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Optical Spectroscopic Sensors Based on Mid-Infrared Semiconductor Lasers

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Optical Sensors".

Deadline for manuscript submissions: closed (30 September 2020) | Viewed by 5436

Special Issue Editor


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Guest Editor
CNR-INO – Istituto Nazionale di Ottica, Largo E. Fermi 6, 50125 Firenze, FI, Italy
Interests: optical sensors; mid-infrared sources; quantum cascade lasers; interband cascade lasers; optical frequency combs; laser noise characterization and stabilization; high-sensitivity molecular spectroscopy; frequency metrology

Special Issue Information

Dear Colleagues,

The global challenges that characterize our time, from climate change modelling to pollution control, biomedical, and homeland security applications, are pushing towards the development of increasingly sensitive, accurate, and robust instrumentation able to detect tiny amounts of specific molecules in gaseous or liquid samples.

The mid-infrared region represents a first choice for the high-sensitivity detection of many simple molecules of environmental interest, since their fundamental ro-vibrational transitions lay there. This region is characterized by strong absorption even by organic compounds, which are of great interest for medicine and biology and many other scientific and technological branches.

During the past decade, advances in semiconductor laser manufacturing opened new doors for the development of robust and compact apparatuses for trace gas sensing in the mid-infrared. Over the years, quantum cascade lasers have become increasingly widespread, easier to find on the market, and with better performance in terms of threshold current, emitted power, tuning range, and stability. Novel comb-emitting devices have been demonstrated and started to be utilized and commercialized, opening the doors, for example, to fast multispecies detection with dual-comb techniques. At the same time, alternative devices like interband cascade lasers have become commercially available and are now being used in spectroscopy, demonstrating their potential thanks to their lower dissipation, interesting narrow linewidth, and possibility of operating at lower wavelengths in the 3–4 µm region. Finally, research is also pursuing the development of other semiconductor devices working in the 2.5–4 µm range, like VECSEL, with results that suggest interesting development prospects. 

Optical sensors characterized by record sensitivity and high selectivity have been reported based on almost all these sources, exploiting a variety of spectroscopic techniques. This Special Issue is dedicated to state-of-the-art optical sensors based such sources, QCLs and ICLs and other semiconductor lasers, working in the mid-infrared. Particular interest will be given to comb-based spectroscopies with QCLs and ICLs, as well as to the progress in the development of such innovative sources. Special attention will also be paid to recent progress in portable sensors, based on techniques as varied as photoacoustic and photothermal spectroscopy, cavity ring-down spectroscopy, frequency or amplitude modulation spectroscopy, techniques based on enhancement cavities or multipass cells, and so on. Contributions reporting emerging photonic technologies for mid-infrared sensors will find their place in this Issue, with particular attention paid to novel and improved sources, comb-emitting semiconductor lasers, novel and improved detectors, and innovative tools (optical resonators, electro-optic devices, waveguides) for the mid-infrared.

Dr. Simone Borri
Guest Editor

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Keywords

  • mid-IR spectroscopic techniques
  • mid-IR semiconductor lasers
  • QCL and ICL optical frequency combs
  • portable optical sensors
  • mid-IR waveguides
  • mid-IR detectors
  • dual comb spectroscopy
  • emerging mid-IR materials and technology

Published Papers (2 papers)

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15 pages, 4009 KiB  
Article
Widely-Tunable Quantum Cascade-Based Sources for the Development of Optical Gas Sensors
by Virginie Zéninari, Raphaël Vallon, Laurent Bizet, Clément Jacquemin, Guillaume Aoust, Grégory Maisons, Mathieu Carras and Bertrand Parvitte
Sensors 2020, 20(22), 6650; https://doi.org/10.3390/s20226650 - 20 Nov 2020
Cited by 5 | Viewed by 2793
Abstract
Spectroscopic techniques based on Distributed FeedBack (DFB) Quantum Cascade Lasers (QCL) provide good results for gas detection in the mid-infrared region in terms of sensibility and selectivity. The main limitation is the QCL relatively low tuning range (~10 cm−1) that prevents [...] Read more.
Spectroscopic techniques based on Distributed FeedBack (DFB) Quantum Cascade Lasers (QCL) provide good results for gas detection in the mid-infrared region in terms of sensibility and selectivity. The main limitation is the QCL relatively low tuning range (~10 cm−1) that prevents from monitoring complex species with broad absorption spectra in the infrared region or performing multi-gas sensing. To obtain a wider tuning range, the first solution presented in this paper consists of the use of a DFB QCL array. Tuning ranges from 1335 to 1387 cm−1 and from 2190 to 2220 cm−1 have been demonstrated. A more common technique that will be presented in a second part is to implement a Fabry–Perot QCL chip in an external-cavity (EC) system so that the laser could be tuned on its whole gain curve. The use of an EC system also allows to perform Intra-Cavity Laser Absorption Spectroscopy, where the gas sample is placed within the laser resonator. Moreover, a technique only using the QCL compliance voltage technique can be used to retrieve the spectrum of the gas inside the cavity, thus no detector outside the cavity is needed. Finally, a specific scheme using an EC coherent QCL array can be developed. All these widely-tunable Quantum Cascade-based sources can be used to demonstrate the development of optical gas sensors. Full article
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9 pages, 2575 KiB  
Letter
Theoretical and Experimental Study of Heterodyne Phase-Sensitive Dispersion Spectroscopy with an Injection-Current-Modulated Quantum Cascade Laser
by Zhen Wang, Kin-Pang Cheong, Mingsheng Li, Qiang Wang and Wei Ren
Sensors 2020, 20(21), 6176; https://doi.org/10.3390/s20216176 - 29 Oct 2020
Cited by 6 | Viewed by 2199
Abstract
We report the theoretical and experimental study of calibration-free heterodyne phase-sensitive dispersion spectroscopy (HPSDS) in the mid-infrared using a direct current modulated mid-infrared quantum cascade laser (QCL). The modulation of QCL current at several hundred MHz or higher generates the synchronous frequency and [...] Read more.
We report the theoretical and experimental study of calibration-free heterodyne phase-sensitive dispersion spectroscopy (HPSDS) in the mid-infrared using a direct current modulated mid-infrared quantum cascade laser (QCL). The modulation of QCL current at several hundred MHz or higher generates the synchronous frequency and intensity modulation of the QCL emission. An analytical model of the phase of the beat note signal in HPSDS is derived by considering the absorption and dispersion processes and incorporating the QCL modulation parameters. In the experiment, a 4.5 μm QCL modulated at 350 MHz was used to measure N2O at 200 Torr in a 10 cm gas cell. The N2O concentrations inferred from the analytical model were compared with the nominal values to show good agreement over the concentration range of 189−805 ppm with a standard deviation <3%. When the QCL wavelength was locked at the line-center of the molecular transition, it was of interest to find that the theoretical model was simplified to that used for near-infrared HPSDS with an electro-optical modulator for laser modulation. Full article
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