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Interfacial Engineering Solutions for Enhanced Degradation of Toxic Contaminants in Water Systems

A special issue of Water (ISSN 2073-4441). This special issue belongs to the section "Wastewater Treatment and Reuse".

Deadline for manuscript submissions: 20 October 2025 | Viewed by 365

Special Issue Editor

School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
Interests: electrochemistry; microbiology; environmental engineering; function materials; advanced oxidation processes
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

The persistence of toxic contaminants in aquatic systems—including industrial effluents (e.g., nitrogenous heterocyclic compounds, dyes, PFAS), microplastics, pharmaceuticals (e.g., antibiotics), and agricultural runoff (e.g., pesticides)—demands innovative interfacial engineering strategies to overcome inefficiencies in conventional remediation. This Special Issue highlights interface design to govern contaminant degradation pathways through tailored interactions at functional surfaces. Key themes include the following:

  1. Selective Adsorption/Degradation: Nanostructured interfaces (e.g., MOFs, MXene composites) for targeting heavy metals, PFAS, and endocrine disruptors;
  2. Dynamic Interfacial Behavior: Mechanisms under real-water conditions (high salinity, multi-contaminant coexistence);
  3. Reaction Efficiency: Advanced oxidation processes (persulfate activation and photocatalytic H2O2 generation) via charge-engineered catalysts;
  4. Anti-Fouling Systems: Self-cleaning membranes (e.g., TiO2-coated ceramics) for sustainable water treatment;
  5. Biohybrid Interfaces: Biocompatible materials enhancing biofilm–catalyst synergy for biodegradation.

We welcome studies on scalable applications, such as electrocatalytic reactors for landfill leachate, solar-driven evaporators for desalination, and 3D-printed scaffolds for microplastic removal. Submissions integrating operando characterization, AI-driven optimization, or lifecycle analysis are encouraged.

Dr. Dan Chen
Guest Editor

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • toxic contaminants
  • interface engineering
  • contaminant sequestration
  • advanced oxidation processes
  • biofilm–electrode interfaces
  • catalytic activation kinetics
  • biocompatible materials
  • anti-fouling interfaces

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Published Papers (1 paper)

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Research

15 pages, 4806 KiB  
Article
Enhanced Electrocatalytic Degradation of Phenol by Mn-MIL-100-Derived Carbon Materials
by Xueping Sun, Haitao Liu, Dan Chen, Ya Zhang, Xinbai Jiang and Jinyou Shen
Water 2025, 17(7), 1103; https://doi.org/10.3390/w17071103 - 7 Apr 2025
Viewed by 267
Abstract
To achieve high electrooxidation efficiency for phenol, this study explored the fabrication of Mn-MIL-100 catalysts at various calcination temperatures, loaded onto a carbon paper (CP) anode. The materials were characterized using scanning electron micros-copy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and X-ray diffraction. Their [...] Read more.
To achieve high electrooxidation efficiency for phenol, this study explored the fabrication of Mn-MIL-100 catalysts at various calcination temperatures, loaded onto a carbon paper (CP) anode. The materials were characterized using scanning electron micros-copy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and X-ray diffraction. Their electrocatalytic activities under various calcination temperatures were evaluated through cyclic voltammetry (CV) tests, while the effect of pH in the Mn-MOF modified CP electrodes on phenol degradation performance was investigated using the potentiostatic discharge method. Mn-MOF@CP calcined at 400 °C and 500 °C (denoted as Mn400@CP and Mn500@CP, respectively) exhibited significantly enhanced cyclic voltammetry current responses in phenol solution, attributed to an increase in oxygen vacancy concentration. A phenol degradation efficiency of 96.00 ± 1.53% was achieved by Mn400@CP within 16 h, while it was only 60.12 ± 2.03% for Mn500@CP and 8.01 ± 2.00% for the blank CP at pH 4. Additionally, Mn400@CP consistently demonstrated superior phenol degradation efficiency over Mn500@CP across various pH values. The outstanding electrocatalytic activity of Mn400@CP for phenol oxidation could be attributed to its lower charge transfer resistance. A radical-mediated oxidation pathway was proposed for the Mn400@CP electrocatalytic system, elucidating its phenol degradation mechanism. These findings highlighted the potential of Mn-MOF-derived carbon-based materials for the degradation of organic contaminants. Full article
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