Advanced Metal Gels: Synthesis and Applications

A special issue of Gels (ISSN 2310-2861). This special issue belongs to the section "Gel Processing and Engineering".

Deadline for manuscript submissions: 15 September 2025 | Viewed by 1664

Special Issue Editors


E-Mail Website
Guest Editor
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325000, China
Interests: metal gels; carbon gels; carbon nanotubes; nanoscience; electrocatalysis; carbon materials

E-Mail Website
Guest Editor
School of Materials Science & Engineering, Beijing Institute of Technoogy, Beijing 100081, China
Interests: metal aerogels; hydrogels; nanoscience; electrocatalysis; smart materials
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

With the attributes of abundant compositions and modulable electronic properties, metals have been widely used since ancient times. The amazing properties unlocked through nanotechnology further stimulate the deep investigation of metals. However, it was not until this century that metal gels—gels entirely structured from nanosized metals—were created. This discovery enables macroscopic metal gels to display unique properties enhanced by nano-effects, greatly broadening the fundamental and industrial investigation of metals.

In the past 15 years, metal gels have been widely studied, from their controlled synthesis to their practical applications. Featuring customizable building blocks, an interconnected porous structure, and unique optical and mechanical properties, wet metal gels and aerogels have been designed for diverse use such as catalysis, sensing, actuators, substrates for surface-enhanced Raman scattering, and so forth. Their enhanced performance and multivarious functions are further expanded by combining metal gels with other exotic materials, such as commercial foams.

Nevertheless, as a class of emerging materials, metal gels remain underdeveloped. Arbitrary material control is still challenging, and killer applications for both metal aerogels and wet gels have yet to be discovered. Hence, this Special Issue expects to collect both original research and reviews that reflect recent advances (experimental and theoretical) or provide new perspectives in terms of developing the synthesis and applications of metal-based aerogels and wet gels. Submissions are welcome (but not limited) areas such as:

  • The design and synthesis of metal aerogels or wet gels;
  • The design and synthesis of metal gel-based porous composites;
  • Theoretical prediction and simulation of the formation process of metal gel-based materials;
  • Applying metal gels in various applications.

Prof. Dr. Yue Hu
Prof. Dr. Ran Du
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Gels is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2100 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • aerogels
  • gels
  • metal aerogels
  • porous materials
  • nanostructures
  • catalysis
  • sensing
  • actuators
  • smart materials

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.

Further information on MDPI's Special Issue policies can be found here.

Published Papers (2 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

16 pages, 4549 KiB  
Article
Revealing the Importance of Iron Aerogel Features as Electrocatalysts for the Oxygen Reduction Reaction
by Judith González-Lavín, Ana Arenillas and Natalia Rey-Raap
Gels 2025, 11(3), 154; https://doi.org/10.3390/gels11030154 - 20 Feb 2025
Viewed by 474
Abstract
Metal nanoparticles supported in carbon materials are the traditional electrocatalyst currently used in many applications. However, these composite materials have many problems associated with the optimization of both components for the specific application, besides the stability of the mixture. Self-supported metallic materials may [...] Read more.
Metal nanoparticles supported in carbon materials are the traditional electrocatalyst currently used in many applications. However, these composite materials have many problems associated with the optimization of both components for the specific application, besides the stability of the mixture. Self-supported metallic materials may be an interesting strategy in order to avoid the traditional carbon supports; however, these metallic materials should present highly active surface area. Iron aerogels are presented in this work as effective and affordable unsupported electrocatalysts. The combination of their metallic structure with high porosity (i.e., 85 m2 g−1 and 0.45 cm3 g−1 of mesopore volume), due to their interconnected tridimensional structure, leads to a great activity versus the oxygen reduction reaction. A method for producing iron aerogels based on microwave-assisted sol–gel methodology is presented. The incorporation of carbon functionalities to the iron aerogels seems to clearly influence the mechanism of the reaction, favoring the direct mechanism of the oxygen reduction reaction and thus notably improving the performance of the electrocatalysts. Chemical vapor deposition seems to be an adequate methodology for incorporating carbon functionalities to the transition metal structure without affecting the tridimensional network and leading to current densities over 4 mA cm−2 and great stability even after 10,000 s. Full article
(This article belongs to the Special Issue Advanced Metal Gels: Synthesis and Applications)
Show Figures

Figure 1

13 pages, 5055 KiB  
Article
Band-Gap Engineering of High-Entropy Fluorite Metal Oxide Nanoparticles Facilitated by Pr3+ Incorporation by Gel Combustion Synthesis
by Mariappan Anandkumar, Kannan Pidugu Kesavan, Shanmugavel Sudarsan, Olga Vladimirovna Zaitseva, Ahmad Ostovari Moghaddam, Daria Valerevna Iarushina and Evgeny Alekseevich Trofimov
Gels 2025, 11(2), 117; https://doi.org/10.3390/gels11020117 - 6 Feb 2025
Viewed by 756
Abstract
Tailoring the bandgap of a material is necessary for improving its optical properties. Here, the optical bandgap of high-entropy oxide Ce0.2Gd0.2Sm0.2Y0.2Zr0.2O2-δ (HEO) nanoparticles was modified using Pr3+. Various concentrations of [...] Read more.
Tailoring the bandgap of a material is necessary for improving its optical properties. Here, the optical bandgap of high-entropy oxide Ce0.2Gd0.2Sm0.2Y0.2Zr0.2O2-δ (HEO) nanoparticles was modified using Pr3+. Various concentrations of Pr3+ (x = 0, 0.01, 0.02, 0.05, 0.075, 0.1, 0.15) were incorporated into the host high-entropy oxide using a gel combustion synthesis. After the gel combustion step, the powders were heat-treated at various temperatures (650 °C, 800 °C, 950 °C) for 2 h. The obtained Pr3+-incorporated HEO powders were characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and UV–visible spectroscopy. The results indicate that, when the samples are calcined at 950 °C, a single-phase cubic fluorite structure is obtained without any phase separation or impurity. The optical absorbance red-shifts to higher wavelengths when the concentration of Pr3+ is increased. This reduces the bandgap of the material from 3.15 eV to 1.87 eV for Pr3+ concentrations of x = 0 (HEO-0) and x = 0.15 (HEO-6), respectively. The obtained HEOs can be suitable candidates for photocatalytic applications due to their absorbance in the visible region. Full article
(This article belongs to the Special Issue Advanced Metal Gels: Synthesis and Applications)
Show Figures

Figure 1

Back to TopTop