapped on the PTFE ball’s surface, generating grooving wear on the samples. SS AISI 304 balls, being softer than the abrasive particles (diamond), also allowed particle entrapment, originating from grooving wear. AISI 52100 steel balls presented particle dynamics that are already known. Thus, this study extends the knowledge already existing, allowing to better select the ball material to be used in ball-cratering tests. Full article

Water is an important resource for human beings, yet there are inhabited places tormented by the scarcity of it. The present study is concerned with places where, seemingly, the best way to get water is through solar distillers. These places should have, typically, high values of solar irradiation and a lack of human and economic resources to build and operate complex equipment. A set of sites scattered around the world was chosen, and then the presumed productivity and thermal efficiency that solar distillers would have if they were installed at these places was calculated. The mathematical model used with this purpose assumes steady state operation; the values of mass of water distilled and distiller efficiency were calculated for every hour, but the results presented are annual averages. Then, an economic study was made based on local costs of construction materials for the distillers, the work force, and the prices of water to predict the payback time of solar distillers. Finally, a study on environmental impact, particularly in terms of greenhouse gas (GHG) emissions, was made to compare reverse osmosis (RO) with solar distillation. For the sites studied, typical values of annual water output are in the range of 414 dm³/m², for Évora, up to 696 dm³/m², for Faya Largeau; the minimum efficiency was found for Évora, as 11.5%, and the maximum efficiency was found for Tessalit, as 15.2%. Payback times are very high, regardless of the areas of the globe where solar distillers are implanted. Regarding the GHG emissions, solar distillation is preferable to RO. Full article

The use of hydrogen as an alternative to fossil fuels for vehicle propulsion is already a reality. However, due to its physical characteristics, storage is still a challenge. There is an innovative way, presented in this study, to store hydrogen in conventional vehicles propelled by spark-ignition reciprocating engines and fuel cells, using hydrogen as fuel; the storage of hydrogen will be at high pressure within small spheres randomly packed in a tank, like the conventional tank of fuel used nowadays in current vehicles. Therefore, the main purpose of the present study is to assess the performance of this storage system and compare it to others already applied by car manufacturers in their cars. In order to evaluate the performance of this storage system, some parameters were taken into account: The energy stored by volume and stored by weight, hydrogen leakage, and compliance with current standards. This system is safer than conventional storage systems since hydrogen is stored inside small spheres containing small amounts of hydrogen. Besides, its gravimetric energy density (GED) is threefold and the volumetric energy density (VED) is about half when compared with homologous values for conventional systems, and both exceed the targets set by the U.S. Department of Energy. Regarding the leakage of hydrogen, it complies with the European Standards, provided a suitable choice of materials and dimensions is made. Full article